Handbook of ionic liquids: fundamentals, applications, and sustainability
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| Weitere Verfasser: | , , , |
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| Format: | Buch |
| Sprache: | English |
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Weinheim, Germany
Wiley-VCH
[2024]
|
| Schlagworte: | |
| Online-Zugang: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35066-7/ Inhaltsverzeichnis |
| Beschreibung: | xviii, 499 Seiten Illustrationen, Diagramme |
| ISBN: | 3527350667 9783527350667 |
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| 020 | |a 3527350667 |9 3-527-35066-7 | ||
| 020 | |a 9783527350667 |c hbk. |9 978-3-527-35066-7 | ||
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| 245 | 1 | 0 | |a Handbook of ionic liquids |b fundamentals, applications, and sustainability |c edited by Sanchayita Rajkhowa, Pardeep Singh, Anik Sen, and Jyotirmoy Sarma |
| 264 | 1 | |a Weinheim, Germany |b Wiley-VCH |c [2024] | |
| 264 | 4 | |c © 2024 | |
| 300 | |a xviii, 499 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Ionische Flüssigkeit |0 (DE-588)7548899-1 |2 gnd |9 rswk-swf |
| 653 | |a Biotechnologie | ||
| 653 | |a Biotechnologie i. d. Chemie | ||
| 653 | |a Biotechnology | ||
| 653 | |a CH31: Biotechnologie i. d. Chemie | ||
| 653 | |a CH40: Katalyse | ||
| 653 | |a CHC0: Nachhaltige u. Grüne Chemie | ||
| 653 | |a Catalysis | ||
| 653 | |a Chemie | ||
| 653 | |a Chemistry | ||
| 653 | |a Ionische Flüssigkeit | ||
| 653 | |a Katalyse | ||
| 653 | |a Nachhaltige u. Grüne Chemie | ||
| 653 | |a Sustainable Chemistry & Green Chemistry | ||
| 655 | 7 | |0 (DE-588)4143413-4 |a Aufsatzsammlung |2 gnd-content | |
| 689 | 0 | 0 | |a Ionische Flüssigkeit |0 (DE-588)7548899-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Singh, Pardeep |0 (DE-588)121433587X |4 edt | |
| 700 | 1 | |a Rajkhowa, Sanchayita |d 1985- |0 (DE-588)1283039532 |4 edt | |
| 700 | 1 | |a Sen, Anik |4 edt | |
| 700 | 1 | |a Sarma, Jyotirmoy |4 edt | |
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| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-527-83950-6 |
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Datensatz im Suchindex
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| adam_text |
CONTENTS
PREFACE
XVII
1
HISTORY
AND
DEVELOPMENT
OF
IONIC
LIQUIDS
1
SUMANA
BRAHMA
AND
RAMESH
L.
GARDAS
1.1
1.2
1.3
1.4
1.5
1.5.1
1.5.2
1.5.3
1.6
1.6.1
1.6.2
1.6.3
1.6.4
1.6.5
1.6.6
1.6.7
1.6.8
1.6.9
1.6.10
1.6.11
1.6.12
1.6.13
1.7
1.8
1.9
INTRODUCTION
1
CONSTITUENTS
OF
ILS
2
THE
BRIEF
HISTORY
3
IONIC
LIQUID-LIKE
SYSTEMS
6
THE
GENERATION
OF
ILS
6
FIRST-GENERATION
ILS
7
SECOND-GENERATION
ILS
7
THIRD-GENERATION
ILS
8
STRUCTURAL
DEVELOPMENT
OF
ILS
9
TASK-SPECIFIC
ILS
(TSILS)
9
CHIRAL
ILS
10
SWITCHABLE
POLARITY
SOLVENT
ILS
11
BIO-ILS
11
POLY-ILS
12
ENERGETIC
ILS
13
METALLIC
ILS
14
PILS
15
ACIDIC
ILS
15
BASIC
ILS
15
NEUTRAL
ILS
16
SUPPORTED
ILS
16
MAGNETIC
ILS
16
SCOPE
OFILS
17
COMMERCIALIZATION
OF
ILS
18
CONCLUSIONS
20
ACKNOWLEDGMENTS
21
REFERENCES
21
VI
CONTENTS
2
GROWTH
OF
IONIC
LIQUIDS
AND
THEIR
APPLICATIONS
29
SUDAKHINA
SAIKIA,
HIMADRI
BORAH,
PANGKITA
DEKA,
AND
REKHA
R,
DUTTA
2.1
2.1.1
2.1.2
2.2
2.2.1
2.2.2
2.2.3
2.2.4
2.2.5
2.2.6
2.3
2.3.1
2.3.1.1
2.3.1.2
2.3.1.3
2.3.2
2.3.2.1
2.3.2.2
2.3.2.3
2.3.3
2.3.4
2.3.5
2.3.6
2.3.7
2.3.8
2.4
INTRODUCTION
29
CATIONS
30
ANIONS
30
GROWTH
OF
IONIC
LIQUIDS
30
QUATERNIZATION
30
ANION
EXCHANGE
32
ACID-BASE
NEUTRALIZATION
32
DIRECT
COMBINATION
33
MICROWAVE-ASSISTED
SYNTHESIS
33
ULTRASOUND-ASSISTED
SYNTHESIS
33
APPLICATIONS
OF
IONIC
LIQUIDS
33
ELECTROCHEMISTRY
33
ELECTRODEPOSITION
34
ELECTROSYNTHESIS
34
ELECTROCATALYSIS
34
SOLVENTS
AND
CATALYSIS
35
IONIC
LIQUIDS
AS
SOLVENTS
FOR
ORGANIC
SYNTHESIS
35
IONIC
LIQUIDS
AS
SOLVENTS
FOR
INORGANIC
SYNTHESIS
37
IONIC
LIQUIDS
AS
CATALYSTS FOR
ORGANIC
REACTIONS
38
SEPARATION
41
HEAT
TRANSPORT
AND
STORAGE
41
ANALYTICS
42
ENGINEERING
42
PERFORMANCE
ADDITIVES
43
BIOTECHNOLOGY
43
CONCLUSION
AND
FUTURE
PROSPECTS
44
REFERENCES
44
3
STUDY
OF
PHYSICOCHEMICAL
PROPERTIES
OF
IONIC
LIQUIDS
51
TRIDIB
MONDAL
AND
PALAS
SAMONTA
3.1
3.2
3.2.1
3.2.2
3.2.3
3.2.4
3.2.5
3.2.6
3.2.7
3.2.8
3.2.9
3.2.10
3.2.11
INTRODUCTION
51
PHYSICOCHEMICAL
PROPERTIES
OF
IONIC
LIQUIDS
52
DENSITY
52
MELTING
POINT
53
THERMAL
STABILITY
AND
DECOMPOSITION
56
CONDUCTIVITY
56
SOLUBILITY
58
SURFACE
TENSION
58
VISCOSITY
59
POLARITY
60
DIFFUSION
60
VAPOR
PRESSURE
61
MISCIBILITY
61
CONTENTS
VII
3.3
CONCLUSION
AND
PERSPECTIVES
62
ACKNOWLEDGMENTS
62
REFERENCES
62
4
IONIC
LIQUIDS
AS
GREEN
SOLVENTS:
ARE
IONIC
LIQUIDS
NONTOXIC
AND
BIODEGRADABLE?
69
HELEN
TREASA
MATHEW,
KUMAR
ABHISEK,
SHASHIKANT
SHIVAJI
VHOTKAR,
ARVIND
KUMAR,
AND
RAMESH
ORAON
4.1
4.2
4.2.1
4.2.2
4.3
4.3.1
INTRODUCTION
69
TOXICITY
AND
BIODEGRADABILITY
OF
IONIC
LIQUIDS
71
TOXICOLOGICAL
EFFECTS
AND
TOXICITY
MECHANISMS
OF
ILS
71
SCOPE
OF
BIODEGRADABLE
AND
NONTOXIC
ILS
76
APPLICATIONS
OF
IONIC
LIQUIDS
AS
GREEN
SOLVENTS
78
IONIC
LIQUIDS
AS
GREEN
SOLVENTS
IN
BIOMASS
UTILIZATION
AND
EXTRACTION
78
4.3.2
4.3.3
4.4
4.4.1
4.4.2
4.4.3
4.5
IONIC
LIQUIDS
AS
GREEN
SOLVENTS
IN
ENERGY
APPLICATIONS
80
IONIC
LIQUIDS
AS
GREEN
SOLVENTS
IN
BIOMEDICAL
APPLICATIONS
81
LONANOFLUIDS
82
PROPERTIES
OF
INFS
82
APPLICATIONS
OF
INFS
85
ARE
LONANOFLUIDS
NONTOXIC
AND
BIODEGRADABLE?
86
CONCLUSION
88
REFERENCES
88
5
PROMISING
USES
OF
IONIC
LIQUIDS
ON
CARBON-CARBON
AND
CARBON-NITROGEN
BOND
FORMATIONS
97
SUDESHNA
KALITA
AND
ANUP
SINGHANIA
5.1
5.2
5.2.1
5.2.1.1
5.2.1.2
5.2.1.3
5.2.1.4
5.2.1.5
5.2.2
5.2.3
5.2.4
5.2.5
5.2.6
5.2.7
5.3
5.3.1
5.3.2
5.3.3
INTRODUCTION
97
CARBON
-
CARBON
BOND
FORMATION
REACTIONS
98
C
-
C
CROSS-COUPLING
REACTIONS
98
HECK
COUPLING
98
SUZUKI
COUPLING
103
SONOGASHIRA
COUPLING
106
STILLE
COUPLING
109
HIYAMA
COUPLING
109
ALDOL
CONDENSATION
111
CLAISEN-SCHMIDT
CONDENSATION
REACTION
113
FRIEDEL-CRAFTS
ALKYLATION
114
DIEL-ALDER
REACTION
114
HENRY
REACTIONS
115
OTHER
C
-
C
BOND
FORMATION
REACTION
116
CARBON
-
NITROGEN
BOND
FORMATION
REACTION
117
BIGINELLI
REACTION
117
N-ALLYLATION
REACTIONS
120
MANNICH
REACTION
121
VIII
CONTENTS
5.3.4
5.4
OTHER
C
-
N
BOND
FORMATION
REACTIONS
123
CONCLUSION
131
REFERENCES
131
6
IONIC
LIQUIDS
IN
SEPARATION
TECHNIQUES
141
HAILU
DEMISSIE,
FIDELIS
0.
AJIBADE,
EDEN
MULU,
JEAN
J.R.
KINHOUN,
TEMITOPE
F.
AJIBADE,
KAYODE
H.
LASISI,
NATHANIEL
A.
NWOGWU,
AND
DANIEL
A.
AYEJOTO
6.1
6.2
6.3
6.3.1
6.3.2
6.3.3
6.3.4
6.3.5
6.3.6
6.3.7
6.4
INTRODUCTION
141
GENERAL
CHARACTERISTICS
OF
ILS
143
THE
USE
OF
ILS
IN
SEPARATION
TECHNOLOGY
145
IL-BASED
SOLID-LIQUID
EXTRACTIONS
145
SIMPLE
SLES
146
MICROWAVE-ASSISTED
EXTRACTIONS
147
ULTRASOUND-ASSISTED
EXTRACTIONS
147
LIQUID-LIQUID
EXTRACTION
148
ILS
AS
MOBILE
PHASE
ADDITIVES
IN
LIQUID
CHROMATOGRAPHY
149
ILS
USED
AS
SURFACE-BONDED
STATIONARY
PHASES
151
CONCLUSIONS
AND
FUTURE
PERSPECTIVES
153
REFERENCES
153
7
POLYMERS
AND
IONIC
LIQUIDS
161
HAILU
DEMISSIE,
FIDELIS
0.
AJIBADE,
JEAN
J.
R.
KINHOUN,
EDEN
MULU,
TEMITOPE
F.
AJIBADE,
EHIAGHE
A.
ELIMIAN,
BASHIR
ADELODUN,
PANKAJ
KUMAR,
AND
OLUWASEYI
A.
AJALA
7.1
7.2
7.3
7.4
7.5
INTRODUCTION
161
PROPERTIES
OF
ILS
163
SYNTHESIS
OF
PILS
166
TYPES
AND
APPLICATION
OF
COMMON
PILS
167
CONCLUSION
167
REFERENCES
172
8
EFFECT
OF
IONIC
LIQUIDS
ON
ELECTROCHEMICAL
BIOSENSORS
AND
OTHER
BIOELECTROCHEMICAL
DEVICES
179
HIMADRI
BORAH,
UPAKUL
DUTTA,
AND
REKHA
R.
DUTTA
8.1
8.2
8.2.1
8.2.2
8.2.3
8.2.4
8.2.5
8.3
8.3.1
8.3.2
8.3.3
INTRODUCTION
179
THE
IMPORTANCE
OF
IONIC
LIQUIDS
IN
ELECTROCHEMISTRY
181
LARGER
ELECTROCHEMICAL
WINDOW
181
IONIC
CONDUCTIVITY
182
HYDROPHOBICITY
183
VISCOSITY
183
CATALYTIC
PERFORMANCE
184
FABRICATION
OF
IL-BASED
SENSING
LAYERS
184
DIRECT
MIXING
184
PHYSICAL
ADSORPTION
185
CASTING
AND
RUBBING
185
CONTENTS
IX
8.3.4
8.3.5
8.3.6
8.3.7
8.4
8.4.1
ELECTRODEPOSITION
185
SOL-GEL
ENCAPSULATION
185
LAYER-BY-LAYER
(LBL)
METHOD
186
SANDWICH-TYPE
IMMUNOASSAY
186
IL-BASED
ELECTROCHEMICAL
BIOSENSORS
186
APPLICATION
OF
RTILS
IN
CONSTRUCTION
OF
ELECTROCHEMICAL
BIOSENSORS
187
8.4.1.1
8.4.1.2
8.4.1.3
8.4.1.4
8.4.1.5
8.5
8.6
CNMS-ILS-BASED
ELECTROCHEMICAL
BIOSENSOR
AS
CANCER
BIOMARKER
189
CNMS-ILS-BASED
ELECTROCHEMICAL
BIOSENSOR
FOR
CARDIAC
DISEASES
190
CNMS-ILS-BASED
ELECTROCHEMICAL
BIOSENSOR
FOR
IMMUNOGLOBULINS
190
CNMS-ILS-BASED
ELECTROCHEMICAL
BIOSENSOR
FOR
NEUROTRANSMITTERS
190
CNMS-ILS-BASED
ELECTROCHEMICAL
GLUCOSE
BIOSENSORS
191
APPLICATION
OF
IONIC
LIQUIDS
IN
BIOELECTROCHEMICAL
DEVICES
191
CONCLUSIONS
AND
FUTURE
PROSPECTS
191
REFERENCES
192
9
NANOPHARMACEUTICALS
WITH
IONIC
LIQUIDS:
A
NOVEL
APPROACH
195
BHARADWAJ
ITTISHREE,
LIPEEKA
ROUT,
VINOD
KASHYAP,
AND
RAHUL
SHARMA
9.1
9.2
9.3
9.4
9.5
9.6
INTRODUCTION
195
APPLICATIONS
OF
IONIC
LIQUIDS
IN
VARIOUS
FIELDS
196
NANOTECHNOLOGY
AND
IONIC
LIQUIDS
197
USE
OF
IONIC
LIQUIDS
IN
NANOCARRIER
DEVELOPMENT
(REPORTED
WORK)
198
IONIC
LIQUID-ASSISTED
METAL
NANOPARTICLES
198
CONCLUSION
201
REFERENCES
201
10
ANTICANCER
ACTIVITY
OF
IONIC
LIQUIDS
203
ATRAYEE
BANASPATI
AND
NIRUPAMJIT
SARMAH
10.1
10.2
10.3
10.4
10.5
INTRODUCTION
203
CLASSIFICATION
OF
IONIC
LIQUIDS
205
TOXICITY
OF
IONIC
LIQUIDS
207
ANTICANCER
POTENTIAL
OF
IONIC
LIQUIDS
209
CONCLUSIONS
AND FUTURE
SCOPE
213
REFERENCES
214
11
IMPORTANCE
OF
IONIC
LIQUIDS
IN
PLANT
DEFENSE:
A
NOVEL
APPROACH
221
MAMUN
MANDAL
AND
ABHIJIT
SARKAR
11.1
11.2
11.3
11.3.1
11.3.2
11.3.3
INTRODUCTION
221
GENERATION
OF
ILS
AND
THEIR
APPLICATION
222
ROLE
OF
ILS
IN
PLANT
DEFENSE
MECHANISMS
224
ILS
AS
ANTIBACTERIAL
AGENTS
224
ILS
AS
ANTIFUNGAL
AGENTS
225
ILS
AS
AN
HERBICIDE
AND
PLANT
GROWTH
PROMOTERS
226
X
CONTENTS
11.3.4
11.3.5
11.3.6
11.4
EFFECTS
OF
ILS
AS
DETERRENTS
227
APPLICATION
OF
ILS
AS
BIOACTIVE
FORMULATIONS
228
ROLE
OF
ILS
IN
SAR
INDUCTION
MECHANISM
228
IL
PRODUCTS
IN
FUTURE
MANAGEMENT
OF
AGRI
INDUSTRIES:
AN
INNOVATIVE
APPROACH
229
11.5
CONCLUSIONS
230
REFERENCES
230
12
THEORETICAL
DESCRIPTION
OF
IONIC
LIQUIDS
235
DANIEL
A.
AYETORO,
NATHANIEL
A.
NWOGWU,
KELECHI
E.
IGWE,
EHIAGHE
A.
ELIMIAN,
HAILU
DEMISSIE,
TEMITOPE
F.
AJIBADE,
ABDULHOMID
YUSUF,
KAYODE
H.
LASISI,
PANKAJ
KUMAR,
BASHIR
ADELODUN,
AND
FIDELIS
0.
AJIBADE
12.1
12.2
12.2.1
12.2.2
12.3
12.4
12.4.1
12.4.2
12.5
12.5.1
12.5.2
12.5.3
12.6
12.7
INTRODUCTION
235
IONIC
LIQUID
DYNAMICS
237
SELF-DIFFUSION
237
VISCOSITY
238
THEORETICAL
ADVANCES
IN
FORCE
FIELDS
AND
ELECTRONIC
STRUCTURES
239
MIXTURES
IN
IONIC
LIQUIDS
241
IONIC
LIQUIDS
AND
INTERFACES
241
IONIC
LIQUIDS
AND
WATER
243
APPLICATIONS
OF
IONIC
LIQUIDS
IN
CHEMICAL
PROCESSES
245
PREAMBLE
245
SEPARATION
AND
PURIFICATION
245
REACTION
MEDIA
IN
CHEMICAL
AND
BIOCHEMICAL
CATALYSIS
245
FUTURE
DEVELOPMENTS
247
CONCLUSION
248
REFERENCES
248
13
THEORETICAL
UNDERSTANDING
OF
IONIC
LIQUID
ADVANCEMENTS
IN
THE
FIELD
OF
MEDICINE
255
MRINAL
K.
SI
13.1
13.2
13.3
13.3.1
13.3.2
13.4
13.4.1
INTRODUCTION
255
A
BRIEF
HISTORY
OF
IONIC
LIQUIDS
AND
DEEP
EUTECTIC
SOLVENTS
257
BIOMEDICAL
APPLICATIONS
257
SOLUBILIZATION
OF
DRUGS
257
PROTEIN
STABILIZATION
258
SUMMARY
AND
FUTURE
ASPECTS
260
DEVELOPING
A
MICROSCOPIC
UNDERSTANDING
TO
ENABLE
TASK-SPECIFIC
DESIGN
260
REFERENCES
260
14
RECENT
DEVELOPMENTS
IN
IONIC
LIQUID
RESEARCH
FROM
ENVIRONMENTAL
PERSPECTIVES
265
PRARTHANA
BORA
AND
SWAPNALI
HAZARIKA
14.1
14.2
INTRODUCTION
265
APPLICATIONS
OF
IONIC
LIQUIDS
267
CONTENTS
14.2.1
14.2.2
14.2.3
14.2.3.1
14.2.3.2
14.2.3.3
14.2.3.4
14.2.4
14.2.5
14.2.6
14.2.7
14.2.8
14.2.9
14.2.10
14.3
14.4
IONIC
LIQUIDS
AS
SOLVENTS
AND
CATALYSTS
267
IONIC
LIQUIDS
IN
ANALYTICAL
CHEMISTRY
268
IONIC
LIQUIDS
IN
ELECTROCHEMICAL
APPLICATIONS
270
IN
ELECTRODEPOSITION
270
ENERGY
MANAGEMENT
270
BIOSCIENCE
271
BIOMECHANICS
271
IONIC
LIQUIDS
IN
INDUSTRIAL
APPLICATIONS
272
IONIC
LIQUID
AS
LUBRICANTS
273
IONIC
LIQUIDS
AS
A
CORROSION
RESISTANT
MATERIAL
274
IONIC
LIQUIDS
AS
ADDITIVES
IN
DRILLING
FLUID
275
IONIC
LIQUIDS
AS
ABSORBENTS
IN
GAS
CAPTURING
276
IONIC
LIQUID
CRYSTALS
277
IONIC
LIQUIDS
IN
BIOMEDICAL
APPLICATIONS
278
LIMITATIONS
OF
IONIC
LIQUIDS
278
CONCLUSION
279
REFERENCES
280
15
IONIC
LIQUIDS
FOR
SUSTAINABLE
BIOMASS
CONVERSION
IN
BIOREFINERY
283
RAKESH
DUTTA
AND
KHEMNATH
PATIR
15.1
15.2
15.3
15.3.1
15.3.2
15.3.3
15.4
15.5
15.6
15.6.1
15.6.2
15.6.3
15.7
INTRODUCTION
283
BIOMASS
AS
A
SOURCE
OF
ORGANIC
COMPOUNDS
AND
FUELS
284
BIOMASS
CONVERSION
PROCESS
285
THERMOCHEMICAL
PROCESS
285
LIGNIN
EXTRACTION
PROCESSES
285
ENZYMATIC
PROCESSES
286
VALUE-ADDED
ORGANIC
COMPOUNDS
FROM
BIOMASS
IN
IONIC
LIQUIDS
286
PRODUCTION
OF
BIODIESEL
WITH
IONIC
LIQUIDS
291
TOXICITY
AND
ECOTOXICITY
OF
ILS
FOR
BIOREFINERY
292
TOXICITY
OF
ILS
USED
IN
BIOREFINERY
293
BIODEGRADATION
OF
ILS
USED
IN
BIOREFINERY
293
CONCLUSION
REGARDING
TOXICITY
AND
BIODEGRADATION
OF
ILS
294
CONCLUSIONS
295
REFERENCES
295
16
IONIC
LIQUIDS
FOR
ATMOSPHERIC
CO
2
CAPTURE:
A
TECHNO-ECONOMIC
ASSESSMENT
301
KUMAR
ABHISEK,
HELEN
T.
MATHEW,
SHASHIKANT
S.
VHATKAR,
DIPTI
S.
SRIVASTAVA,
RAHUL
MINZ,
AND
RAMESH
ORAON
16.1
16.2
16.2.1
16.2.2
16.2.3
INTRODUCTION
301
DIFFERENT
PROCESSES
OF
CO2
CAPTURE
303
MEMBRANE
SEPARATION
304
CRYOGENIC
SEPARATION
305
ABSORPTION
306
XII
CONTENTS
16.2.3.1
16.2.3.2
16.2.3.3
16.2.4
16.2.5
16.3
CHEMICAL
ABSORPTION
306
PHYSICAL
ABSORPTION
311
IONIC
LIQUIDS FOR
PHYSICAL
ABSORPTION
OF
CO
2
313
ADSORPTION
314
IONIC
LIQUIDS
AS
A
CATALYST
FOR
CHEMICAL
FIXATION
OF
CO2
315
CONCLUSION
316
REFERENCES
317
17
RECOVERY
OF
BIOBUTANOL
USING
IONIC
LIQUIDS
333
KALYONI
MOTGHARE,
DIWAKAR
SHENDE,
DHARAM
PAL,
AND
KAILAS
L,
WASEWAR
17.1
17.1.1
17.1.2
17.1.2.1
17.1.2.2
17.1.2.3
17.1.2.4
17.2
17.3
17.3.1
17.3.2
17.4
17.4.1
17.4.1.1
17.4.1.2
17.4.1.3
17.4.1.4
17.4.1.5
17.4.1.6
17.5
17.5.1
17.5.2
17.5.3
17.6
17.7
17.8
INTRODUCTION
333
BIOFUEL
333
CLASSIFICATION
OF
BIOFUELS
333
FIRST
GENERATION
333
SECOND
GENERATION
334
THIRD
GENERATION
334
FOURTH
GENERATION
334
BIOBUTANOL:
FIRST-GENERATION
BIOFUELS
335
BUTANOL
PRODUCTION
335
BUTANOL
PRODUCTION
VIA
BIOCHEMICAL
CONVERSION
335
BUTANOL
PRODUCTION
VIA
PETROCHEMICAL
CONVERSION
336
BUTANOL
RECOVERY
337
BUTANOL
RECOVERY
TECHNIQUES
337
DISTILLATION
337
LIQUID-LIQUID
EXTRACTION
337
PERVAPORATION
338
GAS
STRIPPING
338
PERSTRACTION
338
ADSORPTION
339
IONIC
LIQUIDS
339
IONIC
LIQUIDS:
A
BRIEF
HISTORY
339
PRODUCTION
OF
IONIC
LIQUIDS
341
APPLICATIONS
OF
IONIC
LIQUIDS
341
RECOVERY
OF
BIOBUTANOL
USING
IONIC
LIQUIDS
343
WORLD
BUTANOL
DEMAND
344
CONCLUSION
345
ACKNOWLEDGMENTS
346
REFERENCES
346
18
BIO-CARBOXYLIC
ACID
SEPARATION
BY
IONIC
LIQUIDS
353
ANUJ
KUMAR,
F.M.
ANTONY,
D.Z.
SHENDE,
AND
K.L.
WASEWAR
18.1
18.1.1
INTRODUCTION
353
APPLICATIONS
OF
BIO-CARBOXYLIC
ACIDS
353
CONTENTS
XIII
18.1.2
18.1.3
18.2
18.3
18.4
18.4.1
18.4.2
18.4.3
18.4.4
18.4.5
18.5
MARKET
OF
BIO-CARBOXYLIC
ACIDS
354
PRODUCTION
OF
BIO-CARBOXYLIC
ACIDS
354
IONIC
LIQUIDS
355
CHALLENGES
IN
THE
SEPARATION
OF
BIO-CARBOXYLIC
ACIDS
357
METHODS
FOR
SEPARATING
BIO-CARBOXYLIC
ACIDS
357
DISTILLATION
357
EVAPORATION
359
ADSORPTION
359
MEMBRANE
EXTRACTION
359
SOLVENT
EXTRACTION
360
SEPARATION
OF
BIO-CARBOXYLIC
ACIDS
BY
THE
REACTIVE
EXTRACTION
PROCESS
360
18.6
CONCLUSION
AND
PERSPECTIVES
364
REFERENCES
364
19
CURRENT
TRENDS
IN
QSAR
AND
MACHINE
LEARNING
MODELS
OF
IONIC
LIQUIDS:
EFFICIENT
TOOLS
FOR
DESIGNING
ENVIRONMENTALLY
SAFE
SOLVENTS
FOR
THE
FUTURE
369
SUPRATIK
KAR
AND
JERZY
LESZCZYNSKI
19.1
19.2
19.3
19.4
IONIC
LIQUIDS
AND
THEIR
STRUCTURAL
CHARACTERISTICS
369
PROPERTIES
OF
ILS
372
APPLICATION
OF
ILS
372
DO
ILS
FOLLOW
GREEN
CHEMISTRY
PRINCIPLES
AND
ARE
HAZARD
FREE
FOR
ENVIRONMENT?
375
19.5
19.6
19.7
19.8
19.9
REGULATORY
PROPOSALS
FOR
TOXICITY
ASSESSMENT
OF
ILS
376
WHY
IN
SILICO
MODELING
IS
NEEDED
FOR
ILS
377
PREDICTIVE
TOXICITY
MODELS
FOR
ILS
378
DATABASES
OF
IONIC
LIQUID
380
OVERVIEW
AND
FUTURE
AVENUES
388
DECLARATION
OF
COMPETING
INTEREST
389
ACKNOWLEDGMENTS
389
REFERENCES
389
20
ADVANCES
IN
SIMULATION
RESEARCH
ON
IONIC
LIQUID
ELECTROLYTES
395
HUO
FENG
AND
YUE
BOWEN
20.1
20.1.1
20.1.2
20.1.3
20.2
20.2.1
20.2.2
20.2.3
SIMULATION
METHOD
OF
IONIC
LIQUID
ELECTROLYTES
396
DENSITY
FUNCTIONAL
THEORY
396
AB
INITIO
MOLECULAR
DYNAMICS
SIMULATION
399
MOLECULAR
DYNAMICS
SIMULATION
402
ADVANCES
IN
SIMULATION
OF
IONIC
LIQUID
ELECTROLYTES
IN
BATTERIES
403
IONIC
LIQUIDS
ARE
USED
AS
SOLVENTS
IN
ELECTROLYTES
403
IONIC
LIQUIDS
ARE
USED
AS
SALTS
IN
ELECTROLYTES
407
IONIC
LIQUIDS
ARE
USED
AS
ADDITIVES
IN
ELECTROLYTES
407
XIV|
CONTENTS
20.3
ADVANCES
IN
SIMULATION
OF
IONIC
LIQUID
ELECTROLYTES
IN
CAPACITORS
408
20.3.1
SIMULATION
OF
IONIC
LIQUID
ELECTROLYTES
IN
FLAT-ELECTRODE
CAPACITOR
409
20.3.2
SIMULATION
OF
IONIC
LIQUID ELECTROLYTES
IN
POROUS
ELECTRODE
CAPACITOR
410
20.4
CONCLUSION
413
REFERENCES
414
21
APPLICATIONS
OF
IONIC
LIQUIDS
IN
HETEROCYCLIC
CHEMISTRY
419
SURESH
RAJAMANICKAM
AND
BINOYARGHA
DAM
21.1
INTRODUCTION
419
21.2
APPLICATION
OF
IONIC
LIQUIDS
IN
THE
SYNTHESES
OF
VARIOUS
HETEROCYCLES
421
21.3
CONCLUSION
AND
FUTURE
PROSPECTIVE
440
REFERENCES
440
22
APPLICATION
OF
IONIC
LIQUIDS
IN
DRUG
DEVELOPMENT
443
PARTHA
DUTTA,
CHARU
ARORA,
AND
SANJU
SONI
22.1
INTRODUCTION
443
22.2
CLASSIFICATION
OF
IONIC
LIQUIDS
444
22.3
GENERAL
SYNTHETIC
METHODOLOGIES
444
22.4
AN
OVERVIEW
OF
APPLICATIONS
IN
DIVERSE
FIELDS
445
22.5
SPECIFIC
APPLICATIONS
IN
THE
FIELD
OF
PHARMACEUTICAL
DEVELOPMENT
447
REFERENCES
451
23
APPLICATION
OF
IONIC
LIQUIDS
IN
BIOCATALYSIS
AND
BIOTECHNOLOGY
459
EHIAGHE
AGBOVHIMEN
ELIMIAN,
FIDELIS
ODEDISHEMI
AJIBADE,
TEMITOPE
FAUSAT
AJIBADE,
HAILU
DEMISSIE,
NATHANIEL
AZUBUIKE
NWOGWU,
KAYODE
HASSAN
LASISI,
DANIEL
A.
AYETORO,
AND
EHIZONOMHEN
SOLOMON
OKONOFUA
23.1
INTRODUCTION
460
23.2
PROPERTIES
OF
IONIC
LIQUIDS
460
23.2.1
HYDROPHOBICITY
461
23.2.2
POLARITY
461
23.2.3
PURITY
461
23.2.4
MISCIBILITY
OF
IONIC
LIQUIDS
462
23.2.5
VISCOSITY
462
23.3
WHOLE-CELL
BIOTRANSFORMATIONS
464
23.4
IONIC
LIQUIDS
AS
SOLVENTS
FOR
ENZYME
CATALYSIS
467
23.5
ENZYME
SELECTIVITY
IN
IONIC
LIQUIDS
469
23.5.1
ENANTIOSELECTIVITY
469
23.5.2
REGIOSELECTIVITY
470
23.6
IONIC
LIQUID
STABILITY
OF
ENZYMES
470
CONTENTS
XV
23.7
23.8
23.9
APPLICATION
OF
IONIC
LIQUIDS
IN
BIOETHANOL
PRODUCTION
471
IONIC
LIQUIDS
APPLIED
IN
THE
SYNTHESIS
OF
BIODIESEL
475
CONCLUSION
479
REFERENCES
479
INDEX
489 |
| adam_txt |
CONTENTS
PREFACE
XVII
1
HISTORY
AND
DEVELOPMENT
OF
IONIC
LIQUIDS
1
SUMANA
BRAHMA
AND
RAMESH
L.
GARDAS
1.1
1.2
1.3
1.4
1.5
1.5.1
1.5.2
1.5.3
1.6
1.6.1
1.6.2
1.6.3
1.6.4
1.6.5
1.6.6
1.6.7
1.6.8
1.6.9
1.6.10
1.6.11
1.6.12
1.6.13
1.7
1.8
1.9
INTRODUCTION
1
CONSTITUENTS
OF
ILS
2
THE
BRIEF
HISTORY
3
IONIC
LIQUID-LIKE
SYSTEMS
6
THE
GENERATION
OF
ILS
6
FIRST-GENERATION
ILS
7
SECOND-GENERATION
ILS
7
THIRD-GENERATION
ILS
8
STRUCTURAL
DEVELOPMENT
OF
ILS
9
TASK-SPECIFIC
ILS
(TSILS)
9
CHIRAL
ILS
10
SWITCHABLE
POLARITY
SOLVENT
ILS
11
BIO-ILS
11
POLY-ILS
12
ENERGETIC
ILS
13
METALLIC
ILS
14
PILS
15
ACIDIC
ILS
15
BASIC
ILS
15
NEUTRAL
ILS
16
SUPPORTED
ILS
16
MAGNETIC
ILS
16
SCOPE
OFILS
17
COMMERCIALIZATION
OF
ILS
18
CONCLUSIONS
20
ACKNOWLEDGMENTS
21
REFERENCES
21
VI
CONTENTS
2
GROWTH
OF
IONIC
LIQUIDS
AND
THEIR
APPLICATIONS
29
SUDAKHINA
SAIKIA,
HIMADRI
BORAH,
PANGKITA
DEKA,
AND
REKHA
R,
DUTTA
2.1
2.1.1
2.1.2
2.2
2.2.1
2.2.2
2.2.3
2.2.4
2.2.5
2.2.6
2.3
2.3.1
2.3.1.1
2.3.1.2
2.3.1.3
2.3.2
2.3.2.1
2.3.2.2
2.3.2.3
2.3.3
2.3.4
2.3.5
2.3.6
2.3.7
2.3.8
2.4
INTRODUCTION
29
CATIONS
30
ANIONS
30
GROWTH
OF
IONIC
LIQUIDS
30
QUATERNIZATION
30
ANION
EXCHANGE
32
ACID-BASE
NEUTRALIZATION
32
DIRECT
COMBINATION
33
MICROWAVE-ASSISTED
SYNTHESIS
33
ULTRASOUND-ASSISTED
SYNTHESIS
33
APPLICATIONS
OF
IONIC
LIQUIDS
33
ELECTROCHEMISTRY
33
ELECTRODEPOSITION
34
ELECTROSYNTHESIS
34
ELECTROCATALYSIS
34
SOLVENTS
AND
CATALYSIS
35
IONIC
LIQUIDS
AS
SOLVENTS
FOR
ORGANIC
SYNTHESIS
35
IONIC
LIQUIDS
AS
SOLVENTS
FOR
INORGANIC
SYNTHESIS
37
IONIC
LIQUIDS
AS
CATALYSTS FOR
ORGANIC
REACTIONS
38
SEPARATION
41
HEAT
TRANSPORT
AND
STORAGE
41
ANALYTICS
42
ENGINEERING
42
PERFORMANCE
ADDITIVES
43
BIOTECHNOLOGY
43
CONCLUSION
AND
FUTURE
PROSPECTS
44
REFERENCES
44
3
STUDY
OF
PHYSICOCHEMICAL
PROPERTIES
OF
IONIC
LIQUIDS
51
TRIDIB
MONDAL
AND
PALAS
SAMONTA
3.1
3.2
3.2.1
3.2.2
3.2.3
3.2.4
3.2.5
3.2.6
3.2.7
3.2.8
3.2.9
3.2.10
3.2.11
INTRODUCTION
51
PHYSICOCHEMICAL
PROPERTIES
OF
IONIC
LIQUIDS
52
DENSITY
52
MELTING
POINT
53
THERMAL
STABILITY
AND
DECOMPOSITION
56
CONDUCTIVITY
56
SOLUBILITY
58
SURFACE
TENSION
58
VISCOSITY
59
POLARITY
60
DIFFUSION
60
VAPOR
PRESSURE
61
MISCIBILITY
61
CONTENTS
VII
3.3
CONCLUSION
AND
PERSPECTIVES
62
ACKNOWLEDGMENTS
62
REFERENCES
62
4
IONIC
LIQUIDS
AS
GREEN
SOLVENTS:
ARE
IONIC
LIQUIDS
NONTOXIC
AND
BIODEGRADABLE?
69
HELEN
TREASA
MATHEW,
KUMAR
ABHISEK,
SHASHIKANT
SHIVAJI
VHOTKAR,
ARVIND
KUMAR,
AND
RAMESH
ORAON
4.1
4.2
4.2.1
4.2.2
4.3
4.3.1
INTRODUCTION
69
TOXICITY
AND
BIODEGRADABILITY
OF
IONIC
LIQUIDS
71
TOXICOLOGICAL
EFFECTS
AND
TOXICITY
MECHANISMS
OF
ILS
71
SCOPE
OF
BIODEGRADABLE
AND
NONTOXIC
ILS
76
APPLICATIONS
OF
IONIC
LIQUIDS
AS
GREEN
SOLVENTS
78
IONIC
LIQUIDS
AS
GREEN
SOLVENTS
IN
BIOMASS
UTILIZATION
AND
EXTRACTION
78
4.3.2
4.3.3
4.4
4.4.1
4.4.2
4.4.3
4.5
IONIC
LIQUIDS
AS
GREEN
SOLVENTS
IN
ENERGY
APPLICATIONS
80
IONIC
LIQUIDS
AS
GREEN
SOLVENTS
IN
BIOMEDICAL
APPLICATIONS
81
LONANOFLUIDS
82
PROPERTIES
OF
INFS
82
APPLICATIONS
OF
INFS
85
ARE
LONANOFLUIDS
NONTOXIC
AND
BIODEGRADABLE?
86
CONCLUSION
88
REFERENCES
88
5
PROMISING
USES
OF
IONIC
LIQUIDS
ON
CARBON-CARBON
AND
CARBON-NITROGEN
BOND
FORMATIONS
97
SUDESHNA
KALITA
AND
ANUP
SINGHANIA
5.1
5.2
5.2.1
5.2.1.1
5.2.1.2
5.2.1.3
5.2.1.4
5.2.1.5
5.2.2
5.2.3
5.2.4
5.2.5
5.2.6
5.2.7
5.3
5.3.1
5.3.2
5.3.3
INTRODUCTION
97
CARBON
-
CARBON
BOND
FORMATION
REACTIONS
98
C
-
C
CROSS-COUPLING
REACTIONS
98
HECK
COUPLING
98
SUZUKI
COUPLING
103
SONOGASHIRA
COUPLING
106
STILLE
COUPLING
109
HIYAMA
COUPLING
109
ALDOL
CONDENSATION
111
CLAISEN-SCHMIDT
CONDENSATION
REACTION
113
FRIEDEL-CRAFTS
ALKYLATION
114
DIEL-ALDER
REACTION
114
HENRY
REACTIONS
115
OTHER
C
-
C
BOND
FORMATION
REACTION
116
CARBON
-
NITROGEN
BOND
FORMATION
REACTION
117
BIGINELLI
REACTION
117
N-ALLYLATION
REACTIONS
120
MANNICH
REACTION
121
VIII
CONTENTS
5.3.4
5.4
OTHER
C
-
N
BOND
FORMATION
REACTIONS
123
CONCLUSION
131
REFERENCES
131
6
IONIC
LIQUIDS
IN
SEPARATION
TECHNIQUES
141
HAILU
DEMISSIE,
FIDELIS
0.
AJIBADE,
EDEN
MULU,
JEAN
J.R.
KINHOUN,
TEMITOPE
F.
AJIBADE,
KAYODE
H.
LASISI,
NATHANIEL
A.
NWOGWU,
AND
DANIEL
A.
AYEJOTO
6.1
6.2
6.3
6.3.1
6.3.2
6.3.3
6.3.4
6.3.5
6.3.6
6.3.7
6.4
INTRODUCTION
141
GENERAL
CHARACTERISTICS
OF
ILS
143
THE
USE
OF
ILS
IN
SEPARATION
TECHNOLOGY
145
IL-BASED
SOLID-LIQUID
EXTRACTIONS
145
SIMPLE
SLES
146
MICROWAVE-ASSISTED
EXTRACTIONS
147
ULTRASOUND-ASSISTED
EXTRACTIONS
147
LIQUID-LIQUID
EXTRACTION
148
ILS
AS
MOBILE
PHASE
ADDITIVES
IN
LIQUID
CHROMATOGRAPHY
149
ILS
USED
AS
SURFACE-BONDED
STATIONARY
PHASES
151
CONCLUSIONS
AND
FUTURE
PERSPECTIVES
153
REFERENCES
153
7
POLYMERS
AND
IONIC
LIQUIDS
161
HAILU
DEMISSIE,
FIDELIS
0.
AJIBADE,
JEAN
J.
R.
KINHOUN,
EDEN
MULU,
TEMITOPE
F.
AJIBADE,
EHIAGHE
A.
ELIMIAN,
BASHIR
ADELODUN,
PANKAJ
KUMAR,
AND
OLUWASEYI
A.
AJALA
7.1
7.2
7.3
7.4
7.5
INTRODUCTION
161
PROPERTIES
OF
ILS
163
SYNTHESIS
OF
PILS
166
TYPES
AND
APPLICATION
OF
COMMON
PILS
167
CONCLUSION
167
REFERENCES
172
8
EFFECT
OF
IONIC
LIQUIDS
ON
ELECTROCHEMICAL
BIOSENSORS
AND
OTHER
BIOELECTROCHEMICAL
DEVICES
179
HIMADRI
BORAH,
UPAKUL
DUTTA,
AND
REKHA
R.
DUTTA
8.1
8.2
8.2.1
8.2.2
8.2.3
8.2.4
8.2.5
8.3
8.3.1
8.3.2
8.3.3
INTRODUCTION
179
THE
IMPORTANCE
OF
IONIC
LIQUIDS
IN
ELECTROCHEMISTRY
181
LARGER
ELECTROCHEMICAL
WINDOW
181
IONIC
CONDUCTIVITY
182
HYDROPHOBICITY
183
VISCOSITY
183
CATALYTIC
PERFORMANCE
184
FABRICATION
OF
IL-BASED
SENSING
LAYERS
184
DIRECT
MIXING
184
PHYSICAL
ADSORPTION
185
CASTING
AND
RUBBING
185
CONTENTS
IX
8.3.4
8.3.5
8.3.6
8.3.7
8.4
8.4.1
ELECTRODEPOSITION
185
SOL-GEL
ENCAPSULATION
185
LAYER-BY-LAYER
(LBL)
METHOD
186
SANDWICH-TYPE
IMMUNOASSAY
186
IL-BASED
ELECTROCHEMICAL
BIOSENSORS
186
APPLICATION
OF
RTILS
IN
CONSTRUCTION
OF
ELECTROCHEMICAL
BIOSENSORS
187
8.4.1.1
8.4.1.2
8.4.1.3
8.4.1.4
8.4.1.5
8.5
8.6
CNMS-ILS-BASED
ELECTROCHEMICAL
BIOSENSOR
AS
CANCER
BIOMARKER
189
CNMS-ILS-BASED
ELECTROCHEMICAL
BIOSENSOR
FOR
CARDIAC
DISEASES
190
CNMS-ILS-BASED
ELECTROCHEMICAL
BIOSENSOR
FOR
IMMUNOGLOBULINS
190
CNMS-ILS-BASED
ELECTROCHEMICAL
BIOSENSOR
FOR
NEUROTRANSMITTERS
190
CNMS-ILS-BASED
ELECTROCHEMICAL
GLUCOSE
BIOSENSORS
191
APPLICATION
OF
IONIC
LIQUIDS
IN
BIOELECTROCHEMICAL
DEVICES
191
CONCLUSIONS
AND
FUTURE
PROSPECTS
191
REFERENCES
192
9
NANOPHARMACEUTICALS
WITH
IONIC
LIQUIDS:
A
NOVEL
APPROACH
195
BHARADWAJ
ITTISHREE,
LIPEEKA
ROUT,
VINOD
KASHYAP,
AND
RAHUL
SHARMA
9.1
9.2
9.3
9.4
9.5
9.6
INTRODUCTION
195
APPLICATIONS
OF
IONIC
LIQUIDS
IN
VARIOUS
FIELDS
196
NANOTECHNOLOGY
AND
IONIC
LIQUIDS
197
USE
OF
IONIC
LIQUIDS
IN
NANOCARRIER
DEVELOPMENT
(REPORTED
WORK)
198
IONIC
LIQUID-ASSISTED
METAL
NANOPARTICLES
198
CONCLUSION
201
REFERENCES
201
10
ANTICANCER
ACTIVITY
OF
IONIC
LIQUIDS
203
ATRAYEE
BANASPATI
AND
NIRUPAMJIT
SARMAH
10.1
10.2
10.3
10.4
10.5
INTRODUCTION
203
CLASSIFICATION
OF
IONIC
LIQUIDS
205
TOXICITY
OF
IONIC
LIQUIDS
207
ANTICANCER
POTENTIAL
OF
IONIC
LIQUIDS
209
CONCLUSIONS
AND FUTURE
SCOPE
213
REFERENCES
214
11
IMPORTANCE
OF
IONIC
LIQUIDS
IN
PLANT
DEFENSE:
A
NOVEL
APPROACH
221
MAMUN
MANDAL
AND
ABHIJIT
SARKAR
11.1
11.2
11.3
11.3.1
11.3.2
11.3.3
INTRODUCTION
221
GENERATION
OF
ILS
AND
THEIR
APPLICATION
222
ROLE
OF
ILS
IN
PLANT
DEFENSE
MECHANISMS
224
ILS
AS
ANTIBACTERIAL
AGENTS
224
ILS
AS
ANTIFUNGAL
AGENTS
225
ILS
AS
AN
HERBICIDE
AND
PLANT
GROWTH
PROMOTERS
226
X
CONTENTS
11.3.4
11.3.5
11.3.6
11.4
EFFECTS
OF
ILS
AS
DETERRENTS
227
APPLICATION
OF
ILS
AS
BIOACTIVE
FORMULATIONS
228
ROLE
OF
ILS
IN
SAR
INDUCTION
MECHANISM
228
IL
PRODUCTS
IN
FUTURE
MANAGEMENT
OF
AGRI
INDUSTRIES:
AN
INNOVATIVE
APPROACH
229
11.5
CONCLUSIONS
230
REFERENCES
230
12
THEORETICAL
DESCRIPTION
OF
IONIC
LIQUIDS
235
DANIEL
A.
AYETORO,
NATHANIEL
A.
NWOGWU,
KELECHI
E.
IGWE,
EHIAGHE
A.
ELIMIAN,
HAILU
DEMISSIE,
TEMITOPE
F.
AJIBADE,
ABDULHOMID
YUSUF,
KAYODE
H.
LASISI,
PANKAJ
KUMAR,
BASHIR
ADELODUN,
AND
FIDELIS
0.
AJIBADE
12.1
12.2
12.2.1
12.2.2
12.3
12.4
12.4.1
12.4.2
12.5
12.5.1
12.5.2
12.5.3
12.6
12.7
INTRODUCTION
235
IONIC
LIQUID
DYNAMICS
237
SELF-DIFFUSION
237
VISCOSITY
238
THEORETICAL
ADVANCES
IN
FORCE
FIELDS
AND
ELECTRONIC
STRUCTURES
239
MIXTURES
IN
IONIC
LIQUIDS
241
IONIC
LIQUIDS
AND
INTERFACES
241
IONIC
LIQUIDS
AND
WATER
243
APPLICATIONS
OF
IONIC
LIQUIDS
IN
CHEMICAL
PROCESSES
245
PREAMBLE
245
SEPARATION
AND
PURIFICATION
245
REACTION
MEDIA
IN
CHEMICAL
AND
BIOCHEMICAL
CATALYSIS
245
FUTURE
DEVELOPMENTS
247
CONCLUSION
248
REFERENCES
248
13
THEORETICAL
UNDERSTANDING
OF
IONIC
LIQUID
ADVANCEMENTS
IN
THE
FIELD
OF
MEDICINE
255
MRINAL
K.
SI
13.1
13.2
13.3
13.3.1
13.3.2
13.4
13.4.1
INTRODUCTION
255
A
BRIEF
HISTORY
OF
IONIC
LIQUIDS
AND
DEEP
EUTECTIC
SOLVENTS
257
BIOMEDICAL
APPLICATIONS
257
SOLUBILIZATION
OF
DRUGS
257
PROTEIN
STABILIZATION
258
SUMMARY
AND
FUTURE
ASPECTS
260
DEVELOPING
A
MICROSCOPIC
UNDERSTANDING
TO
ENABLE
TASK-SPECIFIC
DESIGN
260
REFERENCES
260
14
RECENT
DEVELOPMENTS
IN
IONIC
LIQUID
RESEARCH
FROM
ENVIRONMENTAL
PERSPECTIVES
265
PRARTHANA
BORA
AND
SWAPNALI
HAZARIKA
14.1
14.2
INTRODUCTION
265
APPLICATIONS
OF
IONIC
LIQUIDS
267
CONTENTS
14.2.1
14.2.2
14.2.3
14.2.3.1
14.2.3.2
14.2.3.3
14.2.3.4
14.2.4
14.2.5
14.2.6
14.2.7
14.2.8
14.2.9
14.2.10
14.3
14.4
IONIC
LIQUIDS
AS
SOLVENTS
AND
CATALYSTS
267
IONIC
LIQUIDS
IN
ANALYTICAL
CHEMISTRY
268
IONIC
LIQUIDS
IN
ELECTROCHEMICAL
APPLICATIONS
270
IN
ELECTRODEPOSITION
270
ENERGY
MANAGEMENT
270
BIOSCIENCE
271
BIOMECHANICS
271
IONIC
LIQUIDS
IN
INDUSTRIAL
APPLICATIONS
272
IONIC
LIQUID
AS
LUBRICANTS
273
IONIC
LIQUIDS
AS
A
CORROSION
RESISTANT
MATERIAL
274
IONIC
LIQUIDS
AS
ADDITIVES
IN
DRILLING
FLUID
275
IONIC
LIQUIDS
AS
ABSORBENTS
IN
GAS
CAPTURING
276
IONIC
LIQUID
CRYSTALS
277
IONIC
LIQUIDS
IN
BIOMEDICAL
APPLICATIONS
278
LIMITATIONS
OF
IONIC
LIQUIDS
278
CONCLUSION
279
REFERENCES
280
15
IONIC
LIQUIDS
FOR
SUSTAINABLE
BIOMASS
CONVERSION
IN
BIOREFINERY
283
RAKESH
DUTTA
AND
KHEMNATH
PATIR
15.1
15.2
15.3
15.3.1
15.3.2
15.3.3
15.4
15.5
15.6
15.6.1
15.6.2
15.6.3
15.7
INTRODUCTION
283
BIOMASS
AS
A
SOURCE
OF
ORGANIC
COMPOUNDS
AND
FUELS
284
BIOMASS
CONVERSION
PROCESS
285
THERMOCHEMICAL
PROCESS
285
LIGNIN
EXTRACTION
PROCESSES
285
ENZYMATIC
PROCESSES
286
VALUE-ADDED
ORGANIC
COMPOUNDS
FROM
BIOMASS
IN
IONIC
LIQUIDS
286
PRODUCTION
OF
BIODIESEL
WITH
IONIC
LIQUIDS
291
TOXICITY
AND
ECOTOXICITY
OF
ILS
FOR
BIOREFINERY
292
TOXICITY
OF
ILS
USED
IN
BIOREFINERY
293
BIODEGRADATION
OF
ILS
USED
IN
BIOREFINERY
293
CONCLUSION
REGARDING
TOXICITY
AND
BIODEGRADATION
OF
ILS
294
CONCLUSIONS
295
REFERENCES
295
16
IONIC
LIQUIDS
FOR
ATMOSPHERIC
CO
2
CAPTURE:
A
TECHNO-ECONOMIC
ASSESSMENT
301
KUMAR
ABHISEK,
HELEN
T.
MATHEW,
SHASHIKANT
S.
VHATKAR,
DIPTI
S.
SRIVASTAVA,
RAHUL
MINZ,
AND
RAMESH
ORAON
16.1
16.2
16.2.1
16.2.2
16.2.3
INTRODUCTION
301
DIFFERENT
PROCESSES
OF
CO2
CAPTURE
303
MEMBRANE
SEPARATION
304
CRYOGENIC
SEPARATION
305
ABSORPTION
306
XII
CONTENTS
16.2.3.1
16.2.3.2
16.2.3.3
16.2.4
16.2.5
16.3
CHEMICAL
ABSORPTION
306
PHYSICAL
ABSORPTION
311
IONIC
LIQUIDS FOR
PHYSICAL
ABSORPTION
OF
CO
2
313
ADSORPTION
314
IONIC
LIQUIDS
AS
A
CATALYST
FOR
CHEMICAL
FIXATION
OF
CO2
315
CONCLUSION
316
REFERENCES
317
17
RECOVERY
OF
BIOBUTANOL
USING
IONIC
LIQUIDS
333
KALYONI
MOTGHARE,
DIWAKAR
SHENDE,
DHARAM
PAL,
AND
KAILAS
L,
WASEWAR
17.1
17.1.1
17.1.2
17.1.2.1
17.1.2.2
17.1.2.3
17.1.2.4
17.2
17.3
17.3.1
17.3.2
17.4
17.4.1
17.4.1.1
17.4.1.2
17.4.1.3
17.4.1.4
17.4.1.5
17.4.1.6
17.5
17.5.1
17.5.2
17.5.3
17.6
17.7
17.8
INTRODUCTION
333
BIOFUEL
333
CLASSIFICATION
OF
BIOFUELS
333
FIRST
GENERATION
333
SECOND
GENERATION
334
THIRD
GENERATION
334
FOURTH
GENERATION
334
BIOBUTANOL:
FIRST-GENERATION
BIOFUELS
335
BUTANOL
PRODUCTION
335
BUTANOL
PRODUCTION
VIA
BIOCHEMICAL
CONVERSION
335
BUTANOL
PRODUCTION
VIA
PETROCHEMICAL
CONVERSION
336
BUTANOL
RECOVERY
337
BUTANOL
RECOVERY
TECHNIQUES
337
DISTILLATION
337
LIQUID-LIQUID
EXTRACTION
337
PERVAPORATION
338
GAS
STRIPPING
338
PERSTRACTION
338
ADSORPTION
339
IONIC
LIQUIDS
339
IONIC
LIQUIDS:
A
BRIEF
HISTORY
339
PRODUCTION
OF
IONIC
LIQUIDS
341
APPLICATIONS
OF
IONIC
LIQUIDS
341
RECOVERY
OF
BIOBUTANOL
USING
IONIC
LIQUIDS
343
WORLD
BUTANOL
DEMAND
344
CONCLUSION
345
ACKNOWLEDGMENTS
346
REFERENCES
346
18
BIO-CARBOXYLIC
ACID
SEPARATION
BY
IONIC
LIQUIDS
353
ANUJ
KUMAR,
F.M.
ANTONY,
D.Z.
SHENDE,
AND
K.L.
WASEWAR
18.1
18.1.1
INTRODUCTION
353
APPLICATIONS
OF
BIO-CARBOXYLIC
ACIDS
353
CONTENTS
XIII
18.1.2
18.1.3
18.2
18.3
18.4
18.4.1
18.4.2
18.4.3
18.4.4
18.4.5
18.5
MARKET
OF
BIO-CARBOXYLIC
ACIDS
354
PRODUCTION
OF
BIO-CARBOXYLIC
ACIDS
354
IONIC
LIQUIDS
355
CHALLENGES
IN
THE
SEPARATION
OF
BIO-CARBOXYLIC
ACIDS
357
METHODS
FOR
SEPARATING
BIO-CARBOXYLIC
ACIDS
357
DISTILLATION
357
EVAPORATION
359
ADSORPTION
359
MEMBRANE
EXTRACTION
359
SOLVENT
EXTRACTION
360
SEPARATION
OF
BIO-CARBOXYLIC
ACIDS
BY
THE
REACTIVE
EXTRACTION
PROCESS
360
18.6
CONCLUSION
AND
PERSPECTIVES
364
REFERENCES
364
19
CURRENT
TRENDS
IN
QSAR
AND
MACHINE
LEARNING
MODELS
OF
IONIC
LIQUIDS:
EFFICIENT
TOOLS
FOR
DESIGNING
ENVIRONMENTALLY
SAFE
SOLVENTS
FOR
THE
FUTURE
369
SUPRATIK
KAR
AND
JERZY
LESZCZYNSKI
19.1
19.2
19.3
19.4
IONIC
LIQUIDS
AND
THEIR
STRUCTURAL
CHARACTERISTICS
369
PROPERTIES
OF
ILS
372
APPLICATION
OF
ILS
372
DO
ILS
FOLLOW
GREEN
CHEMISTRY
PRINCIPLES
AND
ARE
HAZARD
FREE
FOR
ENVIRONMENT?
375
19.5
19.6
19.7
19.8
19.9
REGULATORY
PROPOSALS
FOR
TOXICITY
ASSESSMENT
OF
ILS
376
WHY
IN
SILICO
MODELING
IS
NEEDED
FOR
ILS
377
PREDICTIVE
TOXICITY
MODELS
FOR
ILS
378
DATABASES
OF
IONIC
LIQUID
380
OVERVIEW
AND
FUTURE
AVENUES
388
DECLARATION
OF
COMPETING
INTEREST
389
ACKNOWLEDGMENTS
389
REFERENCES
389
20
ADVANCES
IN
SIMULATION
RESEARCH
ON
IONIC
LIQUID
ELECTROLYTES
395
HUO
FENG
AND
YUE
BOWEN
20.1
20.1.1
20.1.2
20.1.3
20.2
20.2.1
20.2.2
20.2.3
SIMULATION
METHOD
OF
IONIC
LIQUID
ELECTROLYTES
396
DENSITY
FUNCTIONAL
THEORY
396
AB
INITIO
MOLECULAR
DYNAMICS
SIMULATION
399
MOLECULAR
DYNAMICS
SIMULATION
402
ADVANCES
IN
SIMULATION
OF
IONIC
LIQUID
ELECTROLYTES
IN
BATTERIES
403
IONIC
LIQUIDS
ARE
USED
AS
SOLVENTS
IN
ELECTROLYTES
403
IONIC
LIQUIDS
ARE
USED
AS
SALTS
IN
ELECTROLYTES
407
IONIC
LIQUIDS
ARE
USED
AS
ADDITIVES
IN
ELECTROLYTES
407
XIV|
CONTENTS
20.3
ADVANCES
IN
SIMULATION
OF
IONIC
LIQUID
ELECTROLYTES
IN
CAPACITORS
408
20.3.1
SIMULATION
OF
IONIC
LIQUID
ELECTROLYTES
IN
FLAT-ELECTRODE
CAPACITOR
409
20.3.2
SIMULATION
OF
IONIC
LIQUID ELECTROLYTES
IN
POROUS
ELECTRODE
CAPACITOR
410
20.4
CONCLUSION
413
REFERENCES
414
21
APPLICATIONS
OF
IONIC
LIQUIDS
IN
HETEROCYCLIC
CHEMISTRY
419
SURESH
RAJAMANICKAM
AND
BINOYARGHA
DAM
21.1
INTRODUCTION
419
21.2
APPLICATION
OF
IONIC
LIQUIDS
IN
THE
SYNTHESES
OF
VARIOUS
HETEROCYCLES
421
21.3
CONCLUSION
AND
FUTURE
PROSPECTIVE
440
REFERENCES
440
22
APPLICATION
OF
IONIC
LIQUIDS
IN
DRUG
DEVELOPMENT
443
PARTHA
DUTTA,
CHARU
ARORA,
AND
SANJU
SONI
22.1
INTRODUCTION
443
22.2
CLASSIFICATION
OF
IONIC
LIQUIDS
444
22.3
GENERAL
SYNTHETIC
METHODOLOGIES
444
22.4
AN
OVERVIEW
OF
APPLICATIONS
IN
DIVERSE
FIELDS
445
22.5
SPECIFIC
APPLICATIONS
IN
THE
FIELD
OF
PHARMACEUTICAL
DEVELOPMENT
447
REFERENCES
451
23
APPLICATION
OF
IONIC
LIQUIDS
IN
BIOCATALYSIS
AND
BIOTECHNOLOGY
459
EHIAGHE
AGBOVHIMEN
ELIMIAN,
FIDELIS
ODEDISHEMI
AJIBADE,
TEMITOPE
FAUSAT
AJIBADE,
HAILU
DEMISSIE,
NATHANIEL
AZUBUIKE
NWOGWU,
KAYODE
HASSAN
LASISI,
DANIEL
A.
AYETORO,
AND
EHIZONOMHEN
SOLOMON
OKONOFUA
23.1
INTRODUCTION
460
23.2
PROPERTIES
OF
IONIC
LIQUIDS
460
23.2.1
HYDROPHOBICITY
461
23.2.2
POLARITY
461
23.2.3
PURITY
461
23.2.4
MISCIBILITY
OF
IONIC
LIQUIDS
462
23.2.5
VISCOSITY
462
23.3
WHOLE-CELL
BIOTRANSFORMATIONS
464
23.4
IONIC
LIQUIDS
AS
SOLVENTS
FOR
ENZYME
CATALYSIS
467
23.5
ENZYME
SELECTIVITY
IN
IONIC
LIQUIDS
469
23.5.1
ENANTIOSELECTIVITY
469
23.5.2
REGIOSELECTIVITY
470
23.6
IONIC
LIQUID
STABILITY
OF
ENZYMES
470
CONTENTS
XV
23.7
23.8
23.9
APPLICATION
OF
IONIC
LIQUIDS
IN
BIOETHANOL
PRODUCTION
471
IONIC
LIQUIDS
APPLIED
IN
THE
SYNTHESIS
OF
BIODIESEL
475
CONCLUSION
479
REFERENCES
479
INDEX
489 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author2 | Singh, Pardeep Rajkhowa, Sanchayita 1985- Sen, Anik Sarma, Jyotirmoy |
| author2_role | edt edt edt edt |
| author2_variant | p s ps s r sr a s as j s js |
| author_GND | (DE-588)121433587X (DE-588)1283039532 |
| author_facet | Singh, Pardeep Rajkhowa, Sanchayita 1985- Sen, Anik Sarma, Jyotirmoy |
| building | Verbundindex |
| bvnumber | BV049512109 |
| classification_rvk | VE 7300 VE 6350 |
| ctrlnum | (OCoLC)1429298471 (DE-599)DNB1289337608 |
| discipline | Chemie / Pharmazie |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV049512109 |
| illustrated | Illustrated |
| index_date | 2024-07-03T23:23:19Z |
| indexdate | 2024-07-20T09:04:23Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 3527350667 9783527350667 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-034858135 |
| oclc_num | 1429298471 |
| open_access_boolean | |
| owner | DE-29T DE-11 DE-19 DE-BY-UBM |
| owner_facet | DE-29T DE-11 DE-19 DE-BY-UBM |
| physical | xviii, 499 Seiten Illustrationen, Diagramme |
| publishDate | 2024 |
| publishDateSearch | 2024 |
| publishDateSort | 2024 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Handbook of ionic liquids fundamentals, applications, and sustainability edited by Sanchayita Rajkhowa, Pardeep Singh, Anik Sen, and Jyotirmoy Sarma Weinheim, Germany Wiley-VCH [2024] © 2024 xviii, 499 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Ionische Flüssigkeit (DE-588)7548899-1 gnd rswk-swf Biotechnologie Biotechnologie i. d. Chemie Biotechnology CH31: Biotechnologie i. d. Chemie CH40: Katalyse CHC0: Nachhaltige u. Grüne Chemie Catalysis Chemie Chemistry Ionische Flüssigkeit Katalyse Nachhaltige u. Grüne Chemie Sustainable Chemistry & Green Chemistry (DE-588)4143413-4 Aufsatzsammlung gnd-content Ionische Flüssigkeit (DE-588)7548899-1 s DE-604 Singh, Pardeep (DE-588)121433587X edt Rajkhowa, Sanchayita 1985- (DE-588)1283039532 edt Sen, Anik edt Sarma, Jyotirmoy edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-83950-6 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-83951-3 Erscheint auch als Online-Ausgabe, oBook 978-3-527-83952-0 Erscheint auch als X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35066-7/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034858135&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Handbook of ionic liquids fundamentals, applications, and sustainability Ionische Flüssigkeit (DE-588)7548899-1 gnd |
| subject_GND | (DE-588)7548899-1 (DE-588)4143413-4 |
| title | Handbook of ionic liquids fundamentals, applications, and sustainability |
| title_auth | Handbook of ionic liquids fundamentals, applications, and sustainability |
| title_exact_search | Handbook of ionic liquids fundamentals, applications, and sustainability |
| title_exact_search_txtP | Handbook of ionic liquids fundamentals, applications, and sustainability |
| title_full | Handbook of ionic liquids fundamentals, applications, and sustainability edited by Sanchayita Rajkhowa, Pardeep Singh, Anik Sen, and Jyotirmoy Sarma |
| title_fullStr | Handbook of ionic liquids fundamentals, applications, and sustainability edited by Sanchayita Rajkhowa, Pardeep Singh, Anik Sen, and Jyotirmoy Sarma |
| title_full_unstemmed | Handbook of ionic liquids fundamentals, applications, and sustainability edited by Sanchayita Rajkhowa, Pardeep Singh, Anik Sen, and Jyotirmoy Sarma |
| title_short | Handbook of ionic liquids |
| title_sort | handbook of ionic liquids fundamentals applications and sustainability |
| title_sub | fundamentals, applications, and sustainability |
| topic | Ionische Flüssigkeit (DE-588)7548899-1 gnd |
| topic_facet | Ionische Flüssigkeit Aufsatzsammlung |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35066-7/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034858135&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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