A problem solving approach to aquatic chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, NJ
Wiley
2003
|
| Ausgabe: | internat. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | CD-ROM u.d.T.: Nanoql, animations, and spreadsheet files |
| Beschreibung: | XIV, 585 S. Ill., graph. Darst. 1 CD-ROM (12 cm) |
| ISBN: | 0471413860 |
Internformat
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| 245 | 1 | 0 | |a A problem solving approach to aquatic chemistry |c James N. Jensen |
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| adam_text | Titel: A problem solving approach to aquatic chemistry
Autor: Jensen, James N.
Jahr: 2003
Brief Table of Contents
Part I: Fundamental Concepts 1
Chapter 1: Getting Started with the Fundamental Concepts 3
Chapter 2: Concentration Units 13
Chapter 3: Thermodynamic Basis of Equilibrium 33
Chapter 4: Manipulating Equilibria 67
Part II: Solution of Chemical Equilibrium Problems 87
Chapter 5: Getting Started with the Solution of Chemical Equilibrium Problems 89
Chapter 6: Setting Up Chemical Equilibrium Problems 97
Chapter 7: Algebraic Solution Techniques 121
Chapter 8: Graphical Solution Techniques 141
Chapter 9: Computer Solution Techniques 171
Part III: Acid-Base Equilibria in Homogenous Aqueous Systems 191
Chapter 10: Getting Started with Acid-Base Equilibria in Homogeneous Aqueous Systems 193
Chapter 11: Acids and Bases 203
Chapter 12: Titrations 229
Chapter 13: Alkalinity and Acidity 267
Part IV: Other Equilibria in Homogeneous Aqueous Systems 295
Chapter 14: Getting Started with Other Equilibria in Homogeneous Aqueous Systems 297
Chapter 15: Complexation 305
Chapter 16: Oxidation and Reduction 337
Part V: Heterogeneous Systems 383
Chapter 17: Getting Started with Heterogeneous Systems 385
Chapter 18: Gas-Liquid Equilibria 3 91
Chapter 19: Solid-Liquid Equilibria and the Aquatic Chemistry of Surfaces 417
Part VI: Beyond Dilute Systems at Equilibrium 459
Chapter 20: Getting Started with Beyond Dilute Solutions at Equilibrium 461
Chapter 21: Thermodynamics Revisited: The Effects of Ionic Strength, Temperature, and Pressure 467
Chapter 22: Chemical Kinetics of Aquatic Systems 491
Chapter 23: Putting It All Together: Integrated Chemistry in Aquatic Systems 519
Appendices 537
Appendix A: Background Information 537
Appendix B: A Comparison of Steady State and the Equilibrium State 543
Appendix C: Summary of Procedures 547
Appendix D: Selected Chemical Equilibria 555
Appendix E: Animations 567
Appendix F: Nanoql (also on CD) 573
References 577
Index 581
Table of Contents
Part I: Fundamental Concepts 1
Chapter 1: Getting Started with the Fundamental Concepts 3
1.1 Introduction 3
1.2 Why Calculate Chemical Species Concentrations? 3
1.3 Master Variables: The Importance of pH and pe 7
1.4 Properties of Water 8
1.5 Part I Road Map 9
1.6 Summary 10
1.7 Part I Case Study: Can Methylmercury Be Formed in Wrater? 10
Summary of Key Ideas 12
Chapter 2: Concentration Units 13
2.1 Introduction 13
2.2 Units Analysis 13
2.3 Molar Concentration Units 14
2.4 Mass Concentration Units 18
2.5 Dimensioniess Concentration Units 21
2.6 Equivalents 22
2.7 Review of Units Interconversion 23
2.8 Common Concentration Units in the Gas Phase 23
2.9 Common Concentration Units in the Solid Phase 25
2.10 Activity 25
2.11 Summary- 27
2.12 Part I Case Study: Can Methylmercury Be Formed in Water? 27
Summary of Key Ideas 28
Historical Note: Amadeo Avogadro and Avogadro s Number 29
Problems 30
Chapter 3: Thermodynamic Basis of Equilibrium 33
3.1 Introduction 33
3.2 Thermodynamic Properties 34
3.3 Why Do We Need Thermodynamics to Calculate Species Concentrations? 37
3.4 Thermodynamic Laws 41
3.5 Gibbs Free Energy 44
3 6 Properties of Thermodynamic Functions 46
3 7 Changes in Thermodynamic Properties During Chemical Reactions 49
3.8 Relating Gibbs Free Energy to Species Concentrations 54
3.9 Chemical Equilibrium and the Equilibrium Constant 59
3.10 Summary 60
3.11 Part I Case Study: Can Methylmercury Be Formed in Water? 61
Summary of Key Ideas 62
Historical Note: Josiah Willard Gibbs 63
Problems 63
Chapter 4: Manipulating Equilibria 67
4.1 Introduction 67
4.2 Chemical and Mathematical Forms of Equilibrium 68
4.3 Units of Equilibrium Constants 70
4.4 Reversing Equilibria 72
4.5 Effects of Stoichiometry 73
4.6 Adding Equilibria 75
4.7 Creating Equilibria 76
4.8 Summary 82
4.9 Part I Case Study: Can Methylmercury Be Formed in Water? 82
Summary of Key Ideas 83
Historical Note: Henri-Louis Le Chatelier and Le Chatelier s Principle 84
Problems 85
Part II: Solution of Chemical Equilibrium Problems 87
Chapter 5: Getting Started with the Solution of Chemical Equilibrium Problems 89
5.1 Introduction 89
5.2 A Framework for Solving Equilibrium Problems 89
5.3 Introduction to Defining the Chemical System 91
5.4 Introduction to Enumerating Chemical Species 92
5.5 Introduction to Defining the Constraints on Species Concentrations 92
5.6 Road Map to Part II 94
5.7 Summary 95
5.8 Part II Case Study: Have You Had Your Zinc Today? 95
Summary of Key Ideas 96
Chapter 6: Setting Up Chemical Equilibrium Problems 97
6.1 Introduction 97
6.2 Defining the Chemical System 97
6.3 Enumerating Chemical Species 98
6.4 Defining Constraints on Species Concentrations 104
6.5 Review of Procedures for Setting Up Equilibrium Systems 111
6.6 Concise Mathematical Form for Equilibrium Systems: An Advanced Topic 112
6.7 Summary 113
6.8 Part II Case Study: Have You Had Your Zinc Today? 113
Summary of Key Ideas 117
Problems 117
Chapter 7: Algebraic Solution Techniques 121
7.1 Introduction 121
7.2 Background on Algebraic Solutions 121
7.3 Method of Substitution 123
7.4 Method of Approximation 126
7.5 Summary 133
7.6 Part II Case Study: Have You Had Your Zinc Today 134
Summary ofKeyldeas 137
Problems 138
Chapter 8: Graphical Solution Techniques 141
8.1 Introduction 141
8.2 Introduction to Log Concentration and pC-pH Diagrams 142
8.3 Using pC-pH Diagrams with More Complex Systems 148
8.4 Special Shortcuts for Monoprotic Acids 153
8.5 When Graphical Methods Fail: The Proton Condition 158
8.6 Conclusions 164
8.7 Part II Case Study: Have You Had Your Zinc Today? 165
Summary of Key Ideas 166
Problems 168
Chapter 9: Computer Solution Techniques 171
9.1 Introduction 171
9.2 Chapter Problem 171
9.3 Spreadsheet Solutions 172
9.4 Equilibrium Calculation Software 175
9.5 Sanoql 177
9.6 The Tableau Method and Other Equilibrium Calculation Programs 179
9.7 Summary 188
9.8 Part II Case Study: Have You Had Your Zinc Today 7 189
Summary of Key Ideas 189
Problems 190
Part III: Acid-Base Equilibria in Homogenous Aqueous Systems 191
Chapter 10: Getting Started with Acid-Base Equilibria in Homogenous Aqueous Systems 193
10.1 Introduction 193
10.2 Homogeneous Systems 193
10.3 Types of Reactions in Homogeneous Systems 195
10.4 The Wonderful World of Acids and Bases 196
10.5 Part III Road Map 199
i 0.6 Summary 200
10.7 Part III Case Study: Acid Rain 200
Summary of Key Ideas 201
Chapter 11: Acids and Bases 203
ill Introduction 203
11.2 Definitions of Acids and Bases 203
i 1.3 Acid and Base Strength 207
11.4 Polyprotic Acids 212
i 1.5 Distribution Functions (Alpha Values) 220
11.6 Summary 222
11.7 Part III Case Study: Acid Rain 222
Summary of Key Ideas 224
Problems 225
Chapter 12: Titrations 229
12.1 Introduction 229
12.2 Principles of Acid-Base Titrations 231
12.3 Equivalence Points 234
12.4 Titration of Diprotic Acids 244
12.5 Buffers 247
12.6 Interpretation of Titration Curves with Complex Mixtures 256
12.7 Summary 259
12.8 Part III Case Study: Acid Rain 260
Summary of Key Ideas 262
Problems 264
Chapter 13: Alkalinity and Acidity 267
13.1 Introduction 267
13.2 Alkalinity and the Acid Neutralizing Capacity 267
13.3 Alkalinity and the Charge Balance 271
13.4 Characteristics of Alkalinity and Acidity 273
13.5 Using the Definitions of Alkalinity to Solve Problems 283
13.6 Effects of Other Weak Acids and Bases on Alkalinity 288
13.7 Summary 289
13.8 Part III Case Study: Acid Rain 290
Summary of Key Ideas 291
Problems 292
Part IV: Other Equilibria in Homogenous Aqueous Systems 295
Chapter 14: Getting Started with Other Equilibria in Homogenous Aqueous Systems 197
14.1 Introduction 297
14.2 Electron-sharing Reactions 297
14.3 Electron Transfer 300
14.4 Part IV Road Map 301
14.5 Summary 302
14.6 Part IV Case Study: Which Form of Copper Plating Should You Use? 302
Summary of Key Ideas 303
Chapter 15: Complexation 305
15.1 Introduction 305
15.2 Metals 305
15.3 Ligands 308
15.4 Equilibrium Calculations with Complexes 313
15.5 Systems with Several Metals and Ligands 321
15.6 Applications of Complexation Chemistry 329
15.7 Summary 330
15.8 Part IV Case Study: W hich Form of Copper Plating Should You Use? 330
Summary of Key Ideas 333
Problems 334
Chapter 16: Oxidation and Reduction 337
16.1 Introduction 337
16.2 A Few Definitions 337
16.3 Balancing Redox Reactions 339
16.4 Which Redox Reactions Occur? 346
16.5 Redox Thermodynamics and Oxidant and Reductant Strength 347
16.6 Algebraic Equilibrium Calculations in Systems Undergoing Electron Transfer 353
16.7 Graphical Representations of Systems Undergoing Electron Transfer 358
16.8 Applying Redox Equilibrium Calculations to the Real World 372
16.9 Summary 374
16.10 Part IV Case Study: Which Form of Copper Plating Should You Use? 375
Summary of Key Ideas 377
Historical Note: Walther Hermann Nernst 378
Problems 379
Part V: Heterogeneous Systems 383
Chapter 17: Getting Started with Heterogenous Systems 385
17.1 Introduction 385
17.2 Equilibrium Exchange Between Gas and Aqueous Phases 385
17.3 Equilibrium Exchange Between Solid and Aqueous Phases 387
17.4 Part V Road Map 388
17.5 Summary 388
17.6 Part V Case Study: The Killer Lakes 389
Summary of Key Ideas 389
Chapter 18: Gas-Liquid Equilibria 391
18.1 Introduction 391
18.2 Raoult s Law and Henry s Law 391
18.3 Equilibrium Calculations Involving Gas-Liquid Equilibria 398
18.4 Dissolved Carbon Dioxide 405
18.5 Summary 410
18.6 Part V Case Study: The Killer Lakes 410
Summary of Key Ideas 412
Problems 413
Chapter 19: Solid-Liquid Equilibria and the Aquatic Chemistry of Surfaces 417
19.1 Introduction 417
19.2 Saturation and the Activity of Pure Solids 417
19.3 Equilibrium Calculations Involving Solid-Liquid Equilibria 420
19.4 Factors Affecting Metal Solubility 428
19.5 Solubility of Calcium Carbonate 433
19.6 Summary of the Acid-Base Chemistry of Natural Waters 437
19.7 Aquatic Chemistry of Surfaces 443
19.8 Summary 450
19.9 Part V Case Study: The Killer Lakes 451
Summary of Key Ideas 452
Problems 453
Part VI: Beyond Dilute Systems at Equilibrium 459
Chapter 20: Getting Started with Beyond Dilute Systems at Equilibrium 461
20.1 Introduction 461
20.2 Extensions to Nonideal and Nonstandard Conditions 461
20.3 Nonequilibrium Conditions 464
20.4 Integrated Case Studies 465
20.5 Part VI Road Map 465
20.6 Summary 466
Summary of Key Ideas 466
Chapter 21: Thermodynamics Revisited 467
21.1 Introduction 467
21.2 Effects of Ionic Strength 468
21.3 Effects of Temperature on Chemical Equilibria 479
21.4 Effects of Pressure on Equilibrium Constants 484
21.5 Summary 486
Summary of Key Ideas 487
Historical Note: Jacobus Henricus Van t Hoff 488
Problems 488
Chapter 22: Chemical Kinetics of Aquatic Systems 491
22.1 Introduction 491
22.2 The Need for Chemical Kinetics 492
22.3 Reaction Rates 494
22.4 Common Rate Expressions 500
22.5 More Complex Kinetic Forms 506
22.6 Effects of Temperature and Ionic Strength on Reaction Kinetics 511
22.7 Summary 514
Summary of Key Ideas 515
Problems 516
Chapter 23: Putting It All Together: Integrated Chemistry of Aquatic Systems 519
23.1 Introduction 519
23.2 Integrated Case Study 1: Metal Finishing 519
23.3 Integrated Case Study 2: Oxidation of Ferrous Iron by Oxygen 524
23.4 Integrated Case Study 3: Inorganic Mercury Chemistry in Natural Waters 529
23.5 Summary 535
537
Appendix A: Background information sjv
A.1 Introduction 537
A.2 Chemical Principles 537
A.3 Mathematical Principles 540
A.4 Computer Skills 540
Summary of Key Ideas 542
Appendix B: Equilibrium and Steady State 543
B.I Introduction 543
B.2 Steady-State Analysis 543
B.3 Comparison of Steady State and Equilibrium Solutions 544
Summary of Key Ideas 545
Appendix C: Summary of Procedures 547
C. 1 Oxidation State and Balancing Reactions 547
C.2 Setting Up Chemical Equilibrium Systems (section 6.4) 548
C.3 Algebraic Solution Techniques 549
C.4 Graphical Solutions 549
C.5 Computer Solutions: Tableau Method 552
C.6 Acid-Base Titrations 553
C.7 Complexation (section 15.4.4) 553
C.8 Ionic Strength Effects (section 21.2.7) 554
C.9 Chemical Kinetics (section 22.3.4) 554
Appendix D: Selected Chemical Equilibrium Constants 555
Appendix E: Animations and Example Computer Files 567
E.I Animations 567
E.2 Variation of Equilibrium pH of a Monoprotic Acid Solution with Total Acid Concentration and Ka 567
E.3 How to Draw a pC-pH Diagram 569
E.4 Equilibrium pH During the Titration of a Monoprotic Acid with a Strong Base 570
E.5 Other Computer Files 571
Appendix F: Nanoql (also on CD) 573
F.I Installation 573
F.2 Using and Manipulating Files in Nanoql 573
F.3 Tips on Using Nonoql 575
References 577
Index 581
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| spellingShingle | Jensen, James N. A problem solving approach to aquatic chemistry Equilíbrio químico larpcal Água (análise química) larpcal Environmental chemistry Water chemistry Hydrochemie (DE-588)4072678-2 gnd |
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| title | A problem solving approach to aquatic chemistry |
| title_alt | Nanoql, animations, and spreadsheet files |
| title_auth | A problem solving approach to aquatic chemistry |
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| title_full | A problem solving approach to aquatic chemistry James N. Jensen |
| title_fullStr | A problem solving approach to aquatic chemistry James N. Jensen |
| title_full_unstemmed | A problem solving approach to aquatic chemistry James N. Jensen |
| title_short | A problem solving approach to aquatic chemistry |
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