Chemistry versus physics :: chemical reactions near critical points /
Chemical reactions at high pressures are widely used in modern technology (supercritical extraction is an example). On the other hand, critical phenomena is the more advanced field in statistical mechanics. There are thousands of theoretical and experimental articles published by physicists, chemist...
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| Format: | Elektronisch E-Book |
| Sprache: | English |
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Singapore ; Hackensack, N.J. :
World Scientific Pub. Co.,
©2010.
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| Online-Zugang: | Volltext |
| Zusammenfassung: | Chemical reactions at high pressures are widely used in modern technology (supercritical extraction is an example). On the other hand, critical phenomena is the more advanced field in statistical mechanics. There are thousands of theoretical and experimental articles published by physicists, chemists, biologists, chemical engineers and material scientists, but, to our knowledge, there are no books which link these two phenomena together. This book sums up the results of 222 published articles, both theoretical and experimental, which will be of great benefit to students and all researchers working in this field. |
| Beschreibung: | 1 online resource (xi, 136 pages) : illustrations |
| Bibliographie: | Includes bibliographical references (pages 127-134) and index. |
| ISBN: | 9789814291217 9814291218 9781282761841 1282761846 9786612761843 6612761849 |
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| 245 | 1 | 0 | |a Chemistry versus physics : |b chemical reactions near critical points / |c Moshe Gitterman. |
| 260 | |a Singapore ; |a Hackensack, N.J. : |b World Scientific Pub. Co., |c ©2010. | ||
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| 505 | 0 | |a 1. Criticality and chemistry. 1.1. Critical phenomena. 1.2. Chemical reactions. 1.3. Analogy between critical phenomena and the instability of chemical reactions -- 2. Effect of criticality on chemical reaction. 2.1. The effect of pressure on the equilibrium constant and rate of reaction. 2.2. Effect of phase transformations on chemistry. 2.3. Critical slowing-down of chemical reactions. 2.4. Hydrodynamic equations of reactive binary mixture : piston effect. 2.5. Critical anomalies of chemical equilibria. 2.6. Experiment -- 3. Effect of chemistry on critical phenomena. 3.1. Change of critical parameters due to a chemical reaction. 3.2. Modification of the critical indices. 3.3. Singularity in the degree of dissociation near a critical point. 3.4. Isotope exchange reaction in near-critical systems. 3.5. Singularities of transport coefficients in reactive systems -- 4. Phase separation in reactive systems. 4.1. Multiple solutions of the law of mass action. 4.2. Phase equilibrium in reactive binary mixtures quenched into a metastable state. 4.3. Phase equilibrium in reactive mixtures quenched into an unstable state. 4.4. Thermodynamics of a three-component plasma with a dissociative chemical reaction -- 5. Comments on the geometry of the phase diagram of a reaction mixture. 5.1. Solubility in supercritical fluids. 5.2. Azeotropic points in reactive many-component systems. 5.3. Melting point of reactive binary mixtures. 5.4. Double critical point -- 6. Sound propagation and light scattering in chemically reactive systems. 6.1. Ultrasound attenuation in near-critical reactive mixtures. 6.2. Hydrodynamic analysis of the dispersion relation for sound waves. 6.3. Light scattering from reactive systems. 6.4. Inhomogeneous structure of near-critical reactive systems -- 7. Conclusions. | |
| 520 | |a Chemical reactions at high pressures are widely used in modern technology (supercritical extraction is an example). On the other hand, critical phenomena is the more advanced field in statistical mechanics. There are thousands of theoretical and experimental articles published by physicists, chemists, biologists, chemical engineers and material scientists, but, to our knowledge, there are no books which link these two phenomena together. This book sums up the results of 222 published articles, both theoretical and experimental, which will be of great benefit to students and all researchers working in this field. | ||
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| 650 | 0 | |a Chemistry, Physical and theoretical. |0 http://id.loc.gov/authorities/subjects/sh85023027 | |
| 650 | 2 | |a Chemistry, Physical |0 https://id.nlm.nih.gov/mesh/D002627 | |
| 650 | 6 | |a Phénomène critique (Physique) | |
| 650 | 6 | |a Point critique. | |
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| contents | 1. Criticality and chemistry. 1.1. Critical phenomena. 1.2. Chemical reactions. 1.3. Analogy between critical phenomena and the instability of chemical reactions -- 2. Effect of criticality on chemical reaction. 2.1. The effect of pressure on the equilibrium constant and rate of reaction. 2.2. Effect of phase transformations on chemistry. 2.3. Critical slowing-down of chemical reactions. 2.4. Hydrodynamic equations of reactive binary mixture : piston effect. 2.5. Critical anomalies of chemical equilibria. 2.6. Experiment -- 3. Effect of chemistry on critical phenomena. 3.1. Change of critical parameters due to a chemical reaction. 3.2. Modification of the critical indices. 3.3. Singularity in the degree of dissociation near a critical point. 3.4. Isotope exchange reaction in near-critical systems. 3.5. Singularities of transport coefficients in reactive systems -- 4. Phase separation in reactive systems. 4.1. Multiple solutions of the law of mass action. 4.2. Phase equilibrium in reactive binary mixtures quenched into a metastable state. 4.3. Phase equilibrium in reactive mixtures quenched into an unstable state. 4.4. Thermodynamics of a three-component plasma with a dissociative chemical reaction -- 5. Comments on the geometry of the phase diagram of a reaction mixture. 5.1. Solubility in supercritical fluids. 5.2. Azeotropic points in reactive many-component systems. 5.3. Melting point of reactive binary mixtures. 5.4. Double critical point -- 6. Sound propagation and light scattering in chemically reactive systems. 6.1. Ultrasound attenuation in near-critical reactive mixtures. 6.2. Hydrodynamic analysis of the dispersion relation for sound waves. 6.3. Light scattering from reactive systems. 6.4. Inhomogeneous structure of near-critical reactive systems -- 7. Conclusions. |
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| discipline | Physik |
| format | Electronic eBook |
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Co.,</subfield><subfield code="c">©2010.</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">1 online resource (xi, 136 pages) :</subfield><subfield code="b">illustrations</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">computer</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">online resource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="347" ind1=" " ind2=" "><subfield code="a">data file</subfield><subfield code="2">rda</subfield></datafield><datafield tag="504" ind1=" " ind2=" "><subfield code="a">Includes bibliographical references (pages 127-134) and index.</subfield></datafield><datafield tag="505" ind1="0" ind2=" "><subfield code="a">1. Criticality and chemistry. 1.1. Critical phenomena. 1.2. Chemical reactions. 1.3. Analogy between critical phenomena and the instability of chemical reactions -- 2. Effect of criticality on chemical reaction. 2.1. The effect of pressure on the equilibrium constant and rate of reaction. 2.2. Effect of phase transformations on chemistry. 2.3. Critical slowing-down of chemical reactions. 2.4. Hydrodynamic equations of reactive binary mixture : piston effect. 2.5. Critical anomalies of chemical equilibria. 2.6. Experiment -- 3. Effect of chemistry on critical phenomena. 3.1. Change of critical parameters due to a chemical reaction. 3.2. Modification of the critical indices. 3.3. Singularity in the degree of dissociation near a critical point. 3.4. Isotope exchange reaction in near-critical systems. 3.5. Singularities of transport coefficients in reactive systems -- 4. Phase separation in reactive systems. 4.1. Multiple solutions of the law of mass action. 4.2. Phase equilibrium in reactive binary mixtures quenched into a metastable state. 4.3. Phase equilibrium in reactive mixtures quenched into an unstable state. 4.4. Thermodynamics of a three-component plasma with a dissociative chemical reaction -- 5. Comments on the geometry of the phase diagram of a reaction mixture. 5.1. Solubility in supercritical fluids. 5.2. Azeotropic points in reactive many-component systems. 5.3. Melting point of reactive binary mixtures. 5.4. Double critical point -- 6. Sound propagation and light scattering in chemically reactive systems. 6.1. Ultrasound attenuation in near-critical reactive mixtures. 6.2. Hydrodynamic analysis of the dispersion relation for sound waves. 6.3. Light scattering from reactive systems. 6.4. Inhomogeneous structure of near-critical reactive systems -- 7. Conclusions.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Chemical reactions at high pressures are widely used in modern technology (supercritical extraction is an example). On the other hand, critical phenomena is the more advanced field in statistical mechanics. There are thousands of theoretical and experimental articles published by physicists, chemists, biologists, chemical engineers and material scientists, but, to our knowledge, there are no books which link these two phenomena together. 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| id | ZDB-4-EBA-ocn630164007 |
| illustrated | Illustrated |
| indexdate | 2024-11-27T13:17:13Z |
| institution | BVB |
| institution_GND | http://id.loc.gov/authorities/names/no2001005546 |
| isbn | 9789814291217 9814291218 9781282761841 1282761846 9786612761843 6612761849 |
| language | English |
| oclc_num | 630164007 |
| open_access_boolean | |
| owner | MAIN DE-863 DE-BY-FWS |
| owner_facet | MAIN DE-863 DE-BY-FWS |
| physical | 1 online resource (xi, 136 pages) : illustrations |
| psigel | ZDB-4-EBA |
| publishDate | 2010 |
| publishDateSearch | 2010 |
| publishDateSort | 2010 |
| publisher | World Scientific Pub. Co., |
| record_format | marc |
| spelling | Gitterman, M. Chemistry versus physics : chemical reactions near critical points / Moshe Gitterman. Singapore ; Hackensack, N.J. : World Scientific Pub. Co., ©2010. 1 online resource (xi, 136 pages) : illustrations text txt rdacontent computer c rdamedia online resource cr rdacarrier data file rda Includes bibliographical references (pages 127-134) and index. 1. Criticality and chemistry. 1.1. Critical phenomena. 1.2. Chemical reactions. 1.3. Analogy between critical phenomena and the instability of chemical reactions -- 2. Effect of criticality on chemical reaction. 2.1. The effect of pressure on the equilibrium constant and rate of reaction. 2.2. Effect of phase transformations on chemistry. 2.3. Critical slowing-down of chemical reactions. 2.4. Hydrodynamic equations of reactive binary mixture : piston effect. 2.5. Critical anomalies of chemical equilibria. 2.6. Experiment -- 3. Effect of chemistry on critical phenomena. 3.1. Change of critical parameters due to a chemical reaction. 3.2. Modification of the critical indices. 3.3. Singularity in the degree of dissociation near a critical point. 3.4. Isotope exchange reaction in near-critical systems. 3.5. Singularities of transport coefficients in reactive systems -- 4. Phase separation in reactive systems. 4.1. Multiple solutions of the law of mass action. 4.2. Phase equilibrium in reactive binary mixtures quenched into a metastable state. 4.3. Phase equilibrium in reactive mixtures quenched into an unstable state. 4.4. Thermodynamics of a three-component plasma with a dissociative chemical reaction -- 5. Comments on the geometry of the phase diagram of a reaction mixture. 5.1. Solubility in supercritical fluids. 5.2. Azeotropic points in reactive many-component systems. 5.3. Melting point of reactive binary mixtures. 5.4. Double critical point -- 6. Sound propagation and light scattering in chemically reactive systems. 6.1. Ultrasound attenuation in near-critical reactive mixtures. 6.2. Hydrodynamic analysis of the dispersion relation for sound waves. 6.3. Light scattering from reactive systems. 6.4. Inhomogeneous structure of near-critical reactive systems -- 7. Conclusions. Chemical reactions at high pressures are widely used in modern technology (supercritical extraction is an example). On the other hand, critical phenomena is the more advanced field in statistical mechanics. There are thousands of theoretical and experimental articles published by physicists, chemists, biologists, chemical engineers and material scientists, but, to our knowledge, there are no books which link these two phenomena together. This book sums up the results of 222 published articles, both theoretical and experimental, which will be of great benefit to students and all researchers working in this field. Print version record. English. Critical phenomena (Physics) http://id.loc.gov/authorities/subjects/sh85034140 Critical point. http://id.loc.gov/authorities/subjects/sh85034141 Chemistry, Physical and theoretical. http://id.loc.gov/authorities/subjects/sh85023027 Chemistry, Physical https://id.nlm.nih.gov/mesh/D002627 Phénomène critique (Physique) Point critique. Chimie physique et théorique. physical chemistry. aat SCIENCE Physics General. bisacsh SCIENCE Mechanics General. bisacsh SCIENCE Energy. bisacsh Chemistry, Physical and theoretical fast Critical phenomena (Physics) fast Critical point fast World Scientific (Firm) http://id.loc.gov/authorities/names/no2001005546 has work: Chemistry versus physics (Text) https://id.oclc.org/worldcat/entity/E39PCFqbcCybqcWjgDTYjqfxym https://id.oclc.org/worldcat/ontology/hasWork 981429120X 9789814291200 FWS01 ZDB-4-EBA FWS_PDA_EBA https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=340610 Volltext |
| spellingShingle | Gitterman, M. Chemistry versus physics : chemical reactions near critical points / 1. Criticality and chemistry. 1.1. Critical phenomena. 1.2. Chemical reactions. 1.3. Analogy between critical phenomena and the instability of chemical reactions -- 2. Effect of criticality on chemical reaction. 2.1. The effect of pressure on the equilibrium constant and rate of reaction. 2.2. Effect of phase transformations on chemistry. 2.3. Critical slowing-down of chemical reactions. 2.4. Hydrodynamic equations of reactive binary mixture : piston effect. 2.5. Critical anomalies of chemical equilibria. 2.6. Experiment -- 3. Effect of chemistry on critical phenomena. 3.1. Change of critical parameters due to a chemical reaction. 3.2. Modification of the critical indices. 3.3. Singularity in the degree of dissociation near a critical point. 3.4. Isotope exchange reaction in near-critical systems. 3.5. Singularities of transport coefficients in reactive systems -- 4. Phase separation in reactive systems. 4.1. Multiple solutions of the law of mass action. 4.2. Phase equilibrium in reactive binary mixtures quenched into a metastable state. 4.3. Phase equilibrium in reactive mixtures quenched into an unstable state. 4.4. Thermodynamics of a three-component plasma with a dissociative chemical reaction -- 5. Comments on the geometry of the phase diagram of a reaction mixture. 5.1. Solubility in supercritical fluids. 5.2. Azeotropic points in reactive many-component systems. 5.3. Melting point of reactive binary mixtures. 5.4. Double critical point -- 6. Sound propagation and light scattering in chemically reactive systems. 6.1. Ultrasound attenuation in near-critical reactive mixtures. 6.2. Hydrodynamic analysis of the dispersion relation for sound waves. 6.3. Light scattering from reactive systems. 6.4. Inhomogeneous structure of near-critical reactive systems -- 7. Conclusions. Critical phenomena (Physics) http://id.loc.gov/authorities/subjects/sh85034140 Critical point. http://id.loc.gov/authorities/subjects/sh85034141 Chemistry, Physical and theoretical. http://id.loc.gov/authorities/subjects/sh85023027 Chemistry, Physical https://id.nlm.nih.gov/mesh/D002627 Phénomène critique (Physique) Point critique. Chimie physique et théorique. physical chemistry. aat SCIENCE Physics General. bisacsh SCIENCE Mechanics General. bisacsh SCIENCE Energy. bisacsh Chemistry, Physical and theoretical fast Critical phenomena (Physics) fast Critical point fast |
| subject_GND | http://id.loc.gov/authorities/subjects/sh85034140 http://id.loc.gov/authorities/subjects/sh85034141 http://id.loc.gov/authorities/subjects/sh85023027 https://id.nlm.nih.gov/mesh/D002627 |
| title | Chemistry versus physics : chemical reactions near critical points / |
| title_auth | Chemistry versus physics : chemical reactions near critical points / |
| title_exact_search | Chemistry versus physics : chemical reactions near critical points / |
| title_full | Chemistry versus physics : chemical reactions near critical points / Moshe Gitterman. |
| title_fullStr | Chemistry versus physics : chemical reactions near critical points / Moshe Gitterman. |
| title_full_unstemmed | Chemistry versus physics : chemical reactions near critical points / Moshe Gitterman. |
| title_short | Chemistry versus physics : |
| title_sort | chemistry versus physics chemical reactions near critical points |
| title_sub | chemical reactions near critical points / |
| topic | Critical phenomena (Physics) http://id.loc.gov/authorities/subjects/sh85034140 Critical point. http://id.loc.gov/authorities/subjects/sh85034141 Chemistry, Physical and theoretical. http://id.loc.gov/authorities/subjects/sh85023027 Chemistry, Physical https://id.nlm.nih.gov/mesh/D002627 Phénomène critique (Physique) Point critique. Chimie physique et théorique. physical chemistry. aat SCIENCE Physics General. bisacsh SCIENCE Mechanics General. bisacsh SCIENCE Energy. bisacsh Chemistry, Physical and theoretical fast Critical phenomena (Physics) fast Critical point fast |
| topic_facet | Critical phenomena (Physics) Critical point. Chemistry, Physical and theoretical. Chemistry, Physical Phénomène critique (Physique) Point critique. Chimie physique et théorique. physical chemistry. SCIENCE Physics General. SCIENCE Mechanics General. SCIENCE Energy. Chemistry, Physical and theoretical Critical point |
| url | https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=340610 |
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