Nitroxides :: synthesis, properties and applications /
Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building...
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Cambridge :
Royal Society of Chemistry,
2021.
|
| Schlagworte: | |
| Online-Zugang: | DE-862 DE-863 |
| Zusammenfassung: | Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science. |
| Beschreibung: | 1 online resource |
| ISBN: | 9781788019651 1788019652 9781788019668 1788019660 |
Internformat
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| 520 | |a Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science. | ||
| 505 | 0 | |a Intro -- Title -- Copyright -- Contents -- Chapter 1 A Brief History and Outlook of Nitroxides -- 1.1 Brief History -- 1.2 Nitroxide Reactivity -- 1.3 Conclusion -- References -- Chapter 2 General Approaches to Synthesis of Nitroxides -- 2.1 What are Nitroxides. Limits of Nitroxide Stability -- 2.2 Nitroxide Group Formation -- 2.2.1 From Amines -- 2.2.2 From Hydroxylamines -- 2.2.3 From Alkoxyamines -- 2.2.4 From Nitrones -- 2.3 Some Contemporary Trends in Nitroxide Chemistry | |
| 505 | 8 | |a 2.3.1 Influence of Structural Factors upon Redox Properties of Nitroxides: The Fight for Stability in Biological Systems -- 2.3.2 Electron Spin Relaxation -- 2.4 The Most Important Nitroxide Classes -- 2.4.1 Piperidine Nitroxides -- 2.4.2 Pyrroline Nitroxides -- 2.4.3 Pyrrolidine Nitroxides -- 2.4.4 Isoindoline Nitroxides -- 2.4.5 3-Imidazoline and Imidazolidine Nitroxides -- 2.5 Cyclic Conjugated Nitroxides -- 2.5.1 4,5-Dihydroimidazole-1-oxyls -- 2.5.2 Nitronyl Nitroxides of Benzimidazole Series (BenzoNNRs) -- 2.5.3 Heterocyclic Vinyl Nitroxides -- 2.6 Conclusion -- Acknowledgements | |
| 505 | 8 | |a 3.6 Nitroxide-mediated C-C Bond Formation Reactions -- 3.7 Miscellaneous Reactions Mediated by Nitroxides -- 3.8 Conclusion -- References -- Chapter 4 Spin Probes and Imaging Using Nitroxides -- 4.1 Introduction -- 4.2 NR Oxymetric Probes and EPR Oximetry -- 4.2.1 Basics of EPR Sensitivity of the Nitroxide Probes to Oxygen -- 4.2.2 In Vivo EPR Oximetry Using Nitroxide Probes -- 4.3 NR pH Probes -- 4.3.1 Basics of Spectral Sensitivity of the Nitroxides to pH -- 4.3.2 In Vivo Spectroscopy and Imaging of pH Using Nitroxide Probes -- 4.4 NRs as Thiol-sensitive Probes | |
| 505 | 8 | |a 4.4.1 Basics of GSH Detection Using Nitroxide Probes -- 4.4.2 In Vivo EPR Measurements of Intracellular Glutathione -- 4.5 NRs as Probes for Assessment of Enzymatically Catalyzed Reactions -- 4.6 Conclusion -- Acknowledgements -- References -- Chapter 5 Nitroxides in Battery-related Applications -- 5.1 Context -- 5.2 Organic Batteries Based on Nitroxide Radicals -- 5.3 Variations of Nitroxide Polymer Structures and Their Related Properties -- 5.4 Nanostructures in Nitroxide Polymer Electrodes -- 5.5 Grafting of Nitroxide-containing Polymers onto Carbon Nanotubes | |
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Datensatz im Suchindex
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| contents | Intro -- Title -- Copyright -- Contents -- Chapter 1 A Brief History and Outlook of Nitroxides -- 1.1 Brief History -- 1.2 Nitroxide Reactivity -- 1.3 Conclusion -- References -- Chapter 2 General Approaches to Synthesis of Nitroxides -- 2.1 What are Nitroxides. Limits of Nitroxide Stability -- 2.2 Nitroxide Group Formation -- 2.2.1 From Amines -- 2.2.2 From Hydroxylamines -- 2.2.3 From Alkoxyamines -- 2.2.4 From Nitrones -- 2.3 Some Contemporary Trends in Nitroxide Chemistry 2.3.1 Influence of Structural Factors upon Redox Properties of Nitroxides: The Fight for Stability in Biological Systems -- 2.3.2 Electron Spin Relaxation -- 2.4 The Most Important Nitroxide Classes -- 2.4.1 Piperidine Nitroxides -- 2.4.2 Pyrroline Nitroxides -- 2.4.3 Pyrrolidine Nitroxides -- 2.4.4 Isoindoline Nitroxides -- 2.4.5 3-Imidazoline and Imidazolidine Nitroxides -- 2.5 Cyclic Conjugated Nitroxides -- 2.5.1 4,5-Dihydroimidazole-1-oxyls -- 2.5.2 Nitronyl Nitroxides of Benzimidazole Series (BenzoNNRs) -- 2.5.3 Heterocyclic Vinyl Nitroxides -- 2.6 Conclusion -- Acknowledgements 3.6 Nitroxide-mediated C-C Bond Formation Reactions -- 3.7 Miscellaneous Reactions Mediated by Nitroxides -- 3.8 Conclusion -- References -- Chapter 4 Spin Probes and Imaging Using Nitroxides -- 4.1 Introduction -- 4.2 NR Oxymetric Probes and EPR Oximetry -- 4.2.1 Basics of EPR Sensitivity of the Nitroxide Probes to Oxygen -- 4.2.2 In Vivo EPR Oximetry Using Nitroxide Probes -- 4.3 NR pH Probes -- 4.3.1 Basics of Spectral Sensitivity of the Nitroxides to pH -- 4.3.2 In Vivo Spectroscopy and Imaging of pH Using Nitroxide Probes -- 4.4 NRs as Thiol-sensitive Probes 4.4.1 Basics of GSH Detection Using Nitroxide Probes -- 4.4.2 In Vivo EPR Measurements of Intracellular Glutathione -- 4.5 NRs as Probes for Assessment of Enzymatically Catalyzed Reactions -- 4.6 Conclusion -- Acknowledgements -- References -- Chapter 5 Nitroxides in Battery-related Applications -- 5.1 Context -- 5.2 Organic Batteries Based on Nitroxide Radicals -- 5.3 Variations of Nitroxide Polymer Structures and Their Related Properties -- 5.4 Nanostructures in Nitroxide Polymer Electrodes -- 5.5 Grafting of Nitroxide-containing Polymers onto Carbon Nanotubes |
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| illustrated | Not Illustrated |
| indexdate | 2025-03-18T14:26:24Z |
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| publisher | Royal Society of Chemistry, |
| record_format | marc |
| spelling | Nitroxides : synthesis, properties and applications / edited by Olivier Ouari, Didier Gigmes. Cambridge : Royal Society of Chemistry, 2021. 1 online resource text txt rdacontent computer c rdamedia online resource cr rdacarrier Print version record. Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science. Intro -- Title -- Copyright -- Contents -- Chapter 1 A Brief History and Outlook of Nitroxides -- 1.1 Brief History -- 1.2 Nitroxide Reactivity -- 1.3 Conclusion -- References -- Chapter 2 General Approaches to Synthesis of Nitroxides -- 2.1 What are Nitroxides. Limits of Nitroxide Stability -- 2.2 Nitroxide Group Formation -- 2.2.1 From Amines -- 2.2.2 From Hydroxylamines -- 2.2.3 From Alkoxyamines -- 2.2.4 From Nitrones -- 2.3 Some Contemporary Trends in Nitroxide Chemistry 2.3.1 Influence of Structural Factors upon Redox Properties of Nitroxides: The Fight for Stability in Biological Systems -- 2.3.2 Electron Spin Relaxation -- 2.4 The Most Important Nitroxide Classes -- 2.4.1 Piperidine Nitroxides -- 2.4.2 Pyrroline Nitroxides -- 2.4.3 Pyrrolidine Nitroxides -- 2.4.4 Isoindoline Nitroxides -- 2.4.5 3-Imidazoline and Imidazolidine Nitroxides -- 2.5 Cyclic Conjugated Nitroxides -- 2.5.1 4,5-Dihydroimidazole-1-oxyls -- 2.5.2 Nitronyl Nitroxides of Benzimidazole Series (BenzoNNRs) -- 2.5.3 Heterocyclic Vinyl Nitroxides -- 2.6 Conclusion -- Acknowledgements 3.6 Nitroxide-mediated C-C Bond Formation Reactions -- 3.7 Miscellaneous Reactions Mediated by Nitroxides -- 3.8 Conclusion -- References -- Chapter 4 Spin Probes and Imaging Using Nitroxides -- 4.1 Introduction -- 4.2 NR Oxymetric Probes and EPR Oximetry -- 4.2.1 Basics of EPR Sensitivity of the Nitroxide Probes to Oxygen -- 4.2.2 In Vivo EPR Oximetry Using Nitroxide Probes -- 4.3 NR pH Probes -- 4.3.1 Basics of Spectral Sensitivity of the Nitroxides to pH -- 4.3.2 In Vivo Spectroscopy and Imaging of pH Using Nitroxide Probes -- 4.4 NRs as Thiol-sensitive Probes 4.4.1 Basics of GSH Detection Using Nitroxide Probes -- 4.4.2 In Vivo EPR Measurements of Intracellular Glutathione -- 4.5 NRs as Probes for Assessment of Enzymatically Catalyzed Reactions -- 4.6 Conclusion -- Acknowledgements -- References -- Chapter 5 Nitroxides in Battery-related Applications -- 5.1 Context -- 5.2 Organic Batteries Based on Nitroxide Radicals -- 5.3 Variations of Nitroxide Polymer Structures and Their Related Properties -- 5.4 Nanostructures in Nitroxide Polymer Electrodes -- 5.5 Grafting of Nitroxide-containing Polymers onto Carbon Nanotubes Nitroxides. http://id.loc.gov/authorities/subjects/sh93001861 Radicaux aminoxyles. Nitroxides fast Chemistry Science Ouari, Olivier, editor. Gigmes, Didier, editor. has work: Nitroxides (Text) https://id.oclc.org/worldcat/entity/E39PCYjWQd4MbtmdRVRTrvh9Mq https://id.oclc.org/worldcat/ontology/hasWork Print version: Nitroxides. Cambridge : Royal Society of Chemistry, 2021 9781788019651 (OCoLC)1242738095 |
| spellingShingle | Nitroxides : synthesis, properties and applications / Intro -- Title -- Copyright -- Contents -- Chapter 1 A Brief History and Outlook of Nitroxides -- 1.1 Brief History -- 1.2 Nitroxide Reactivity -- 1.3 Conclusion -- References -- Chapter 2 General Approaches to Synthesis of Nitroxides -- 2.1 What are Nitroxides. Limits of Nitroxide Stability -- 2.2 Nitroxide Group Formation -- 2.2.1 From Amines -- 2.2.2 From Hydroxylamines -- 2.2.3 From Alkoxyamines -- 2.2.4 From Nitrones -- 2.3 Some Contemporary Trends in Nitroxide Chemistry 2.3.1 Influence of Structural Factors upon Redox Properties of Nitroxides: The Fight for Stability in Biological Systems -- 2.3.2 Electron Spin Relaxation -- 2.4 The Most Important Nitroxide Classes -- 2.4.1 Piperidine Nitroxides -- 2.4.2 Pyrroline Nitroxides -- 2.4.3 Pyrrolidine Nitroxides -- 2.4.4 Isoindoline Nitroxides -- 2.4.5 3-Imidazoline and Imidazolidine Nitroxides -- 2.5 Cyclic Conjugated Nitroxides -- 2.5.1 4,5-Dihydroimidazole-1-oxyls -- 2.5.2 Nitronyl Nitroxides of Benzimidazole Series (BenzoNNRs) -- 2.5.3 Heterocyclic Vinyl Nitroxides -- 2.6 Conclusion -- Acknowledgements 3.6 Nitroxide-mediated C-C Bond Formation Reactions -- 3.7 Miscellaneous Reactions Mediated by Nitroxides -- 3.8 Conclusion -- References -- Chapter 4 Spin Probes and Imaging Using Nitroxides -- 4.1 Introduction -- 4.2 NR Oxymetric Probes and EPR Oximetry -- 4.2.1 Basics of EPR Sensitivity of the Nitroxide Probes to Oxygen -- 4.2.2 In Vivo EPR Oximetry Using Nitroxide Probes -- 4.3 NR pH Probes -- 4.3.1 Basics of Spectral Sensitivity of the Nitroxides to pH -- 4.3.2 In Vivo Spectroscopy and Imaging of pH Using Nitroxide Probes -- 4.4 NRs as Thiol-sensitive Probes 4.4.1 Basics of GSH Detection Using Nitroxide Probes -- 4.4.2 In Vivo EPR Measurements of Intracellular Glutathione -- 4.5 NRs as Probes for Assessment of Enzymatically Catalyzed Reactions -- 4.6 Conclusion -- Acknowledgements -- References -- Chapter 5 Nitroxides in Battery-related Applications -- 5.1 Context -- 5.2 Organic Batteries Based on Nitroxide Radicals -- 5.3 Variations of Nitroxide Polymer Structures and Their Related Properties -- 5.4 Nanostructures in Nitroxide Polymer Electrodes -- 5.5 Grafting of Nitroxide-containing Polymers onto Carbon Nanotubes Nitroxides. http://id.loc.gov/authorities/subjects/sh93001861 Radicaux aminoxyles. Nitroxides fast |
| subject_GND | http://id.loc.gov/authorities/subjects/sh93001861 |
| title | Nitroxides : synthesis, properties and applications / |
| title_auth | Nitroxides : synthesis, properties and applications / |
| title_exact_search | Nitroxides : synthesis, properties and applications / |
| title_full | Nitroxides : synthesis, properties and applications / edited by Olivier Ouari, Didier Gigmes. |
| title_fullStr | Nitroxides : synthesis, properties and applications / edited by Olivier Ouari, Didier Gigmes. |
| title_full_unstemmed | Nitroxides : synthesis, properties and applications / edited by Olivier Ouari, Didier Gigmes. |
| title_short | Nitroxides : |
| title_sort | nitroxides synthesis properties and applications |
| title_sub | synthesis, properties and applications / |
| topic | Nitroxides. http://id.loc.gov/authorities/subjects/sh93001861 Radicaux aminoxyles. Nitroxides fast |
| topic_facet | Nitroxides. Radicaux aminoxyles. Nitroxides |
| work_keys_str_mv | AT ouariolivier nitroxidessynthesispropertiesandapplications AT gigmesdidier nitroxidessynthesispropertiesandapplications |