A primer in frustrated Lewis pair hydrogenation :: concepts to applications /
"Written for senior undergraduate and graduate students, as well as those chemists unfamiliar with 'frustrated Lewis pairs (FLPs)', this text serves as an introduction to both the concept and application of FLPs in hydrogenation catalysis. The book begins by setting the stage as it wa...
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
London :
Royal Society of Chemistry,
[2022]
|
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Zusammenfassung: | "Written for senior undergraduate and graduate students, as well as those chemists unfamiliar with 'frustrated Lewis pairs (FLPs)', this text serves as an introduction to both the concept and application of FLPs in hydrogenation catalysis. The book begins by setting the stage as it was around the turn of the century. While the dramatic impacts of catalysis were undeniable, there was dependence of such technologies on transition metal chemistry. Contrastingly, the chemistry of main group elements was dominated by Lewis acid-base behavior. However, these perceptions were altered with the discovery of the ability of 'frustrated Lewis paris (FLPs)' to activate dihydrogen. The basic features, and mechanisms of action of these unique main group systems are chronicled, while the evolution of the initial findings to applications in catalytic hydrogenation is discussed. A subsequent chapter focuses on the breadth of organic substrates for which borane based FLP hydrogenations are effective. This is furthered with a chapter on the metal-free enantioselective reductions. FLP chemistry is not limited to systems involving boranes and this book also catalgoues a range of FLP hydrogenation catalysts involving elements from across the periodic table. The final chapter in the book describes other directions of interest where the applications of the concept of FLP hydrogenation are beginning to emerge"-- |
| Beschreibung: | 1 online resource (xi, 172 pages) : illustrations. |
| Bibliographie: | Includes bibliographical references and index. |
| ISBN: | 9781839168598 1839168595 9781839165061 1839165065 |
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| 520 | |a "Written for senior undergraduate and graduate students, as well as those chemists unfamiliar with 'frustrated Lewis pairs (FLPs)', this text serves as an introduction to both the concept and application of FLPs in hydrogenation catalysis. The book begins by setting the stage as it was around the turn of the century. While the dramatic impacts of catalysis were undeniable, there was dependence of such technologies on transition metal chemistry. Contrastingly, the chemistry of main group elements was dominated by Lewis acid-base behavior. However, these perceptions were altered with the discovery of the ability of 'frustrated Lewis paris (FLPs)' to activate dihydrogen. The basic features, and mechanisms of action of these unique main group systems are chronicled, while the evolution of the initial findings to applications in catalytic hydrogenation is discussed. A subsequent chapter focuses on the breadth of organic substrates for which borane based FLP hydrogenations are effective. This is furthered with a chapter on the metal-free enantioselective reductions. FLP chemistry is not limited to systems involving boranes and this book also catalgoues a range of FLP hydrogenation catalysts involving elements from across the periodic table. The final chapter in the book describes other directions of interest where the applications of the concept of FLP hydrogenation are beginning to emerge"-- |c Back cover. | ||
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| 650 | 2 | |a Catalysis |0 https://id.nlm.nih.gov/mesh/D002384 | |
| 650 | 6 | |a Hydrogénation. | |
| 650 | 6 | |a Catalyse. | |
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| contents | Context, background, and discovery -- The nature of frustrated Lewis pairs -- Borane-based FLP hydrogenations -- Borane-based asymmetric FLP hydrogenations -- Structural variations of FLPs -- Other directions for FLP hydrogenations. |
| ctrlnum | (OCoLC)1360436561 |
| dewey-full | 547.23 |
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| id | ZDB-4-EBA-on1360436561 |
| illustrated | Illustrated |
| indexdate | 2024-11-27T13:30:40Z |
| institution | BVB |
| isbn | 9781839168598 1839168595 9781839165061 1839165065 |
| language | English |
| oclc_num | 1360436561 |
| open_access_boolean | |
| owner | MAIN DE-863 DE-BY-FWS |
| owner_facet | MAIN DE-863 DE-BY-FWS |
| physical | 1 online resource (xi, 172 pages) : illustrations. |
| psigel | ZDB-4-EBA |
| publishDate | 2022 |
| publishDateSearch | 2022 |
| publishDateSort | 2022 |
| publisher | Royal Society of Chemistry, |
| record_format | marc |
| spelling | Stephan, Douglas W., author. A primer in frustrated Lewis pair hydrogenation : concepts to applications / by Douglas W. Stephan. London : Royal Society of Chemistry, [2022] ©2022 1 online resource (xi, 172 pages) : illustrations. text txt rdacontent computer c rdamedia online resource cr rdacarrier Includes bibliographical references and index. Context, background, and discovery -- The nature of frustrated Lewis pairs -- Borane-based FLP hydrogenations -- Borane-based asymmetric FLP hydrogenations -- Structural variations of FLPs -- Other directions for FLP hydrogenations. "Written for senior undergraduate and graduate students, as well as those chemists unfamiliar with 'frustrated Lewis pairs (FLPs)', this text serves as an introduction to both the concept and application of FLPs in hydrogenation catalysis. The book begins by setting the stage as it was around the turn of the century. While the dramatic impacts of catalysis were undeniable, there was dependence of such technologies on transition metal chemistry. Contrastingly, the chemistry of main group elements was dominated by Lewis acid-base behavior. However, these perceptions were altered with the discovery of the ability of 'frustrated Lewis paris (FLPs)' to activate dihydrogen. The basic features, and mechanisms of action of these unique main group systems are chronicled, while the evolution of the initial findings to applications in catalytic hydrogenation is discussed. A subsequent chapter focuses on the breadth of organic substrates for which borane based FLP hydrogenations are effective. This is furthered with a chapter on the metal-free enantioselective reductions. FLP chemistry is not limited to systems involving boranes and this book also catalgoues a range of FLP hydrogenation catalysts involving elements from across the periodic table. The final chapter in the book describes other directions of interest where the applications of the concept of FLP hydrogenation are beginning to emerge"-- Back cover. Print version record. Hydrogenation. http://id.loc.gov/authorities/subjects/sh85063436 Catalysis. http://id.loc.gov/authorities/subjects/sh85020938 Chemical reactions. http://id.loc.gov/authorities/subjects/sh85022952 Hydrogenation https://id.nlm.nih.gov/mesh/D006865 Catalysis https://id.nlm.nih.gov/mesh/D002384 Hydrogénation. Catalyse. Catalysis fast Chemical reactions fast Hydrogenation fast Print version: Stephan, Douglas W. Primer in frustrated Lewis pair hydrogenation. London : Royal Society of Chemistry, [2022] 9781839162442 (DLC) 2022304346 (OCoLC)1246283487 FWS01 ZDB-4-EBA FWS_PDA_EBA https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=3580090 Volltext |
| spellingShingle | Stephan, Douglas W. A primer in frustrated Lewis pair hydrogenation : concepts to applications / Context, background, and discovery -- The nature of frustrated Lewis pairs -- Borane-based FLP hydrogenations -- Borane-based asymmetric FLP hydrogenations -- Structural variations of FLPs -- Other directions for FLP hydrogenations. Hydrogenation. http://id.loc.gov/authorities/subjects/sh85063436 Catalysis. http://id.loc.gov/authorities/subjects/sh85020938 Chemical reactions. http://id.loc.gov/authorities/subjects/sh85022952 Hydrogenation https://id.nlm.nih.gov/mesh/D006865 Catalysis https://id.nlm.nih.gov/mesh/D002384 Hydrogénation. Catalyse. Catalysis fast Chemical reactions fast Hydrogenation fast |
| subject_GND | http://id.loc.gov/authorities/subjects/sh85063436 http://id.loc.gov/authorities/subjects/sh85020938 http://id.loc.gov/authorities/subjects/sh85022952 https://id.nlm.nih.gov/mesh/D006865 https://id.nlm.nih.gov/mesh/D002384 |
| title | A primer in frustrated Lewis pair hydrogenation : concepts to applications / |
| title_auth | A primer in frustrated Lewis pair hydrogenation : concepts to applications / |
| title_exact_search | A primer in frustrated Lewis pair hydrogenation : concepts to applications / |
| title_full | A primer in frustrated Lewis pair hydrogenation : concepts to applications / by Douglas W. Stephan. |
| title_fullStr | A primer in frustrated Lewis pair hydrogenation : concepts to applications / by Douglas W. Stephan. |
| title_full_unstemmed | A primer in frustrated Lewis pair hydrogenation : concepts to applications / by Douglas W. Stephan. |
| title_short | A primer in frustrated Lewis pair hydrogenation : |
| title_sort | primer in frustrated lewis pair hydrogenation concepts to applications |
| title_sub | concepts to applications / |
| topic | Hydrogenation. http://id.loc.gov/authorities/subjects/sh85063436 Catalysis. http://id.loc.gov/authorities/subjects/sh85020938 Chemical reactions. http://id.loc.gov/authorities/subjects/sh85022952 Hydrogenation https://id.nlm.nih.gov/mesh/D006865 Catalysis https://id.nlm.nih.gov/mesh/D002384 Hydrogénation. Catalyse. Catalysis fast Chemical reactions fast Hydrogenation fast |
| topic_facet | Hydrogenation. Catalysis. Chemical reactions. Hydrogenation Catalysis Hydrogénation. Catalyse. Chemical reactions |
| url | https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=3580090 |
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