Handbook of cyclization reactions:
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| Sprache: | English |
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| ISBN: | 9783527320882 |
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CONTENTS CONTENTS TO VOLUME 2 XV PREFECE XVU LIST OF CONTRIBUTORS TO
VOLUME 1 XIX 1 ASYMMETRIE CATALYSIS OF DIELS-ALDER REACTION 1 HAIFENG DU
AND KUILING DING 1.1 INTRODUCTION 1 1.2 ASYMMETRIE DIELS-ALDER REACTION
2 1.2.1 LEWIS ACID CATALYZED ASYMMETRIE DIELS-ALDER REACTION 2 1.2.1.1
CHIRAL BORON, ALUMINUM, AND INDIUM COMPLEXES 2 1.2.1.2 CHIRAL COPPER,
MAGNESIUM, AND ZINC COMPLEXES 7 1.2.1.3 CHIRAL TRANSITION METAL
COMPLEXES 10 1.2.1.4 CHIRAL RARE EARTH METAL COMPLEXES 12 1.2.2
ORGANOCATALYSIS OF ASYMMETRIE DIELS-ALDER REACTION 14 1.2.2.1 CHIRAL
SECONDARY AMINE CATALYZED ASYMMETRIE DIELS-ALDER REACTION 14 1.2.2.2
CHIRAL PRIMARY AMINE CATALYZED ASYMMETRIE DIELS-ALDER REACTION 1 6
1.2.2.3 BRANSTED ACID CATALYZED ASYMMETRIE DIELS-ALDER REACTION 17
1.2.2.4 BIFUNCTIONAL ORGANOCATALYSIS OF ASYMMETRIE DIELS-ALDER REACTION
VIA HYDROGEN BONDING 19 1.3 ASYMMETRIE OXA-DIELS-ALDER REACTION 21 1.3.1
LEWIS ACID CATALYZED ASYMMETRIE OXA-DIELS-ALDER REACTION 21 1.3.1.1
CHIRAL ALUMINUM, BORON, AND INDIUM COMPLEXES 21 BIBLIOGRAFISCHE
INFORMATIONEN HTTP://D-NB.INFO/994010451 DIGITALISIERT DURCH VI CONTENTS
1.3.2.2 CHIRAL SECONDARY AMINE CATALYZED ASYMMETRIE OXA-DIELS-ALDER
REACTION 39 1.4 REPRESENTATIVE APPLICATIONS IN TOTAL SYNTHESIS 41 1.5
CONCLUSION 46 1.6 EXPERIMENTAL: SELECTED PROCEDURES 46 1.6.1 PROCEDURE
FOR THE PREPARATION OF CHIRAL BORON COMPLEX 8B (R = O-TOL, AR * PH) AND
ITS APPLICATION IN ASYMMETRIE DIELS-ALDER REACTIONS 46 1.6.2 PROCEDURE
FOR CHIRAL SECONDARY AMINE 42 CATALYZED ASYMMETRIE DIELS-ALDER REACTION
OF CYCLOPENTADIENE WITH (E)-CINNAMALDEHYDE 47 1.6.3 PROCEDURE FOR
65/TI/70 CATALYZED ASYMMETRIE HETERO DIELS-ALDER REACTION OF
BENZALDEHYDE WITH DANISHEFSKY'S DIENE 47 1.6.4 PROCEDURE FOR THE
PREPARATION OF THE CHIRAL CHROMIUM COMPLEX (IS, 2R)-76A AND ITS
APPLICATION IN THE ASYMMETRIE HETERO DIELS-ALDER REACTION OF ETHYL VINYL
ETHER WITH CROTONALDEHYDE 47 1.6.5 PROCEDURE FOR CHIRAL COPPER COMPLEX
82A CATALYZED REACTION OF ASYMMETRIE HETERO ETHYL PYRUVATE WITH
DANISHEFSKY'S DIENE 48 1.6.6 PROCEDURE FOR THE PREPARATION OF CHIRAL
DIRHODIUM CARBOXAMIDATE COMPLEX 95 AND ITS APPLICATION IN THE ASYMMETRIE
HETERO DIELS*ALDER REACTION OF PHENYLPROPARGYL ALDEHYDE WITH
DANISHEFSKY'S DIENE 48 1.6.7 PROCEDURE FOR TADDOL 52 PROMOTED ASYMMETRIE
HETERO DIELS-ALDER REACTIO CONTENTS VII 3.2.1 BEGINNING OF LEWIS ACID
CATALYZED 1,3-DC OF NITRONES 89 3.2.2 CHIRAL LEWIS ACID CATALYZED 1,3-DC
OF NITRONES AND A,SS-UNSATURATED CARBONYL COMPOUNDS BEARING ANCILLARY
COORDINATING GROUP 91 3.2.3 ASYMMETRIE 1,3-DC OF NITRONES AND
A,SS-UNSATURATED ALDEHYDES 95 3.2.3.1 ORGANOCATALYSIS 95 3.2.3.2 LEWIS
ACID CATALYSIS 96 3.2.4 ASYMMETRIE 1,3-DC OF NITRONES AND OTHER
ELECTRON-DEFICIENT OLEFINS 101 3.2.5 INVERSE ELECTRON DEMAND 1,3-DC OF
NITRONES 103 3.2.6 KINUGASA REACTION 105 3.3 AZOMETHINE YLIDES 107 3.3.1
EARLY EXAMPLES OF ASYMMETRIE 1,3-DC OF N-METALATED AZOMETHINE YLIDES
DERIVED FROM ALDIMINES OF OT-AMINO ACID ESTERS 108 3.3.2 DEVELOPMENT OF
ASYMMETRIE 1,3-DC OF N-METALATED AZOMETHINE YLIDES WITH A,SS-UNSATURATED
CARBONYL COMPOUNDS 109 3.3.3 ASYMMETRIE 1,3-DCOF N-METALATED AZOMETHINE
YLIDES WITH VINYL SULFONES AND NITROALKENES 117 3.3.4 ORGANOCATALYTIC
ASYMMETRIE 1,3-DC OF AZOMETHINE YLIDES 119 3.3.5 TRANSITION METAL
CATALYZED 1,3-DC OFMUENCHNONES 121 3.3.6 LEWIS ACID CATALYZED 1,3-DC OF
AZOMETHINE YLIDE DERIVED FRO VIII CONTENTS 3.7.1 LEWIS ACID CATALYZED
ASYMMETRIE 1,3-DC OF DIAZO COMPOUNDS WITH OC,SS-UNSATURATED CARBONYL
COMPOUNDS 155 3.7.2 LEWIS ACID CATALYZED 1,3-DC OF DIAZO COMPOUNDS WITH
ALKYNES 157 3.8 CONDUSIONS 158 3.9 EXPERIMENTAL: SELECTED EXPERIMENTAL
359 3.9.1 PREPARATION OF N-BENZYLIDENEBENZYLAMINE N-OXIDE 259 3.9.2
GENERAL PROCEDURE FOR THE PREPARATION OF THE ALDIMINE OF N-ARYLIDENE
AMINO ACID ESTER 259 3.9.3 PREPARATION OF
L-BENZYLIDENE-3-OXOPYRAZOLIDIN-L-IUM-2-IDE 360 3.9.4 PREPARATION OF
TERT-BUTYL DIAZOACETATE 160 REFERENCES 160 4 INTRAMOLECULAR 1,2-ADDITION
AND 1,4-ADDITION REACTIONS 269 XIYAN LU AND XIULING HAN 4.1 INTRODUCTION
169 4.2 CYCLIZATION VIA INTRAMOLECULAR 1,2-ADDITION REACTIONS 269 4.2.1
1,2-ADDITION OF CARBONYL COMPOUNDS 169 4.2.1.1 1,2-ADDITION OFDICARBONYL
COMPOUNDS (ALDOL REACTION) 169 4.2.1.2 VINYLOGOUS ALDOL REACTION 173
4.2.1.3 1,2-ADDITION OF ALKENE-, ALKYNE- OR ARENE-SUBSTITUTED CARBONYL
COMPOUNDS 277 4.2.2 1,2-ADDITION OF IMINES 182 4.2.2.1 1,2-ADDITION OF
ALKENE OR ALKYNE SUBSTITUTED IMINO COMPOUNDS (IMINO ENE REACTIONS) 182
4.2.2.2 NUCLEOPHILIC ADDITION TO IMINO GROUPS 286 4.2.3 1,2-ADDITION
OFNITRILES 192 4.2.3.1 ACID-CATALYZED REACTIONS 192 4.2.3.2
BASE-CATALYZED REACTIONS 192 CONTENTS IX 4.5.2 1,2-ADDITION OF ARENE
SUBSTITUTED CARBONYL COMPOUNDS 218 4.5.2.1 REPRESENTATIVE PROCEDURE FOR
ASYMMETRIE CYCLIZATION OF O-(ACYLMETHYLOXY)-ARYLBORONIC ACID TO FURNISH
THE OPTICALLY ACTIVE CYCLOALKANOLS 228 4.5.3 NUCLEOPHILIC ADDITION TO
IMINO GROUPS 218 4.5.3.1 TYPICAL PROCEDURE FOR THE PALLADIUM-CATALYZED
INDOLE SYNTHESIS 218 4.5.4 1,2-ADDITION OFNITRILES 228 4.5.4.1 PROCEDURE
FOR THE 1.2-ADDITION OF NITRILE 218 4.5.5 1,2-ADDITION OFNITRILES 219
4.5.5.1 SYNTHESIS OF ENANTIOMERICALLY ENRICHED ATROPOISOMERS OF
2-ARYLPYRIDINES 219 4.5.6 CATALYZED 1,4-ADDITION REACTIONS 219 4.5.6.1
TYPICAL PROCEDURE FOR THE PHOSPHINE-CATALYZED TANDEM NUCLEOPHILIC
ADDITIONS 229 4.5.7 CATALYTIC ASYMMETRIE INTRAMOLECULAR CYCLIZATION VIA
1,4-ADDITION 219 4.5.7.1 GENERAL PROCEDURE FOR ASYMMETRIE 1,4-ADDITION
229 REFERENCES 220 5 CYCLIC CARBOMETALLATION OF ALKENES, ARENES, ALKYNES
AND ALLENES 227 RON CRIGG AND MARTYN INMAN 5.1 INTRODUCTION 227 5.2
CARBOMETALLATION OF ALKENES 228 5.2.1 STOICHIOMETRIC INTRAMOLECULAR
CARBOMETALLATION OF ALKENES 228 5.2. X CONTENTS 5.9.4 SYNTHESIS OF 207
263 REFERENCES 264 6 TRANSITION METAL-CATALYZED INTRAMOLECULAR
ALLYLATION REACTIONS 271 ZHAN LU AND SHENGMING MA 6.1 INTRODUCTION 271
6.2 PALLADIUM-CATALYZED INTRAMOLECULAR ALLYLATION REACTIONS 272 6.2.1
CYCLIC ALLYLATIONS OF CARBONUCLEOPHILES 272 6.2.2 CYCLIC ALLYLIC
AMINATIONS 282 6.2.3 CYDIC O- OR S-ALLYLATION 294 6.3 IRIDIUM-CATALYZED
INTRAMOLECULAR ALLYLATION REACTIONS 301 6.4 NI-CATALYZED INTRAMOLECULAR
ALLYLATION REACTIONS 304 6.5 RH-CATALYZED INTRAMOLECULAR ALLYLATION
REACTIONS 304 6.6 CONCLUSION AND PERSPECTIVES 305 6.7 EXPERIMENTAL:
SELECTED PROCEDURES 305 6.7.1 SYNTHESIS OFOPTICALLY ACTIVE CARBOCYCLE 9
WITH CHIRAL IIGAND S-7B 305 6.7.2 SYNTHESIS OF LACTONE 15(N = 4) IN AN
AQUEOUS-ORGANIC BIPHASIC SYSTEM 306 6.7.3 SYNTHESIS OF LACTONE 25A IN AN
AQUEOUS-ORGANIC BIPHASIC SYSTEM 306 6.7.4 SYNTHESIS OF
(4S,5S)-3-OXO-5-VINYL-L-AZA-BICYCLO[2.2.2]OCTANE-4- CARBOXYLIC ACID
ETHYL ESTER 307 6.7.5 SYNTHESIS OF TRANS-2-VINYLCYDOPENTANECARBALDEHYDE
307 6.7.6 SYNTHESIS OF 3-VINYLINDAN-L,L-DICARBOXYLIC ACID DIETHYL ESTER
307 CONTENTS XI 7.8 CONCLUSION AND PERSPECTIVES 357 7.9 EXPERIMENTAL:
SELECTED PROCEDURES 357 7.9.1 SYNTHESIS OFCOMPOUND 4 357 7.9.2 SYNTHESIS
OFCOMPOUND 17 357 7.9.3 SYNTHESIS OF COMPOUND 44 (R = PH) 358 7.9.4
SYNTHESIS OFCOMPOUND 86 358 7.9.5 SYNTHESIS OF COMPOUND 91 359 7.9.6
SYNTHESIS OF COMPOUND 100 (Z = BOC, N = 2) 359 7.9.7 SYNTHESIS
OFCOMPOUND 135 359 7.9.8 SYNTHESIS OFCOMPOUND 261 360 7.9.9 SYNTHESIS
OFCOMPOUND 278 360 7.9.10 SYNTHESIS OFCOMPOUND 291 360 REFERENCES 362 8
TRANSITION METAL-MEDIATED [2 + 2 + 2] CYCLOADDITIONS 367 DAVID LEBCEUF,
VINCENT CANDON, AND MAX MALACRIA 8.1 INTRODUCTION 367 8.2 BENZENE
DERIVATIVES 368 8.2.1 RAPID CONSTRUCTION OF FUNCTIONALIZED BENZENES
USING HETEROATOM-SUBSTITUTED ALKYNES 368 8.2.1.1 ALKYNYLSILANES 368
8.2.1.2 ALKYNYLBORONATES 369 8.2.1.3 YNAMIDES 370 8.2.1.4
ALKYNYLPHOSPHINES 370 8.2.1.5 ALKYNYLHALIDES 370 8.2.2 RAPID
CONSTRUCTION OF THE NAPHTHALENE CORE FROM TRANSIEN XII CONTENTS 8.6
EXPERIMENTAL: SELECTED PROCEDURES 397 8.6.1 SYNTHESIS OF COMPOUND 9 397
8.6.2 SYNTHESIS OFCOMPOUND 31 397 8.6.3 SYNTHESIS OFCOMPOUND 67 397
8.6.4 SYNTHESIS OF COMPOUNDS 100 AND 101 398 8.6.5 SYNTHESIS OFCOMPOUND
116 398 8.6.6 SYNTHESIS OFCOMPOUND 145 398 8.6.7 SYNTHESIS OFCOMPOUND
174 399 REFERENCES 400 9 CYCLIZATIONS BASED ON CYCLOMETALLATION 407 HAO
CUO AND SHENGMING MA 9.1 INTRODUCTION 407 9.2 TITANIUM-CATALYZED
CYCLIZATIONS 407 9.3 ZIRCONIUM-CATALYZED CYCLIZATIONS 414 9.4
RUTHENIUM-CATALYZED CYCLIZATIONS 419 9.5 COBALT-CATALYZED CYCLIZATIONS
425 9.6 RHODIUM-CATALYZED CYCLIZATIONS 427 9.7 IRIDIUM-CATALYZED
CYCLIZATIONS 439 9.8 NICKEL-CATALYZED CYCLIZATIONS 440 9.9
PAUADIUM-CATALYZED CYDIZATIONS 448 9.10 CONCLUSION AND PERSPECTIVES 449
9.11 EXPERIMENTAL: SELECTED PROCEDURES 450 9.11.1 TYPICAL PROCEDURE FOR
THE TITANIUM-CATALYZED CYDIZATIONS SHOW CONTENTS XIII 10.2 CYCLIZATION
REACTIONS OF ALKENES 457 10.2.1 CYCLIZATION WITH TETHERED NUCLEOPHILES
457 10.2.2 HYDROARYLATION REACTIONS 460 10.2.3 OTHER CASCADE PROCESSES
462 10.3 CYCLIZATION REACTIONS OF ALKYNES 466 10.3.1 CYCLIZATION WITH
TETHERED NUCLEOPHILES 466 10.3.2 DOMINO SP-SP 2 COUPLING AND CYCLIZATION
475 10.3.3 CYDIZATION/FUNCTIONAL GROUP MIGRATION REACTIONS 479 10.3.4
CYCLIZATION WITH CARBONYLS/IMINES/EPOXIDES/ACETALS/THIOACETALS, AND SO
ON 483 10.3.4.1 ALIPHATIC TETHER 483 10.3.4.2 AROMATIC TETHER 486 10.3.5
HYDROARYLATION REACTIONS 501 10.3.6 MISCELLANIOUS CYCLIZATION REACTIONS
502 10.4 CYCLIZATION REACTIONS OF ALLENES 504 10.4.1 CYCLIZATION WITH
TETHERED NUCLEOPHILES 504 10.4.2 CYCLIZATION WITH CARBONYLS 512 10.4.3
HYDROARYLATION REACTIONS 523 10.5 CONCLUSION AND PERSPECTIVE 525 10.6
EXPERIMENTAL: SELECTED PROCEDURES 516 10.6.1 SYNTHESIS OFCOMPOUND 13 526
10.6.2 SYNTHESIS OF COMPOUND 20 526 10.6.3 SYNTHESIS OF COMPOUND 40 527
10.6.4 SYNTHESIS OFCOMPOUND 82 527 10.6. XIV CONTENTS 11.2.3.2
ASYMMETRIE OLEFIN METATHESIS USING RUTHENIUM CATALYST 552 11.2.4
POLYMER-SUPPORTED CATALYSTS 554 11.2.5 SYNTHESIS OFNATURAL PRODUCTS
USING RCM 557 11.3 RING-CLOSING METATHESIS OF ENYNES 562 11.3.1
SYNTHESIS OF CARBO- AND HETERO-CYCLES USING RING-CLOSING METATHESIS OF
ENYNES 562 11.3.2 RING-CLOSING METATHESIS OFDIENYNES 573 11.3.3
RING-OPENING METATHESIS-RING-CLOSING METATHESIS OF CYDOALKENE-YNES 578
11.3.4 SYNTHESIS OFNATURAL PRODUCTS USING RING-CLOSING METATHESIS OF
ENYNE 586 11.4 PERSPECTIVE 592 11.5 EXPERIMENTAL: SELECTED PROCEDURE 592
11.5.1 TYPICAL PROCEDURE FOR THE SYNTHESIS OF A CYCLIZED COMPOUND FROM
ENYNE USING RCM 592 REFERENCES 59J 12 RING-CLOSING METATHESIS OF ALKYNES
599 PAUL W. DAVIES 12.1 INTRODUCTION 599 12.2 ALKYNE METATHESIS 599 12.3
RING-CLOSING ALKYNE METATHESIS AS A SYNTHETIC STRATEGY 600 12.4 CATALYST
SYSTEMS FOR RING-CLOSING ALKYNE METATHESIS 602 12.4.1 THE MORTREUX
"INSTANT" SYSTEM 602 12.4.2 TUNGSTEN ALKYLIDYNE CATALYSTS 602 12.4.3
MOLYBDENUM-BASED CATALYSTS 603 12.4.4 COMPARISON OF THE REACTION SYSTEMS
604 12. CHANG-LIANG SUN, BI-JIE LI, AND ZHANG-JIE SHI XV CONTENTS TO
VOLUME 2 13 TRANSITION-METAL-CATALYZED CYCLOISOMERIZATIONS AND
NUCLEOPHILIC CYCLIZATION OF ENYNES 625 ELENA HERRERO-COEMEZ AND ANTONIO
M. ECHAVARREN 14 CYCLOPROPANATION, EPOXIDATION AND AZIRIDINATION
REACTIONS 687 SONG YE AND YONG TANG 15 CYCLIZATION OF CYCLOPROPANE- OR
CYCLOPROPENE-CONTAINING COMPOUNDS 733 JUNLIANG ZHANG AND YUANJING XIAO
16 TRANSITION METAL-CATALYZED RING EXPANSION CYCLIZATION REACTIONS 823
MASAHIRO YOSHIDA AND YOSHIMITSU NAGAO 17 HYDROMETALLATION-INITIATED
CYCLIZATION REACTIONS 843 ISAMU MATSUDA 18 CATALYTIC DIPOLAR
CYCLOADDITIONS OF ALKYNES WITH AZIDES AND NITRILE OXIDES 927 VALERY V.
FOKIN 19 ELECTROPHILIC CYCLIZATIONS 952 FELIX RODRIGUEZ AND FRANCISCO].
FANANDS 20 CYCLIZATIONS BASED ON C-H ACTIVATION 992 DAVID A. CAPRETTO,
ZIGANG LI, AND CHUAN HE 21 FRIEDEL-CRAFTS TYPE CYCLIZATIONS 2025 RYUJI
HAYASHI AND GREGORY R. COOK 22 MACROLACTONES AND MACROLACTAMS 2055 INDEX
2243 XVI CONTENTS TO VOLUME 2 23 FREE RADICAL CYCLIZATION REACTIONS 2099
JAKE ZIMMERMAN, AMANDA HALLOWAY, AND MUKUND P. SIBI 24 PHOTOCYCLIZATION
REACTIONS 2249 AXEL G. CRIESBECK 25 ASYMMETRIE ORGANOCATALYZED
CYCLIZATION REACTIONS 1199 LIU-ZHU GONG, JUNJIANG, MENG-XIA XUE, AND
SHI-WEI LUO |
| any_adam_object | 1 |
| author2 | Ma, Shengming |
| author2_role | edt |
| author2_variant | s m sm |
| author_GND | (DE-588)140430717 |
| author_facet | Ma, Shengming |
| building | Verbundindex |
| bvnumber | BV025559866 |
| classification_rvk | VK 5500 VK 6000 |
| classification_tum | CHE 662f CHE 624f CHE 673f CHE 667f CHE 672f CHE 660f |
| ctrlnum | (DE-599)BVBBV025559866 |
| discipline | Chemie / Pharmazie Chemie |
| format | Book |
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| id | DE-604.BV025559866 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-20T10:33:35Z |
| institution | BVB |
| isbn | 9783527320882 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-019100119 |
| open_access_boolean | |
| publishDateSort | 0000 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Handbook of cyclization reactions ed. by Shengming Ma Weinheim Wiley-VCH txt rdacontent n rdamedia nc rdacarrier Organische Synthese (DE-588)4075695-6 gnd rswk-swf Cyclisation (DE-588)4127354-0 gnd rswk-swf Cyclische Verbindungen (DE-588)4140612-6 gnd rswk-swf Organische Synthese (DE-588)4075695-6 s Cyclische Verbindungen (DE-588)4140612-6 s DE-604 Cyclisation (DE-588)4127354-0 s Ma, Shengming (DE-588)140430717 edt text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3294450&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019100119&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Handbook of cyclization reactions Organische Synthese (DE-588)4075695-6 gnd Cyclisation (DE-588)4127354-0 gnd Cyclische Verbindungen (DE-588)4140612-6 gnd |
| subject_GND | (DE-588)4075695-6 (DE-588)4127354-0 (DE-588)4140612-6 |
| title | Handbook of cyclization reactions |
| title_auth | Handbook of cyclization reactions |
| title_exact_search | Handbook of cyclization reactions |
| title_full | Handbook of cyclization reactions ed. by Shengming Ma |
| title_fullStr | Handbook of cyclization reactions ed. by Shengming Ma |
| title_full_unstemmed | Handbook of cyclization reactions ed. by Shengming Ma |
| title_short | Handbook of cyclization reactions |
| title_sort | handbook of cyclization reactions |
| topic | Organische Synthese (DE-588)4075695-6 gnd Cyclisation (DE-588)4127354-0 gnd Cyclische Verbindungen (DE-588)4140612-6 gnd |
| topic_facet | Organische Synthese Cyclisation Cyclische Verbindungen |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3294450&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019100119&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT mashengming handbookofcyclizationreactions |