Holdings: Cyclization reactions

Cyclization reactions:

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Bibliographic Details
Main Authors:	Thebtaranonth, Chachanat (Author), Thebtaranonth, Yodhathai (Author)
Format:	Book
Language:	English
Published:	Boca Raton u.a. CRC Press 1994
Series:	New directions in organic and biological chemistry
Subjects:	Cyclisation (chimie) Ring formation (Chemistry) Cyclische Verbindungen Cyclisation Organische Synthese
Online Access:	Inhaltsverzeichnis
Physical Description:	370 S. graph. Darst.
ISBN:	0849378613

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MARC


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adam_text	CYCLIZATION REACTIONS C. THEBTARANONTH PROFESSOR DEPARTMENT OF CHEMISTRY MAHIDOL UNIVERSITY BANGKOK, THAILAND Y. THEBTARANONTH PROFESSOR DEPARTMENT OF CHEMISTRY MAHIDOL UNIVERSITY BANGKOK, THAILAND & ) CRC PRESS BOCA RATON ANN ARBOR LONDON TOKYO TABLE OF CONTENTS CHAPTER 1 CYCLIZATION REACTIONS 1 CHAPTER 2 CATIONIC CYCLIZATION I. INTRODUCTION 5 II. CYCLIZATION OF CARBOCATIONS 6 III. CYCLIZATION OF IMINIUM IONS 17 A. CYCLIZATION OF IMINIUM IONS BY INTERNAL NUCLEOPHILES 17 B. CYCLIZATION OF IMINIUM IONS INITIATED BY EXTERNAL NUCLEOPHILES 23 C. REARRANGEMENT-CYCLIZATION OF IMINIUM IONS 28 D. IMINIUM LON-INITIATED MULTIPLE CYCLIZATION OF UNACTIVATED POLYENES 35 IV. CYCLIZATION OF OXONIUM AND THIONIUM IONS 38 A. CYCLIZATION OF OXONIUM IONS 38 B. CYCLIZATION OF THIONIUM IONS 46 V. CYCLIZATION OF VINYL-, ALLYL-, PROPARGYL- AND AUENYLSILANES 50 A. CYCLIZATION OF VINYLSILANES 50 B. CYCLIZATION OF ALLYLSILANES 55 C. CYCLIZATION OF PROPARGYL- AND AUENYLSILANES 63 VI. CONCLUSION 69 REFERENCES 69 CHAPTER 3 RADICAL CYCLIZATION I. INTRODUCTION 77 II. CYCLIZATION TO UNACTIVATED ALKENES AND ALKYNES 77 A. ALKYL RADICALS 78 B. VINYL AND ARYL RADICALS 90 C. ACYL, THIOACYL, IMIDOYL AND IMINYL RADICALS 96 III. CYCLIZATION TO ACTIVATED OLEFINS AND CARBONYL FUNCTIONS 103 A. CYCLIZATION TO ACTIVATED OLEFINS 103 B. CYCLIZATION TO CARBONYL FUNCTIONS 115 IV. TANDEM CYCLIZATION 120 A. TANDEM CYCLIZATION AD HB 121 B. TANDEM CYCLIZATION TO FORM TRIQUINANE SKELETONS 129 V. CYCLIZATION INVOLVING ATOM OR GROUP TRANSFER, RADICAL TRANSLOCATION, REARRANGEMENT, OR FRAGMENTATION PROCESSES 134 A. CYCLIZATION INVOLVING ATOM OR GROUP TRANSFER 134 B. CYCLIZATION INVOLVING RADICAL TRANSLOCATION 138 C. CYCLIZATION INVOLVING RADICAL REARRANGEMENT 145 D. CYCLIZATION INVOLVING RADICAL FRAGMENTATION 151 VI. CONCLUSION 157 REFERENCES 158 CHAPTER 4 ANIONIC CYCLIZATION I. INTRODUCTION 169 IL CYCLIZATION VIA SJV 2 AND S/V T DISPLACEMENTS 169 III. CYCLIZATION VIA ADDITION TO CARBONYL, IMINE, IMINIUM, OXONIUM AND THIONIUM FUNCTIONS 182 A. ADDITION TO CARBONYL FUNCTIONS 182 B. ADDITION TO IMINE, IMINIUM, OXONIUM AND THIONIUM FUNCTIONS 194 IV. CYCLIZATION VIA CONJUGATE ADDITION 199 A. THE DIRECT MICHAEL ADDITION 199 B. MICHAEL-INITIATED RING CLOSURE (MIRC) 203 1. TANDEM MICHAEL ADDITION-S W 2 DISPLACEMENT 205 2. TANDEM MICHAEL ADDITION-AIDOL CONDENSATION 206 3. TANDEM MICHAEL ADDITION-DIECKMANN CONDENSATION ..208 4. MULTIPLE MICHAEL ADDITIONS 212 5. MICHAEL-INITIATED CYCLOPROPANATION 221 V. CYCLIZATION OF ALLYLSILANES AND ALLYLSTANNANES 225 VI. CYCLIZATION INVOLVING ADDITION TO UNACTIVATED OLEFINIC BONDS 232 VII. CONCLUSION 241 REFERENCES 242 CHAPTER 5 METAL-CATALYZED CYCLIZATION I. INTRODUCTION 255 IL PALLADIUM-CATALYZED CYCLIZATION 255 A. THE HECK AND RELATED REACTIONS 256 B. CYCLIZATION INVOLVING 7T-ALLYL METAL COMPLEXES 271 C. THE STILLE REACTION 279 III. METAL-CATALYZED CARBONYLATIVE CYCLIZATION 282 A. CARBONYLATIVE CYCLIZATION RELATED TO PALLADIUM-CATALYZED CYCLIZATION 283 B. THE PAUSON-KHAND AND RELATED REACTIONS 289 IV. METAL-CATALYZED CARBON-HETEROATOM BOND FORMATION 298 A. PALLADIUM-CATALYZED CARBON-HETEROATOM BOND FORMATION ....298 B. SILVER AND MERCURY SALT-CATALYZED CARBON-HETEROATOM BOND FORMATION 303 V. SAMARIUM(II) IODIDE-CATALYZED CYCLIZATION 312 VI. CONCLUSION 320 REFERENCES 321 CHAPTER 6 MISCELLANEOUS CYCLIZATIONS I. INTRODUCTION 331 II. MACROLACTONIZATION 331 A. THE COREY-NICOLAOU METHOD 331 B. THE MASUMUNE METHOD 332 C. THE MUKAIYAMA METHOD 332 D. THE YAMAGUCHI METHOD 332 E. THE MITSUNOBU METHOD 333 F. THE STEGLICH AND KECK METHOD 333 III. VICINAL TRICARBONYL CYCLIZATION 337 A. CYCLIZATION INVOLVING THE VICINAL TRICARBONYL SYSTEM 338 B. CYCLIZATION INVOLVING THE VINYL TRICARBONYL SYSTEM 342 IV. CYCLIZATION OF ENEDIYNES AND RELATED SYSTEMS 346 A. THE BERGMAN CYCLIZATION AND RELATED REACTIONS 347 B. CYCLIZATION OF CALICHEAMICINS, ESPERAMICINS, DYNEMICINS AND NEOCARZINOSTATIN CHROMOPHORE 354 V. FINAL REMARKS 358 REFERENCES 358 INDEX 365
any_adam_object	1
author	Thebtaranonth, Chachanat Thebtaranonth, Yodhathai
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discipline	Chemie / Pharmazie Chemie
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physical	370 S. graph. Darst.
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publisher	CRC Press
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series2	New directions in organic and biological chemistry
spelling	Thebtaranonth, Chachanat Verfasser aut Cyclization reactions C. Thebtaranonth ; Y. Thebtaranonth Boca Raton u.a. CRC Press 1994 370 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier New directions in organic and biological chemistry Cyclisation (chimie) ram Ring formation (Chemistry) Cyclische Verbindungen (DE-588)4140612-6 gnd rswk-swf Cyclisation (DE-588)4127354-0 gnd rswk-swf Organische Synthese (DE-588)4075695-6 gnd rswk-swf Cyclische Verbindungen (DE-588)4140612-6 s Organische Synthese (DE-588)4075695-6 s Cyclisation (DE-588)4127354-0 s DE-604 Thebtaranonth, Yodhathai Verfasser aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005869841&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Thebtaranonth, Chachanat Thebtaranonth, Yodhathai Cyclization reactions Cyclisation (chimie) ram Ring formation (Chemistry) Cyclische Verbindungen (DE-588)4140612-6 gnd Cyclisation (DE-588)4127354-0 gnd Organische Synthese (DE-588)4075695-6 gnd
subject_GND	(DE-588)4140612-6 (DE-588)4127354-0 (DE-588)4075695-6
title	Cyclization reactions
title_auth	Cyclization reactions
title_exact_search	Cyclization reactions
title_full	Cyclization reactions C. Thebtaranonth ; Y. Thebtaranonth
title_fullStr	Cyclization reactions C. Thebtaranonth ; Y. Thebtaranonth
title_full_unstemmed	Cyclization reactions C. Thebtaranonth ; Y. Thebtaranonth
title_short	Cyclization reactions
title_sort	cyclization reactions
topic	Cyclisation (chimie) ram Ring formation (Chemistry) Cyclische Verbindungen (DE-588)4140612-6 gnd Cyclisation (DE-588)4127354-0 gnd Organische Synthese (DE-588)4075695-6 gnd
topic_facet	Cyclisation (chimie) Ring formation (Chemistry) Cyclische Verbindungen Cyclisation Organische Synthese
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005869841&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
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