Theory of Molecular Rydberg States.:
The first single-authored book dedicated to the theory of molecular Rydberg states by multi-channel quantum defect and ab initio methods.
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Cambridge :
Cambridge University Press,
2011.
|
| Schriftenreihe: | Cambridge molecular science series.
|
| Schlagworte: | |
| Online-Zugang: | DE-862 DE-863 |
| Zusammenfassung: | The first single-authored book dedicated to the theory of molecular Rydberg states by multi-channel quantum defect and ab initio methods. |
| Beschreibung: | 7.6.1 The optical density matrix. |
| Beschreibung: | 1 online resource (332 pages) |
| Bibliographie: | Includes bibliographical references and index. |
| ISBN: | 9781139100861 1139100866 9781139101523 1139101528 9781139099516 1139099515 9780511994814 0511994818 1107218063 9781107218062 1139098837 9781139098830 |
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| 245 | 1 | 0 | |a Theory of Molecular Rydberg States. |
| 260 | |a Cambridge : |b Cambridge University Press, |c 2011. | ||
| 300 | |a 1 online resource (332 pages) | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 490 | 1 | |a Cambridge Molecular Science | |
| 505 | 0 | |a Cover; THEORY OF MOLECULAR RYDBERG STATES; Cambridge Molecular Science; Title; Copyright; Contents; Preface; 1 Molecular Rydberg states; 1.1 The nature of Rydberg states; 1.2 Organization of the text; References; 2 The quantum defect picture; 2.1 Introduction; 2.2 Coulomb wavefunctions; 2.2.1 Closed-channel solutions: E <I; 2.2.2 Strongly closed channels; 2.3 Single-channel quantization; 2.4 Coupled channels; 2.4.1 Open-channel case; 2.4.2 Resonant case; 2.4.3 Closed-channel case; References; 3 Ab-initio quantum defects; 3.1 Traditional quantum chemistry. | |
| 505 | 8 | |a 3.2 Constrained ab-initio wavefunctions3.3 The R-matrix matching procedure; 3.4 The Wigner-Eisbud R-matrix; 3.4.1 R-matrix derivation; 3.4.2 Buttle correction; 3.5 Variational R-matrix theory; 3.5.1 Standard method; 3.5.2 Eigenchannel method; 3.5.3 Convergence tests; 3.5.4 Spheroidal basis functions; 3.6 Rydberg-valence interactions; 3.7 The influence of positive ion dipoles; 3.7.1 General considerations; 3.7.2 Group II mono-fluorides; 3.7.3 Dipole modified Coulomb functions; References; 4 Frame transformations and channel interactions; 4.1 Physical assumptions; 4.1.1 The classical picture. | |
| 505 | 8 | |a 4.1.2 Frame transformation types4.2 Rotational channel interactions; 4.2.1 Elementary case (b)? case (d) transformation; 4.2.2?-doubling; 4.2.3 l-uncoupling in non-penetrating series; 4.2.4 Stroboscopic beats between electronic and nuclear motion; 4.3 Vibrational channel interactions; 4.3.1 Bound-state eigenvalues; 4.3.2 Vibrationally induced auto-ionization and rotational branching ratios; 4.4 Vibronic channel interactions; 4.4.1 Configuration interaction; 4.4.2 Jahn-Teller channel coupling; References; 5 Competitive fragmentation; 5.1 Perturbation model for diatomic species. | |
| 505 | 8 | |a 5.2 Diatomic predissociation5.3 Dissociative recombination and related phenomena; 5.3.1 Competing processes; 5.3.2 Two-step theory; 5.4 R-matrix formulation; 5.5 Vibronically induced dissociative recombination of H3+; 5.5.1 The Jahn-Teller mechanism; 5.5.2 A spectroscopic related model; References; 6 Photo-excitation; 6.1 Introduction; 6.2 n-photon discrete absorption; 6.2.1 Single-photon absorption; 6.2.2 Coherent two-photon absorption; 6.3 Spherical tensor representation; 6.4 Spatial selectivity; 6.5 Resonant two-photon excitation; 6.6 Multiphoton band structure; 6.6.1 Symmetric tops. | |
| 505 | 8 | |a 6.6.2 Asymmetric tops6.7 Angular momentum decoupling in high Rydberg states; 6.8 ZEKE intensities; 6.8.1 Asymmetric band profiles; 6.8.2 Symmetry selection rules; References; 7 Photo-ionization; 7.1 Boundary conditions and cross-sections; 7.2 The photo-ionization matrix element; 7.3 Integrated cross-section; 7.3.1 General formulation; 7.3.2 Photo-ionization selection rules; 7.4 Differential cross-section; 7.4.1 General formulation; 7.4.2 Asymmetry parameters; 7.4.3 Information content; 7.5 Fixed molecule angular distribution; 7.6 Resonant two-photon ionization. | |
| 500 | |a 7.6.1 The optical density matrix. | ||
| 520 | |a The first single-authored book dedicated to the theory of molecular Rydberg states by multi-channel quantum defect and ab initio methods. | ||
| 588 | 0 | |a Print version record. | |
| 504 | |a Includes bibliographical references and index. | ||
| 546 | |a English. | ||
| 650 | 0 | |a Rydberg states. |0 http://id.loc.gov/authorities/subjects/sh85116116 | |
| 650 | 0 | |a Energy levels (Quantum mechanics) |0 http://id.loc.gov/authorities/subjects/sh85043142 | |
| 650 | 0 | |a Ionization. |0 http://id.loc.gov/authorities/subjects/sh85067822 | |
| 650 | 6 | |a États de Rydberg. | |
| 650 | 6 | |a Niveaux d'énergie (Mécanique quantique) | |
| 650 | 6 | |a Ionisation. | |
| 650 | 7 | |a ionization. |2 aat | |
| 650 | 7 | |a SCIENCE |x Molecular Physics. |2 bisacsh | |
| 650 | 7 | |a SCIENCE |x Physics |x Nuclear. |2 bisacsh | |
| 650 | 7 | |a Energy levels (Quantum mechanics) |2 fast | |
| 650 | 7 | |a Ionization |2 fast | |
| 650 | 7 | |a Rydberg states |2 fast | |
| 758 | |i has work: |a Theory of Molecular Rydberg States (Text) |1 https://id.oclc.org/worldcat/entity/E39PCGT9wxXktWBRRXP6mxWTDy |4 https://id.oclc.org/worldcat/ontology/hasWork | ||
| 776 | 0 | 8 | |i Print version: |a Child, M.S. |t Theory of Molecular Rydberg States. |d Cambridge : Cambridge University Press, ©2011 |z 9780521769952 |
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Datensatz im Suchindex
| DE-BY-FWS_katkey | ZDB-4-EBA-ocn768731911 |
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| adam_text | |
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| author | Child, M. S. |
| author_GND | http://id.loc.gov/authorities/names/n80035819 |
| author_facet | Child, M. S. |
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| author_sort | Child, M. S. |
| author_variant | m s c ms msc |
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| callnumber-search | QC454.A8 C45 2011 |
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| contents | Cover; THEORY OF MOLECULAR RYDBERG STATES; Cambridge Molecular Science; Title; Copyright; Contents; Preface; 1 Molecular Rydberg states; 1.1 The nature of Rydberg states; 1.2 Organization of the text; References; 2 The quantum defect picture; 2.1 Introduction; 2.2 Coulomb wavefunctions; 2.2.1 Closed-channel solutions: E <I; 2.2.2 Strongly closed channels; 2.3 Single-channel quantization; 2.4 Coupled channels; 2.4.1 Open-channel case; 2.4.2 Resonant case; 2.4.3 Closed-channel case; References; 3 Ab-initio quantum defects; 3.1 Traditional quantum chemistry. 3.2 Constrained ab-initio wavefunctions3.3 The R-matrix matching procedure; 3.4 The Wigner-Eisbud R-matrix; 3.4.1 R-matrix derivation; 3.4.2 Buttle correction; 3.5 Variational R-matrix theory; 3.5.1 Standard method; 3.5.2 Eigenchannel method; 3.5.3 Convergence tests; 3.5.4 Spheroidal basis functions; 3.6 Rydberg-valence interactions; 3.7 The influence of positive ion dipoles; 3.7.1 General considerations; 3.7.2 Group II mono-fluorides; 3.7.3 Dipole modified Coulomb functions; References; 4 Frame transformations and channel interactions; 4.1 Physical assumptions; 4.1.1 The classical picture. 4.1.2 Frame transformation types4.2 Rotational channel interactions; 4.2.1 Elementary case (b)? case (d) transformation; 4.2.2?-doubling; 4.2.3 l-uncoupling in non-penetrating series; 4.2.4 Stroboscopic beats between electronic and nuclear motion; 4.3 Vibrational channel interactions; 4.3.1 Bound-state eigenvalues; 4.3.2 Vibrationally induced auto-ionization and rotational branching ratios; 4.4 Vibronic channel interactions; 4.4.1 Configuration interaction; 4.4.2 Jahn-Teller channel coupling; References; 5 Competitive fragmentation; 5.1 Perturbation model for diatomic species. 5.2 Diatomic predissociation5.3 Dissociative recombination and related phenomena; 5.3.1 Competing processes; 5.3.2 Two-step theory; 5.4 R-matrix formulation; 5.5 Vibronically induced dissociative recombination of H3+; 5.5.1 The Jahn-Teller mechanism; 5.5.2 A spectroscopic related model; References; 6 Photo-excitation; 6.1 Introduction; 6.2 n-photon discrete absorption; 6.2.1 Single-photon absorption; 6.2.2 Coherent two-photon absorption; 6.3 Spherical tensor representation; 6.4 Spatial selectivity; 6.5 Resonant two-photon excitation; 6.6 Multiphoton band structure; 6.6.1 Symmetric tops. 6.6.2 Asymmetric tops6.7 Angular momentum decoupling in high Rydberg states; 6.8 ZEKE intensities; 6.8.1 Asymmetric band profiles; 6.8.2 Symmetry selection rules; References; 7 Photo-ionization; 7.1 Boundary conditions and cross-sections; 7.2 The photo-ionization matrix element; 7.3 Integrated cross-section; 7.3.1 General formulation; 7.3.2 Photo-ionization selection rules; 7.4 Differential cross-section; 7.4.1 General formulation; 7.4.2 Asymmetry parameters; 7.4.3 Information content; 7.5 Fixed molecule angular distribution; 7.6 Resonant two-photon ionization. |
| ctrlnum | (OCoLC)768731911 |
| dewey-full | 539.7 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 539 - Modern physics |
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| discipline | Physik |
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| id | ZDB-4-EBA-ocn768731911 |
| illustrated | Not Illustrated |
| indexdate | 2025-04-11T08:37:29Z |
| institution | BVB |
| isbn | 9781139100861 1139100866 9781139101523 1139101528 9781139099516 1139099515 9780511994814 0511994818 1107218063 9781107218062 1139098837 9781139098830 |
| language | English |
| oclc_num | 768731911 |
| open_access_boolean | |
| owner | MAIN DE-862 DE-BY-FWS DE-863 DE-BY-FWS |
| owner_facet | MAIN DE-862 DE-BY-FWS DE-863 DE-BY-FWS |
| physical | 1 online resource (332 pages) |
| psigel | ZDB-4-EBA FWS_PDA_EBA ZDB-4-EBA |
| publishDate | 2011 |
| publishDateSearch | 2011 |
| publishDateSort | 2011 |
| publisher | Cambridge University Press, |
| record_format | marc |
| series | Cambridge molecular science series. |
| series2 | Cambridge Molecular Science |
| spelling | Child, M. S. http://id.loc.gov/authorities/names/n80035819 Theory of Molecular Rydberg States. Cambridge : Cambridge University Press, 2011. 1 online resource (332 pages) text txt rdacontent computer c rdamedia online resource cr rdacarrier Cambridge Molecular Science Cover; THEORY OF MOLECULAR RYDBERG STATES; Cambridge Molecular Science; Title; Copyright; Contents; Preface; 1 Molecular Rydberg states; 1.1 The nature of Rydberg states; 1.2 Organization of the text; References; 2 The quantum defect picture; 2.1 Introduction; 2.2 Coulomb wavefunctions; 2.2.1 Closed-channel solutions: E <I; 2.2.2 Strongly closed channels; 2.3 Single-channel quantization; 2.4 Coupled channels; 2.4.1 Open-channel case; 2.4.2 Resonant case; 2.4.3 Closed-channel case; References; 3 Ab-initio quantum defects; 3.1 Traditional quantum chemistry. 3.2 Constrained ab-initio wavefunctions3.3 The R-matrix matching procedure; 3.4 The Wigner-Eisbud R-matrix; 3.4.1 R-matrix derivation; 3.4.2 Buttle correction; 3.5 Variational R-matrix theory; 3.5.1 Standard method; 3.5.2 Eigenchannel method; 3.5.3 Convergence tests; 3.5.4 Spheroidal basis functions; 3.6 Rydberg-valence interactions; 3.7 The influence of positive ion dipoles; 3.7.1 General considerations; 3.7.2 Group II mono-fluorides; 3.7.3 Dipole modified Coulomb functions; References; 4 Frame transformations and channel interactions; 4.1 Physical assumptions; 4.1.1 The classical picture. 4.1.2 Frame transformation types4.2 Rotational channel interactions; 4.2.1 Elementary case (b)? case (d) transformation; 4.2.2?-doubling; 4.2.3 l-uncoupling in non-penetrating series; 4.2.4 Stroboscopic beats between electronic and nuclear motion; 4.3 Vibrational channel interactions; 4.3.1 Bound-state eigenvalues; 4.3.2 Vibrationally induced auto-ionization and rotational branching ratios; 4.4 Vibronic channel interactions; 4.4.1 Configuration interaction; 4.4.2 Jahn-Teller channel coupling; References; 5 Competitive fragmentation; 5.1 Perturbation model for diatomic species. 5.2 Diatomic predissociation5.3 Dissociative recombination and related phenomena; 5.3.1 Competing processes; 5.3.2 Two-step theory; 5.4 R-matrix formulation; 5.5 Vibronically induced dissociative recombination of H3+; 5.5.1 The Jahn-Teller mechanism; 5.5.2 A spectroscopic related model; References; 6 Photo-excitation; 6.1 Introduction; 6.2 n-photon discrete absorption; 6.2.1 Single-photon absorption; 6.2.2 Coherent two-photon absorption; 6.3 Spherical tensor representation; 6.4 Spatial selectivity; 6.5 Resonant two-photon excitation; 6.6 Multiphoton band structure; 6.6.1 Symmetric tops. 6.6.2 Asymmetric tops6.7 Angular momentum decoupling in high Rydberg states; 6.8 ZEKE intensities; 6.8.1 Asymmetric band profiles; 6.8.2 Symmetry selection rules; References; 7 Photo-ionization; 7.1 Boundary conditions and cross-sections; 7.2 The photo-ionization matrix element; 7.3 Integrated cross-section; 7.3.1 General formulation; 7.3.2 Photo-ionization selection rules; 7.4 Differential cross-section; 7.4.1 General formulation; 7.4.2 Asymmetry parameters; 7.4.3 Information content; 7.5 Fixed molecule angular distribution; 7.6 Resonant two-photon ionization. 7.6.1 The optical density matrix. The first single-authored book dedicated to the theory of molecular Rydberg states by multi-channel quantum defect and ab initio methods. Print version record. Includes bibliographical references and index. English. Rydberg states. http://id.loc.gov/authorities/subjects/sh85116116 Energy levels (Quantum mechanics) http://id.loc.gov/authorities/subjects/sh85043142 Ionization. http://id.loc.gov/authorities/subjects/sh85067822 États de Rydberg. Niveaux d'énergie (Mécanique quantique) Ionisation. ionization. aat SCIENCE Molecular Physics. bisacsh SCIENCE Physics Nuclear. bisacsh Energy levels (Quantum mechanics) fast Ionization fast Rydberg states fast has work: Theory of Molecular Rydberg States (Text) https://id.oclc.org/worldcat/entity/E39PCGT9wxXktWBRRXP6mxWTDy https://id.oclc.org/worldcat/ontology/hasWork Print version: Child, M.S. Theory of Molecular Rydberg States. Cambridge : Cambridge University Press, ©2011 9780521769952 Cambridge molecular science series. http://id.loc.gov/authorities/names/n2002011690 |
| spellingShingle | Child, M. S. Theory of Molecular Rydberg States. Cambridge molecular science series. Cover; THEORY OF MOLECULAR RYDBERG STATES; Cambridge Molecular Science; Title; Copyright; Contents; Preface; 1 Molecular Rydberg states; 1.1 The nature of Rydberg states; 1.2 Organization of the text; References; 2 The quantum defect picture; 2.1 Introduction; 2.2 Coulomb wavefunctions; 2.2.1 Closed-channel solutions: E <I; 2.2.2 Strongly closed channels; 2.3 Single-channel quantization; 2.4 Coupled channels; 2.4.1 Open-channel case; 2.4.2 Resonant case; 2.4.3 Closed-channel case; References; 3 Ab-initio quantum defects; 3.1 Traditional quantum chemistry. 3.2 Constrained ab-initio wavefunctions3.3 The R-matrix matching procedure; 3.4 The Wigner-Eisbud R-matrix; 3.4.1 R-matrix derivation; 3.4.2 Buttle correction; 3.5 Variational R-matrix theory; 3.5.1 Standard method; 3.5.2 Eigenchannel method; 3.5.3 Convergence tests; 3.5.4 Spheroidal basis functions; 3.6 Rydberg-valence interactions; 3.7 The influence of positive ion dipoles; 3.7.1 General considerations; 3.7.2 Group II mono-fluorides; 3.7.3 Dipole modified Coulomb functions; References; 4 Frame transformations and channel interactions; 4.1 Physical assumptions; 4.1.1 The classical picture. 4.1.2 Frame transformation types4.2 Rotational channel interactions; 4.2.1 Elementary case (b)? case (d) transformation; 4.2.2?-doubling; 4.2.3 l-uncoupling in non-penetrating series; 4.2.4 Stroboscopic beats between electronic and nuclear motion; 4.3 Vibrational channel interactions; 4.3.1 Bound-state eigenvalues; 4.3.2 Vibrationally induced auto-ionization and rotational branching ratios; 4.4 Vibronic channel interactions; 4.4.1 Configuration interaction; 4.4.2 Jahn-Teller channel coupling; References; 5 Competitive fragmentation; 5.1 Perturbation model for diatomic species. 5.2 Diatomic predissociation5.3 Dissociative recombination and related phenomena; 5.3.1 Competing processes; 5.3.2 Two-step theory; 5.4 R-matrix formulation; 5.5 Vibronically induced dissociative recombination of H3+; 5.5.1 The Jahn-Teller mechanism; 5.5.2 A spectroscopic related model; References; 6 Photo-excitation; 6.1 Introduction; 6.2 n-photon discrete absorption; 6.2.1 Single-photon absorption; 6.2.2 Coherent two-photon absorption; 6.3 Spherical tensor representation; 6.4 Spatial selectivity; 6.5 Resonant two-photon excitation; 6.6 Multiphoton band structure; 6.6.1 Symmetric tops. 6.6.2 Asymmetric tops6.7 Angular momentum decoupling in high Rydberg states; 6.8 ZEKE intensities; 6.8.1 Asymmetric band profiles; 6.8.2 Symmetry selection rules; References; 7 Photo-ionization; 7.1 Boundary conditions and cross-sections; 7.2 The photo-ionization matrix element; 7.3 Integrated cross-section; 7.3.1 General formulation; 7.3.2 Photo-ionization selection rules; 7.4 Differential cross-section; 7.4.1 General formulation; 7.4.2 Asymmetry parameters; 7.4.3 Information content; 7.5 Fixed molecule angular distribution; 7.6 Resonant two-photon ionization. Rydberg states. http://id.loc.gov/authorities/subjects/sh85116116 Energy levels (Quantum mechanics) http://id.loc.gov/authorities/subjects/sh85043142 Ionization. http://id.loc.gov/authorities/subjects/sh85067822 États de Rydberg. Niveaux d'énergie (Mécanique quantique) Ionisation. ionization. aat SCIENCE Molecular Physics. bisacsh SCIENCE Physics Nuclear. bisacsh Energy levels (Quantum mechanics) fast Ionization fast Rydberg states fast |
| subject_GND | http://id.loc.gov/authorities/subjects/sh85116116 http://id.loc.gov/authorities/subjects/sh85043142 http://id.loc.gov/authorities/subjects/sh85067822 |
| title | Theory of Molecular Rydberg States. |
| title_auth | Theory of Molecular Rydberg States. |
| title_exact_search | Theory of Molecular Rydberg States. |
| title_full | Theory of Molecular Rydberg States. |
| title_fullStr | Theory of Molecular Rydberg States. |
| title_full_unstemmed | Theory of Molecular Rydberg States. |
| title_short | Theory of Molecular Rydberg States. |
| title_sort | theory of molecular rydberg states |
| topic | Rydberg states. http://id.loc.gov/authorities/subjects/sh85116116 Energy levels (Quantum mechanics) http://id.loc.gov/authorities/subjects/sh85043142 Ionization. http://id.loc.gov/authorities/subjects/sh85067822 États de Rydberg. Niveaux d'énergie (Mécanique quantique) Ionisation. ionization. aat SCIENCE Molecular Physics. bisacsh SCIENCE Physics Nuclear. bisacsh Energy levels (Quantum mechanics) fast Ionization fast Rydberg states fast |
| topic_facet | Rydberg states. Energy levels (Quantum mechanics) Ionization. États de Rydberg. Niveaux d'énergie (Mécanique quantique) Ionisation. ionization. SCIENCE Molecular Physics. SCIENCE Physics Nuclear. Ionization Rydberg states |
| work_keys_str_mv | AT childms theoryofmolecularrydbergstates |