Cyclization reactions:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Boca Raton u.a.
CRC Press
1994
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| Schriftenreihe: | New directions in organic and biological chemistry
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 370 S. graph. Darst. |
| ISBN: | 0849378613 |
Internformat
MARC
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Datensatz im Suchindex
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| adam_text | CYCLIZATION REACTIONS C. THEBTARANONTH PROFESSOR DEPARTMENT OF CHEMISTRY
MAHIDOL UNIVERSITY BANGKOK, THAILAND Y. THEBTARANONTH PROFESSOR
DEPARTMENT OF CHEMISTRY MAHIDOL UNIVERSITY BANGKOK, THAILAND & ) CRC
PRESS BOCA RATON ANN ARBOR LONDON TOKYO TABLE OF CONTENTS CHAPTER 1
CYCLIZATION REACTIONS 1 CHAPTER 2 CATIONIC CYCLIZATION I. INTRODUCTION 5
II. CYCLIZATION OF CARBOCATIONS 6 III. CYCLIZATION OF IMINIUM IONS 17 A.
CYCLIZATION OF IMINIUM IONS BY INTERNAL NUCLEOPHILES 17 B. CYCLIZATION
OF IMINIUM IONS INITIATED BY EXTERNAL NUCLEOPHILES 23 C.
REARRANGEMENT-CYCLIZATION OF IMINIUM IONS 28 D. IMINIUM LON-INITIATED
MULTIPLE CYCLIZATION OF UNACTIVATED POLYENES 35 IV. CYCLIZATION OF
OXONIUM AND THIONIUM IONS 38 A. CYCLIZATION OF OXONIUM IONS 38 B.
CYCLIZATION OF THIONIUM IONS 46 V. CYCLIZATION OF VINYL-, ALLYL-,
PROPARGYL- AND AUENYLSILANES 50 A. CYCLIZATION OF VINYLSILANES 50 B.
CYCLIZATION OF ALLYLSILANES 55 C. CYCLIZATION OF PROPARGYL- AND
AUENYLSILANES 63 VI. CONCLUSION 69 REFERENCES 69 CHAPTER 3 RADICAL
CYCLIZATION I. INTRODUCTION 77 II. CYCLIZATION TO UNACTIVATED ALKENES
AND ALKYNES 77 A. ALKYL RADICALS 78 B. VINYL AND ARYL RADICALS 90 C.
ACYL, THIOACYL, IMIDOYL AND IMINYL RADICALS 96 III. CYCLIZATION TO
ACTIVATED OLEFINS AND CARBONYL FUNCTIONS 103 A. CYCLIZATION TO ACTIVATED
OLEFINS 103 B. CYCLIZATION TO CARBONYL FUNCTIONS 115 IV. TANDEM
CYCLIZATION 120 A. TANDEM CYCLIZATION AD HB 121 B. TANDEM CYCLIZATION TO
FORM TRIQUINANE SKELETONS 129 V. CYCLIZATION INVOLVING ATOM OR GROUP
TRANSFER, RADICAL TRANSLOCATION, REARRANGEMENT, OR FRAGMENTATION
PROCESSES 134 A. CYCLIZATION INVOLVING ATOM OR GROUP TRANSFER 134 B.
CYCLIZATION INVOLVING RADICAL TRANSLOCATION 138 C. CYCLIZATION INVOLVING
RADICAL REARRANGEMENT 145 D. CYCLIZATION INVOLVING RADICAL FRAGMENTATION
151 VI. CONCLUSION 157 REFERENCES 158 CHAPTER 4 ANIONIC CYCLIZATION I.
INTRODUCTION 169 IL CYCLIZATION VIA SJV 2 AND S/V T DISPLACEMENTS 169
III. CYCLIZATION VIA ADDITION TO CARBONYL, IMINE, IMINIUM, OXONIUM AND
THIONIUM FUNCTIONS 182 A. ADDITION TO CARBONYL FUNCTIONS 182 B. ADDITION
TO IMINE, IMINIUM, OXONIUM AND THIONIUM FUNCTIONS 194 IV. CYCLIZATION
VIA CONJUGATE ADDITION 199 A. THE DIRECT MICHAEL ADDITION 199 B.
MICHAEL-INITIATED RING CLOSURE (MIRC) 203 1. TANDEM MICHAEL ADDITION-S W
2 DISPLACEMENT 205 2. TANDEM MICHAEL ADDITION-AIDOL CONDENSATION 206 3.
TANDEM MICHAEL ADDITION-DIECKMANN CONDENSATION ..208 4. MULTIPLE MICHAEL
ADDITIONS 212 5. MICHAEL-INITIATED CYCLOPROPANATION 221 V. CYCLIZATION
OF ALLYLSILANES AND ALLYLSTANNANES 225 VI. CYCLIZATION INVOLVING
ADDITION TO UNACTIVATED OLEFINIC BONDS 232 VII. CONCLUSION 241
REFERENCES 242 CHAPTER 5 METAL-CATALYZED CYCLIZATION I. INTRODUCTION 255
IL PALLADIUM-CATALYZED CYCLIZATION 255 A. THE HECK AND RELATED REACTIONS
256 B. CYCLIZATION INVOLVING 7T-ALLYL METAL COMPLEXES 271 C. THE STILLE
REACTION 279 III. METAL-CATALYZED CARBONYLATIVE CYCLIZATION 282 A.
CARBONYLATIVE CYCLIZATION RELATED TO PALLADIUM-CATALYZED CYCLIZATION 283
B. THE PAUSON-KHAND AND RELATED REACTIONS 289 IV. METAL-CATALYZED
CARBON-HETEROATOM BOND FORMATION 298 A. PALLADIUM-CATALYZED
CARBON-HETEROATOM BOND FORMATION ....298 B. SILVER AND MERCURY
SALT-CATALYZED CARBON-HETEROATOM BOND FORMATION 303 V. SAMARIUM(II)
IODIDE-CATALYZED CYCLIZATION 312 VI. CONCLUSION 320 REFERENCES 321
CHAPTER 6 MISCELLANEOUS CYCLIZATIONS I. INTRODUCTION 331 II.
MACROLACTONIZATION 331 A. THE COREY-NICOLAOU METHOD 331 B. THE MASUMUNE
METHOD 332 C. THE MUKAIYAMA METHOD 332 D. THE YAMAGUCHI METHOD 332 E.
THE MITSUNOBU METHOD 333 F. THE STEGLICH AND KECK METHOD 333 III.
VICINAL TRICARBONYL CYCLIZATION 337 A. CYCLIZATION INVOLVING THE VICINAL
TRICARBONYL SYSTEM 338 B. CYCLIZATION INVOLVING THE VINYL TRICARBONYL
SYSTEM 342 IV. CYCLIZATION OF ENEDIYNES AND RELATED SYSTEMS 346 A. THE
BERGMAN CYCLIZATION AND RELATED REACTIONS 347 B. CYCLIZATION OF
CALICHEAMICINS, ESPERAMICINS, DYNEMICINS AND NEOCARZINOSTATIN
CHROMOPHORE 354 V. FINAL REMARKS 358 REFERENCES 358 INDEX 365
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| id | DE-604.BV008874966 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:26:27Z |
| institution | BVB |
| isbn | 0849378613 |
| language | English |
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| physical | 370 S. graph. Darst. |
| publishDate | 1994 |
| publishDateSearch | 1994 |
| publishDateSort | 1994 |
| publisher | CRC Press |
| record_format | marc |
| series2 | New directions in organic and biological chemistry |
| spelling | Thebtaranonth, Chachanat Verfasser aut Cyclization reactions C. Thebtaranonth ; Y. Thebtaranonth Boca Raton u.a. CRC Press 1994 370 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier New directions in organic and biological chemistry Cyclisation (chimie) ram Ring formation (Chemistry) Cyclische Verbindungen (DE-588)4140612-6 gnd rswk-swf Cyclisation (DE-588)4127354-0 gnd rswk-swf Organische Synthese (DE-588)4075695-6 gnd rswk-swf Cyclische Verbindungen (DE-588)4140612-6 s Organische Synthese (DE-588)4075695-6 s Cyclisation (DE-588)4127354-0 s DE-604 Thebtaranonth, Yodhathai Verfasser aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005869841&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Thebtaranonth, Chachanat Thebtaranonth, Yodhathai Cyclization reactions Cyclisation (chimie) ram Ring formation (Chemistry) Cyclische Verbindungen (DE-588)4140612-6 gnd Cyclisation (DE-588)4127354-0 gnd Organische Synthese (DE-588)4075695-6 gnd |
| subject_GND | (DE-588)4140612-6 (DE-588)4127354-0 (DE-588)4075695-6 |
| title | Cyclization reactions |
| title_auth | Cyclization reactions |
| title_exact_search | Cyclization reactions |
| title_full | Cyclization reactions C. Thebtaranonth ; Y. Thebtaranonth |
| title_fullStr | Cyclization reactions C. Thebtaranonth ; Y. Thebtaranonth |
| title_full_unstemmed | Cyclization reactions C. Thebtaranonth ; Y. Thebtaranonth |
| title_short | Cyclization reactions |
| title_sort | cyclization reactions |
| topic | Cyclisation (chimie) ram Ring formation (Chemistry) Cyclische Verbindungen (DE-588)4140612-6 gnd Cyclisation (DE-588)4127354-0 gnd Organische Synthese (DE-588)4075695-6 gnd |
| topic_facet | Cyclisation (chimie) Ring formation (Chemistry) Cyclische Verbindungen Cyclisation Organische Synthese |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005869841&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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