Holdings: Physical chemistry of ionic materials

Physical chemistry of ionic materials: ions and electrons in solids

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Bibliographic Details
Main Author:	Maier, Joachim 1955- (Author)
Format:	Book
Language:	English German
Published:	Chichester Wiley 2004
Subjects:	Solid state chemistry Elektron Kristallgitter Ion Festkörperphysik Festkörperchemie Gitterbaufehler Lehrbuch
Online Access:	Table of contents Inhaltsverzeichnis
Item Description:	Includes bibliographical references and index.
Physical Description:	537 S. Ill., graph. Darst.
ISBN:	0471999911 0470870761

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Record in the Search Index

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adam_text	PHYSICAL CHEMISTRY OF LONIC MATERIALS IONS AND ELECTRONS IN SOLIDS JOACHIM MAIER MAX-PLANCK-INSTITUT FUER FESTKOERPERFORSCHUNG, HEISENBERGSTRASSE 1, 70569 STUTTGART, GERMANY JOHN WILEY & SONS, LTD CONTENTS 1 INTRODUCTION 11 1.1 MOTIVATION 11 1.2 THE DEFECT CONCEPT: POINT DEFECTS AS THE MAIN ACTORS 14 2 BONDING ASPECTS: FROM ATOMS TO SOLID STATE 23 2.1 CHEMICAL BONDING IN SIMPLE MOLECULES 23 2.1.1 IDEAL COVALENT BONDING 23 2.1.2 POLAR COVALENT BONDING 27 2.1.3 THE IONIC BONDING 30 2.1.4 METALLIC BONDING 31 2.1.5 FURTHER INTERMEDIATE FORMS OF CHEMICAL BONDING 32 2.1.6 TWO-BODY POTENTIAL FUNCTIONS 33 2.2 MANY ATOMS IN CONTACT: THE SOLID STATE AS A GIANT MOLECULE 35 2.2.1 THE BAND MODEL 36 2.2.2 IONIC CRYSTALS 50 2.2.3 MOLECULAR CRYSTALS 56 2.2.4 COVALENT CRYSTALS 57 2.2.5 METALLIC CRYSTALS 59 2.2.6 MIXED FORMS OF BONDING IN SOLIDS 60 2.2.7 CRYSTAL STRUCTURE AND SOLID STATE STRUCTURE 61 3 PHONONS 65 3.1 EINSTEIN AND DEBYE MODEIS 65 3.2 COMPLICATIONS 69 4 EQUILIBRIUM THERMODYNAMICS OF THE PERFECT SOLID 72 4.1 PRELIMINARY REMARKS 72 4.2 THE FORMALISM OF EQUILIBRIUM THERMODYNAMICS 72 4.3 EXAMPLES OF EQUILIBRIUM THERMODYNAMICS 86 4.3.1 SOLID-SOLID PHASE TRANSITION 86 4.3.2 MELTING AND EVAPORATION 88 4.3.3 SOLID-SOLID REACTION 89 4.3.4 SOLID-GAS REACTION 89 CONTENTS \ 4.3.5 PHASE EQUILIBRIA AND MIXING REACTIONS 93 4.3.6 SPATIAL EQUILIBRIA IN INHOMOGENEOUS SYSTEMS 100 4.3.7 THERMODYNAMICS OF ELASTICALLY DEFORMED SOLIDS 103 4.3.8 THE THERMODYNAMIC FUNCTIONS OF STATE OF THE PERFECT SOLID . . . 104 EQUILIBRIUM THERMODYNAMICS OF THE REAL SOLID 108 5.1 PRELIMINARY REMARKS 108 5.2 EQUILIBRIUM THERMODYNAMICS OF POINT DEFECT FORMATION 109 5.3 EQUILIBRIUM THERMODYNAMICS OF ELECTRONIC DEFECTS 125 5.4 HIGHER-DIMENSIONAL DEFECTS 134 5.4.1 EQUILIBRIUM CONCENTRATION 134 5.4.2 DISLOCATIONS: STRUCTURE AND ENERGETICS 136 5.4.3 INTERFACES: STRUCTURE AND ENERGETICS 140 5.4.4 INTERFACIAL THERMODYNAMICS AND LOCAL MECHANICAL EQUILIBRIA . . 146 5.5 POINT DEFECT REACTIONS 155 5.5.1 SIMPLE INTERNAL DEFECT EQUILIBRIA 155 5.5.2 EXTERNAL DEFECT EQUILIBRIA 161 5.6 DOPING EFFECTS 177 5.7 INTERACTIONS BETWEEN DEFECTS 200 5.7.1 ASSOCIATES 201 5.7.2 ACTIVITY COEMCIENTS 210 5.8 BOUNDARY LAYERS AND SIZE EFFECTS 217 5.8.1 GENERAL 217 5.8.2 CONCENTRATION PROFILES IN THE SPACE CHARGE ZONES 223 5.8.3 CONDUCTIVITY EFFECTS 228 5.8.4 DEFECT THERMODYNAMICS OF THE INTERFACE 233 5.8.5 EXAMPLES AND SUPPLEMENTARY COMMENTS . . . 241 KINETICS AND IRREVERSIBLE THERMODYNAMICS 268 6.1 TRANSPORT AND REACTION 268 6.1.1 TRANSPORT AND REACTION IN THE LIGHT OF IRREVERSIBLE THERMODYNAMICS 269 6.1.2 TRANSPORT AND REACTION IN THE LIGHT OF CHEMICAL KINETICS 275 6.2 ELECTRICAL MOBILITY 283 6.2.1 ION MOBILITY 283 6.2.2 ELECTRON MOBILITY 292 6.3 PHENOMENOLOGICAL DIFFUSION COEMCIENTS 294 6.3.1 ION CONDUCTION AND SELF-DIFFUSION 295 6.3.2 TRACER DIFFUSION 296 6.3.3 CHEMICAL DIFFUSION 300 6.3.4 A COMPARISON OF THE PHENOMENOLOGICAL DIFFUSION COEMCIENTS . . 305 6.4 CONCENTRATION PROFILES 307 9 6.5 DIFFUSION KINETICS OF STOICHIOMETRY CHANGE 312 6.6 COMPLICATIONS OF MATTER TRANSPORT 319 6.6.1 INTERNAL INTERACTIONS 319 6.6.2 BOUNDARY LAYERS AND GRAIN BOUNDARIES 332 6.7 SURFACE REACTIONS 338 6.7.1 ELEMENTARY PROCESSES 338 6.7.2 COUPLED REACTIONS 340 6.7.3 PHENOMENOLOGICAL RATE CONSTANTS 347 6.7.4 REACTIVITY, CHEMICAL RESISTANCE AND CHEMICAL CAPACITANCE . . . 361 6.8 CATALYSIS 362 6.9 SOLID STATE REACTIONS 367 6.9.1 FUNDAMENTAL PRINCIPLES 367 6.9.2 MORPHOLOGICAL AND MECHANISTIC COMPLICATIONS 378 6.10 NONLINEAR PHENOMENA 382 6.10.1 IRREVERSIBLE THERMODYNAMICS AND CHEMICAL KINETICS FAR FROM EQUILIBRIUM, AND THE SPECIAL ROLE OF AUTOCATALYSIS 382 6.10.2 NONEQUILIBRIUM STRUCTURES IN TIME AND SPACE 388 6.10.3 THE CONCEPT OF FRACTAL GEOMETRY 393 SOLID STATE ELECTROCHEMISTRY: MEASUREMENT TECHNIQUES AND APPLICATIONS 399 7.1 PRELIMINARY REMARKS: CURRENT AND VOLTAGE IN THE LIGHT OF DEFECT CHEMISTRY 399 7.2 OPEN CIRCUIT CELLS 404 7.2.1 EQUILIBRIUM CELLS: THERMODYNAMIC MEASUREMENTS AND POTENTIOMETRIE SENSORS . . 404 7.2.2 PERMEATION CELLS AND CHEMICAL POLARIZATION: MEASUREMENT OF TRANSPORT PARAMETERS AND CHEMICAL FILTERS . .413 7.3 CELLS UNDER CURRENT LOAD 418 7.3.1 ELECTROCHEMICAL PUMPS, CONDUCTIVITY SENSORS AND OTHER APPLICATIONS 418 7.3.2 MEASUREMENT CELLS 424 7.3.3 BULK AND PHASE BOUNDARY EFFECTS 426 7.3.4 STOICHIOMETRY POLARIZATION 444 7.3.5 COULOMETRIC TITRATION 460 7.3.6 IMPEDANCE SPECTROSCOPY 462 7.3.7 INHOMOGENEITIES AND HETEROGENEITIES: MANY-POINT MEASUREMENTS AND POINT ELECTRODES 473 7.4 CELLS GENERATING CURRENT 481 7.4.1 GENERAL 481 7.4.2 FUEL CELLS 482 7.4.3 BATTERIES 487 7.4.4 TABLES 495 10 CONTENTS 8 BIBLIOGRAPHY 500 INDEX 527
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publisher	Wiley
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spelling	Maier, Joachim 1955- Verfasser (DE-588)121789160 aut Festkörper, Fehler und Funktion Physical chemistry of ionic materials ions and electrons in solids Joachim Maier Chichester Wiley 2004 537 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index. Solid state chemistry Elektron (DE-588)4125978-6 gnd rswk-swf Kristallgitter (DE-588)4139853-1 gnd rswk-swf Ion (DE-588)4027597-8 gnd rswk-swf Festkörperphysik (DE-588)4016921-2 gnd rswk-swf Festkörperchemie (DE-588)4129288-1 gnd rswk-swf Gitterbaufehler (DE-588)4125030-8 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Festkörperphysik (DE-588)4016921-2 s Festkörperchemie (DE-588)4129288-1 s 1\p DE-604 Gitterbaufehler (DE-588)4125030-8 s 2\p DE-604 Elektron (DE-588)4125978-6 s 3\p DE-604 Kristallgitter (DE-588)4139853-1 s 4\p DE-604 Ion (DE-588)4027597-8 s 5\p DE-604 http://www.loc.gov/catdir/toc/wiley041/2003070294.html Table of contents GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010667913&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 5\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk
spellingShingle	Maier, Joachim 1955- Physical chemistry of ionic materials ions and electrons in solids Solid state chemistry Elektron (DE-588)4125978-6 gnd Kristallgitter (DE-588)4139853-1 gnd Ion (DE-588)4027597-8 gnd Festkörperphysik (DE-588)4016921-2 gnd Festkörperchemie (DE-588)4129288-1 gnd Gitterbaufehler (DE-588)4125030-8 gnd
subject_GND	(DE-588)4125978-6 (DE-588)4139853-1 (DE-588)4027597-8 (DE-588)4016921-2 (DE-588)4129288-1 (DE-588)4125030-8 (DE-588)4123623-3
title	Physical chemistry of ionic materials ions and electrons in solids
title_alt	Festkörper, Fehler und Funktion
title_auth	Physical chemistry of ionic materials ions and electrons in solids
title_exact_search	Physical chemistry of ionic materials ions and electrons in solids
title_full	Physical chemistry of ionic materials ions and electrons in solids Joachim Maier
title_fullStr	Physical chemistry of ionic materials ions and electrons in solids Joachim Maier
title_full_unstemmed	Physical chemistry of ionic materials ions and electrons in solids Joachim Maier
title_short	Physical chemistry of ionic materials
title_sort	physical chemistry of ionic materials ions and electrons in solids
title_sub	ions and electrons in solids
topic	Solid state chemistry Elektron (DE-588)4125978-6 gnd Kristallgitter (DE-588)4139853-1 gnd Ion (DE-588)4027597-8 gnd Festkörperphysik (DE-588)4016921-2 gnd Festkörperchemie (DE-588)4129288-1 gnd Gitterbaufehler (DE-588)4125030-8 gnd
topic_facet	Solid state chemistry Elektron Kristallgitter Ion Festkörperphysik Festkörperchemie Gitterbaufehler Lehrbuch
url	http://www.loc.gov/catdir/toc/wiley041/2003070294.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010667913&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT maierjoachim festkorperfehlerundfunktion AT maierjoachim physicalchemistryofionicmaterialsionsandelectronsinsolids

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