Physical chemistry of ionic materials: ions and electrons in solids
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English German |
| Veröffentlicht: |
Chichester
Wiley
2004
|
| Schlagworte: | |
| Online-Zugang: | Table of contents Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index. |
| Beschreibung: | 537 S. Ill., graph. Darst. |
| ISBN: | 0471999911 0470870761 |
Internformat
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Datensatz im Suchindex
| _version_ | 1805075492350459904 |
|---|---|
| adam_text |
PHYSICAL CHEMISTRY OF LONIC MATERIALS IONS AND ELECTRONS IN SOLIDS
JOACHIM MAIER MAX-PLANCK-INSTITUT FUER FESTKOERPERFORSCHUNG,
HEISENBERGSTRASSE 1, 70569 STUTTGART, GERMANY JOHN WILEY & SONS, LTD
CONTENTS 1 INTRODUCTION 11 1.1 MOTIVATION 11 1.2 THE DEFECT CONCEPT:
POINT DEFECTS AS THE MAIN ACTORS 14 2 BONDING ASPECTS: FROM ATOMS TO
SOLID STATE 23 2.1 CHEMICAL BONDING IN SIMPLE MOLECULES 23 2.1.1 IDEAL
COVALENT BONDING 23 2.1.2 POLAR COVALENT BONDING 27 2.1.3 THE IONIC
BONDING 30 2.1.4 METALLIC BONDING 31 2.1.5 FURTHER INTERMEDIATE FORMS OF
CHEMICAL BONDING 32 2.1.6 TWO-BODY POTENTIAL FUNCTIONS 33 2.2 MANY ATOMS
IN CONTACT: THE SOLID STATE AS A GIANT MOLECULE 35 2.2.1 THE BAND MODEL
36 2.2.2 IONIC CRYSTALS 50 2.2.3 MOLECULAR CRYSTALS 56 2.2.4 COVALENT
CRYSTALS 57 2.2.5 METALLIC CRYSTALS 59 2.2.6 MIXED FORMS OF BONDING IN
SOLIDS 60 2.2.7 CRYSTAL STRUCTURE AND SOLID STATE STRUCTURE 61 3 PHONONS
65 3.1 EINSTEIN AND DEBYE MODEIS 65 3.2 COMPLICATIONS 69 4 EQUILIBRIUM
THERMODYNAMICS OF THE PERFECT SOLID 72 4.1 PRELIMINARY REMARKS 72 4.2
THE FORMALISM OF EQUILIBRIUM THERMODYNAMICS 72 4.3 EXAMPLES OF
EQUILIBRIUM THERMODYNAMICS 86 4.3.1 SOLID-SOLID PHASE TRANSITION 86
4.3.2 MELTING AND EVAPORATION 88 4.3.3 SOLID-SOLID REACTION 89 4.3.4
SOLID-GAS REACTION 89 CONTENTS \ 4.3.5 PHASE EQUILIBRIA AND MIXING
REACTIONS 93 4.3.6 SPATIAL EQUILIBRIA IN INHOMOGENEOUS SYSTEMS 100 4.3.7
THERMODYNAMICS OF ELASTICALLY DEFORMED SOLIDS 103 4.3.8 THE
THERMODYNAMIC FUNCTIONS OF STATE OF THE PERFECT SOLID . . . 104
EQUILIBRIUM THERMODYNAMICS OF THE REAL SOLID 108 5.1 PRELIMINARY REMARKS
108 5.2 EQUILIBRIUM THERMODYNAMICS OF POINT DEFECT FORMATION 109 5.3
EQUILIBRIUM THERMODYNAMICS OF ELECTRONIC DEFECTS 125 5.4
HIGHER-DIMENSIONAL DEFECTS 134 5.4.1 EQUILIBRIUM CONCENTRATION 134 5.4.2
DISLOCATIONS: STRUCTURE AND ENERGETICS 136 5.4.3 INTERFACES: STRUCTURE
AND ENERGETICS 140 5.4.4 INTERFACIAL THERMODYNAMICS AND LOCAL MECHANICAL
EQUILIBRIA . . 146 5.5 POINT DEFECT REACTIONS 155 5.5.1 SIMPLE INTERNAL
DEFECT EQUILIBRIA 155 5.5.2 EXTERNAL DEFECT EQUILIBRIA 161 5.6 DOPING
EFFECTS 177 5.7 INTERACTIONS BETWEEN DEFECTS 200 5.7.1 ASSOCIATES 201
5.7.2 ACTIVITY COEMCIENTS 210 5.8 BOUNDARY LAYERS AND SIZE EFFECTS 217
5.8.1 GENERAL 217 5.8.2 CONCENTRATION PROFILES IN THE SPACE CHARGE ZONES
223 5.8.3 CONDUCTIVITY EFFECTS 228 5.8.4 DEFECT THERMODYNAMICS OF THE
INTERFACE 233 5.8.5 EXAMPLES AND SUPPLEMENTARY COMMENTS . . . 241
KINETICS AND IRREVERSIBLE THERMODYNAMICS 268 6.1 TRANSPORT AND REACTION
268 6.1.1 TRANSPORT AND REACTION IN THE LIGHT OF IRREVERSIBLE
THERMODYNAMICS 269 6.1.2 TRANSPORT AND REACTION IN THE LIGHT OF CHEMICAL
KINETICS 275 6.2 ELECTRICAL MOBILITY 283 6.2.1 ION MOBILITY 283 6.2.2
ELECTRON MOBILITY 292 6.3 PHENOMENOLOGICAL DIFFUSION COEMCIENTS 294
6.3.1 ION CONDUCTION AND SELF-DIFFUSION 295 6.3.2 TRACER DIFFUSION 296
6.3.3 CHEMICAL DIFFUSION 300 6.3.4 A COMPARISON OF THE PHENOMENOLOGICAL
DIFFUSION COEMCIENTS . . 305 6.4 CONCENTRATION PROFILES 307 9 6.5
DIFFUSION KINETICS OF STOICHIOMETRY CHANGE 312 6.6 COMPLICATIONS OF
MATTER TRANSPORT 319 6.6.1 INTERNAL INTERACTIONS 319 6.6.2 BOUNDARY
LAYERS AND GRAIN BOUNDARIES 332 6.7 SURFACE REACTIONS 338 6.7.1
ELEMENTARY PROCESSES 338 6.7.2 COUPLED REACTIONS 340 6.7.3
PHENOMENOLOGICAL RATE CONSTANTS 347 6.7.4 REACTIVITY, CHEMICAL
RESISTANCE AND CHEMICAL CAPACITANCE . . . 361 6.8 CATALYSIS 362 6.9
SOLID STATE REACTIONS 367 6.9.1 FUNDAMENTAL PRINCIPLES 367 6.9.2
MORPHOLOGICAL AND MECHANISTIC COMPLICATIONS 378 6.10 NONLINEAR PHENOMENA
382 6.10.1 IRREVERSIBLE THERMODYNAMICS AND CHEMICAL KINETICS FAR FROM
EQUILIBRIUM, AND THE SPECIAL ROLE OF AUTOCATALYSIS 382 6.10.2
NONEQUILIBRIUM STRUCTURES IN TIME AND SPACE 388 6.10.3 THE CONCEPT OF
FRACTAL GEOMETRY 393 SOLID STATE ELECTROCHEMISTRY: MEASUREMENT
TECHNIQUES AND APPLICATIONS 399 7.1 PRELIMINARY REMARKS: CURRENT AND
VOLTAGE IN THE LIGHT OF DEFECT CHEMISTRY 399 7.2 OPEN CIRCUIT CELLS 404
7.2.1 EQUILIBRIUM CELLS: THERMODYNAMIC MEASUREMENTS AND POTENTIOMETRIE
SENSORS . . 404 7.2.2 PERMEATION CELLS AND CHEMICAL POLARIZATION:
MEASUREMENT OF TRANSPORT PARAMETERS AND CHEMICAL FILTERS . .413 7.3
CELLS UNDER CURRENT LOAD 418 7.3.1 ELECTROCHEMICAL PUMPS, CONDUCTIVITY
SENSORS AND OTHER APPLICATIONS 418 7.3.2 MEASUREMENT CELLS 424 7.3.3
BULK AND PHASE BOUNDARY EFFECTS 426 7.3.4 STOICHIOMETRY POLARIZATION 444
7.3.5 COULOMETRIC TITRATION 460 7.3.6 IMPEDANCE SPECTROSCOPY 462 7.3.7
INHOMOGENEITIES AND HETEROGENEITIES: MANY-POINT MEASUREMENTS AND POINT
ELECTRODES 473 7.4 CELLS GENERATING CURRENT 481 7.4.1 GENERAL 481 7.4.2
FUEL CELLS 482 7.4.3 BATTERIES 487 7.4.4 TABLES 495 10 CONTENTS 8
BIBLIOGRAPHY 500 INDEX 527 |
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| dewey-ones | 541 - Physical chemistry |
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| discipline | Chemie / Pharmazie Physik Chemie |
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| publisher | Wiley |
| record_format | marc |
| spelling | Maier, Joachim 1955- Verfasser (DE-588)121789160 aut Festkörper, Fehler und Funktion Physical chemistry of ionic materials ions and electrons in solids Joachim Maier Chichester Wiley 2004 537 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index. Solid state chemistry Elektron (DE-588)4125978-6 gnd rswk-swf Kristallgitter (DE-588)4139853-1 gnd rswk-swf Ion (DE-588)4027597-8 gnd rswk-swf Festkörperphysik (DE-588)4016921-2 gnd rswk-swf Festkörperchemie (DE-588)4129288-1 gnd rswk-swf Gitterbaufehler (DE-588)4125030-8 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Festkörperphysik (DE-588)4016921-2 s Festkörperchemie (DE-588)4129288-1 s 1\p DE-604 Gitterbaufehler (DE-588)4125030-8 s 2\p DE-604 Elektron (DE-588)4125978-6 s 3\p DE-604 Kristallgitter (DE-588)4139853-1 s 4\p DE-604 Ion (DE-588)4027597-8 s 5\p DE-604 http://www.loc.gov/catdir/toc/wiley041/2003070294.html Table of contents GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010667913&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 5\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Maier, Joachim 1955- Physical chemistry of ionic materials ions and electrons in solids Solid state chemistry Elektron (DE-588)4125978-6 gnd Kristallgitter (DE-588)4139853-1 gnd Ion (DE-588)4027597-8 gnd Festkörperphysik (DE-588)4016921-2 gnd Festkörperchemie (DE-588)4129288-1 gnd Gitterbaufehler (DE-588)4125030-8 gnd |
| subject_GND | (DE-588)4125978-6 (DE-588)4139853-1 (DE-588)4027597-8 (DE-588)4016921-2 (DE-588)4129288-1 (DE-588)4125030-8 (DE-588)4123623-3 |
| title | Physical chemistry of ionic materials ions and electrons in solids |
| title_alt | Festkörper, Fehler und Funktion |
| title_auth | Physical chemistry of ionic materials ions and electrons in solids |
| title_exact_search | Physical chemistry of ionic materials ions and electrons in solids |
| title_full | Physical chemistry of ionic materials ions and electrons in solids Joachim Maier |
| title_fullStr | Physical chemistry of ionic materials ions and electrons in solids Joachim Maier |
| title_full_unstemmed | Physical chemistry of ionic materials ions and electrons in solids Joachim Maier |
| title_short | Physical chemistry of ionic materials |
| title_sort | physical chemistry of ionic materials ions and electrons in solids |
| title_sub | ions and electrons in solids |
| topic | Solid state chemistry Elektron (DE-588)4125978-6 gnd Kristallgitter (DE-588)4139853-1 gnd Ion (DE-588)4027597-8 gnd Festkörperphysik (DE-588)4016921-2 gnd Festkörperchemie (DE-588)4129288-1 gnd Gitterbaufehler (DE-588)4125030-8 gnd |
| topic_facet | Solid state chemistry Elektron Kristallgitter Ion Festkörperphysik Festkörperchemie Gitterbaufehler Lehrbuch |
| url | http://www.loc.gov/catdir/toc/wiley041/2003070294.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010667913&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT maierjoachim festkorperfehlerundfunktion AT maierjoachim physicalchemistryofionicmaterialsionsandelectronsinsolids |