Verfügbarkeit: Halide perovskite semiconductors

Halide perovskite semiconductors: structures, characterization, properties, and phenomena

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Bibliographische Detailangaben
Weitere Verfasser:	Zhou, Yuanyuan (HerausgeberIn), Mora-Seró, Iván (HerausgeberIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Weinheim Wiley-VCH [2024]
Schlagworte:	CH92: Festkörperchemie Chemie Chemistry Components & Devices EE60: Komponenten u. Bauelemente Electrical & Electronics Engineering Elektrotechnik u. Elektronik Festkörperchemie Halbleiter Komponenten u. Bauelemente MSA0: Werkstoffprüfung Materials Characterization Materials Science Materialwissenschaften Perowskit Solid State Chemistry Werkstoffprüfung
Online-Zugang:	http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34809-1/ Inhaltsverzeichnis
Beschreibung:	xvi, 495 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm
ISBN:	9783527348091

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245	1	0	\|a Halide perovskite semiconductors \|b structures, characterization, properties, and phenomena \|c edited by Yuanyuan Zhou and Iván Mora-Seró
264		1	\|a Weinheim \|b Wiley-VCH \|c [2024]
300			\|a xvi, 495 Seiten \|b Illustrationen, Diagramme \|c 24.4 cm x 17 cm
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653			\|a CH92: Festkörperchemie
653			\|a Chemie
653			\|a Chemistry
653			\|a Components & Devices
653			\|a EE60: Komponenten u. Bauelemente
653			\|a Electrical & Electronics Engineering
653			\|a Elektrotechnik u. Elektronik
653			\|a Festkörperchemie
653			\|a Halbleiter
653			\|a Komponenten u. Bauelemente
653			\|a MSA0: Werkstoffprüfung
653			\|a Materials Characterization
653			\|a Materials Science
653			\|a Materialwissenschaften
653			\|a Perowskit
653			\|a Solid State Chemistry
653			\|a Werkstoffprüfung
700	1		\|a Zhou, Yuanyuan \|4 edt
700	1		\|a Mora-Seró, Iván \|4 edt
710	2		\|a Wiley-VCH \|0 (DE-588)16179388-5 \|4 pbl
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Datensatz im Suchindex

_version_	1805083498426400768
adam_text	CONTENTS PREFACE XV 1 INTRODUCTION TO PEROVSKITE 1 TIANWEI DUAN, IVAN MORA-SERA, AND YUANYUAN ZHOU 1.1 1.2 1.3 1.4 EVOLUTION OF PEROVSKITE 1 STRUCTURE OF PEROVSKITE 2 PROPERTY AND APPLICATION OF PEROVSKITE 4 SUMMARY AND OUTLOOK 7 REFERENCES 7 2 HALIDE PEROVSKITE SINGLE CRYSTALS 9 CLARA ARANDA-ALONSO AND MICHAEL SALIBA 2.1 2.2 2.2.1 2.2.2 2.2.3 2.3 2.3.1 2.3.2 2.3.3 2.3.4 2.3.5 2.3.6 2.4 2.4.1 INTRODUCTION 9 CRYSTAL STRUCTURE 9 LEAD-BASED PEROVSKITE SINGLE CRYSTALS 10 LEAD-FREE PEROVSKITE SINGLE CRYSTALS 12 ALL-INORGANIC PEROVSKITE SINGLE CRYSTALS 13 SYNTHESIS METHODS 14 ANTISOLVENT VAPOR-ASSISTED CRYSTALLIZATION (AVC) METHOD 14 SOLUTION TEMPERATURE LOWERING (STL) METHOD 15 BRIDGMAN METHOD 16 SLOW EVAPORATION METHOD 17 INVERSE TEMPERATURE CRYSTALLIZATION (ITC) METHOD 19 METHODS FOR 2D AND 1D PEROVSKITE SINGLE CRYSTALS 20 OPTOELECTRONIC PROPERTIES OF HALIDE PEROVSKITE SINGLE CRYSTALS 21 UV-VIS ABSORPTION, PHOTOLUMINESCENCE (PL), AND TRANSIENT DECAYS: TRPL AND TPV 21 2.4.2 2.4.2.1 2.4.2.2 2.5 2.5.1 2.5.2 ELECTRONIC PROPERTIES 23 SPACE-CHARGE-LIMITED CURRENT (SCLC) 23 IMPEDANCE SPECTROSCOPY (IS) 26 APPLICATIONS 29 PHOTODETECTORS 29 X-RAY DETECTION 30 VI CONTENTS 2.5.3 2.5.4 2.5.5 2.5.6 Y-RAY DETECTION AND SCINTILLATORS 30 SOLAR CELLS 32 LIGHT EMITTING DIODES 38 MEMRISTORS 41 ACKNOWLEDGMENTS 43 REFERENCES 43 3 HALIDE PEROVSKITE NANOCRYSTALS 49 SAMRAT DAS ADHIKARI, ANDRES F. GUALDRON-REYES, AND IVAN MORA-SERO 3.1 3.2 3.2.1 3.2.2 3.2.3 3.2.4 3.3 3.3.1 3.3.2 3.3.3 3.4 3.5 3.6 3.6.1 3.6.1.1 3.6.1.2 3.6.1.3 3.7 3.7.1 3.7.2 3.7.3 3.7.4 3.8 3.8.1 3.8.2 3.9 INTRODUCTION 49 METHODOLOGY 51 HOT-INJECTION (HI) METHOD 51 LIGAND-ASSISTED REPRECIPITATION (LARP) METHOD 54 MICROWAVE-ASSISTED SYNTHESIS 55 BALL-MILLING PROCESS 55 QUANTUM CONFINEMENT EFFECT 57 NANOCUBES 57 NANOPLATELETS 58 NANOWIRES 59 SOLUTION-PROCESSED HALIDE EXCHANGE 59 POST-SYNTHESIS DEFECT RECOVERY 61 DIFFERENT SHAPES OF THE NANOCRYSTALS 62 SHAPE-CONTROLLING REACTION PARAMETERS 63 TEMPERATURE 63 ANNEALING TIME 63 ROLE OF CAPPING-LIGAND 64 DOPING IN PEROVSKITE NANOCRYSTALS 64 MN 2+ DOPING 65 LANTHANIDE DOPING 65 OTHER B-SITE DOPANTS 67 POSTSYNTHESIS DOPING 67 LEAD-FREE PEROVSKITE NANOCRYSTALS 69 CLASSIFICATIONS ACCORDING TO THE STRUCTURE AND COMPOSITIONS 69 CHALLENGES OF THE LEAD-FREE PEROVSKITES 69 SUMMARY 70 REFERENCES 71 4 DIMENSIONALITY MODULATION IN HALIDE PEROVSKITES 79 AKRITI, JEE YUNG PARK, SHUCHEN ZHANG, AND LETIAN DOU 4.1 4.1.1 CLASSIFICATION OF LOW-DIMENSIONAL PEROVSKITES 79 MORPHOLOGICAL LOW-DIMENSIONAL PEROVSKITES THROUGH SIZE REDUCTION (ABX, PEROVSKITES) 79 4.1.2 MOLECULAR LOW-DIMENSIONAL PEROVSKITES THROUGH STRUCTURE TUNING (NON-ABX, PEROVSKITES) 80 CONTENTS VII 4.2 SYNTHESIS AND CHARACTERIZATION OF MORPHOLOGICAL LOW-DIMENSIONAL (ABX 3 ) HALIDE PEROVSKITES 80 4.2.1 4.2.2 4.2.3 4.3 OD QUANTUM DOTS 80 ID NANOWIRES 81 2D NANOPLATELETS 82 SYNTHESIS AND CHARACTERIZATION OF MOLECULAR LOW-DIMENSIONAL (NON-ABX,) HALIDE PEROVSKITES 83 4.3.1 4.3.1.1 4.3.1.2 4.3.2 4.3.3 4.3.3.1 4.3.3.2 4.4 4.5 OD 83 SYNTHESIS AND PROPERTIES OF OD PEROVSKITES 83 OD CESIUM LEAD HALIDES 87 ID 88 2D AND QUASI-2D 90 SYNTHESIS OF 2D AND QUASI-2D PEROVSKITES SINGLE CRYSTAL 90 SYNTHESIS OF 2D AND QUASI-2D PEROVSKITES NANOCRYSTAL 99 APPLICATIONS OF LOW-DIMENSIONAL HALIDE PEROVSKITES 101 CURRENT CHALLENGES AND PROSPECTS OF LOW-DIMENSIONAL HALIDE PEROVSKITES 104 REFERENCES 106 5 HALIDE DOUBLE PEROVSKITES 115 CARINA PAREJA-RIVERA, DULCE ZUGASTI-FERNANDEZ, PAUL OLALDE-VELASCO, AND DIEGO SOLIS-IBARRA 5.1 5.2 5.2.1 5.2.2 5.2.3 5.3 5.3.1 5.3.2 5.3.3 5.3.4 5.3.5 5.4 5.4.1 5.4.1.1 5.4.1.2 5.4.2 5.4.3 5.4.4 5.4.5 5.5 DEFINITION AND STRUCTURE 116 PROPERTIES 118 CHEMICAL DOPING 121 RANDOM ORDERING 122 STABILITY 122 APPLICATIONS IN SOLAR CELLS AND LEDS 123 PHOTOVOLTAIC SOLAR CELLS 123 LIGHT-EMITTING DIODES (LEDS) 125 WHITE-LEDS 125 PHOSPHORUS 126 TWO OR MORE PHOSPHORUS 126 OTHER APPLICATIONS 126 PHOTODETECTORS 127 UV DETECTORS 128 X-RAY DETECTORS 128 MEMRISTORS 130 PHOTOCATALYSIS 131 SENSORS 131 FUTURE APPLICATIONS 132 RELATED MATERIALS: LAYERED DOUBLE PEROVSKITES AND VACANCY ORDERED DOUBLE PEROVSKITES 132 5.5.1 5.5.2 DIMENSIONAL REDUCTION 132 VACANCY ORDERED PEROVSKITES 133 VIII CONTENTS 5.5.2.1 5.5.2.2 5.5.2.3 5.6 A 2 B(IV)X 6 : B(IV) SUBSTITUTION + VACANCIES 134 A 3 B(III)X 9 : B(III) SUBSTITUTION + VACANCIES 135 A 2 B(II)B 2 (III)X 12 : B(II), B(III) SUBSTITUTION + VACANCIES YY 135 CONCLUSIONS 135 REFERENCES 136 6 TIN HALIDE PEROVSKITE SOLAR CELLS 147 XIANYUAN JIANG, ZIHAO ZANG, AND ZHIJUN NING 6.1 6.2 6.2.1 6.2.2 6.2.3 6.3 6.3.1 6.3.2 6.4 6.4.1 6.4.2 6.4.3 6.5 6.5.1 6.5.2 6.6 INTRODUCTION 147 TIN PEROVSKITE PROPERTIES 148 CRYSTAL STRUCTURE 148 BAND STRUCTURE AND OXIDATION 149 ELECTRICAL PROPERTIES AND DEFECTS 151 PEROVSKITE COMPOSITION ENGINEERING 151 THREE-DIMENSIONAL TPSC 151 LOW-DIMENSIONAL TPSC 153 ADDITIVES MANIPULATION 155 CRYSTALLIZATION REGULATORS 155 DEOXIDIZERS 156 INTERFACES PASSIVATING MATERIALS 156 DEVICE ARCHITECTURE ENGINEERING 156 NORMAL AND INVERTED STRUCTURES 156 BAND ALIGNMENT 157 CONCLUSION 158 REFERENCES 158 7 FUNDAMENTALS AND SYNTHESIS METHODS OF METAL HALIDE PEROVSKITE THIN FILMS 165 MINGWEI HAO, TANGHAO LIU, YALAN ZHANG, TIANWEI DUAN, AND YUANYUAN ZHOU 7.1 7.2 7.2.1 7.2.1.1 7.2.1.2 7.2.1.3 7.2.2 7.2.2.1 7.2.2.2 7.2.2.3 7.3 7.3.1 7.3.1.1 7.3.1.2 7.3.2 7.3.2.1 INTRODUCTION 165 FUNDAMENTALS OF MHPS THIN FILMS 166 CRYSTAL STRUCTURES AND COMPOSITIONS 166 3D MHPS 167 LEAD-FREE MHPS 168 2D MHPS 170 MICROSTRUCTURES 171 TYPES OF THE GBS 171 GRAIN SIZE AND DISTRIBUTION 172 CRYSTALLOGRAPHIC ORIENTATIONS 173 THIN FILM GROWTH MECHANISM 173 CRYSTAL NUCLEATION MECHANISM 173 NUCLEATION THEORY 173 INFLUENCES ON NUCLEATION 176 CRYSTAL GROWTH MECHANISM 176 BASIC GROWTH THEORY 176 CONTENTS IX 7.3.2.2 7.4 7.4.1 7.4.1.1 7.4.1.2 7.4.2 7.4.2.1 7.4.2.2 7.5 7.5.1 7.5.1.1 7.5.1.2 7.5.13 7.5.2 7.5.2.1 7.5.2.2 7.6 7.6.1 7.6.2 7.63 7.6.4 7.6.5 7.7 7.7.1 7.7.1.1 7.7.1.2 7.7.2 7.8 GRAIN-COARSENING THEORY 178 ONE-STEP GROWTH 180 GROWTH FROM SOLUTIONS 180 SPIN-COATING 180 DROP-CASTING 182 GROWTH FROM VAPOR PHASE 184 THERMAL EVAPORATION 184 PULSED LASER DEPOSITION 185 TWO-STEP GROWTH 186 GROWTH FROM SOLUTIONS 187 IMMERSION METHOD 187 SPIN-COATING METHOD 189 ELECTRO/CHEMICAL BATH DEPOSITION 190 GROWTH FROM VAPOR PHASE 190 VAPOR-ASSISTED SOLUTION PROCESSING 190 SEQUENTIAL VAPOR DEPOSITION 191 SCALABLE GROWTH METHODS 192 BLADE COATING 193 SLOT-DIE COATING 195 SPRAY COATING 196 MENISCUS-ASSISTED SOLUTION PRINTING 197 INKJET PRINTING 199 POSTDEPOSITION TREATMENTS 200 ANNEALING 200 SOLVENT ANNEALING 200 VACUUM-ASSISTED ANNEALING 201 ORGANIC-GAS DOSING 201 SUMMARY 203 ACKNOWLEDGMENTS 204 REFERENCES 204 8 FIRST PRINCIPLES ATOMISTIC THEORY OF HALIDE PEROVSKITES 215 LINN LEPPERT 8.1 INTRODUCTION: WHAT I TALK ABOUT WHEN I TALK ABOUT FIRST PRINCIPLES CALCULATIONS OF HALIDE PEROVSKITES 215 8.2 8.2.1 8.2.2 8.2.2.1 8.2.2.2 8.2.3 8.2.4 8.2.4.1 8.2.4.2 8.2.43 STRUCTURAL PROPERTIES 217 A SHORT INTRODUCTION TO DENSITY FUNCTIONAL THEORY 217 DFT CALCULATIONS IN PRACTICE 218 APPROXIMATIONS 218 CALCULATIONS OF STRUCTURAL PROPERTIES 222 ZERO-TEMPERATURE CALCULATIONS FOR HALIDE PEROVSKITES 223 STRUCTURAL DYNAMICS 227 MOLECULAR DYNAMICS: FROM CLASSICAL FORCE FIELDS TO DFT ACCURACY 227 PEROVSKITES AND THE BREAKDOWN OF THE HARMONIC APPROXIMATION 228 A PRIMER ON ION MIGRATION 229 CONTENTS 8.3 OPTOELECTRONIC PROPERTIES 231 8.3.1 ELECTRONIC BAND STRUCTURES 232 8.3.1.1 WHAT CAN DFT TELL US ABOUT BAND GAPS OF SOLIDS? 232 8.3.1.2 A SHORT INTRODUCTION TO THE GW APPROACH 233 8.3.1.3 THE BAND STRUCTURE OF HALIDE PEROVSKITES: A TIGHT-BINDING PERSPECTIVE 235 8.3.1.4 TOWARD PREDICTIVE BAND STRUCTURE CALCULATIONS FOR HALIDE PEROVSKITES 237 8.3.2 OPTICAL PROPERTIES 239 8.3.2.1 A SHORT INTRODUCTION TO THE BETHE-SALPETER EQUATION APPROACH 239 8.3.2.2 NEUTRAL EXCITATIONS IN HALIDE PEROVSKITES 240 8.4 CONCLUDING REMARKS: FIRST PERSON SINGULAR 242 ACKNOWLEDGMENTS 243 REFERENCES 243 9 COMPARING THE CHARGE DYNAMICS IN MAPBBR 3 AND MAPBL 3 USING MICROWAVE PHOTOCONDUCTANCE MEASUREMENTS 251 TOM J. SAVENIJE, JIASHANG ZHAO, AND VALENTINA M. CASELLI 9.1 TIME-RESOLVED MICROWAVE CONDUCTIVITY 251 9.2 GLOBAL MODELING OF TRMC DATA 254 9.3 TRMC MEASUREMENTS ON MAPBI, AND MAPBBR, 255 9.4 TRMC MEASUREMENTS ON MAPBI, AND MAPBBR 3 WITH CHARGE SELECTIVE CONTACTS 258 ACKNOWLEDGEMENT 261 REFERENCES 261 10 HOT CARRIERS IN HALIDE PEROVSKITES 263 JIA WEI MELVIN LIM, YUE WANG, AND TZE CHIEN SUM 10.1 INTRODUCTION 263 10.1.1 POTENTIAL OF PEROVSKITES FOR NEXT-GENERATION PHOTOVOLTAICS 264 10.2 HOT CARRIER COOLING MECHANISMS 265 10.3 SLOW HOT CARRIER COOLING IN HALIDE PEROVSKITES 266 10.3.1 HOT PHONON BOTTLENECK 266 10.3.2 AUGER HEATING OF HOT CARRIERS 268 10.3.3 LARGE POLARON FORMATION 268 10.3.4 SPECTROSCOPIC SIGNATURE OF HOT CARRIERS 269 10.3.4.1 TRANSIENT ABSORPTION 270 10.3.4.2 FLUORESCENCE-BASED TECHNIQUES 272 10.3.5 HOT CARRIER EXTRACTION 274 10.4 UTILIZING HOT CARRIERS IN HALIDE PEROVSKITES 275 10.4.1 HOT CARRIER SOLAR CELL 275 10.4.2 TOWARD THE REALIZATION OF PEROVSKITE HOT CARRIER SOLAR CELLS 277 10.4.2.1 COOLING LOSS TO THE LATTICE 277 10.4.2.2 ENERGY SELECTIVE CONTACTS 279 10.4.2.3 LOSS OF COLD CARRIERS 279 CONTENTS XI 10.5 10.5.1 10.6 10.6.1 10.6.2 10.6.3 MULTIPLE EXCITON GENERATION 280 MEG METRICS 281 MULTIPLE EXCITON GENERATION MECHANISMS 283 THE DEBATE OVER THE MEG THRESHOLD AND MEG MECHANISM 283 UNDERLYING MECHANISM OF THE EFFICIENT MEG IN PEROVSKITE 285 CONTROVERSY AND PITFALLS OVER PHOTOCHARGING AND ARTIFACTUAL MEG SIGNAL 287 10.7 10.7.1 10.7.2 10.7.3 10.7.4 10.7.4.1 10.7.4.2 10.8 10.8.1 10.8.2 10.9 EFFICIENT MULTIPLE EXCITON GENERATION IN HALIDE PEROVSKITES 289 LOW MULTIPLE EXCITON GENERATION THRESHOLD 290 HIGH MULTIPLE EXCITON GENERATION EFFICIENCY 291 LARGE MULTIPLE EXCITON GENERATION QUANTUM YIELD 291 SPECTROSCOPIC SIGNATURES OF MULTIPLE EXCITON GENERATION 292 TRANSIENT ABSORPTION SPECTROSCOPY 292 PHOTOCURRENT-BASED TECHNIQUES 294 UTILIZING MULTIPLE EXCITON GENERATION IN HALIDE PEROVSKITES 296 MULTIPLE EXCITON GENERATION SOLAR CELLS 296 POTENTIAL OF MULTIPLE EXCITON GENERATION SOLAR CELLS 298 CONCLUSION AND OUTLOOK 299 REFERENCES 300 11 IONIC TRANSPORT IN PEROVSKITE SEMICONDUCTORS 305 WENKE ZHOU, YICHENG ZHAO, AND QING ZHAO 11.1 11.2 11.3 11.4 11.4.1 11.4.2 11.4.3 11.4.4 11.4.5 11.5 11.5.1 11.5.2 11.5.3 11.5.4 11.6 THEORETICAL BASIS OF IONIC TRANSPORT 305 CHARACTERIZATIONS OF IONIC TRANSPORT 306 MOBILE IONS IN PEROVSKITE FILM UNDER ELECTRIC FIELD 309 THE FACTORS AFFECTING IONIC TRANSPORT IN PEROVSKITES 311 MOISTURE 311 LIGHT ILLUMINATION 311 PEROVSKITE COMPOSITION 313 GRAIN BOUNDARY 315 LATTICE STRAIN 317 THE IMPACT OF IONIC TRANSPORT ON PEROVSKITE FILMS AND DEVICES 318 PHASE SEGREGATION 318 DOPING EFFECTS 320 SCLC AND TFT DEVICES 321 DEGRADATION IN FUNCTIONAL DEVICES 322 SUMMARY AND OUTLOOK 322 REFERENCES 324 12 LIGHT EMISSION OF HALIDE PEROVSKITES 329 DAVID O. TIEDE, JUAN F. GALISTEO-LOPEZ, AND HERNAN MIGUEZ 12.1 12.2 12.2.1 12.2.2 INTRODUCTION 329 CHARGE-CARRIER RECOMBINATION IN LEAD-HALIDE PEROVSKITES 330 MONOMOLECULAR RECOMBINATION 331 BIMOLECULAR RECOMBINATION 334 XII CONTENTS 12.2.3 12.2.4 12.2.5 TRIMOLECULAR RECOMBINATION 335 RECOMBINATION CONSTANTS IN EXCITONIC SYSTEMS 336 COMMON RECOMBINATION DYNAMICS MEASUREMENT TECHNIQUES AND EXPERIMENTAL EVIDENCE 337 12.3 12.4 12.5 PHOTOINDUCED EFFECTS ON CHARGE CARRIER RECOMBINATION 338 LASING IN LEAD-HALIDE PEROVSKITES 341 CONCLUSIONS 345 REFERENCES 345 13 EPITAXY AND STRAIN ENGINEERING OF HALIDE PEROVSKITES 351 YANG HU, JIE JIANG, LIFU ZHANG, YUNFENG SHI, AND JIAN SHI 13.1 13.2 13.2.1 13.2.2 13.2.3 13.3 13.3.1 13.3.2 13.4 INTRODUCTION 351 EPITAXY OF THIN FILM AND NANOSTRUCTURES 353 EPITAXIAL SUBSTRATES 353 EPITAXIAL GROWTH AND DEFECTS FORMATION MECHANISMS 355 EXPERIMENTAL PROGRESSES 358 STRAIN ENGINEERING 360 THEORETICAL PROGRESSES 361 EXPERIMENTAL PROGRESSES 363 OPPORTUNITIES AND CHALLENGES 365 ACKNOWLEDGMENTS 366 REFERENCES 367 14 ELECTRON MICROSCOPY OF PEROVSKITE SOLAR CELL MATERIALS 377 MATHIAS U. ROTHMANN, WEI LI, AND ZHIWEI TAO 14.1 14.2 14.3 14.4 14.4.1 14.4.1.1 14.4.1.2 14.4.1.3 14.4.2 14.4.2.1 14.4.2.2 14.4.3 14.4.3.1 14.4.3.2 14.4.3.3 14.4.4 14.4.4.1 14.4.4.2 14.4.4.3 14.4.4.4 INTRODUCTION 377 FUNDAMENTALS OF ELECTRON MICROSCOPY 377 SIGNAL GENERATION 379 SEM 381 CATHODOLUMINESCENCE 381 COMPARISON OF CL AND PHOTOLUMINESCENCE (PL) 382 WORKING PRINCIPLE 382 CL FOR PEROVSKITES 383 ELECTRON-BEAM-INDUCED CURRENT 387 WORKING PRINCIPLE OF EBIC 387 APPLICATIONS 387 ELECTRON BACKSCATTER DIFFRACTION 389 DIFFERENCES BETWEEN EBSD, XRD, AND TEM 390 WORKING PRINCIPLE OF EBSD 391 EBSD FOR PEROVSKITES 392 TEM 395 SAMPLE PREPARATION AND TRANSFER 395 IMAGING CONDITIONS 398 BEAM DAMAGE 400 EXAMPLES OF APPLICATIONS OF TEM 402 CONTENTS XIII 14.5 CONCLUSIONS 406 ACKNOWLEDGMENTS 407 REFERENCES 407 15 IN SITU CHARACTERIZATION OF HALIDE PEROVSKITE SYNTHESIS 411 MAGED ABDELSAMIE, TIM KODALLE, MRIGANKA SINGH, AND CAROLIN M. SUTTER-FELLA 15.1 INTRODUCTION 411 15.2 FUNDAMENTALS OF X-RAY SCATTERING AND FLUORESCENCE TECHNIQUES 412 15.2.1 GRAZING INCIDENCE WIDE-ANGLE X-RAY SCATTERING (GIWAXS) 413 15.2.2 GRAZING INCIDENCE SMALL-ANGLE X-RAY SCATTERING (GISAXS) 414 15.2.3 X-RAY FLUORESCENCE (XRF) 416 15.2.4 SELECTED EXAMPLES FOR IN SITU X-RAY SCATTERING AND FLUORESCENCE 416 15.2.4.1 IN SITU GIWAXS TO STUDY CRYSTALLIZATION KINETICS AND A-SITE DOPING 416 15.2.4.2 IN SITU GIWAXS TO PROBE FILM EVOLUTION VIA ANTISOLVENT AND GAS JET TREATMENTS 418 15.2.4.3 IN SITU X-RAY DIFFRACTION (XRD), XRF, AND GISAXS TO PROBE THE PBCL 2 -DERIVED FORMATION OF MAPBI, 420 15.2.4.4 IN SITU GIWAXS TO PROBE THE 2D PEROVSKITE FORMATION ON 3D FILMS 420 15.3 IN SITU OPTICAL SPECTROSCOPY 423 15.3.1 FUNDAMENTALS OF ABSORPTION AND EMISSION OF LIGHT IN HALIDE PEROVSKITES 423 15.3.2 SETUP DESIGN FOR IN SITU OPTICAL SPECTROSCOPY 425 15.3.3 SELECTED EXAMPLES FOR IN SITU OPTICAL SPECTROSCOPY 426 15.3.3.1 FAST IN SITU REFLECTANCE MEASUREMENTS TO CHARACTERIZE THE PEROVSKITE FORMATION 426 15.3.3.2 IN SITU UV-VIS ABSORBANCE CHARACTERIZATION DURING THE DRYING STAGE 427 15.3.3.3 IN SITU PHOTOLUMINESCENCE CHARACTERIZATION TO INVESTIGATE THE ROLE OF THE PRECURSOR 428 15.4 EXAMPLES OF IN SITU MULTIMODAL CHARACTERIZATION DURING SOLUTION-BASED FABRICATION 430 15.5 PROBING BEAM-SAMPLE INTERACTION 435 15.6 SUMMARY AND OUTLOOK 437 ACKNOWLEDGMENTS 437 REFERENCES 437 16 MULTIMODAL CHARACTERIZATION OF HALIDE PEROVSKITES: FROM THE MACRO TO THE ATOMIC SCALE 443 TIARNAN A. S. DOHERTY AND SAMUEL D. STRANKS 16.1 INTRODUCTION 443 16.2 EARLY MULTIMODAL CHARACTERIZATION WORK 445 16.3 RECENT MULTIMODAL CHARACTERIZATION 450 16.3.1 SUBGRAIN FEATURES 450 XIV CONTENTS 16.3.2 16.3.3 16.4 16.4.1 16.4.2 16.4.3 16.4.4 16.5 STRAIN AND PHOTOPHYSICS 453 ATOMIC SCALE MULTIMODAL STUDIES 462 PRESSING CHALLENGES AND OPPORTUNITIES 464 CHALLENGES: BEAM DAMAGE 464 CHALLENGES: RESOLUTION LIMITS 469 CHALLENGES: IMAGE REGISTRATION AND SAMPLE FABRICATION 470 CHALLENGES: FACILITY ACCESS AND DATA ACQUISITION 471 OUTLOOK AND OPPORTUNITIES 471 REFERENCES 475 INDEX 483
adam_txt	CONTENTS PREFACE XV 1 INTRODUCTION TO PEROVSKITE 1 TIANWEI DUAN, IVAN MORA-SERA, AND YUANYUAN ZHOU 1.1 1.2 1.3 1.4 EVOLUTION OF PEROVSKITE 1 STRUCTURE OF PEROVSKITE 2 PROPERTY AND APPLICATION OF PEROVSKITE 4 SUMMARY AND OUTLOOK 7 REFERENCES 7 2 HALIDE PEROVSKITE SINGLE CRYSTALS 9 CLARA ARANDA-ALONSO AND MICHAEL SALIBA 2.1 2.2 2.2.1 2.2.2 2.2.3 2.3 2.3.1 2.3.2 2.3.3 2.3.4 2.3.5 2.3.6 2.4 2.4.1 INTRODUCTION 9 CRYSTAL STRUCTURE 9 LEAD-BASED PEROVSKITE SINGLE CRYSTALS 10 LEAD-FREE PEROVSKITE SINGLE CRYSTALS 12 ALL-INORGANIC PEROVSKITE SINGLE CRYSTALS 13 SYNTHESIS METHODS 14 ANTISOLVENT VAPOR-ASSISTED CRYSTALLIZATION (AVC) METHOD 14 SOLUTION TEMPERATURE LOWERING (STL) METHOD 15 BRIDGMAN METHOD 16 SLOW EVAPORATION METHOD 17 INVERSE TEMPERATURE CRYSTALLIZATION (ITC) METHOD 19 METHODS FOR 2D AND 1D PEROVSKITE SINGLE CRYSTALS 20 OPTOELECTRONIC PROPERTIES OF HALIDE PEROVSKITE SINGLE CRYSTALS 21 UV-VIS ABSORPTION, PHOTOLUMINESCENCE (PL), AND TRANSIENT DECAYS: TRPL AND TPV 21 2.4.2 2.4.2.1 2.4.2.2 2.5 2.5.1 2.5.2 ELECTRONIC PROPERTIES 23 SPACE-CHARGE-LIMITED CURRENT (SCLC) 23 IMPEDANCE SPECTROSCOPY (IS) 26 APPLICATIONS 29 PHOTODETECTORS 29 X-RAY DETECTION 30 VI CONTENTS 2.5.3 2.5.4 2.5.5 2.5.6 Y-RAY DETECTION AND SCINTILLATORS 30 SOLAR CELLS 32 LIGHT EMITTING DIODES 38 MEMRISTORS 41 ACKNOWLEDGMENTS 43 REFERENCES 43 3 HALIDE PEROVSKITE NANOCRYSTALS 49 SAMRAT DAS ADHIKARI, ANDRES F. GUALDRON-REYES, AND IVAN MORA-SERO 3.1 3.2 3.2.1 3.2.2 3.2.3 3.2.4 3.3 3.3.1 3.3.2 3.3.3 3.4 3.5 3.6 3.6.1 3.6.1.1 3.6.1.2 3.6.1.3 3.7 3.7.1 3.7.2 3.7.3 3.7.4 3.8 3.8.1 3.8.2 3.9 INTRODUCTION 49 METHODOLOGY 51 HOT-INJECTION (HI) METHOD 51 LIGAND-ASSISTED REPRECIPITATION (LARP) METHOD 54 MICROWAVE-ASSISTED SYNTHESIS 55 BALL-MILLING PROCESS 55 QUANTUM CONFINEMENT EFFECT 57 NANOCUBES 57 NANOPLATELETS 58 NANOWIRES 59 SOLUTION-PROCESSED HALIDE EXCHANGE 59 POST-SYNTHESIS DEFECT RECOVERY 61 DIFFERENT SHAPES OF THE NANOCRYSTALS 62 SHAPE-CONTROLLING REACTION PARAMETERS 63 TEMPERATURE 63 ANNEALING TIME 63 ROLE OF CAPPING-LIGAND 64 DOPING IN PEROVSKITE NANOCRYSTALS 64 MN 2+ DOPING 65 LANTHANIDE DOPING 65 OTHER B-SITE DOPANTS 67 POSTSYNTHESIS DOPING 67 LEAD-FREE PEROVSKITE NANOCRYSTALS 69 CLASSIFICATIONS ACCORDING TO THE STRUCTURE AND COMPOSITIONS 69 CHALLENGES OF THE LEAD-FREE PEROVSKITES 69 SUMMARY 70 REFERENCES 71 4 DIMENSIONALITY MODULATION IN HALIDE PEROVSKITES 79 AKRITI, JEE YUNG PARK, SHUCHEN ZHANG, AND LETIAN DOU 4.1 4.1.1 CLASSIFICATION OF LOW-DIMENSIONAL PEROVSKITES 79 MORPHOLOGICAL LOW-DIMENSIONAL PEROVSKITES THROUGH SIZE REDUCTION (ABX, PEROVSKITES) 79 4.1.2 MOLECULAR LOW-DIMENSIONAL PEROVSKITES THROUGH STRUCTURE TUNING (NON-ABX, PEROVSKITES) 80 CONTENTS VII 4.2 SYNTHESIS AND CHARACTERIZATION OF MORPHOLOGICAL LOW-DIMENSIONAL (ABX 3 ) HALIDE PEROVSKITES 80 4.2.1 4.2.2 4.2.3 4.3 OD QUANTUM DOTS 80 ID NANOWIRES 81 2D NANOPLATELETS 82 SYNTHESIS AND CHARACTERIZATION OF MOLECULAR LOW-DIMENSIONAL (NON-ABX,) HALIDE PEROVSKITES 83 4.3.1 4.3.1.1 4.3.1.2 4.3.2 4.3.3 4.3.3.1 4.3.3.2 4.4 4.5 OD 83 SYNTHESIS AND PROPERTIES OF OD PEROVSKITES 83 OD CESIUM LEAD HALIDES 87 ID 88 2D AND QUASI-2D 90 SYNTHESIS OF 2D AND QUASI-2D PEROVSKITES SINGLE CRYSTAL 90 SYNTHESIS OF 2D AND QUASI-2D PEROVSKITES NANOCRYSTAL 99 APPLICATIONS OF LOW-DIMENSIONAL HALIDE PEROVSKITES 101 CURRENT CHALLENGES AND PROSPECTS OF LOW-DIMENSIONAL HALIDE PEROVSKITES 104 REFERENCES 106 5 HALIDE DOUBLE PEROVSKITES 115 CARINA PAREJA-RIVERA, DULCE ZUGASTI-FERNANDEZ, PAUL OLALDE-VELASCO, AND DIEGO SOLIS-IBARRA 5.1 5.2 5.2.1 5.2.2 5.2.3 5.3 5.3.1 5.3.2 5.3.3 5.3.4 5.3.5 5.4 5.4.1 5.4.1.1 5.4.1.2 5.4.2 5.4.3 5.4.4 5.4.5 5.5 DEFINITION AND STRUCTURE 116 PROPERTIES 118 CHEMICAL DOPING 121 RANDOM ORDERING 122 STABILITY 122 APPLICATIONS IN SOLAR CELLS AND LEDS 123 PHOTOVOLTAIC SOLAR CELLS 123 LIGHT-EMITTING DIODES (LEDS) 125 WHITE-LEDS 125 PHOSPHORUS 126 TWO OR MORE PHOSPHORUS 126 OTHER APPLICATIONS 126 PHOTODETECTORS 127 UV DETECTORS 128 X-RAY DETECTORS 128 MEMRISTORS 130 PHOTOCATALYSIS 131 SENSORS 131 FUTURE APPLICATIONS 132 RELATED MATERIALS: LAYERED DOUBLE PEROVSKITES AND VACANCY ORDERED DOUBLE PEROVSKITES 132 5.5.1 5.5.2 DIMENSIONAL REDUCTION 132 VACANCY ORDERED PEROVSKITES 133 VIII CONTENTS 5.5.2.1 5.5.2.2 5.5.2.3 5.6 A 2 B(IV)X 6 : B(IV) SUBSTITUTION + VACANCIES 134 A 3 B(III)X 9 : B(III) SUBSTITUTION + VACANCIES 135 A 2 B(II)B 2 (III)X 12 : B(II), B(III) SUBSTITUTION + VACANCIES YY 135 CONCLUSIONS 135 REFERENCES 136 6 TIN HALIDE PEROVSKITE SOLAR CELLS 147 XIANYUAN JIANG, ZIHAO ZANG, AND ZHIJUN NING 6.1 6.2 6.2.1 6.2.2 6.2.3 6.3 6.3.1 6.3.2 6.4 6.4.1 6.4.2 6.4.3 6.5 6.5.1 6.5.2 6.6 INTRODUCTION 147 TIN PEROVSKITE PROPERTIES 148 CRYSTAL STRUCTURE 148 BAND STRUCTURE AND OXIDATION 149 ELECTRICAL PROPERTIES AND DEFECTS 151 PEROVSKITE COMPOSITION ENGINEERING 151 THREE-DIMENSIONAL TPSC 151 LOW-DIMENSIONAL TPSC 153 ADDITIVES MANIPULATION 155 CRYSTALLIZATION REGULATORS 155 DEOXIDIZERS 156 INTERFACES PASSIVATING MATERIALS 156 DEVICE ARCHITECTURE ENGINEERING 156 NORMAL AND INVERTED STRUCTURES 156 BAND ALIGNMENT 157 CONCLUSION 158 REFERENCES 158 7 FUNDAMENTALS AND SYNTHESIS METHODS OF METAL HALIDE PEROVSKITE THIN FILMS 165 MINGWEI HAO, TANGHAO LIU, YALAN ZHANG, TIANWEI DUAN, AND YUANYUAN ZHOU 7.1 7.2 7.2.1 7.2.1.1 7.2.1.2 7.2.1.3 7.2.2 7.2.2.1 7.2.2.2 7.2.2.3 7.3 7.3.1 7.3.1.1 7.3.1.2 7.3.2 7.3.2.1 INTRODUCTION 165 FUNDAMENTALS OF MHPS THIN FILMS 166 CRYSTAL STRUCTURES AND COMPOSITIONS 166 3D MHPS 167 LEAD-FREE MHPS 168 2D MHPS 170 MICROSTRUCTURES 171 TYPES OF THE GBS 171 GRAIN SIZE AND DISTRIBUTION 172 CRYSTALLOGRAPHIC ORIENTATIONS 173 THIN FILM GROWTH MECHANISM 173 CRYSTAL NUCLEATION MECHANISM 173 NUCLEATION THEORY 173 INFLUENCES ON NUCLEATION 176 CRYSTAL GROWTH MECHANISM 176 BASIC GROWTH THEORY 176 CONTENTS IX 7.3.2.2 7.4 7.4.1 7.4.1.1 7.4.1.2 7.4.2 7.4.2.1 7.4.2.2 7.5 7.5.1 7.5.1.1 7.5.1.2 7.5.13 7.5.2 7.5.2.1 7.5.2.2 7.6 7.6.1 7.6.2 7.63 7.6.4 7.6.5 7.7 7.7.1 7.7.1.1 7.7.1.2 7.7.2 7.8 GRAIN-COARSENING THEORY 178 ONE-STEP GROWTH 180 GROWTH FROM SOLUTIONS 180 SPIN-COATING 180 DROP-CASTING 182 GROWTH FROM VAPOR PHASE 184 THERMAL EVAPORATION 184 PULSED LASER DEPOSITION 185 TWO-STEP GROWTH 186 GROWTH FROM SOLUTIONS 187 IMMERSION METHOD 187 SPIN-COATING METHOD 189 ELECTRO/CHEMICAL BATH DEPOSITION 190 GROWTH FROM VAPOR PHASE 190 VAPOR-ASSISTED SOLUTION PROCESSING 190 SEQUENTIAL VAPOR DEPOSITION 191 SCALABLE GROWTH METHODS 192 BLADE COATING 193 SLOT-DIE COATING 195 SPRAY COATING 196 MENISCUS-ASSISTED SOLUTION PRINTING 197 INKJET PRINTING 199 POSTDEPOSITION TREATMENTS 200 ANNEALING 200 SOLVENT ANNEALING 200 VACUUM-ASSISTED ANNEALING 201 ORGANIC-GAS DOSING 201 SUMMARY 203 ACKNOWLEDGMENTS 204 REFERENCES 204 8 FIRST PRINCIPLES ATOMISTIC THEORY OF HALIDE PEROVSKITES 215 LINN LEPPERT 8.1 INTRODUCTION: WHAT I TALK ABOUT WHEN I TALK ABOUT FIRST PRINCIPLES CALCULATIONS OF HALIDE PEROVSKITES 215 8.2 8.2.1 8.2.2 8.2.2.1 8.2.2.2 8.2.3 8.2.4 8.2.4.1 8.2.4.2 8.2.43 STRUCTURAL PROPERTIES 217 A SHORT INTRODUCTION TO DENSITY FUNCTIONAL THEORY 217 DFT CALCULATIONS IN PRACTICE 218 APPROXIMATIONS 218 CALCULATIONS OF STRUCTURAL PROPERTIES 222 ZERO-TEMPERATURE CALCULATIONS FOR HALIDE PEROVSKITES 223 STRUCTURAL DYNAMICS 227 MOLECULAR DYNAMICS: FROM CLASSICAL FORCE FIELDS TO DFT ACCURACY 227 PEROVSKITES AND THE BREAKDOWN OF THE HARMONIC APPROXIMATION 228 A PRIMER ON ION MIGRATION 229 CONTENTS 8.3 OPTOELECTRONIC PROPERTIES 231 8.3.1 ELECTRONIC BAND STRUCTURES 232 8.3.1.1 WHAT CAN DFT TELL US ABOUT BAND GAPS OF SOLIDS? 232 8.3.1.2 A SHORT INTRODUCTION TO THE GW APPROACH 233 8.3.1.3 THE BAND STRUCTURE OF HALIDE PEROVSKITES: A TIGHT-BINDING PERSPECTIVE 235 8.3.1.4 TOWARD PREDICTIVE BAND STRUCTURE CALCULATIONS FOR HALIDE PEROVSKITES 237 8.3.2 OPTICAL PROPERTIES 239 8.3.2.1 A SHORT INTRODUCTION TO THE BETHE-SALPETER EQUATION APPROACH 239 8.3.2.2 NEUTRAL EXCITATIONS IN HALIDE PEROVSKITES 240 8.4 CONCLUDING REMARKS: FIRST PERSON SINGULAR 242 ACKNOWLEDGMENTS 243 REFERENCES 243 9 COMPARING THE CHARGE DYNAMICS IN MAPBBR 3 AND MAPBL 3 USING MICROWAVE PHOTOCONDUCTANCE MEASUREMENTS 251 TOM J. SAVENIJE, JIASHANG ZHAO, AND VALENTINA M. CASELLI 9.1 TIME-RESOLVED MICROWAVE CONDUCTIVITY 251 9.2 GLOBAL MODELING OF TRMC DATA 254 9.3 TRMC MEASUREMENTS ON MAPBI, AND MAPBBR, 255 9.4 TRMC MEASUREMENTS ON MAPBI, AND MAPBBR 3 WITH CHARGE SELECTIVE CONTACTS 258 ACKNOWLEDGEMENT 261 REFERENCES 261 10 HOT CARRIERS IN HALIDE PEROVSKITES 263 JIA WEI MELVIN LIM, YUE WANG, AND TZE CHIEN SUM 10.1 INTRODUCTION 263 10.1.1 POTENTIAL OF PEROVSKITES FOR NEXT-GENERATION PHOTOVOLTAICS 264 10.2 HOT CARRIER COOLING MECHANISMS 265 10.3 SLOW HOT CARRIER COOLING IN HALIDE PEROVSKITES 266 10.3.1 HOT PHONON BOTTLENECK 266 10.3.2 AUGER HEATING OF HOT CARRIERS 268 10.3.3 LARGE POLARON FORMATION 268 10.3.4 SPECTROSCOPIC SIGNATURE OF HOT CARRIERS 269 10.3.4.1 TRANSIENT ABSORPTION 270 10.3.4.2 FLUORESCENCE-BASED TECHNIQUES 272 10.3.5 HOT CARRIER EXTRACTION 274 10.4 UTILIZING HOT CARRIERS IN HALIDE PEROVSKITES 275 10.4.1 HOT CARRIER SOLAR CELL 275 10.4.2 TOWARD THE REALIZATION OF PEROVSKITE HOT CARRIER SOLAR CELLS 277 10.4.2.1 COOLING LOSS TO THE LATTICE 277 10.4.2.2 ENERGY SELECTIVE CONTACTS 279 10.4.2.3 LOSS OF COLD CARRIERS 279 CONTENTS XI 10.5 10.5.1 10.6 10.6.1 10.6.2 10.6.3 MULTIPLE EXCITON GENERATION 280 MEG METRICS 281 MULTIPLE EXCITON GENERATION MECHANISMS 283 THE DEBATE OVER THE MEG THRESHOLD AND MEG MECHANISM 283 UNDERLYING MECHANISM OF THE EFFICIENT MEG IN PEROVSKITE 285 CONTROVERSY AND PITFALLS OVER PHOTOCHARGING AND ARTIFACTUAL MEG SIGNAL 287 10.7 10.7.1 10.7.2 10.7.3 10.7.4 10.7.4.1 10.7.4.2 10.8 10.8.1 10.8.2 10.9 EFFICIENT MULTIPLE EXCITON GENERATION IN HALIDE PEROVSKITES 289 LOW MULTIPLE EXCITON GENERATION THRESHOLD 290 HIGH MULTIPLE EXCITON GENERATION EFFICIENCY 291 LARGE MULTIPLE EXCITON GENERATION QUANTUM YIELD 291 SPECTROSCOPIC SIGNATURES OF MULTIPLE EXCITON GENERATION 292 TRANSIENT ABSORPTION SPECTROSCOPY 292 PHOTOCURRENT-BASED TECHNIQUES 294 UTILIZING MULTIPLE EXCITON GENERATION IN HALIDE PEROVSKITES 296 MULTIPLE EXCITON GENERATION SOLAR CELLS 296 POTENTIAL OF MULTIPLE EXCITON GENERATION SOLAR CELLS 298 CONCLUSION AND OUTLOOK 299 REFERENCES 300 11 IONIC TRANSPORT IN PEROVSKITE SEMICONDUCTORS 305 WENKE ZHOU, YICHENG ZHAO, AND QING ZHAO 11.1 11.2 11.3 11.4 11.4.1 11.4.2 11.4.3 11.4.4 11.4.5 11.5 11.5.1 11.5.2 11.5.3 11.5.4 11.6 THEORETICAL BASIS OF IONIC TRANSPORT 305 CHARACTERIZATIONS OF IONIC TRANSPORT 306 MOBILE IONS IN PEROVSKITE FILM UNDER ELECTRIC FIELD 309 THE FACTORS AFFECTING IONIC TRANSPORT IN PEROVSKITES 311 MOISTURE 311 LIGHT ILLUMINATION 311 PEROVSKITE COMPOSITION 313 GRAIN BOUNDARY 315 LATTICE STRAIN 317 THE IMPACT OF IONIC TRANSPORT ON PEROVSKITE FILMS AND DEVICES 318 PHASE SEGREGATION 318 DOPING EFFECTS 320 SCLC AND TFT DEVICES 321 DEGRADATION IN FUNCTIONAL DEVICES 322 SUMMARY AND OUTLOOK 322 REFERENCES 324 12 LIGHT EMISSION OF HALIDE PEROVSKITES 329 DAVID O. TIEDE, JUAN F. GALISTEO-LOPEZ, AND HERNAN MIGUEZ 12.1 12.2 12.2.1 12.2.2 INTRODUCTION 329 CHARGE-CARRIER RECOMBINATION IN LEAD-HALIDE PEROVSKITES 330 MONOMOLECULAR RECOMBINATION 331 BIMOLECULAR RECOMBINATION 334 XII CONTENTS 12.2.3 12.2.4 12.2.5 TRIMOLECULAR RECOMBINATION 335 RECOMBINATION CONSTANTS IN EXCITONIC SYSTEMS 336 COMMON RECOMBINATION DYNAMICS MEASUREMENT TECHNIQUES AND EXPERIMENTAL EVIDENCE 337 12.3 12.4 12.5 PHOTOINDUCED EFFECTS ON CHARGE CARRIER RECOMBINATION 338 LASING IN LEAD-HALIDE PEROVSKITES 341 CONCLUSIONS 345 REFERENCES 345 13 EPITAXY AND STRAIN ENGINEERING OF HALIDE PEROVSKITES 351 YANG HU, JIE JIANG, LIFU ZHANG, YUNFENG SHI, AND JIAN SHI 13.1 13.2 13.2.1 13.2.2 13.2.3 13.3 13.3.1 13.3.2 13.4 INTRODUCTION 351 EPITAXY OF THIN FILM AND NANOSTRUCTURES 353 EPITAXIAL SUBSTRATES 353 EPITAXIAL GROWTH AND DEFECTS FORMATION MECHANISMS 355 EXPERIMENTAL PROGRESSES 358 STRAIN ENGINEERING 360 THEORETICAL PROGRESSES 361 EXPERIMENTAL PROGRESSES 363 OPPORTUNITIES AND CHALLENGES 365 ACKNOWLEDGMENTS 366 REFERENCES 367 14 ELECTRON MICROSCOPY OF PEROVSKITE SOLAR CELL MATERIALS 377 MATHIAS U. ROTHMANN, WEI LI, AND ZHIWEI TAO 14.1 14.2 14.3 14.4 14.4.1 14.4.1.1 14.4.1.2 14.4.1.3 14.4.2 14.4.2.1 14.4.2.2 14.4.3 14.4.3.1 14.4.3.2 14.4.3.3 14.4.4 14.4.4.1 14.4.4.2 14.4.4.3 14.4.4.4 INTRODUCTION 377 FUNDAMENTALS OF ELECTRON MICROSCOPY 377 SIGNAL GENERATION 379 SEM 381 CATHODOLUMINESCENCE 381 COMPARISON OF CL AND PHOTOLUMINESCENCE (PL) 382 WORKING PRINCIPLE 382 CL FOR PEROVSKITES 383 ELECTRON-BEAM-INDUCED CURRENT 387 WORKING PRINCIPLE OF EBIC 387 APPLICATIONS 387 ELECTRON BACKSCATTER DIFFRACTION 389 DIFFERENCES BETWEEN EBSD, XRD, AND TEM 390 WORKING PRINCIPLE OF EBSD 391 EBSD FOR PEROVSKITES 392 TEM 395 SAMPLE PREPARATION AND TRANSFER 395 IMAGING CONDITIONS 398 BEAM DAMAGE 400 EXAMPLES OF APPLICATIONS OF TEM 402 CONTENTS XIII 14.5 CONCLUSIONS 406 ACKNOWLEDGMENTS 407 REFERENCES 407 15 IN SITU CHARACTERIZATION OF HALIDE PEROVSKITE SYNTHESIS 411 MAGED ABDELSAMIE, TIM KODALLE, MRIGANKA SINGH, AND CAROLIN M. SUTTER-FELLA 15.1 INTRODUCTION 411 15.2 FUNDAMENTALS OF X-RAY SCATTERING AND FLUORESCENCE TECHNIQUES 412 15.2.1 GRAZING INCIDENCE WIDE-ANGLE X-RAY SCATTERING (GIWAXS) 413 15.2.2 GRAZING INCIDENCE SMALL-ANGLE X-RAY SCATTERING (GISAXS) 414 15.2.3 X-RAY FLUORESCENCE (XRF) 416 15.2.4 SELECTED EXAMPLES FOR IN SITU X-RAY SCATTERING AND FLUORESCENCE 416 15.2.4.1 IN SITU GIWAXS TO STUDY CRYSTALLIZATION KINETICS AND A-SITE DOPING 416 15.2.4.2 IN SITU GIWAXS TO PROBE FILM EVOLUTION VIA ANTISOLVENT AND GAS JET TREATMENTS 418 15.2.4.3 IN SITU X-RAY DIFFRACTION (XRD), XRF, AND GISAXS TO PROBE THE PBCL 2 -DERIVED FORMATION OF MAPBI, 420 15.2.4.4 IN SITU GIWAXS TO PROBE THE 2D PEROVSKITE FORMATION ON 3D FILMS 420 15.3 IN SITU OPTICAL SPECTROSCOPY 423 15.3.1 FUNDAMENTALS OF ABSORPTION AND EMISSION OF LIGHT IN HALIDE PEROVSKITES 423 15.3.2 SETUP DESIGN FOR IN SITU OPTICAL SPECTROSCOPY 425 15.3.3 SELECTED EXAMPLES FOR IN SITU OPTICAL SPECTROSCOPY 426 15.3.3.1 FAST IN SITU REFLECTANCE MEASUREMENTS TO CHARACTERIZE THE PEROVSKITE FORMATION 426 15.3.3.2 IN SITU UV-VIS ABSORBANCE CHARACTERIZATION DURING THE DRYING STAGE 427 15.3.3.3 IN SITU PHOTOLUMINESCENCE CHARACTERIZATION TO INVESTIGATE THE ROLE OF THE PRECURSOR 428 15.4 EXAMPLES OF IN SITU MULTIMODAL CHARACTERIZATION DURING SOLUTION-BASED FABRICATION 430 15.5 PROBING BEAM-SAMPLE INTERACTION 435 15.6 SUMMARY AND OUTLOOK 437 ACKNOWLEDGMENTS 437 REFERENCES 437 16 MULTIMODAL CHARACTERIZATION OF HALIDE PEROVSKITES: FROM THE MACRO TO THE ATOMIC SCALE 443 TIARNAN A. S. DOHERTY AND SAMUEL D. STRANKS 16.1 INTRODUCTION 443 16.2 EARLY MULTIMODAL CHARACTERIZATION WORK 445 16.3 RECENT MULTIMODAL CHARACTERIZATION 450 16.3.1 SUBGRAIN FEATURES 450 XIV CONTENTS 16.3.2 16.3.3 16.4 16.4.1 16.4.2 16.4.3 16.4.4 16.5 STRAIN AND PHOTOPHYSICS 453 ATOMIC SCALE MULTIMODAL STUDIES 462 PRESSING CHALLENGES AND OPPORTUNITIES 464 CHALLENGES: BEAM DAMAGE 464 CHALLENGES: RESOLUTION LIMITS 469 CHALLENGES: IMAGE REGISTRATION AND SAMPLE FABRICATION 470 CHALLENGES: FACILITY ACCESS AND DATA ACQUISITION 471 OUTLOOK AND OPPORTUNITIES 471 REFERENCES 475 INDEX 483
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discipline	Chemie / Pharmazie
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id	DE-604.BV049566596
illustrated	Illustrated
index_date	2024-07-03T23:29:38Z
indexdate	2024-07-20T07:49:30Z
institution	BVB
institution_GND	(DE-588)16179388-5
isbn	9783527348091
language	English
oai_aleph_id	oai:aleph.bib-bvb.de:BVB01-034911883
oclc_num	1427323666
open_access_boolean
owner	DE-29T DE-19 DE-BY-UBM
owner_facet	DE-29T DE-19 DE-BY-UBM
physical	xvi, 495 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm
publishDate	2024
publishDateSearch	2024
publishDateSort	2024
publisher	Wiley-VCH
record_format	marc
spelling	Halide perovskite semiconductors structures, characterization, properties, and phenomena edited by Yuanyuan Zhou and Iván Mora-Seró Weinheim Wiley-VCH [2024] xvi, 495 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm txt rdacontent n rdamedia nc rdacarrier CH92: Festkörperchemie Chemie Chemistry Components & Devices EE60: Komponenten u. Bauelemente Electrical & Electronics Engineering Elektrotechnik u. Elektronik Festkörperchemie Halbleiter Komponenten u. Bauelemente MSA0: Werkstoffprüfung Materials Characterization Materials Science Materialwissenschaften Perowskit Solid State Chemistry Werkstoffprüfung Zhou, Yuanyuan edt Mora-Seró, Iván edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-82901-9 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-82903-3 Erscheint auch als Online-Ausgabe, oBook 978-3-527-82902-6 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34809-1/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034911883&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p vlb 20230406 DE-101 https://d-nb.info/provenance/plan#vlb
spellingShingle	Halide perovskite semiconductors structures, characterization, properties, and phenomena
title	Halide perovskite semiconductors structures, characterization, properties, and phenomena
title_auth	Halide perovskite semiconductors structures, characterization, properties, and phenomena
title_exact_search	Halide perovskite semiconductors structures, characterization, properties, and phenomena
title_exact_search_txtP	Halide perovskite semiconductors structures, characterization, properties, and phenomena
title_full	Halide perovskite semiconductors structures, characterization, properties, and phenomena edited by Yuanyuan Zhou and Iván Mora-Seró
title_fullStr	Halide perovskite semiconductors structures, characterization, properties, and phenomena edited by Yuanyuan Zhou and Iván Mora-Seró
title_full_unstemmed	Halide perovskite semiconductors structures, characterization, properties, and phenomena edited by Yuanyuan Zhou and Iván Mora-Seró
title_short	Halide perovskite semiconductors
title_sort	halide perovskite semiconductors structures characterization properties and phenomena
title_sub	structures, characterization, properties, and phenomena
url	http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34809-1/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034911883&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT zhouyuanyuan halideperovskitesemiconductorsstructurescharacterizationpropertiesandphenomena AT moraseroivan halideperovskitesemiconductorsstructurescharacterizationpropertiesandphenomena AT wileyvch halideperovskitesemiconductorsstructurescharacterizationpropertiesandphenomena

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