Water in biological and chemical processes :: from structure and dynamics to function /
Building up from microscopic basics to observed complex functions, this insightful monograph explains and describes how the unique molecular properties of water give rise to its structural and dynamical behaviour which in turn translates into its role in biological and chemical processes. The discus...
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| 1. Verfasser: | |
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Cambridge :
Cambridge University Press,
2013.
|
| Schriftenreihe: | Cambridge molecular science series.
|
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Zusammenfassung: | Building up from microscopic basics to observed complex functions, this insightful monograph explains and describes how the unique molecular properties of water give rise to its structural and dynamical behaviour which in turn translates into its role in biological and chemical processes. The discussion of the biological functions of water details not only the stabilising effect of water in proteins and DNA, but also the direct role that water molecules themselves play in biochemical processes, such as enzyme kinetics, protein synthesis and drug-DNA interaction. The overview of the behaviour of water in chemical systems discusses hydrophilic, hydrophobic and amphiphilic effects, as well as the interactions of water with micelles, reverse micelles, microemulsions and carbon nanotubes. Supported by extensive experimental and computer simulation data, highlighting many of the recent advances in the study of water in complex systems, this is an ideal resource for anyone studying water at the molecular level. |
| Beschreibung: | 1 online resource (xviii, 356 pages) |
| Bibliographie: | Includes bibliographical references and index. |
| ISBN: | 9781107416765 1107416760 9781139583947 1139583948 9781680159929 1680159925 |
| Zugangseinschränkungen: | Access restricted to Ryerson students, faculty and staff. |
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| 505 | 0 | |6 880-01 |a Part I. Bulk Water: 1. Uniqueness of water -- 2. Anomalies of water -- 3. Dynamics of water: molecular motions and hydrogen bond breaking kinetics -- 4. Inherent structures of liquid water -- 5. pH of water -- Part II. Water in Biology: Dynamical View and Function: 6. Biological water -- 7. Explicit role of water in biological functions -- 8. Hydration of proteins -- 9. Can we understand protein hydration layer: lessons from computer simulations -- 10. Water in and around DNA and RNA -- 11. Role of water in protein-DNA interaction -- 12. Water surrounding lipid bilayers -- 13. Water in Darwin's world -- Part III. Water in Complex Chemical Systems: 14. Hydrophilic effects -- 15. Hydrophobic effects -- 16. Aqueous binary mixtures: amphiphilic effect -- 17. Water in and around micelles, reverse micelles and microemulsions -- 18. Water in carbon nanotubes -- Part IV. Bulk Water: Advanced Topics: 19. Entropy of water -- 20. Freezing of water into ice -- 21. Supercritical water -- 22. Microscopic approaches to understand water anomalies. | |
| 520 | |a Building up from microscopic basics to observed complex functions, this insightful monograph explains and describes how the unique molecular properties of water give rise to its structural and dynamical behaviour which in turn translates into its role in biological and chemical processes. The discussion of the biological functions of water details not only the stabilising effect of water in proteins and DNA, but also the direct role that water molecules themselves play in biochemical processes, such as enzyme kinetics, protein synthesis and drug-DNA interaction. The overview of the behaviour of water in chemical systems discusses hydrophilic, hydrophobic and amphiphilic effects, as well as the interactions of water with micelles, reverse micelles, microemulsions and carbon nanotubes. Supported by extensive experimental and computer simulation data, highlighting many of the recent advances in the study of water in complex systems, this is an ideal resource for anyone studying water at the molecular level. | ||
| 506 | |a Access restricted to Ryerson students, faculty and staff. |5 CaOTR | ||
| 650 | 0 | |a Water in the body. |0 http://id.loc.gov/authorities/subjects/sh85145573 | |
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| 880 | 0 | 0 | |6 505-01/(S |g Machine generated contents note: |g pt. I |t Bulk water -- |g 1. |t Uniqueness of water -- |g 1.1. |t Introduction -- |g 1.2. |t Molecular structure -- |g 1.3. |t Six unique features -- |g 1.4. |t Modeling of water -- |g 1.5. |t Conclusion -- |g 2. |t Anomalies of water -- |g 2.1. |t Anomalous properties -- |g 2.1.1. |t Density maximum -- |g 2.1.2. |t Isobaric specific heat (CP) -- |g 2.1.3. |t Isothermal compressibility (κT) -- |g 2.1.4. |t Coefficient of thermal expansion (αP) -- |g 2.1.5. |t Dynamic anomalies present at low temperature -- |g 2.2. |t Translational and orientational order -- |g 2.3. |t Temperature--density range of water anomalies -- |g 2.4. |t Conclusion -- |g Appendix 2.A |t Microscopic expressions of specific heat, isothermal compressibility, and coefficient of thermal expansion -- |g Appendix 2.B |t Quantification of spatial order in water -- |g 3. |t Dynamics of water: molecular motions and hydrogen-bond-breaking kinetics -- |g 3.1. |t Introduction -- |g 3.2. |t Timescales of translational and rotational motion -- |g 3.3. |t Jump reorientation motion in water -- |g 3.4. |t Effects of temperature on water motion -- |g 3.5. |t Translational diffusion -- |g 3.6. |t Hydrogen-bond lifetime dynamics -- |g 3.7. |t Vibrational dynamics of the O--H bond -- |g 3.8. |t Dielectric relaxation -- |g 3.9. |t Solvation dynamics -- |g 3.10. |t Ionic conductivity of rigid ions in water -- |g 3.11. |t Electron transfer reactions in water -- |g 3.12. |t Motion becomes collective at low temperature -- |g 3.13. |t Conclusion -- |g Appendix 3.A |t Rotational time correlation functions -- |g Appendix 3.B |t Quantification of hydrogen-bond lifetime dynamics -- |g 4. |t Inherent structures of liquid water -- |g 4.1. |t Introduction -- |g 4.2. |t Transition between inherent structures of water -- |g 4.3. |t Connected water cluster moves during transition -- |g 4.4. |t HB network restructuring -- |g 4.5. |t Coordination number fluctuation in inherent structure and corresponding dynamics in parent liquid -- |g 4.6. |t Low-energy excitations in liquid water -- |g 4.7. |t Conclusion -- |g 5. |t pH of water -- |g 5.1. |t Introduction -- |g 5.2. |t Temperature and pressure dependence of pH -- |g 5.3. |t Mechanism of autoionization -- |g 5.4. |t pH of blood -- |g 5.5. |t Food and blood pH -- |g 5.6. |t pH of seawater -- |g 5.7. |t Conclusion -- |g pt. II |t Water in biology -- |g 6. |t Biological water -- |g 6.1. |t Introduction -- |g 6.2. |t Relaxation measurements -- |g 6.3. |t Unique characteristics of biological water -- |g 6.4. |t Phenomenological models and simple theories -- |g 6.5. |t Protein--glass transition and hydration-layer dynamics -- |g 6.6. |t Protein aggregation and biological water -- |g 6.7. |t Conclusion -- |g Appendix 6 |t The dynamic exchange model -- |g 7. |t essential chemical for life processes: water in biological functions -- |g 7.1. |t Introduction -- |g 7.2. |t Role of water in enzyme kinetics -- |g 7.3. |t Role of water in drug--DNA intercalation -- |g 7.4. |t Role of water in the biological function of RNA -- |g 7.5. |t Water-mediated molecular recognition -- |g 7.6. |t Protein folding and protein association: role of biological water -- |g 7.7. |t Role of water in beta-amyloid aggregation in Alzheimer disease -- |g 7.7.1. |t Role of water in the early stages of oligomer formation -- |g 7.7.2. |t Role of water in the late stages of fibril growth -- |g 7.8. |t Role of water in photosynthesis -- |g 7.9. |t Conclusion -- |g 8. |t Hydration of proteins -- |g 8.1. |t Introduction -- |g 8.2. |t What is the thickness of the hydration shell-- |g 8.3. |t How structured is the water in the hydration shell of a protein-- |g 8.4. |t Orientational arrangement of water molecules at the surface -- |g 8.5. |t Dynamics of the protein hydration shell: experimental studies -- |g 8.5.1. |t Dielectric spectrum -- |g 8.5.2. |t Nuclear magnetic resonance studies -- |g 8.5.3. |t Quasi-elastic neutron-scattering experiments -- |g 8.5.4. |t Vibrational spectroscopy -- |g 8.5.5. |t Solvation dynamics -- |g 8.6. |t Conclusion -- |g Appendix 8.A |t Orientation of water molecules in the hydration layer -- |g 9. |t Understanding the protein hydration layer: lessons from computer simulations -- |g 9.1. |t Introduction -- |g 9.2. |t Molecular motion in the hydration layer -- |g 9.3. |t Hydrogen-bond lifetime dynamics -- |g 9.4. |t Computer simulation of solvation dynamics -- |g 9.5. |t Dielectric relaxation -- |g 9.6. |t Explanation of anomalous dynamics in the hydration layer -- |g 9.7. |t Protein--glass transition at 200 K: role of water dynamics -- |g 9.8. |t Free-energy barrier for escape of water molecules from protein hydration layer -- |g 9.9. |t Conclusion -- |g 10. |t Water in and around DNA and RNA -- |g 10.1. |t Introduction: the unique role of water in stabilizing DNA and RNA -- |g 10.2. |t Hydration of different constituents -- |g 10.3. |t Groove structure and water dynamics -- |g 10.4. |t Translational and rotational dynamics of water molecules in the grooves -- |g 10.5. |t Solvation dynamics -- |g 10.6. |t Entropy of groove water and dynamics -- |g 10.7. |t Correlation between diffusion and entropy: Adam--Gibbs relation -- |g 10.8. |t Sequence dependence of DNA hydration: spine of hydration in AT minor groove -- |g 10.9. |t Effects of nanoconfinement and surface-specific interactions -- |g 10.10. |t Water around RNA -- |g 10.10.1. |t Structure of water around RNA -- |g 10.10.2. |t Dynamics of water around RNA -- |g 10.11. |t Conclusion -- |g Appendix 10.A |t Hydrogen-bonding pattern around DNA -- |g 11. |t Protein--DNA interaction: the role of water as a facilitator -- |g 11.1. |t Introduction -- |g 11.2. |t Structural analysis of protein--DNA complex: classification of hydration water -- |g 11.3. |t Dynamics of water around a protein--DNA complex -- |g 11.4. |t Role of water in thermodynamics of protein--DNA interactions -- |g 11.5. |t Protein diffusion along DNA -- |g 11.6. |t Conclusion -- |g 12. |t Water surrounding lipid bilayers: its role as a lubricant -- |g 12.1. |t Introduction -- |g 12.2. |t Hydration of different constituents: phospholipids and buried proteins -- |g 12.3. |t Rugged energy landscape for water motion -- |g 12.4. |t Translational and rotational dynamics of water -- |g 12.5. |t Solvation dynamics -- |g 12.6. |t Transport of small molecules across the bilayer -- |g 12.7. |t Transport of large molecules across the bilayer -- |g 12.8. |t Electrostatic potential across the membrane -- |g 12.9. |t Conclusion -- |g 13. |t role of water in biochemical selection and protein synthesis -- |g 13.1. |t Introduction -- |g 13.2. |t Role of water in kinetic proofreading -- |g 13.2.1. |t Brief analysis of the Hopefield--Ninio approach to kinetic proofreading -- |g 13.2.2. |t Analysis of experimental results in the light of the Hopfield--Ninio formulation -- |g 13.2.3. |t Aminoacylation of tRNA during protein synthesis -- |g 13.2.4. |t tRNA selection in ribosome -- |g 13.2.5. |t DNA replication -- |g 13.3. |t Water as a lubricant of life -- |g 13.4. |t Conclusion -- |g pt. |
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Datensatz im Suchindex
| DE-BY-FWS_katkey | ZDB-4-EBA-ocn867631290 |
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| adam_text | |
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| author | Bagchi, B. (Biman) |
| author_GND | http://id.loc.gov/authorities/names/nr92020039 |
| author_facet | Bagchi, B. (Biman) |
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| collection | ZDB-4-EBA |
| contents | Part I. Bulk Water: 1. Uniqueness of water -- 2. Anomalies of water -- 3. Dynamics of water: molecular motions and hydrogen bond breaking kinetics -- 4. Inherent structures of liquid water -- 5. pH of water -- Part II. Water in Biology: Dynamical View and Function: 6. Biological water -- 7. Explicit role of water in biological functions -- 8. Hydration of proteins -- 9. Can we understand protein hydration layer: lessons from computer simulations -- 10. Water in and around DNA and RNA -- 11. Role of water in protein-DNA interaction -- 12. Water surrounding lipid bilayers -- 13. Water in Darwin's world -- Part III. Water in Complex Chemical Systems: 14. Hydrophilic effects -- 15. Hydrophobic effects -- 16. Aqueous binary mixtures: amphiphilic effect -- 17. Water in and around micelles, reverse micelles and microemulsions -- 18. Water in carbon nanotubes -- Part IV. Bulk Water: Advanced Topics: 19. Entropy of water -- 20. Freezing of water into ice -- 21. Supercritical water -- 22. Microscopic approaches to understand water anomalies. |
| ctrlnum | (OCoLC)867631290 |
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| dewey-ones | 612 - Human physiology |
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| dewey-search | 612/.01522 |
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Bulk Water: 1. Uniqueness of water -- 2. Anomalies of water -- 3. Dynamics of water: molecular motions and hydrogen bond breaking kinetics -- 4. Inherent structures of liquid water -- 5. pH of water -- Part II. Water in Biology: Dynamical View and Function: 6. Biological water -- 7. Explicit role of water in biological functions -- 8. Hydration of proteins -- 9. Can we understand protein hydration layer: lessons from computer simulations -- 10. Water in and around DNA and RNA -- 11. Role of water in protein-DNA interaction -- 12. Water surrounding lipid bilayers -- 13. Water in Darwin's world -- Part III. Water in Complex Chemical Systems: 14. Hydrophilic effects -- 15. Hydrophobic effects -- 16. Aqueous binary mixtures: amphiphilic effect -- 17. Water in and around micelles, reverse micelles and microemulsions -- 18. Water in carbon nanotubes -- Part IV. Bulk Water: Advanced Topics: 19. Entropy of water -- 20. Freezing of water into ice -- 21. Supercritical water -- 22. Microscopic approaches to understand water anomalies.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Building up from microscopic basics to observed complex functions, this insightful monograph explains and describes how the unique molecular properties of water give rise to its structural and dynamical behaviour which in turn translates into its role in biological and chemical processes. The discussion of the biological functions of water details not only the stabilising effect of water in proteins and DNA, but also the direct role that water molecules themselves play in biochemical processes, such as enzyme kinetics, protein synthesis and drug-DNA interaction. The overview of the behaviour of water in chemical systems discusses hydrophilic, hydrophobic and amphiphilic effects, as well as the interactions of water with micelles, reverse micelles, microemulsions and carbon nanotubes. Supported by extensive experimental and computer simulation data, highlighting many of the recent advances in the study of water in complex systems, this is an ideal resource for anyone studying water at the molecular level.</subfield></datafield><datafield tag="506" ind1=" " ind2=" "><subfield code="a">Access restricted to Ryerson students, faculty and staff.</subfield><subfield code="5">CaOTR</subfield></datafield><datafield tag="650" ind1=" " ind2="0"><subfield code="a">Water in the body.</subfield><subfield code="0">http://id.loc.gov/authorities/subjects/sh85145573</subfield></datafield><datafield tag="650" ind1=" " ind2="0"><subfield code="a">Water chemistry.</subfield><subfield code="0">http://id.loc.gov/authorities/subjects/sh85145539</subfield></datafield><datafield tag="650" ind1=" " ind2="6"><subfield code="a">Eau dans l'organisme.</subfield></datafield><datafield tag="650" ind1=" " ind2="6"><subfield code="a">Eau</subfield><subfield code="x">Chimie.</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">MEDICAL</subfield><subfield code="x">Physiology.</subfield><subfield code="2">bisacsh</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">SCIENCE</subfield><subfield code="x">Life Sciences</subfield><subfield code="x">Human Anatomy & Physiology.</subfield><subfield code="2">bisacsh</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Water chemistry</subfield><subfield code="2">fast</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Water in the body</subfield><subfield code="2">fast</subfield></datafield><datafield tag="758" ind1=" " ind2=" "><subfield code="i">has work:</subfield><subfield code="a">Water in biological and chemical processes (Text)</subfield><subfield code="1">https://id.oclc.org/worldcat/entity/E39PCFxtwWbDmmDPKdYyKjTPwC</subfield><subfield code="4">https://id.oclc.org/worldcat/ontology/hasWork</subfield></datafield><datafield tag="776" ind1="0" ind2="8"><subfield code="i">Print version:</subfield><subfield code="a">Bagchi, B. (Biman).</subfield><subfield code="t">Water in biological and chemical processes</subfield><subfield code="z">9781107037298</subfield><subfield code="w">(DLC) 2013013114</subfield><subfield code="w">(OCoLC)849822303</subfield></datafield><datafield tag="830" ind1=" " ind2="0"><subfield code="a">Cambridge molecular science series.</subfield><subfield code="0">http://id.loc.gov/authorities/names/n2002011690</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="l">FWS01</subfield><subfield code="p">ZDB-4-EBA</subfield><subfield code="q">FWS_PDA_EBA</subfield><subfield code="u">https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=622098</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="880" ind1="0" ind2="0"><subfield code="6">505-01/(S</subfield><subfield code="g">Machine generated contents note:</subfield><subfield code="g">pt. I</subfield><subfield code="t">Bulk water --</subfield><subfield code="g">1.</subfield><subfield code="t">Uniqueness of water --</subfield><subfield code="g">1.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">1.2.</subfield><subfield code="t">Molecular structure --</subfield><subfield code="g">1.3.</subfield><subfield code="t">Six unique features --</subfield><subfield code="g">1.4.</subfield><subfield code="t">Modeling of water --</subfield><subfield code="g">1.5.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">2.</subfield><subfield code="t">Anomalies of water --</subfield><subfield code="g">2.1.</subfield><subfield code="t">Anomalous properties --</subfield><subfield code="g">2.1.1.</subfield><subfield code="t">Density maximum --</subfield><subfield code="g">2.1.2.</subfield><subfield code="t">Isobaric specific heat (CP) --</subfield><subfield code="g">2.1.3.</subfield><subfield code="t">Isothermal compressibility (κT) --</subfield><subfield code="g">2.1.4.</subfield><subfield code="t">Coefficient of thermal expansion (αP) --</subfield><subfield code="g">2.1.5.</subfield><subfield code="t">Dynamic anomalies present at low temperature --</subfield><subfield code="g">2.2.</subfield><subfield code="t">Translational and orientational order --</subfield><subfield code="g">2.3.</subfield><subfield code="t">Temperature--density range of water anomalies --</subfield><subfield code="g">2.4.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">Appendix 2.A</subfield><subfield code="t">Microscopic expressions of specific heat, isothermal compressibility, and coefficient of thermal expansion --</subfield><subfield code="g">Appendix 2.B</subfield><subfield code="t">Quantification of spatial order in water --</subfield><subfield code="g">3.</subfield><subfield code="t">Dynamics of water: molecular motions and hydrogen-bond-breaking kinetics --</subfield><subfield code="g">3.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">3.2.</subfield><subfield code="t">Timescales of translational and rotational motion --</subfield><subfield code="g">3.3.</subfield><subfield code="t">Jump reorientation motion in water --</subfield><subfield code="g">3.4.</subfield><subfield code="t">Effects of temperature on water motion --</subfield><subfield code="g">3.5.</subfield><subfield code="t">Translational diffusion --</subfield><subfield code="g">3.6.</subfield><subfield code="t">Hydrogen-bond lifetime dynamics --</subfield><subfield code="g">3.7.</subfield><subfield code="t">Vibrational dynamics of the O--H bond --</subfield><subfield code="g">3.8.</subfield><subfield code="t">Dielectric relaxation --</subfield><subfield code="g">3.9.</subfield><subfield code="t">Solvation dynamics --</subfield><subfield code="g">3.10.</subfield><subfield code="t">Ionic conductivity of rigid ions in water --</subfield><subfield code="g">3.11.</subfield><subfield code="t">Electron transfer reactions in water --</subfield><subfield code="g">3.12.</subfield><subfield code="t">Motion becomes collective at low temperature --</subfield><subfield code="g">3.13.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">Appendix 3.A</subfield><subfield code="t">Rotational time correlation functions --</subfield><subfield code="g">Appendix 3.B</subfield><subfield code="t">Quantification of hydrogen-bond lifetime dynamics --</subfield><subfield code="g">4.</subfield><subfield code="t">Inherent structures of liquid water --</subfield><subfield code="g">4.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">4.2.</subfield><subfield code="t">Transition between inherent structures of water --</subfield><subfield code="g">4.3.</subfield><subfield code="t">Connected water cluster moves during transition --</subfield><subfield code="g">4.4.</subfield><subfield code="t">HB network restructuring --</subfield><subfield code="g">4.5.</subfield><subfield code="t">Coordination number fluctuation in inherent structure and corresponding dynamics in parent liquid --</subfield><subfield code="g">4.6.</subfield><subfield code="t">Low-energy excitations in liquid water --</subfield><subfield code="g">4.7.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">5.</subfield><subfield code="t">pH of water --</subfield><subfield code="g">5.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">5.2.</subfield><subfield code="t">Temperature and pressure dependence of pH --</subfield><subfield code="g">5.3.</subfield><subfield code="t">Mechanism of autoionization --</subfield><subfield code="g">5.4.</subfield><subfield code="t">pH of blood --</subfield><subfield code="g">5.5.</subfield><subfield code="t">Food and blood pH --</subfield><subfield code="g">5.6.</subfield><subfield code="t">pH of seawater --</subfield><subfield code="g">5.7.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">pt. II</subfield><subfield code="t">Water in biology --</subfield><subfield code="g">6.</subfield><subfield code="t">Biological water --</subfield><subfield code="g">6.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">6.2.</subfield><subfield code="t">Relaxation measurements --</subfield><subfield code="g">6.3.</subfield><subfield code="t">Unique characteristics of biological water --</subfield><subfield code="g">6.4.</subfield><subfield code="t">Phenomenological models and simple theories --</subfield><subfield code="g">6.5.</subfield><subfield code="t">Protein--glass transition and hydration-layer dynamics --</subfield><subfield code="g">6.6.</subfield><subfield code="t">Protein aggregation and biological water --</subfield><subfield code="g">6.7.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">Appendix 6</subfield><subfield code="t">The dynamic exchange model --</subfield><subfield code="g">7.</subfield><subfield code="t">essential chemical for life processes: water in biological functions --</subfield><subfield code="g">7.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">7.2.</subfield><subfield code="t">Role of water in enzyme kinetics --</subfield><subfield code="g">7.3.</subfield><subfield code="t">Role of water in drug--DNA intercalation --</subfield><subfield code="g">7.4.</subfield><subfield code="t">Role of water in the biological function of RNA --</subfield><subfield code="g">7.5.</subfield><subfield code="t">Water-mediated molecular recognition --</subfield><subfield code="g">7.6.</subfield><subfield code="t">Protein folding and protein association: role of biological water --</subfield><subfield code="g">7.7.</subfield><subfield code="t">Role of water in beta-amyloid aggregation in Alzheimer disease --</subfield><subfield code="g">7.7.1.</subfield><subfield code="t">Role of water in the early stages of oligomer formation --</subfield><subfield code="g">7.7.2.</subfield><subfield code="t">Role of water in the late stages of fibril growth --</subfield><subfield code="g">7.8.</subfield><subfield code="t">Role of water in photosynthesis --</subfield><subfield code="g">7.9.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">8.</subfield><subfield code="t">Hydration of proteins --</subfield><subfield code="g">8.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">8.2.</subfield><subfield code="t">What is the thickness of the hydration shell--</subfield><subfield code="g">8.3.</subfield><subfield code="t">How structured is the water in the hydration shell of a protein--</subfield><subfield code="g">8.4.</subfield><subfield code="t">Orientational arrangement of water molecules at the surface --</subfield><subfield code="g">8.5.</subfield><subfield code="t">Dynamics of the protein hydration shell: experimental studies --</subfield><subfield code="g">8.5.1.</subfield><subfield code="t">Dielectric spectrum --</subfield><subfield code="g">8.5.2.</subfield><subfield code="t">Nuclear magnetic resonance studies --</subfield><subfield code="g">8.5.3.</subfield><subfield code="t">Quasi-elastic neutron-scattering experiments --</subfield><subfield code="g">8.5.4.</subfield><subfield code="t">Vibrational spectroscopy --</subfield><subfield code="g">8.5.5.</subfield><subfield code="t">Solvation dynamics --</subfield><subfield code="g">8.6.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">Appendix 8.A</subfield><subfield code="t">Orientation of water molecules in the hydration layer --</subfield><subfield code="g">9.</subfield><subfield code="t">Understanding the protein hydration layer: lessons from computer simulations --</subfield><subfield code="g">9.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">9.2.</subfield><subfield code="t">Molecular motion in the hydration layer --</subfield><subfield code="g">9.3.</subfield><subfield code="t">Hydrogen-bond lifetime dynamics --</subfield><subfield code="g">9.4.</subfield><subfield code="t">Computer simulation of solvation dynamics --</subfield><subfield code="g">9.5.</subfield><subfield code="t">Dielectric relaxation --</subfield><subfield code="g">9.6.</subfield><subfield code="t">Explanation of anomalous dynamics in the hydration layer --</subfield><subfield code="g">9.7.</subfield><subfield code="t">Protein--glass transition at 200 K: role of water dynamics --</subfield><subfield code="g">9.8.</subfield><subfield code="t">Free-energy barrier for escape of water molecules from protein hydration layer --</subfield><subfield code="g">9.9.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">10.</subfield><subfield code="t">Water in and around DNA and RNA --</subfield><subfield code="g">10.1.</subfield><subfield code="t">Introduction: the unique role of water in stabilizing DNA and RNA --</subfield><subfield code="g">10.2.</subfield><subfield code="t">Hydration of different constituents --</subfield><subfield code="g">10.3.</subfield><subfield code="t">Groove structure and water dynamics --</subfield><subfield code="g">10.4.</subfield><subfield code="t">Translational and rotational dynamics of water molecules in the grooves --</subfield><subfield code="g">10.5.</subfield><subfield code="t">Solvation dynamics --</subfield><subfield code="g">10.6.</subfield><subfield code="t">Entropy of groove water and dynamics --</subfield><subfield code="g">10.7.</subfield><subfield code="t">Correlation between diffusion and entropy: Adam--Gibbs relation --</subfield><subfield code="g">10.8.</subfield><subfield code="t">Sequence dependence of DNA hydration: spine of hydration in AT minor groove --</subfield><subfield code="g">10.9.</subfield><subfield code="t">Effects of nanoconfinement and surface-specific interactions --</subfield><subfield code="g">10.10.</subfield><subfield code="t">Water around RNA --</subfield><subfield code="g">10.10.1.</subfield><subfield code="t">Structure of water around RNA --</subfield><subfield code="g">10.10.2.</subfield><subfield code="t">Dynamics of water around RNA --</subfield><subfield code="g">10.11.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">Appendix 10.A</subfield><subfield code="t">Hydrogen-bonding pattern around DNA --</subfield><subfield code="g">11.</subfield><subfield code="t">Protein--DNA interaction: the role of water as a facilitator --</subfield><subfield code="g">11.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">11.2.</subfield><subfield code="t">Structural analysis of protein--DNA complex: classification of hydration water --</subfield><subfield code="g">11.3.</subfield><subfield code="t">Dynamics of water around a protein--DNA complex --</subfield><subfield code="g">11.4.</subfield><subfield code="t">Role of water in thermodynamics of protein--DNA interactions --</subfield><subfield code="g">11.5.</subfield><subfield code="t">Protein diffusion along DNA --</subfield><subfield code="g">11.6.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">12.</subfield><subfield code="t">Water surrounding lipid bilayers: its role as a lubricant --</subfield><subfield code="g">12.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">12.2.</subfield><subfield code="t">Hydration of different constituents: phospholipids and buried proteins --</subfield><subfield code="g">12.3.</subfield><subfield code="t">Rugged energy landscape for water motion --</subfield><subfield code="g">12.4.</subfield><subfield code="t">Translational and rotational dynamics of water --</subfield><subfield code="g">12.5.</subfield><subfield code="t">Solvation dynamics --</subfield><subfield code="g">12.6.</subfield><subfield code="t">Transport of small molecules across the bilayer --</subfield><subfield code="g">12.7.</subfield><subfield code="t">Transport of large molecules across the bilayer --</subfield><subfield code="g">12.8.</subfield><subfield code="t">Electrostatic potential across the membrane --</subfield><subfield code="g">12.9.</subfield><subfield code="t">Conclusion --</subfield><subfield code="g">13.</subfield><subfield code="t">role of water in biochemical selection and protein synthesis --</subfield><subfield code="g">13.1.</subfield><subfield code="t">Introduction --</subfield><subfield code="g">13.2.</subfield><subfield code="t">Role of water in kinetic proofreading --</subfield><subfield code="g">13.2.1.</subfield><subfield code="t">Brief analysis of the Hopefield--Ninio approach to kinetic proofreading --</subfield><subfield code="g">13.2.2.</subfield><subfield code="t">Analysis of experimental results in the light of the Hopfield--Ninio formulation --</subfield><subfield code="g">13.2.3.</subfield><subfield code="t">Aminoacylation of tRNA during protein synthesis --</subfield><subfield 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| id | ZDB-4-EBA-ocn867631290 |
| illustrated | Not Illustrated |
| indexdate | 2024-11-27T13:25:42Z |
| institution | BVB |
| isbn | 9781107416765 1107416760 9781139583947 1139583948 9781680159929 1680159925 |
| language | English |
| oclc_num | 867631290 |
| open_access_boolean | |
| owner | MAIN DE-863 DE-BY-FWS |
| owner_facet | MAIN DE-863 DE-BY-FWS |
| physical | 1 online resource (xviii, 356 pages) |
| psigel | ZDB-4-EBA |
| publishDate | 2013 |
| publishDateSearch | 2013 |
| publishDateSort | 2013 |
| publisher | Cambridge University Press, |
| record_format | marc |
| series | Cambridge molecular science series. |
| series2 | Cambridge molecular science |
| spelling | Bagchi, B. (Biman), author. https://id.oclc.org/worldcat/entity/E39PBJj8TxthGx4C4K6kYpV9jC http://id.loc.gov/authorities/names/nr92020039 Water in biological and chemical processes : from structure and dynamics to function / Biman Bagchi, Indian Institute of Science, Bangalore. Cambridge : Cambridge University Press, 2013. 1 online resource (xviii, 356 pages) text txt rdacontent computer c rdamedia online resource cr rdacarrier Cambridge molecular science Includes bibliographical references and index. Print version record. 880-01 Part I. Bulk Water: 1. Uniqueness of water -- 2. Anomalies of water -- 3. Dynamics of water: molecular motions and hydrogen bond breaking kinetics -- 4. Inherent structures of liquid water -- 5. pH of water -- Part II. Water in Biology: Dynamical View and Function: 6. Biological water -- 7. Explicit role of water in biological functions -- 8. Hydration of proteins -- 9. Can we understand protein hydration layer: lessons from computer simulations -- 10. Water in and around DNA and RNA -- 11. Role of water in protein-DNA interaction -- 12. Water surrounding lipid bilayers -- 13. Water in Darwin's world -- Part III. Water in Complex Chemical Systems: 14. Hydrophilic effects -- 15. Hydrophobic effects -- 16. Aqueous binary mixtures: amphiphilic effect -- 17. Water in and around micelles, reverse micelles and microemulsions -- 18. Water in carbon nanotubes -- Part IV. Bulk Water: Advanced Topics: 19. Entropy of water -- 20. Freezing of water into ice -- 21. Supercritical water -- 22. Microscopic approaches to understand water anomalies. Building up from microscopic basics to observed complex functions, this insightful monograph explains and describes how the unique molecular properties of water give rise to its structural and dynamical behaviour which in turn translates into its role in biological and chemical processes. The discussion of the biological functions of water details not only the stabilising effect of water in proteins and DNA, but also the direct role that water molecules themselves play in biochemical processes, such as enzyme kinetics, protein synthesis and drug-DNA interaction. The overview of the behaviour of water in chemical systems discusses hydrophilic, hydrophobic and amphiphilic effects, as well as the interactions of water with micelles, reverse micelles, microemulsions and carbon nanotubes. Supported by extensive experimental and computer simulation data, highlighting many of the recent advances in the study of water in complex systems, this is an ideal resource for anyone studying water at the molecular level. Access restricted to Ryerson students, faculty and staff. CaOTR Water in the body. http://id.loc.gov/authorities/subjects/sh85145573 Water chemistry. http://id.loc.gov/authorities/subjects/sh85145539 Eau dans l'organisme. Eau Chimie. MEDICAL Physiology. bisacsh SCIENCE Life Sciences Human Anatomy & Physiology. bisacsh Water chemistry fast Water in the body fast has work: Water in biological and chemical processes (Text) https://id.oclc.org/worldcat/entity/E39PCFxtwWbDmmDPKdYyKjTPwC https://id.oclc.org/worldcat/ontology/hasWork Print version: Bagchi, B. (Biman). Water in biological and chemical processes 9781107037298 (DLC) 2013013114 (OCoLC)849822303 Cambridge molecular science series. http://id.loc.gov/authorities/names/n2002011690 FWS01 ZDB-4-EBA FWS_PDA_EBA https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=622098 Volltext 505-01/(S Machine generated contents note: pt. I Bulk water -- 1. Uniqueness of water -- 1.1. Introduction -- 1.2. Molecular structure -- 1.3. Six unique features -- 1.4. Modeling of water -- 1.5. Conclusion -- 2. Anomalies of water -- 2.1. Anomalous properties -- 2.1.1. Density maximum -- 2.1.2. Isobaric specific heat (CP) -- 2.1.3. Isothermal compressibility (κT) -- 2.1.4. Coefficient of thermal expansion (αP) -- 2.1.5. Dynamic anomalies present at low temperature -- 2.2. Translational and orientational order -- 2.3. Temperature--density range of water anomalies -- 2.4. Conclusion -- Appendix 2.A Microscopic expressions of specific heat, isothermal compressibility, and coefficient of thermal expansion -- Appendix 2.B Quantification of spatial order in water -- 3. Dynamics of water: molecular motions and hydrogen-bond-breaking kinetics -- 3.1. Introduction -- 3.2. Timescales of translational and rotational motion -- 3.3. Jump reorientation motion in water -- 3.4. Effects of temperature on water motion -- 3.5. Translational diffusion -- 3.6. Hydrogen-bond lifetime dynamics -- 3.7. Vibrational dynamics of the O--H bond -- 3.8. Dielectric relaxation -- 3.9. Solvation dynamics -- 3.10. Ionic conductivity of rigid ions in water -- 3.11. Electron transfer reactions in water -- 3.12. Motion becomes collective at low temperature -- 3.13. Conclusion -- Appendix 3.A Rotational time correlation functions -- Appendix 3.B Quantification of hydrogen-bond lifetime dynamics -- 4. Inherent structures of liquid water -- 4.1. Introduction -- 4.2. Transition between inherent structures of water -- 4.3. Connected water cluster moves during transition -- 4.4. HB network restructuring -- 4.5. Coordination number fluctuation in inherent structure and corresponding dynamics in parent liquid -- 4.6. Low-energy excitations in liquid water -- 4.7. Conclusion -- 5. pH of water -- 5.1. Introduction -- 5.2. Temperature and pressure dependence of pH -- 5.3. Mechanism of autoionization -- 5.4. pH of blood -- 5.5. Food and blood pH -- 5.6. pH of seawater -- 5.7. Conclusion -- pt. II Water in biology -- 6. Biological water -- 6.1. Introduction -- 6.2. Relaxation measurements -- 6.3. Unique characteristics of biological water -- 6.4. Phenomenological models and simple theories -- 6.5. Protein--glass transition and hydration-layer dynamics -- 6.6. Protein aggregation and biological water -- 6.7. Conclusion -- Appendix 6 The dynamic exchange model -- 7. essential chemical for life processes: water in biological functions -- 7.1. Introduction -- 7.2. Role of water in enzyme kinetics -- 7.3. Role of water in drug--DNA intercalation -- 7.4. Role of water in the biological function of RNA -- 7.5. Water-mediated molecular recognition -- 7.6. Protein folding and protein association: role of biological water -- 7.7. Role of water in beta-amyloid aggregation in Alzheimer disease -- 7.7.1. Role of water in the early stages of oligomer formation -- 7.7.2. Role of water in the late stages of fibril growth -- 7.8. Role of water in photosynthesis -- 7.9. Conclusion -- 8. Hydration of proteins -- 8.1. Introduction -- 8.2. What is the thickness of the hydration shell-- 8.3. How structured is the water in the hydration shell of a protein-- 8.4. Orientational arrangement of water molecules at the surface -- 8.5. Dynamics of the protein hydration shell: experimental studies -- 8.5.1. Dielectric spectrum -- 8.5.2. Nuclear magnetic resonance studies -- 8.5.3. Quasi-elastic neutron-scattering experiments -- 8.5.4. Vibrational spectroscopy -- 8.5.5. Solvation dynamics -- 8.6. Conclusion -- Appendix 8.A Orientation of water molecules in the hydration layer -- 9. Understanding the protein hydration layer: lessons from computer simulations -- 9.1. Introduction -- 9.2. Molecular motion in the hydration layer -- 9.3. Hydrogen-bond lifetime dynamics -- 9.4. Computer simulation of solvation dynamics -- 9.5. Dielectric relaxation -- 9.6. Explanation of anomalous dynamics in the hydration layer -- 9.7. Protein--glass transition at 200 K: role of water dynamics -- 9.8. Free-energy barrier for escape of water molecules from protein hydration layer -- 9.9. Conclusion -- 10. Water in and around DNA and RNA -- 10.1. Introduction: the unique role of water in stabilizing DNA and RNA -- 10.2. Hydration of different constituents -- 10.3. Groove structure and water dynamics -- 10.4. Translational and rotational dynamics of water molecules in the grooves -- 10.5. Solvation dynamics -- 10.6. Entropy of groove water and dynamics -- 10.7. Correlation between diffusion and entropy: Adam--Gibbs relation -- 10.8. Sequence dependence of DNA hydration: spine of hydration in AT minor groove -- 10.9. Effects of nanoconfinement and surface-specific interactions -- 10.10. Water around RNA -- 10.10.1. Structure of water around RNA -- 10.10.2. Dynamics of water around RNA -- 10.11. Conclusion -- Appendix 10.A Hydrogen-bonding pattern around DNA -- 11. Protein--DNA interaction: the role of water as a facilitator -- 11.1. Introduction -- 11.2. Structural analysis of protein--DNA complex: classification of hydration water -- 11.3. Dynamics of water around a protein--DNA complex -- 11.4. Role of water in thermodynamics of protein--DNA interactions -- 11.5. Protein diffusion along DNA -- 11.6. Conclusion -- 12. Water surrounding lipid bilayers: its role as a lubricant -- 12.1. Introduction -- 12.2. Hydration of different constituents: phospholipids and buried proteins -- 12.3. Rugged energy landscape for water motion -- 12.4. Translational and rotational dynamics of water -- 12.5. Solvation dynamics -- 12.6. Transport of small molecules across the bilayer -- 12.7. Transport of large molecules across the bilayer -- 12.8. Electrostatic potential across the membrane -- 12.9. Conclusion -- 13. role of water in biochemical selection and protein synthesis -- 13.1. Introduction -- 13.2. Role of water in kinetic proofreading -- 13.2.1. Brief analysis of the Hopefield--Ninio approach to kinetic proofreading -- 13.2.2. Analysis of experimental results in the light of the Hopfield--Ninio formulation -- 13.2.3. Aminoacylation of tRNA during protein synthesis -- 13.2.4. tRNA selection in ribosome -- 13.2.5. DNA replication -- 13.3. Water as a lubricant of life -- 13.4. Conclusion -- pt. |
| spellingShingle | Bagchi, B. (Biman) Water in biological and chemical processes : from structure and dynamics to function / Cambridge molecular science series. Part I. Bulk Water: 1. Uniqueness of water -- 2. Anomalies of water -- 3. Dynamics of water: molecular motions and hydrogen bond breaking kinetics -- 4. Inherent structures of liquid water -- 5. pH of water -- Part II. Water in Biology: Dynamical View and Function: 6. Biological water -- 7. Explicit role of water in biological functions -- 8. Hydration of proteins -- 9. Can we understand protein hydration layer: lessons from computer simulations -- 10. Water in and around DNA and RNA -- 11. Role of water in protein-DNA interaction -- 12. Water surrounding lipid bilayers -- 13. Water in Darwin's world -- Part III. Water in Complex Chemical Systems: 14. Hydrophilic effects -- 15. Hydrophobic effects -- 16. Aqueous binary mixtures: amphiphilic effect -- 17. Water in and around micelles, reverse micelles and microemulsions -- 18. Water in carbon nanotubes -- Part IV. Bulk Water: Advanced Topics: 19. Entropy of water -- 20. Freezing of water into ice -- 21. Supercritical water -- 22. Microscopic approaches to understand water anomalies. Water in the body. http://id.loc.gov/authorities/subjects/sh85145573 Water chemistry. http://id.loc.gov/authorities/subjects/sh85145539 Eau dans l'organisme. Eau Chimie. MEDICAL Physiology. bisacsh SCIENCE Life Sciences Human Anatomy & Physiology. bisacsh Water chemistry fast Water in the body fast |
| subject_GND | http://id.loc.gov/authorities/subjects/sh85145573 http://id.loc.gov/authorities/subjects/sh85145539 |
| title | Water in biological and chemical processes : from structure and dynamics to function / |
| title_auth | Water in biological and chemical processes : from structure and dynamics to function / |
| title_exact_search | Water in biological and chemical processes : from structure and dynamics to function / |
| title_full | Water in biological and chemical processes : from structure and dynamics to function / Biman Bagchi, Indian Institute of Science, Bangalore. |
| title_fullStr | Water in biological and chemical processes : from structure and dynamics to function / Biman Bagchi, Indian Institute of Science, Bangalore. |
| title_full_unstemmed | Water in biological and chemical processes : from structure and dynamics to function / Biman Bagchi, Indian Institute of Science, Bangalore. |
| title_short | Water in biological and chemical processes : |
| title_sort | water in biological and chemical processes from structure and dynamics to function |
| title_sub | from structure and dynamics to function / |
| topic | Water in the body. http://id.loc.gov/authorities/subjects/sh85145573 Water chemistry. http://id.loc.gov/authorities/subjects/sh85145539 Eau dans l'organisme. Eau Chimie. MEDICAL Physiology. bisacsh SCIENCE Life Sciences Human Anatomy & Physiology. bisacsh Water chemistry fast Water in the body fast |
| topic_facet | Water in the body. Water chemistry. Eau dans l'organisme. Eau Chimie. MEDICAL Physiology. SCIENCE Life Sciences Human Anatomy & Physiology. Water chemistry Water in the body |
| url | https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=622098 |
| work_keys_str_mv | AT bagchib waterinbiologicalandchemicalprocessesfromstructureanddynamicstofunction |