Heterogeneous catalysis: solid catalysts, kinetics, transport effects, catalytic reactors
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin
De Gruyter
[2023]
|
| Ausgabe: | 2nd edition |
| Schriftenreihe: | De Gruyter graduate
|
| Schlagworte: | |
| Online-Zugang: | https://www.degruyter.com/isbn/9783111032481 Inhaltsverzeichnis |
| Beschreibung: | XIII, 153 Seiten Illustrationen, Diagramme (überwiegend farbig) |
| ISBN: | 9783111032481 3111032485 |
Internformat
MARC
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| 015 | |a 23,N17 |2 dnb | ||
| 016 | 7 | |a 1286726247 |2 DE-101 | |
| 020 | |a 9783111032481 |c pbk. |9 978-3-11-103248-1 | ||
| 020 | |a 3111032485 |9 3-11-103248-5 | ||
| 035 | |a (OCoLC)1410398517 | ||
| 035 | |a (DE-599)DNB1286726247 | ||
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| 041 | 0 | |a eng | |
| 044 | |a gw |c XA-DE-BE | ||
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| 084 | |a VK 5570 |0 (DE-625)147405:253 |2 rvk | ||
| 100 | 1 | |a Shaikh, Abdullah |e Verfasser |0 (DE-588)1217036601 |4 aut | |
| 245 | 1 | 0 | |a Heterogeneous catalysis |b solid catalysts, kinetics, transport effects, catalytic reactors |c Abdullah A. Shaikh |
| 250 | |a 2nd edition | ||
| 264 | 1 | |a Berlin |b De Gruyter |c [2023] | |
| 264 | 4 | |c © 2023 | |
| 300 | |a XIII, 153 Seiten |b Illustrationen, Diagramme (überwiegend farbig) | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a De Gruyter graduate | |
| 650 | 0 | 7 | |a Heterogene Katalyse |0 (DE-588)4123377-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Technische Chemie |0 (DE-588)4078178-1 |2 gnd |9 rswk-swf |
| 653 | |a Katalyse | ||
| 653 | |a Reaktionstechnik | ||
| 653 | |a Technische Chemie | ||
| 653 | |a Physikalische Chemis | ||
| 653 | |a Physical Chemistry | ||
| 653 | |a Catalysis | ||
| 653 | |a Catalysts | ||
| 653 | |a Chemical Engineering | ||
| 653 | |a Chemical Process Engineering | ||
| 653 | |a TB: Textbook | ||
| 689 | 0 | 0 | |a Heterogene Katalyse |0 (DE-588)4123377-3 |D s |
| 689 | 0 | 1 | |a Technische Chemie |0 (DE-588)4078178-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 710 | 2 | |a Walter de Gruyter GmbH & Co. KG |0 (DE-588)10095502-2 |4 pbl | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-11-103300-6 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-11-103251-1 |
| 856 | 4 | 2 | |m X:MVB |u https://www.degruyter.com/isbn/9783111032481 |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034622774&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-034622774 | ||
Datensatz im Suchindex
| _version_ | 1804185903675998208 |
|---|---|
| adam_text | CONTENTS
PREFACE
TO
THE
SECOND
EDITION
-
V
PREFACE
TO
THE
FIRST
EDITION
-
VII
ACKNOWLEDGMENTS
-
IX
1
1.1
1.2
1.2.1
1.2.2
1.2.3
1.2.4
1.2.5
1.2.6
1.3
INTRODUCTION
-
1
INDUSTRIAL
IMPORTANCE
OF
HETEROGENEOUS
CATALYSIS
-
2
GENERAL
CHARACTERISTICS
OF
SOLID
CATALYSTS
-
3
ACTIVATION
ENERGY
-
4
CLASSIFICATION
BY
FUNCTIONALITY
-
5
SELECTIVITY
OF
SOLID
CATALYSTS
-
6
THE
CATALYTIC
SITE
-
7
COMPOSITION
AND
PREPARATION
OF
SOLID
CATALYSTS
-
7
NAMING
OF
SOLID
CATALYSTS
-
10
THE
CATALYTIC
SEQUENCE
-
11
REFERENCES
-
14
2
2.1
2.2
2.2.1
2.2.2
2.2.3
2.2.4
2.3
2.3.1
2.3.2
2.3.3
2.4
2.4.1
2.4.2
ADSORPTION
-
15
TYPES
OF
ADSORPTION
-
15
COMPARISON
BETWEEN
PHYSICAL
AND
CHEMICAL
ADSORPTION
-
16
SURFACE
COVERAGE
-
17
HEAT
OF
ADSORPTION
-
17
CATALYTIC
CYCLE
-
18
RATE
OF
ADSORPTION
-
19
ADSORPTION
ISOTHERMS
-
20
LANGMUIR
ISOTHERM
-
21
COMPETITIVE
ADSORPTION
-
23
DETERMINATION
OF
SURFACE
AREA
-
24
OTHER
ISOTHERMS
-
26
BET
ISOTHERM
----
28
SURFACE
AREA
BY
BET
ISOTHERM
-
30
REFERENCES
-
30
3
3.1
3.1.1
CHARACTERIZATION
OF
SOLID
CATALYSTS
-
32
PHYSICAL
CHARACTERIZATION
-
32
DETERMINATION
OF
SURFACE
AREA,
TOTAL
PORE
VOLUME,
AND
MEAN
PORE
RADIUS
-
33
3.1.2
3.2
PORE-SIZE
DISTRIBUTION
-
37
CHEMICAL
AND
STRUCTURAL
CHARACTERIZATION
-
41
XII
-
CONTENTS
3.2.1
ELECTRON
MICROSCOPY
-----
42
3.3
MECHANICAL
CHARACTERIZATION
-
45
REFERENCES
----
48
4
KINETICS
OF
CATALYTIC
REACTIONS
----
49
4.1
CLASSIFICATION
OF
KINETIC
MODELS
-----
49
4.2
LANGMUIR-HINSHELWOOD
(L-H)
MODEL
-----
50
4.2.1
IRREVERSIBLE,
UNIMOLECULAR,
SURFACE
REACTIONS
-
50
4.2.2
IRREVERSIBLE,
BIMOLECULAR,
SURFACE
REACTIONS
-----
51
4.2.3
INHIBITION
IN
BIMOLECULAR
SURFACE
REACTIONS
-----
53
4.2.4
REVERSIBLE,
UNIMOLECULAR,
REACTIONS
-
54
4.2.5
REVERSIBLE,
BIMOLECULAR,
REACTIONS
-
54
4.2.6
IRREVERSIBLE,
BIMOLECULAR,
REACTIONS:
DIFFERENT
SITES
-
55
4.3
ELEY-RIDEAI
(E-R)
MODEL
-----
56
4.4
EVALUATION
OF
KINETIC
PARAMETERS
-
57
4.5
EFFECT
OF
TEMPERATURE
ON
REACTION
RATE
----
60
REFERENCES
-
62
5
TRANSPORT
EFFECTS
IN
CATALYTIC
REACTIONS
-
63
5.1
EXTERNAL
AND
INTERNAL
MASS
TRANSFER
-
63
5.2
THE
EFFECTIVENESS
FACTOR
-
64
5.2.1
ISOTHERMAL
FIRST-ORDER
CATALYTIC
REACTIONS
-
66
5.2.2
EFFECTIVENESS
FACTOR
FOR
FIRST-ORDER
REACTIONS
----
69
5.2.3
EFFECTIVENESS
FACTORS
FOR
OTHER
CATALYST
SHAPES
-
70
5.2.4
PARAMETER
ESTIMATION
-
71
5.3
BEHAVIOR
OF
OBSERVED
REACTION
RATE:
FALSIFICATION
OF
KINETIC
DATA
-
75
5.4
LABORATORY
REACTORS
-
76
REFERENCES
-
80
6
DEACTIVATION
OF
SOLID
CATALYSTS
-
81
6.1
CAUSES
OF
DEACTIVATION
-
82
6.2
DEACTIVATION
BY
THERMAL
DEGRADATION
-
84
6.3
DEACTIVATION
BY
FOULING
------
84
6.4
DEACTIVATION
BY
POISONING
------
86
6.5
OTHER
CAUSES
OF
DEACTIVATION
-
87
6.6
KINETICS
OF
CATALYST
DEACTIVATION
-
88
6.6.1
CATALYST
ACTIVITY
--------
88
6.6.2
KINETICS
OF
CATALYST
COKING
-
90
6.7
CATALYST
REACTIVATION
-
91
REFERENCES
-
94
CONTENTS
-
XIII
7
INDUSTRIAL
CATALYTIC
REACTORS
-
95
7.1
TYPES
OF
REACTORS
AND
APPLICATIONS
-
95
7.1.1
PACKED-BED
REACTOR
FAMILY
-
96
7.1.2
FLUIDIZED-BED
REACTOR
FAMILY
-
100
7.2
DESIGN
OF
ISOTHERMAL
PACKED-BED
REACTOR
-
101
7.2.1
CAUTIONARY
REMARKS
-
103
7.3
DESIGN
OF
ISOTHERMAL
TRANSPORT-LINE
REACTOR
-
105
7.4
THREE-PHASE
CATALYTIC
REACTORS
-
106
REFERENCES
-
109
8
MAJOR
INDUSTRIAL
APPLICATIONS
-
110
8.1
APPLICATIONS
IN
PETROLEUM
REFINING
-
110
8.2
APPLICATIONS
IN
THE
PETROCHEMICALS
INDUSTRY
-
114
8.3
APPLICATIONS
IN
ENVIRONMENTAL
PROTECTION
-
115
REFERENCES
-
119
9
COMPUTATIONAL
CASE
STUDIES
-
120
9.1
PUBLISHED
MODELS
AND
SIMULATORS
-
121
9.1.1
ADSORPTION
ISOTHERMS
OF
C2H4
IN
NAX
ZEOLITE
-
122
9.1.2
SURFACE
KINETICS
WITH
PORE
DIFFUSION
RESISTANCE
-
123
9.1.3
NON-ISOTHERMAL
EFFECTIVENESS
FACTOR
-
123
9.1.4
CONVERSION
OF
ETHYLBENZENE
TO
STYRENE
IN
THE
PRESENCE
OF
STEAM
-
125
9.1.5
PRESSURE
DROP
IN
A
PACKED-BED
REACTOR
-
126
9.1.6
SLURRY
REACTOR
WITH
DECLINING
CATALYST
ACTIVITY
-
127
9.2
APPLIED
CATALYSIS
DESIGN
PROBLEM
-
128
9.3
OPEN-ENDED
CATALYSIS
DESIGN
PROBLEMS
-
133
9.3.1
ELEMENTARY
COMPUTATIONAL
THOUGHT
EXPERIMENT
-
133
9.3.2
INTERMEDIATE
COMPUTATIONAL
THOUGHT
EXPERIMENT
-
133
REFERENCES
-
134
PROBLEMS
-
135
INDEX
----
147
|
| adam_txt |
CONTENTS
PREFACE
TO
THE
SECOND
EDITION
-
V
PREFACE
TO
THE
FIRST
EDITION
-
VII
ACKNOWLEDGMENTS
-
IX
1
1.1
1.2
1.2.1
1.2.2
1.2.3
1.2.4
1.2.5
1.2.6
1.3
INTRODUCTION
-
1
INDUSTRIAL
IMPORTANCE
OF
HETEROGENEOUS
CATALYSIS
-
2
GENERAL
CHARACTERISTICS
OF
SOLID
CATALYSTS
-
3
ACTIVATION
ENERGY
-
4
CLASSIFICATION
BY
FUNCTIONALITY
-
5
SELECTIVITY
OF
SOLID
CATALYSTS
-
6
THE
CATALYTIC
SITE
-
7
COMPOSITION
AND
PREPARATION
OF
SOLID
CATALYSTS
-
7
NAMING
OF
SOLID
CATALYSTS
-
10
THE
CATALYTIC
SEQUENCE
-
11
REFERENCES
-
14
2
2.1
2.2
2.2.1
2.2.2
2.2.3
2.2.4
2.3
2.3.1
2.3.2
2.3.3
2.4
2.4.1
2.4.2
ADSORPTION
-
15
TYPES
OF
ADSORPTION
-
15
COMPARISON
BETWEEN
PHYSICAL
AND
CHEMICAL
ADSORPTION
-
16
SURFACE
COVERAGE
-
17
HEAT
OF
ADSORPTION
-
17
CATALYTIC
CYCLE
-
18
RATE
OF
ADSORPTION
-
19
ADSORPTION
ISOTHERMS
-
20
LANGMUIR
ISOTHERM
-
21
COMPETITIVE
ADSORPTION
-
23
DETERMINATION
OF
SURFACE
AREA
-
24
OTHER
ISOTHERMS
-
26
BET
ISOTHERM
----
28
SURFACE
AREA
BY
BET
ISOTHERM
-
30
REFERENCES
-
30
3
3.1
3.1.1
CHARACTERIZATION
OF
SOLID
CATALYSTS
-
32
PHYSICAL
CHARACTERIZATION
-
32
DETERMINATION
OF
SURFACE
AREA,
TOTAL
PORE
VOLUME,
AND
MEAN
PORE
RADIUS
-
33
3.1.2
3.2
PORE-SIZE
DISTRIBUTION
-
37
CHEMICAL
AND
STRUCTURAL
CHARACTERIZATION
-
41
XII
-
CONTENTS
3.2.1
ELECTRON
MICROSCOPY
-----
42
3.3
MECHANICAL
CHARACTERIZATION
-
45
REFERENCES
----
48
4
KINETICS
OF
CATALYTIC
REACTIONS
----
49
4.1
CLASSIFICATION
OF
KINETIC
MODELS
-----
49
4.2
LANGMUIR-HINSHELWOOD
(L-H)
MODEL
-----
50
4.2.1
IRREVERSIBLE,
UNIMOLECULAR,
SURFACE
REACTIONS
-
50
4.2.2
IRREVERSIBLE,
BIMOLECULAR,
SURFACE
REACTIONS
-----
51
4.2.3
INHIBITION
IN
BIMOLECULAR
SURFACE
REACTIONS
-----
53
4.2.4
REVERSIBLE,
UNIMOLECULAR,
REACTIONS
-
54
4.2.5
REVERSIBLE,
BIMOLECULAR,
REACTIONS
-
54
4.2.6
IRREVERSIBLE,
BIMOLECULAR,
REACTIONS:
DIFFERENT
SITES
-
55
4.3
ELEY-RIDEAI
(E-R)
MODEL
-----
56
4.4
EVALUATION
OF
KINETIC
PARAMETERS
-
57
4.5
EFFECT
OF
TEMPERATURE
ON
REACTION
RATE
----
60
REFERENCES
-
62
5
TRANSPORT
EFFECTS
IN
CATALYTIC
REACTIONS
-
63
5.1
EXTERNAL
AND
INTERNAL
MASS
TRANSFER
-
63
5.2
THE
EFFECTIVENESS
FACTOR
-
64
5.2.1
ISOTHERMAL
FIRST-ORDER
CATALYTIC
REACTIONS
-
66
5.2.2
EFFECTIVENESS
FACTOR
FOR
FIRST-ORDER
REACTIONS
----
69
5.2.3
EFFECTIVENESS
FACTORS
FOR
OTHER
CATALYST
SHAPES
-
70
5.2.4
PARAMETER
ESTIMATION
-
71
5.3
BEHAVIOR
OF
OBSERVED
REACTION
RATE:
FALSIFICATION
OF
KINETIC
DATA
-
75
5.4
LABORATORY
REACTORS
-
76
REFERENCES
-
80
6
DEACTIVATION
OF
SOLID
CATALYSTS
-
81
6.1
CAUSES
OF
DEACTIVATION
-
82
6.2
DEACTIVATION
BY
THERMAL
DEGRADATION
-
84
6.3
DEACTIVATION
BY
FOULING
------
84
6.4
DEACTIVATION
BY
POISONING
------
86
6.5
OTHER
CAUSES
OF
DEACTIVATION
-
87
6.6
KINETICS
OF
CATALYST
DEACTIVATION
-
88
6.6.1
CATALYST
ACTIVITY
--------
88
6.6.2
KINETICS
OF
CATALYST
COKING
-
90
6.7
CATALYST
REACTIVATION
-
91
REFERENCES
-
94
CONTENTS
-
XIII
7
INDUSTRIAL
CATALYTIC
REACTORS
-
95
7.1
TYPES
OF
REACTORS
AND
APPLICATIONS
-
95
7.1.1
PACKED-BED
REACTOR
FAMILY
-
96
7.1.2
FLUIDIZED-BED
REACTOR
FAMILY
-
100
7.2
DESIGN
OF
ISOTHERMAL
PACKED-BED
REACTOR
-
101
7.2.1
CAUTIONARY
REMARKS
-
103
7.3
DESIGN
OF
ISOTHERMAL
TRANSPORT-LINE
REACTOR
-
105
7.4
THREE-PHASE
CATALYTIC
REACTORS
-
106
REFERENCES
-
109
8
MAJOR
INDUSTRIAL
APPLICATIONS
-
110
8.1
APPLICATIONS
IN
PETROLEUM
REFINING
-
110
8.2
APPLICATIONS
IN
THE
PETROCHEMICALS
INDUSTRY
-
114
8.3
APPLICATIONS
IN
ENVIRONMENTAL
PROTECTION
-
115
REFERENCES
-
119
9
COMPUTATIONAL
CASE
STUDIES
-
120
9.1
PUBLISHED
MODELS
AND
SIMULATORS
-
121
9.1.1
ADSORPTION
ISOTHERMS
OF
C2H4
IN
NAX
ZEOLITE
-
122
9.1.2
SURFACE
KINETICS
WITH
PORE
DIFFUSION
RESISTANCE
-
123
9.1.3
NON-ISOTHERMAL
EFFECTIVENESS
FACTOR
-
123
9.1.4
CONVERSION
OF
ETHYLBENZENE
TO
STYRENE
IN
THE
PRESENCE
OF
STEAM
-
125
9.1.5
PRESSURE
DROP
IN
A
PACKED-BED
REACTOR
-
126
9.1.6
SLURRY
REACTOR
WITH
DECLINING
CATALYST
ACTIVITY
-
127
9.2
APPLIED
CATALYSIS
DESIGN
PROBLEM
-
128
9.3
OPEN-ENDED
CATALYSIS
DESIGN
PROBLEMS
-
133
9.3.1
ELEMENTARY
COMPUTATIONAL
THOUGHT
EXPERIMENT
-
133
9.3.2
INTERMEDIATE
COMPUTATIONAL
THOUGHT
EXPERIMENT
-
133
REFERENCES
-
134
PROBLEMS
-
135
INDEX
----
147 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Shaikh, Abdullah |
| author_GND | (DE-588)1217036601 |
| author_facet | Shaikh, Abdullah |
| author_role | aut |
| author_sort | Shaikh, Abdullah |
| author_variant | a s as |
| building | Verbundindex |
| bvnumber | BV049362635 |
| classification_rvk | VE 7040 VN 7340 VK 5570 |
| ctrlnum | (OCoLC)1410398517 (DE-599)DNB1286726247 |
| discipline | Chemie / Pharmazie |
| discipline_str_mv | Chemie / Pharmazie |
| edition | 2nd edition |
| format | Book |
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| id | DE-604.BV049362635 |
| illustrated | Illustrated |
| index_date | 2024-07-03T22:52:25Z |
| indexdate | 2024-07-10T10:02:38Z |
| institution | BVB |
| institution_GND | (DE-588)10095502-2 |
| isbn | 9783111032481 3111032485 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-034622774 |
| oclc_num | 1410398517 |
| open_access_boolean | |
| owner | DE-11 |
| owner_facet | DE-11 |
| physical | XIII, 153 Seiten Illustrationen, Diagramme (überwiegend farbig) |
| publishDate | 2023 |
| publishDateSearch | 2023 |
| publishDateSort | 2023 |
| publisher | De Gruyter |
| record_format | marc |
| series2 | De Gruyter graduate |
| spelling | Shaikh, Abdullah Verfasser (DE-588)1217036601 aut Heterogeneous catalysis solid catalysts, kinetics, transport effects, catalytic reactors Abdullah A. Shaikh 2nd edition Berlin De Gruyter [2023] © 2023 XIII, 153 Seiten Illustrationen, Diagramme (überwiegend farbig) txt rdacontent n rdamedia nc rdacarrier De Gruyter graduate Heterogene Katalyse (DE-588)4123377-3 gnd rswk-swf Technische Chemie (DE-588)4078178-1 gnd rswk-swf Katalyse Reaktionstechnik Technische Chemie Physikalische Chemis Physical Chemistry Catalysis Catalysts Chemical Engineering Chemical Process Engineering TB: Textbook Heterogene Katalyse (DE-588)4123377-3 s Technische Chemie (DE-588)4078178-1 s DE-604 Walter de Gruyter GmbH & Co. KG (DE-588)10095502-2 pbl Erscheint auch als Online-Ausgabe, EPUB 978-3-11-103300-6 Erscheint auch als Online-Ausgabe, PDF 978-3-11-103251-1 X:MVB https://www.degruyter.com/isbn/9783111032481 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034622774&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Shaikh, Abdullah Heterogeneous catalysis solid catalysts, kinetics, transport effects, catalytic reactors Heterogene Katalyse (DE-588)4123377-3 gnd Technische Chemie (DE-588)4078178-1 gnd |
| subject_GND | (DE-588)4123377-3 (DE-588)4078178-1 |
| title | Heterogeneous catalysis solid catalysts, kinetics, transport effects, catalytic reactors |
| title_auth | Heterogeneous catalysis solid catalysts, kinetics, transport effects, catalytic reactors |
| title_exact_search | Heterogeneous catalysis solid catalysts, kinetics, transport effects, catalytic reactors |
| title_exact_search_txtP | Heterogeneous catalysis solid catalysts, kinetics, transport effects, catalytic reactors |
| title_full | Heterogeneous catalysis solid catalysts, kinetics, transport effects, catalytic reactors Abdullah A. Shaikh |
| title_fullStr | Heterogeneous catalysis solid catalysts, kinetics, transport effects, catalytic reactors Abdullah A. Shaikh |
| title_full_unstemmed | Heterogeneous catalysis solid catalysts, kinetics, transport effects, catalytic reactors Abdullah A. Shaikh |
| title_short | Heterogeneous catalysis |
| title_sort | heterogeneous catalysis solid catalysts kinetics transport effects catalytic reactors |
| title_sub | solid catalysts, kinetics, transport effects, catalytic reactors |
| topic | Heterogene Katalyse (DE-588)4123377-3 gnd Technische Chemie (DE-588)4078178-1 gnd |
| topic_facet | Heterogene Katalyse Technische Chemie |
| url | https://www.degruyter.com/isbn/9783111032481 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034622774&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT shaikhabdullah heterogeneouscatalysissolidcatalystskineticstransporteffectscatalyticreactors AT walterdegruytergmbhcokg heterogeneouscatalysissolidcatalystskineticstransporteffectscatalyticreactors |