Organometallic chemistry /:
Designed for teaching, this book can be used as an introductory text for chemistry undergraduates and will also provide a bridge to more advanced courses.
Gespeichert in:
| Weitere Verfasser: | , |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English Japanese |
| Veröffentlicht: |
Cambridge, UK :
Royal Society of Chemistry,
2021.
|
| Schriftenreihe: | Coordination chemistry fundamentals series ;
1. |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Zusammenfassung: | Designed for teaching, this book can be used as an introductory text for chemistry undergraduates and will also provide a bridge to more advanced courses. |
| Beschreibung: | 1 online resource (xvi, 283 pages) : illustrations (some color) |
| ISBN: | 9781839164200 1839164204 9781839164217 1839164212 |
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| 505 | 0 | |a Intro -- Title -- Copyright -- Preface -- Author Biography -- Contents -- Section 1: Basics -- Chapter 1 What is Organometallic Chemistry -- 1.1 Organic Chemistry and Inorganic Chemistry -- 1.2 Coordination Chemistry -- 1.3 Organometallic Chemistry -- References -- Chapter 2 Basic Concepts Relating to Organometallic Complexes -- 2.1 Introduction -- 2.2 EAN Rule -- 2.3 Eighteen Electron Rule (18e Rule) -- 2.4 Electron Counting -- 2.4.1 Transition Metal -- 2.4.2 Ligand -- 2.4.3 Total Charge of the Complex -- 2.4.4 Importance of Electron Counting | |
| 505 | 8 | |a 3.3.2 Ligand Field Theory (LFT) -- 3.3.3 Reason for the Establishment of the 18e Rule -- 3.4 Reason Why a Four-coordinate d8 Complex Adopts a Square-planar Structure -- References -- Chapter 4 Carbonyl, Olefin and Phosphine Complexes -- 4.1 Introduction -- 4.2 Carbonyl Complexes -- 4.3 Olefin Complexes -- 4.3.1 Change in Oxidation State of the Metal -- 4.3.2 Substituents on the Olefin -- 4.3.3 Fluxionality: Olefin Rotational Motion -- 4.3.4 C C Double Bond Length of the Olefin -- 4.3.5 Bent Back Angle of the Olefin -- 4.4 Phosphine Complexes -- References | |
| 505 | 8 | |a Chapter 5 Carbene Complexes -- Complexes with M C Double Bonds -- 5.1 History of Carbene Complexes -- 5.2 Properties of Carbene Complexes -- 5.3 Reactivity of Carbene Complexes -- References -- Chapter 6 Basic Reactions of Organometallic Complexes -- 6.1 Introduction -- 6.2 Oxidative Addition -- 6.2.1 Vaska's Complex -- 6.2.2 C-H Bond Activation -- 6.2.3 Orthometallation -- 6.2.4 Ease of Oxidative Addition -- 6.3 Reductive Elimination -- 6.3.1 Reductive Elimination in cis-[MR2L2] (L = Phosphine, M = Ni, Pd, Pt) -- 6.3.2 Ease of Reductive Elimination | |
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| 650 | 0 | |a Organometallic chemistry. |0 http://id.loc.gov/authorities/subjects/sh86004134 | |
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| contents | Intro -- Title -- Copyright -- Preface -- Author Biography -- Contents -- Section 1: Basics -- Chapter 1 What is Organometallic Chemistry -- 1.1 Organic Chemistry and Inorganic Chemistry -- 1.2 Coordination Chemistry -- 1.3 Organometallic Chemistry -- References -- Chapter 2 Basic Concepts Relating to Organometallic Complexes -- 2.1 Introduction -- 2.2 EAN Rule -- 2.3 Eighteen Electron Rule (18e Rule) -- 2.4 Electron Counting -- 2.4.1 Transition Metal -- 2.4.2 Ligand -- 2.4.3 Total Charge of the Complex -- 2.4.4 Importance of Electron Counting 3.3.2 Ligand Field Theory (LFT) -- 3.3.3 Reason for the Establishment of the 18e Rule -- 3.4 Reason Why a Four-coordinate d8 Complex Adopts a Square-planar Structure -- References -- Chapter 4 Carbonyl, Olefin and Phosphine Complexes -- 4.1 Introduction -- 4.2 Carbonyl Complexes -- 4.3 Olefin Complexes -- 4.3.1 Change in Oxidation State of the Metal -- 4.3.2 Substituents on the Olefin -- 4.3.3 Fluxionality: Olefin Rotational Motion -- 4.3.4 C C Double Bond Length of the Olefin -- 4.3.5 Bent Back Angle of the Olefin -- 4.4 Phosphine Complexes -- References Chapter 5 Carbene Complexes -- Complexes with M C Double Bonds -- 5.1 History of Carbene Complexes -- 5.2 Properties of Carbene Complexes -- 5.3 Reactivity of Carbene Complexes -- References -- Chapter 6 Basic Reactions of Organometallic Complexes -- 6.1 Introduction -- 6.2 Oxidative Addition -- 6.2.1 Vaska's Complex -- 6.2.2 C-H Bond Activation -- 6.2.3 Orthometallation -- 6.2.4 Ease of Oxidative Addition -- 6.3 Reductive Elimination -- 6.3.1 Reductive Elimination in cis-[MR2L2] (L = Phosphine, M = Ni, Pd, Pt) -- 6.3.2 Ease of Reductive Elimination |
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| discipline | Chemie / Pharmazie |
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| id | ZDB-4-EBA-on1261762247 |
| illustrated | Illustrated |
| indexdate | 2024-11-27T13:30:21Z |
| institution | BVB |
| isbn | 9781839164200 1839164204 9781839164217 1839164212 |
| language | English Japanese |
| oclc_num | 1261762247 |
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| physical | 1 online resource (xvi, 283 pages) : illustrations (some color) |
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| publisher | Royal Society of Chemistry, |
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| series | Coordination chemistry fundamentals series ; |
| series2 | Coordination chemistry fundamentals |
| spelling | Organometallic chemistry / editors: Hiroshi Nakazawa, Julian Koe. Cambridge, UK : Royal Society of Chemistry, 2021. 1 online resource (xvi, 283 pages) : illustrations (some color) text txt rdacontent computer c rdamedia online resource cr rdacarrier Coordination chemistry fundamentals Print version record. Intro -- Title -- Copyright -- Preface -- Author Biography -- Contents -- Section 1: Basics -- Chapter 1 What is Organometallic Chemistry -- 1.1 Organic Chemistry and Inorganic Chemistry -- 1.2 Coordination Chemistry -- 1.3 Organometallic Chemistry -- References -- Chapter 2 Basic Concepts Relating to Organometallic Complexes -- 2.1 Introduction -- 2.2 EAN Rule -- 2.3 Eighteen Electron Rule (18e Rule) -- 2.4 Electron Counting -- 2.4.1 Transition Metal -- 2.4.2 Ligand -- 2.4.3 Total Charge of the Complex -- 2.4.4 Importance of Electron Counting 3.3.2 Ligand Field Theory (LFT) -- 3.3.3 Reason for the Establishment of the 18e Rule -- 3.4 Reason Why a Four-coordinate d8 Complex Adopts a Square-planar Structure -- References -- Chapter 4 Carbonyl, Olefin and Phosphine Complexes -- 4.1 Introduction -- 4.2 Carbonyl Complexes -- 4.3 Olefin Complexes -- 4.3.1 Change in Oxidation State of the Metal -- 4.3.2 Substituents on the Olefin -- 4.3.3 Fluxionality: Olefin Rotational Motion -- 4.3.4 C C Double Bond Length of the Olefin -- 4.3.5 Bent Back Angle of the Olefin -- 4.4 Phosphine Complexes -- References Chapter 5 Carbene Complexes -- Complexes with M C Double Bonds -- 5.1 History of Carbene Complexes -- 5.2 Properties of Carbene Complexes -- 5.3 Reactivity of Carbene Complexes -- References -- Chapter 6 Basic Reactions of Organometallic Complexes -- 6.1 Introduction -- 6.2 Oxidative Addition -- 6.2.1 Vaska's Complex -- 6.2.2 C-H Bond Activation -- 6.2.3 Orthometallation -- 6.2.4 Ease of Oxidative Addition -- 6.3 Reductive Elimination -- 6.3.1 Reductive Elimination in cis-[MR2L2] (L = Phosphine, M = Ni, Pd, Pt) -- 6.3.2 Ease of Reductive Elimination Designed for teaching, this book can be used as an introductory text for chemistry undergraduates and will also provide a bridge to more advanced courses. Organometallic chemistry. http://id.loc.gov/authorities/subjects/sh86004134 Chimie organométallique. Organometallic chemistry fast Nakazawa, Hiroshi, 1952- editor. https://id.oclc.org/worldcat/entity/E39PCjM7Xp7xWrfVbKHybWGkcP http://id.loc.gov/authorities/names/no2022047016 Koe, Julian (Julian R.), editor. http://id.loc.gov/authorities/names/no2022047030 Print version: ORGANOMETALLIC CHEMISTRY. [Place of publication not identified] : ROYAL SOCIETY OF CHEMISTR, 2021 1839164069 (OCoLC)1223069511 Coordination chemistry fundamentals series ; 1. http://id.loc.gov/authorities/names/no2022046998 FWS01 ZDB-4-EBA FWS_PDA_EBA https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=2970166 Volltext |
| spellingShingle | Organometallic chemistry / Coordination chemistry fundamentals series ; Intro -- Title -- Copyright -- Preface -- Author Biography -- Contents -- Section 1: Basics -- Chapter 1 What is Organometallic Chemistry -- 1.1 Organic Chemistry and Inorganic Chemistry -- 1.2 Coordination Chemistry -- 1.3 Organometallic Chemistry -- References -- Chapter 2 Basic Concepts Relating to Organometallic Complexes -- 2.1 Introduction -- 2.2 EAN Rule -- 2.3 Eighteen Electron Rule (18e Rule) -- 2.4 Electron Counting -- 2.4.1 Transition Metal -- 2.4.2 Ligand -- 2.4.3 Total Charge of the Complex -- 2.4.4 Importance of Electron Counting 3.3.2 Ligand Field Theory (LFT) -- 3.3.3 Reason for the Establishment of the 18e Rule -- 3.4 Reason Why a Four-coordinate d8 Complex Adopts a Square-planar Structure -- References -- Chapter 4 Carbonyl, Olefin and Phosphine Complexes -- 4.1 Introduction -- 4.2 Carbonyl Complexes -- 4.3 Olefin Complexes -- 4.3.1 Change in Oxidation State of the Metal -- 4.3.2 Substituents on the Olefin -- 4.3.3 Fluxionality: Olefin Rotational Motion -- 4.3.4 C C Double Bond Length of the Olefin -- 4.3.5 Bent Back Angle of the Olefin -- 4.4 Phosphine Complexes -- References Chapter 5 Carbene Complexes -- Complexes with M C Double Bonds -- 5.1 History of Carbene Complexes -- 5.2 Properties of Carbene Complexes -- 5.3 Reactivity of Carbene Complexes -- References -- Chapter 6 Basic Reactions of Organometallic Complexes -- 6.1 Introduction -- 6.2 Oxidative Addition -- 6.2.1 Vaska's Complex -- 6.2.2 C-H Bond Activation -- 6.2.3 Orthometallation -- 6.2.4 Ease of Oxidative Addition -- 6.3 Reductive Elimination -- 6.3.1 Reductive Elimination in cis-[MR2L2] (L = Phosphine, M = Ni, Pd, Pt) -- 6.3.2 Ease of Reductive Elimination Organometallic chemistry. http://id.loc.gov/authorities/subjects/sh86004134 Chimie organométallique. Organometallic chemistry fast |
| subject_GND | http://id.loc.gov/authorities/subjects/sh86004134 |
| title | Organometallic chemistry / |
| title_auth | Organometallic chemistry / |
| title_exact_search | Organometallic chemistry / |
| title_full | Organometallic chemistry / editors: Hiroshi Nakazawa, Julian Koe. |
| title_fullStr | Organometallic chemistry / editors: Hiroshi Nakazawa, Julian Koe. |
| title_full_unstemmed | Organometallic chemistry / editors: Hiroshi Nakazawa, Julian Koe. |
| title_short | Organometallic chemistry / |
| title_sort | organometallic chemistry |
| topic | Organometallic chemistry. http://id.loc.gov/authorities/subjects/sh86004134 Chimie organométallique. Organometallic chemistry fast |
| topic_facet | Organometallic chemistry. Chimie organométallique. Organometallic chemistry |
| url | https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=2970166 |
| work_keys_str_mv | AT nakazawahiroshi organometallicchemistry AT koejulian organometallicchemistry |