The origin of chirality in the molecules of life :: from awareness to current theories and perspectives of this unsolved problem /
This book provides an interdisciplinary review of one of the great unsolved mysteries that has fascinated scientists for over 150 years: the origin of chirality in biomolecules. It is fundamental, comprehensive and structured to be accessible for educational purposes.
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Cambridge :
Royal Society of Chemistry,
2022.
|
| Ausgabe: | Second edition. |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Zusammenfassung: | This book provides an interdisciplinary review of one of the great unsolved mysteries that has fascinated scientists for over 150 years: the origin of chirality in biomolecules. It is fundamental, comprehensive and structured to be accessible for educational purposes. |
| Beschreibung: | 1 online resource (1 volume) |
| ISBN: | 9781839163685 9781839163692 1839163690 1839163682 |
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| 245 | 1 | 4 | |a The origin of chirality in the molecules of life : |b from awareness to current theories and perspectives of this unsolved problem / |c Albert Guijarro. |
| 250 | |a Second edition. | ||
| 264 | 1 | |a Cambridge : |b Royal Society of Chemistry, |c 2022. | |
| 300 | |a 1 online resource (1 volume) | ||
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| 505 | 0 | |a Intro -- Title -- Copyright -- Contents -- Chapter 1 Introduction and Historical Background -- 1.1 Introduction -- 1.2 The Contribution of Pasteur -- 1.2.1 Quartz -- 1.2.2 Tartaric Acid and the Tartrates -- 1.3 The Nature of the Problem -- References -- Chapter 2 The Concept of Chirality -- 2.1 Introduction -- 2.2 The First Absolute Stereochemical Determination of a Molecule, Again Tartaric Acid -- 2.2.1 X-Ray Crystallography to Determine Absolute Configuration -- 2.2.2 Chiroptical Methods of Absolute Determination -- 2.3 Molecular Symmetry and Chirality -- 2.3.1 Symmetry Elements | |
| 505 | 8 | |a 2.3.2 Point Groups -- 2.4 True and False Chirality -- 2.5 The Discrete Symmetry Operators -- 2.5.1 The Space Inversion: The Parity Operator, P̂ -- 2.5.2 The Time Reversion: The Time Reversal Operator, T̂ -- 2.5.3 The Charge Conjugation: The Charge Conjugation Operator, Ĉ -- 2.6 The Failure of the Experiments of Pasteur, Curie and Others: Experiments in the Absence of Chirality and Experiments Under the Influence of False or True Chirality -- 2.6.1 Experiments in the Absence of a Chiral Field -- 2.6.2 Experiments Under False Chiral Influence -- 2.6.3 Experiments Under True Chiral Influence | |
| 505 | 8 | |a 2.7 Expected Effect of True and False Chirality on Molecules -- 2.8 Quantum Mechanical Treatment of Molecular Chirality -- References -- Chapter 3 Theories of the Origin of Biomolecular Homochirality -- 3.1 Introduction -- 3.2 Chance Theories -- 3.2.1 Amplification of Tiny Stochastic Imbalances -- 3.2.2 Polymerizations Above a Critical Chain Length: Macromolecules -- 3.3 Deterministic Theories -- References -- Chapter 4 Chiral Physical Forces -- 4.1 Background -- 4.2 The Weak Interaction and the Parity Violation | |
| 505 | 8 | |a 5.2.2 Theoretical Models Derived from Frank's Original Model -- 5.2.3 Attempts Looking for Autocatalytic Amplification of the Weak Force -- 5.2.4 Amplification of Chirality in Chemical Reactions -- 5.2.5 Self-replication -- 5.3 Amplification of Chirality by Cooperative Forces: Growing Polymers and Supramolecular Assemblies -- 5.3.1 Amplification of Chirality in Polymerization -- 5.3.2 Amplification of Chirality in Supramolecular Assemblies -- 5.4 The Yamagata Cumulative Mechanism -- 5.5 The Salam Phase Transition -- 5.6 Amplification of Scalemic Compounds: Eutectic Mixtures | |
| 520 | |a This book provides an interdisciplinary review of one of the great unsolved mysteries that has fascinated scientists for over 150 years: the origin of chirality in biomolecules. It is fundamental, comprehensive and structured to be accessible for educational purposes. | ||
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| 650 | 0 | |a Biochemistry. |0 http://id.loc.gov/authorities/subjects/sh85014171 | |
| 650 | 2 | |a Biochemistry |0 https://id.nlm.nih.gov/mesh/D001671 | |
| 650 | 6 | |a Chiralité. | |
| 650 | 6 | |a Biochimie. | |
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| 650 | 7 | |a Chirality |2 fast | |
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| contents | Intro -- Title -- Copyright -- Contents -- Chapter 1 Introduction and Historical Background -- 1.1 Introduction -- 1.2 The Contribution of Pasteur -- 1.2.1 Quartz -- 1.2.2 Tartaric Acid and the Tartrates -- 1.3 The Nature of the Problem -- References -- Chapter 2 The Concept of Chirality -- 2.1 Introduction -- 2.2 The First Absolute Stereochemical Determination of a Molecule, Again Tartaric Acid -- 2.2.1 X-Ray Crystallography to Determine Absolute Configuration -- 2.2.2 Chiroptical Methods of Absolute Determination -- 2.3 Molecular Symmetry and Chirality -- 2.3.1 Symmetry Elements 2.3.2 Point Groups -- 2.4 True and False Chirality -- 2.5 The Discrete Symmetry Operators -- 2.5.1 The Space Inversion: The Parity Operator, P̂ -- 2.5.2 The Time Reversion: The Time Reversal Operator, T̂ -- 2.5.3 The Charge Conjugation: The Charge Conjugation Operator, Ĉ -- 2.6 The Failure of the Experiments of Pasteur, Curie and Others: Experiments in the Absence of Chirality and Experiments Under the Influence of False or True Chirality -- 2.6.1 Experiments in the Absence of a Chiral Field -- 2.6.2 Experiments Under False Chiral Influence -- 2.6.3 Experiments Under True Chiral Influence 2.7 Expected Effect of True and False Chirality on Molecules -- 2.8 Quantum Mechanical Treatment of Molecular Chirality -- References -- Chapter 3 Theories of the Origin of Biomolecular Homochirality -- 3.1 Introduction -- 3.2 Chance Theories -- 3.2.1 Amplification of Tiny Stochastic Imbalances -- 3.2.2 Polymerizations Above a Critical Chain Length: Macromolecules -- 3.3 Deterministic Theories -- References -- Chapter 4 Chiral Physical Forces -- 4.1 Background -- 4.2 The Weak Interaction and the Parity Violation 5.2.2 Theoretical Models Derived from Frank's Original Model -- 5.2.3 Attempts Looking for Autocatalytic Amplification of the Weak Force -- 5.2.4 Amplification of Chirality in Chemical Reactions -- 5.2.5 Self-replication -- 5.3 Amplification of Chirality by Cooperative Forces: Growing Polymers and Supramolecular Assemblies -- 5.3.1 Amplification of Chirality in Polymerization -- 5.3.2 Amplification of Chirality in Supramolecular Assemblies -- 5.4 The Yamagata Cumulative Mechanism -- 5.5 The Salam Phase Transition -- 5.6 Amplification of Scalemic Compounds: Eutectic Mixtures |
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| dewey-sort | 3547 41223 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | Second edition. |
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| id | ZDB-4-EBA-on1334564688 |
| illustrated | Not Illustrated |
| indexdate | 2024-11-27T13:30:35Z |
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| isbn | 9781839163685 9781839163692 1839163690 1839163682 |
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| publisher | Royal Society of Chemistry, |
| record_format | marc |
| spelling | Guijarro, Albert, author. http://id.loc.gov/authorities/names/nb2008025182 The origin of chirality in the molecules of life : from awareness to current theories and perspectives of this unsolved problem / Albert Guijarro. Second edition. Cambridge : Royal Society of Chemistry, 2022. 1 online resource (1 volume) text txt rdacontent computer c rdamedia online resource cr rdacarrier Print version record. Intro -- Title -- Copyright -- Contents -- Chapter 1 Introduction and Historical Background -- 1.1 Introduction -- 1.2 The Contribution of Pasteur -- 1.2.1 Quartz -- 1.2.2 Tartaric Acid and the Tartrates -- 1.3 The Nature of the Problem -- References -- Chapter 2 The Concept of Chirality -- 2.1 Introduction -- 2.2 The First Absolute Stereochemical Determination of a Molecule, Again Tartaric Acid -- 2.2.1 X-Ray Crystallography to Determine Absolute Configuration -- 2.2.2 Chiroptical Methods of Absolute Determination -- 2.3 Molecular Symmetry and Chirality -- 2.3.1 Symmetry Elements 2.3.2 Point Groups -- 2.4 True and False Chirality -- 2.5 The Discrete Symmetry Operators -- 2.5.1 The Space Inversion: The Parity Operator, P̂ -- 2.5.2 The Time Reversion: The Time Reversal Operator, T̂ -- 2.5.3 The Charge Conjugation: The Charge Conjugation Operator, Ĉ -- 2.6 The Failure of the Experiments of Pasteur, Curie and Others: Experiments in the Absence of Chirality and Experiments Under the Influence of False or True Chirality -- 2.6.1 Experiments in the Absence of a Chiral Field -- 2.6.2 Experiments Under False Chiral Influence -- 2.6.3 Experiments Under True Chiral Influence 2.7 Expected Effect of True and False Chirality on Molecules -- 2.8 Quantum Mechanical Treatment of Molecular Chirality -- References -- Chapter 3 Theories of the Origin of Biomolecular Homochirality -- 3.1 Introduction -- 3.2 Chance Theories -- 3.2.1 Amplification of Tiny Stochastic Imbalances -- 3.2.2 Polymerizations Above a Critical Chain Length: Macromolecules -- 3.3 Deterministic Theories -- References -- Chapter 4 Chiral Physical Forces -- 4.1 Background -- 4.2 The Weak Interaction and the Parity Violation 5.2.2 Theoretical Models Derived from Frank's Original Model -- 5.2.3 Attempts Looking for Autocatalytic Amplification of the Weak Force -- 5.2.4 Amplification of Chirality in Chemical Reactions -- 5.2.5 Self-replication -- 5.3 Amplification of Chirality by Cooperative Forces: Growing Polymers and Supramolecular Assemblies -- 5.3.1 Amplification of Chirality in Polymerization -- 5.3.2 Amplification of Chirality in Supramolecular Assemblies -- 5.4 The Yamagata Cumulative Mechanism -- 5.5 The Salam Phase Transition -- 5.6 Amplification of Scalemic Compounds: Eutectic Mixtures This book provides an interdisciplinary review of one of the great unsolved mysteries that has fascinated scientists for over 150 years: the origin of chirality in biomolecules. It is fundamental, comprehensive and structured to be accessible for educational purposes. Chirality. http://id.loc.gov/authorities/subjects/sh85024443 Biochemistry. http://id.loc.gov/authorities/subjects/sh85014171 Biochemistry https://id.nlm.nih.gov/mesh/D001671 Chiralité. Biochimie. biochemistry. aat Biochemistry fast Chirality fast has work: The origin of chirality in the molecules of life (Text) https://id.oclc.org/worldcat/entity/E39PCGJYMKVKvmgBPvvHTdqfFX https://id.oclc.org/worldcat/ontology/hasWork Print version: Guijarro, Albert. Origin of chirality in the molecules of life. Second edition. Cambridge : Royal Society of Chemistry, 2021 9781839162343 (OCoLC)1268129966 FWS01 ZDB-4-EBA FWS_PDA_EBA https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=3308369 Volltext |
| spellingShingle | Guijarro, Albert The origin of chirality in the molecules of life : from awareness to current theories and perspectives of this unsolved problem / Intro -- Title -- Copyright -- Contents -- Chapter 1 Introduction and Historical Background -- 1.1 Introduction -- 1.2 The Contribution of Pasteur -- 1.2.1 Quartz -- 1.2.2 Tartaric Acid and the Tartrates -- 1.3 The Nature of the Problem -- References -- Chapter 2 The Concept of Chirality -- 2.1 Introduction -- 2.2 The First Absolute Stereochemical Determination of a Molecule, Again Tartaric Acid -- 2.2.1 X-Ray Crystallography to Determine Absolute Configuration -- 2.2.2 Chiroptical Methods of Absolute Determination -- 2.3 Molecular Symmetry and Chirality -- 2.3.1 Symmetry Elements 2.3.2 Point Groups -- 2.4 True and False Chirality -- 2.5 The Discrete Symmetry Operators -- 2.5.1 The Space Inversion: The Parity Operator, P̂ -- 2.5.2 The Time Reversion: The Time Reversal Operator, T̂ -- 2.5.3 The Charge Conjugation: The Charge Conjugation Operator, Ĉ -- 2.6 The Failure of the Experiments of Pasteur, Curie and Others: Experiments in the Absence of Chirality and Experiments Under the Influence of False or True Chirality -- 2.6.1 Experiments in the Absence of a Chiral Field -- 2.6.2 Experiments Under False Chiral Influence -- 2.6.3 Experiments Under True Chiral Influence 2.7 Expected Effect of True and False Chirality on Molecules -- 2.8 Quantum Mechanical Treatment of Molecular Chirality -- References -- Chapter 3 Theories of the Origin of Biomolecular Homochirality -- 3.1 Introduction -- 3.2 Chance Theories -- 3.2.1 Amplification of Tiny Stochastic Imbalances -- 3.2.2 Polymerizations Above a Critical Chain Length: Macromolecules -- 3.3 Deterministic Theories -- References -- Chapter 4 Chiral Physical Forces -- 4.1 Background -- 4.2 The Weak Interaction and the Parity Violation 5.2.2 Theoretical Models Derived from Frank's Original Model -- 5.2.3 Attempts Looking for Autocatalytic Amplification of the Weak Force -- 5.2.4 Amplification of Chirality in Chemical Reactions -- 5.2.5 Self-replication -- 5.3 Amplification of Chirality by Cooperative Forces: Growing Polymers and Supramolecular Assemblies -- 5.3.1 Amplification of Chirality in Polymerization -- 5.3.2 Amplification of Chirality in Supramolecular Assemblies -- 5.4 The Yamagata Cumulative Mechanism -- 5.5 The Salam Phase Transition -- 5.6 Amplification of Scalemic Compounds: Eutectic Mixtures Chirality. http://id.loc.gov/authorities/subjects/sh85024443 Biochemistry. http://id.loc.gov/authorities/subjects/sh85014171 Biochemistry https://id.nlm.nih.gov/mesh/D001671 Chiralité. Biochimie. biochemistry. aat Biochemistry fast Chirality fast |
| subject_GND | http://id.loc.gov/authorities/subjects/sh85024443 http://id.loc.gov/authorities/subjects/sh85014171 https://id.nlm.nih.gov/mesh/D001671 |
| title | The origin of chirality in the molecules of life : from awareness to current theories and perspectives of this unsolved problem / |
| title_auth | The origin of chirality in the molecules of life : from awareness to current theories and perspectives of this unsolved problem / |
| title_exact_search | The origin of chirality in the molecules of life : from awareness to current theories and perspectives of this unsolved problem / |
| title_full | The origin of chirality in the molecules of life : from awareness to current theories and perspectives of this unsolved problem / Albert Guijarro. |
| title_fullStr | The origin of chirality in the molecules of life : from awareness to current theories and perspectives of this unsolved problem / Albert Guijarro. |
| title_full_unstemmed | The origin of chirality in the molecules of life : from awareness to current theories and perspectives of this unsolved problem / Albert Guijarro. |
| title_short | The origin of chirality in the molecules of life : |
| title_sort | origin of chirality in the molecules of life from awareness to current theories and perspectives of this unsolved problem |
| title_sub | from awareness to current theories and perspectives of this unsolved problem / |
| topic | Chirality. http://id.loc.gov/authorities/subjects/sh85024443 Biochemistry. http://id.loc.gov/authorities/subjects/sh85014171 Biochemistry https://id.nlm.nih.gov/mesh/D001671 Chiralité. Biochimie. biochemistry. aat Biochemistry fast Chirality fast |
| topic_facet | Chirality. Biochemistry. Biochemistry Chiralité. Biochimie. biochemistry. Chirality |
| url | https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=3308369 |
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