Mössbauer spectroscopy: applications in chemistry and materials science
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Weinheim
Wiley-VCH
[2024]
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Schlagworte: | |
Online-Zugang: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34691-2/ Inhaltsverzeichnis |
Beschreibung: | xiii, 316 Seiten Illustrationen 24.4 cm x 17 cm |
ISBN: | 9783527346912 |
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020 | |a 9783527346912 |c hbk. : circa EUR 149.00 (DE) (freier Preis), circa EUR 153.20 (AT) (freier Preis) |9 978-3-527-34691-2 | ||
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084 | |a 540 |2 23sdnb | ||
245 | 1 | 0 | |a Mössbauer spectroscopy |b applications in chemistry and materials science |c edited by Yann Garcia, Junhu Wang, and Tao Zhang |
264 | 1 | |a Weinheim |b Wiley-VCH |c [2024] | |
264 | 4 | |c © 2024 | |
300 | |a xiii, 316 Seiten |b Illustrationen |c 24.4 cm x 17 cm | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
650 | 0 | 7 | |a Mößbauer-Spektroskopie |0 (DE-588)4170352-2 |2 gnd |9 rswk-swf |
653 | |a Analyse u. Charakterisierung von Nanosystemen | ||
653 | |a Analysis/Characterization of Nanosystems | ||
653 | |a CH15: Spektroskopie | ||
653 | |a Chemie | ||
653 | |a Chemistry | ||
653 | |a MSA0: Werkstoffprüfung | ||
653 | |a Materials Characterization | ||
653 | |a Materials Science | ||
653 | |a Materialwissenschaften | ||
653 | |a NT80: Analyse u. Charakterisierung von Nanosystemen | ||
653 | |a Nanotechnologie | ||
653 | |a Nanotechnology | ||
653 | |a Spectroscopy | ||
653 | |a Spektroskopie | ||
653 | |a Werkstoffprüfung | ||
655 | 7 | |0 (DE-588)4143413-4 |a Aufsatzsammlung |2 gnd-content | |
689 | 0 | 0 | |a Mößbauer-Spektroskopie |0 (DE-588)4170352-2 |D s |
689 | 0 | |5 DE-604 | |
700 | 1 | |a Garcia, Yann |0 (DE-588)1260237060 |4 edt | |
700 | 1 | |a Wang, Junhu |0 (DE-588)1315449897 |4 edt | |
700 | 1 | |a Zhang, Tao |4 edt | |
710 | 2 | |a Wiley-VCH |0 (DE-588)16179388-5 |4 pbl | |
776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-527-82494-6 |
776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-527-82493-9 |
776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, oBook |z 978-3-527-82495-3 |
856 | 4 | 2 | |m X:MVB |u http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34691-2/ |
856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034310300&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-034310300 |
Datensatz im Suchindex
_version_ | 1805088226201829376 |
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adam_text |
CONTENTS
PREFACE
XI
1
APPLICATION
OF
MDSSBAUER
SPECTROSCOPY
TO
ENERGY
MATERIALS
1
PIERRE-EMMANUEL
LIPPENS,
JEAN-CLAUDE
JUMAS,
AND
JOSETTE
OLIVIER-FOURCADE
1.1
INTRODUCTION
1
1.2
MDSSBAUER
SPECTROSCOPY
FOR
LI-ION
AND
NA-ION
BATTERIES
2
1.2.1
CHARACTERIZATION
OF
ELECTRODE
MATERIALS
AND
ELECTROCHEMICAL
REACTIONS
2
1.2.2
TIN-BASED
NEGATIVE
ELECTRODE
MATERIALS
FOR
LI-ION
BATTERIES
3
1.2.2.1
ELECTROCHEMICAL
REACTIONS
OF
LITHIUM
WITH
TIN
3
1.2.2.2
TIN
OXIDES
7
1.2.2.3
TIN
BOROPHOSPHATES
10
1.2.2.4
TIN-BASED
INTERMETALLICS
13
1.2.3
IRON-BASED
ELECTRODE
MATERIALS
17
1.2.3.1
LIFEPO
4
AS
POSITIVE
ELECTRODE
MATERIAL
FOR
LI-ION
BATTERIES
17
1.2.3.2
FE,
19PO4(OH)
57(H2O).43/C
AS
POSITIVE
ELECTRODE
MATERIAL
FOR
LI-ION
BATTERIES
IS
1.2.3.3
NA,
5
FE
0
5TI,
S(PO,)3/C
AS
ELECTRODE
MATERIAL
FOR
NA-ION
BATTERIES
19
1.3
MOSSBAUER
SPECTROSCOPY
OF
TIN-BASED
CATALYSTS
21
1.3.1
REFORMING
CATALYSIS
21
1.3.2
REDOX
PROPERTIES
OF
PT-SN
BASED
CATALYSTS
22
1.3.3
TRIMETALLIC
PT-SN-IN
BASED
CATALYSTS
24
1.4
CONCLUSION
26
ACKNOWLEDGMENTS
27
REFERENCES
27
2
MDSSBAUER
SPECTRAL
STUDIES
OF
IRON
PHOSPHATE
CONTAINING
MINERALS
AND
COMPOUNDS
33
GARY
J.
LONG
AND
FERNANDE
GRANDJEAN
2.1
INTRODUCTION
33
2.2
THERMODYNAMIC
PROPERTIES
OF
IRON
PHOSPHATE
CONTAINING
COMPOUNDS
34
VI
CONTENTS
2.3
ROOM
TEMPERATURE
MOSSBAUER
SPECTRA
OF
IRON
PHOSPHATE
CONTAINING
MINERALS
37
2.4
2.5
ANALYSIS
OF
MAGNETICALLY
ORDERED
MDSSBAUER
SPECTRA
50
STRUCTURAL
AND
THERMODYNAMIC
PROPERTIES
OF
THE
POLYMORPHS
OF
FEPO
4
53
2.5.1
2.6
2.7
POLYMORPHS
OF
FEPO
4
53
MDSSBAUER
SPECTRA
OF
A-FEPO4
55
MAGNETIC
STRUCTURE
OF
A-FEPO4,
OBTAINED
BY
MDSSBAUER
SPECTROSCOPY
57
2.7.1
2.8
2.9
2.9.1
2.9.2
MAGNETIC
STRUCTURE
OF
A-FEPO4
57
TEMPERATURE
DEPENDENCE
OF
THE
A-FEPO4
STRUCTURE
TILT
ANGLE
60
MDSSBAUER
SPECTRAL
STUDIES
ON
METASTABLE
POLYMORPHS
OF
FEPO
4
62
CRYSTALLOGRAPHIC
STRUCTURES
OF
TWO
POLYMORPHS
OF
FEPO42H,O
62
PREPARATION
AND
CRYSTALLOGRAPHIC
STRUCTURES OF
THE
TWO
POLYMORPHS,
Y-FEPO,
AND
Z-FEPO,
62
2.9.3
2.9.4
MDSSBAUER
SPECTRAL
STUDIES
OF
FEPO
4
METASTABLE
POLYMORPHS
64
PREPARATION
AND
MDSSBAUER
SPECTRA
OF
SYNTHETIC
HETEROSITE,
(FE,MN)PO
4
67
2.9.5
2.10
2.10.1
2.10.2
2.10.3
2.10.4
FITS
OF
THE
MAGNETIC
MDSSBAUER
SPECTRA
OF
N-FE
.
MN,
1PO4
68
MDSSBAUER
SPECTRAL
STUDIES
OF
VARIOUS
IRON
PHOSPHATE
COMPOUNDS
73
MDSSBAUER
SPECTRAL
PROPERTIES
OF
A-FE,(PO,)O
74
MDSSBAUER
SPECTRAL
PROPERTIES
OF
FE
3
(PO
4
)O
3
79
PREPARATION
AND
STRUCTURAL
PROPERTIES
OF
FE
9
(PO
4
)O
8
80
MDSSBAUER
SPECTRAL
PROPERTIES
OF
FE
9
(PO
4
)O
8
81
ACKNOWLEDGMENTS
85
REFERENCES
AND
NOTES
85
3
MDSSBAUER
SPECTROSCOPIC
INVESTIGATION
OF
FE-BASED
SILICIDES
93
XIAO
CHEN,
JUNHU
WANG,
AND
CHANGHAI
LIANG
3.1
3.2
INTRODUCTION
93
MDSSBAUER
SPECTROSCOPIC
INVESTIGATION
OF
IRON
SILICIDES
PREPARED
BY
MECHANICAL
ALLOYING
AND
HEAT
TREATMENT
95
3.3
MDSSBAUER
SPECTRA
OF
IRON
SILICIDE
ON
SILICA
PREPARED
BY
PYROLYSIS
OF
FERROCENE-POLYDIMETHYLSILANE
COMPOSITES
99
3.4
SYNTHESIS
AND
MDSSBAUER
SPECTRA
OF
IRON
SILICIDES
BY
TEMPERATURE-PROGRAMMED
SILICIFICATION
102
3.5
3.6
MDSSBAUER
SPECTROSCOPIC
INVESTIGATION
OF
DOPED
IRON
SILICIDES
104
CONCLUSION
AND
PERSPECTIVE
107
REFERENCES
108
4
MDSSBAUER
SPECTROSCOPY
OF
CATALYSTS
113
KAROLY
LAZAR
4.1
4.2
INTRODUCTION
113
PRINCIPLES
OF
THE
MDSSBAUER
EFFECT
AND
OUTLOOK
OF
ITS
APPLICATION
FOR
CATALYST
STUDIES
116
CONTENTS
VII
4.2.1
4.2.2
BRIEF
OVERVIEW
OF
THE
BASICS
OF
MDSSBAUER
SPECTROSCOPY
116
MDSSBAUER
SPECTROSCOPY
FROM
THE
POINT
OF
VIEW
OF
CATALYST
STUDIES
-
PARTICULAR
FEATURES
117
4.2.3
4.2.4
4.2.4.1
4.2.4.2
4.2.4.3
4.2.5
4.3
4.3.1
THE
PROBABILITY
OF
THE
MDSSBAUER
EFFECT
-
F-FACTOR
AND
SIZE
EFFECTS
118
VARIANTS
OF
THE
TECHNIQUE
120
57
CO
EMISSION
SPECTROSCOPY
120
SYNCHROTRON-BASED
NFS
(NUCLEAR
FORWARD
SCATTERING)
122
CONVERSION
ELECTRON
MDSSBAUER
SPECTROSCOPY
122
TECHNICAL
IMPLEMENTATIONS
-
EXPERIMENTAL
CONDITIONS
123
HETEROGENEOUS
CATALYSTS
124
SITES
ON
SUPPORTED
PARTICLES
WITH
DIFFERENT
PARTICIPATION
IN
CATALYTIC
PROCESSES
124
4.3.2
4.3.3
4.3.3.1
4.3.3.2
4.3.3.3
4.4
4.5
4.5.1
COLLECTIVE
EFFECTS
IN
PARTICLES
(MAGNETISM)
125
CASE
STUDIES
126
METALS
AND
ALLOYS
126
OXIDE
CATALYSTS
130
CATALYSTS
WITH
FE-N,
FE-C,
AND
FE-N-C
CENTERS
133
BIOCATALYSTS
-
ENZYMES
135
HOMOGENEOUS
CATALYSTS
-
FROZEN
SOLUTIONS
135
STUDIES
ON
REACTION
INTERMEDIATES
-
TIME-RESOLVED
FREEZE-QUENCHED
SPECTRA
136
4.6
CONCLUSIONS
137
ACKNOWLEDGMENT
137
REFERENCES
138
5
APPLICATION
OF
MDSSBAUER
SPECTROSCOPY
IN
STUDYING
CATALYSTS
FOR
CO
OXIDATION
AND
PREFERENTIAL
OXIDATION
OF
CO
IN
H2
145
KUO
LIU,
JUNHU
WANG,
AND
TOO
ZHANG
5.1
5.2
5.2.1
5.2.2
5.2.3
5.2.4
5.3
5.3.1
5.3.2
5.3.3
5.3.3.1
5.3.3.2
5.3.4
5.4
INTRODUCTION
145
APPLICATION
OF
MDSSBAUER
SPECTROSCOPY
IN
CO
OXIDATION
147
57
FE
MDSSBAUER
SPECTROSCOPY
147
119
SN
MDSSBAUER
SPECTROSCOPY
150
197
AU
MDSSBAUER
SPECTROSCOPY
151
193
IR
MDSSBAUER
SPECTROSCOPY
152
APPLICATION
OF
MDSSBAUER
SPECTROSCOPY
IN
PROX
153
PTFE
CONTAINING
CATALYSTS
153
AU-BASED
CATALYSTS
155
IRFE-CONTAINING
CATALYSTS
158
POROUS
CARBON
SUPPORTED
IRFE
CATALYSTS
158
SIO
2
AND
AL,O,
SUPPORTED
IRFE
CATALYSTS
159
CUO/CEO
2
WITH
FE
2
O
3
ADDITIVE
165
CONCLUDING
REMARKS
165
ACKNOWLEDGMENTS
166
REFERENCES
166
VIII
CONTENTS
6
APPLICATION
OF
57
FE
MOSSBAUER
SPECTROSCOPY
IN
STUDYING
FE-N-C
CATALYSTS
FOR
OXYGEN
REDUCTION
REACTION
IN
PROTON
EXCHANGE
MEMBRANE
FUEL
CELLS
171
XINLONG
XU,
JUNHU
WANG,
SULI
WANG,
AND
GONGQUAN
SUN
6.1
6.2
6.2.1
6.2.2
INTRODUCTION
171
ADVANCED
57
FE
MDSSBAUER
SPECTROSCOPY
TECHNIQUE
173
ROOM
TEMPERATURE
57
FE
MDSSBAUER
SPECTROSCOPY
173
LOW
TEMPERATURE
AND
COMPUTATIONAL
57
FE
MDSSBAUER
SPECTROSCOPY
174
6.2.3
6.3
6.3.1
6.3.2
6.3.3
6.3.3.1
6.3.3.2
6.4
IN
SITU
ELECTROCHEMICAL
57
FE
MDSSBAUER
SPECTROSCOPY
175
CHARACTERIZATION
OF
FE-N-C
USING
57
FE
MDSSBAUER
SPECTROSCOPY
177
IDENTIFICATION
OF
ACTIVE
SITES
177
INVESTIGATION
OF
DEGRADATION
MECHANISM
180
OPTIMIZATION
FOR
SYNTHESIS
OF
FE-N-C
184
PRECURSOR
COMPOSITION
184
HEAT
TREATMENT
185
SUMMARY
AND
PERSPECTIVE
187
ACKNOWLEDGMENTS
188
REFERENCES
188
7
197
AU
MDSSBAUER
SPECTROSCOPY
OF
THIOLATE-PROTECTED
GOLD
CLUSTERS
195
NORIMICHI
KOJIMA,
YASUHIRO
KOBAQYASHI,
AND
MAKOTO
SETO
7.1
7.2
7.3
7.3.1
7.3.2
7.3.3
7.3.4
7.3.5
INTRODUCTION
195
SYNTHESIS
OF
THIOLATE
PROTECTED
GOLD
CLUSTERS
197
197
AU
MDSSBAUER
SPECTROSCOPY
OF
GOLD
NANO-CLUSTERS
198
EXPERIMENTAL
PROCEDURE
OF
197
AU
MDSSBAUER
SPECTROSCOPY
198
197
AU
MDSSBAUER
SPECTRA
OF
AU
N
(SG)
M
(N
=
10^55)
198
MOLECULAR
STRUCTURE
AND
197
AU
MDSSBAUER
SPECTRA
OF
AU
10
(SG)
10
198
MOLECULAR
STRUCTURE
AND
197
AU
MDSSBAUER
SPECTRA
OF
AU
25
(SG)
18
200
STRUCTURAL
EVOLUTION
OF
AUYY(SG)M
(N
=
10^55)
BASED
ON
197
AU
MDSSBAUER
SPECTROSCOPY
201
7.3.6
7.3.7
7.4
197
AU
MDSSBAUER
SPECTRA
OF
AU
2
4PD
1
(SC
12
H25)
18
204
197
AU
MDSSBAUER
SPECTRA
OF
AUYY(SC12H25)M
205
CONCLUSION
208
ACKNOWLEDGMENTS
208
REFERENCES
209
8
197
AU
MDSSBAUER
SPECTROSCOPY
OF
GOLD
MIXED-VALENCE
COMPLEXES,
CS2[AU
'
X2][AU"Y,](X,
Y
=
CL,
BR,
1)
AND
[NH;
(CH,)YYNH]2[(AU
'
12)(AU"4)
(13)21
(N
=
7,
8)
213
NORIMICHI
KOJIMA,
YASUHIRO
KOBAQYASHI,
AND
MAKOTO
SETO
8.1
8.2
8.2.1
INTRODUCTION
213
EXPERIMENTAL
PROCEDURE
216
SYNTHESIS
AND
CHARACTERIZATION
216
CONTENTS
IX
8.2.1.1
8.2.1.2
8.2.2
8.3
8.4
8.5
8.5.1
CS[AU
'
X,][AU"Y4]
(X,
Y
=
C1,
BR,
I)
216
[NH,(CH,),NHA]2[(AU
'
T,)(AUYY1)(1,)21
(N
=
7,
8)
217
197
AU
MDSSBAUER
SPECTROSCOPY
217
CRYSTAL
STRUCTURE
OF
CS[AU
'
X2][AUYYY4]
(X,
Y
=
C1,
BR,
I)
218
CHEMICAL
BOND
OF
AU-X
IN
[AU
I
X
2
]
"
AND
[AU"X,]
221
MDSSBAUER
PARAMETERS
OF
197
AU
IN
[AUTX]
AND
[AUYYX4]
223
MDSSBAUER
PARAMETERS
OF
197
AU
IN
(C
4
H
9
)
4
N[AU
I
X
2
]
AND
(C,H,),N[AU"X,]
224
8.5.1.1
8.5.1.2
8.5.2
ISOMER
SHIFT
224
QUADRUPOLE
SPLITTING
224
MDSSBAUER
PARAMETERS
OF
197
AU
IN
CS
[AUX
][AU"X4]
(X
=
CL,BR,I)
225
8.5.2.1
8.5.2.2
8.5.23
8.6
8.7
8.7.1
8.7.2
8.73
8.7.4
8.8
8.8.1
ISOMER
SHIFT
225
QUADRUPOLE
SPLITTING
226
ANALYSIS
OF
197
AU
MDSSBAUER
PARAMETERS
FOR
CS,[AU
'
X2][AU"X4]
226
CHARGE
TRANSFER
INTERACTION
IN
CS[AU
'
X,][AU"X,]
(X
=
C1,
BR,
I)
227
197
AU
MDSSBAUER
SPECTRA
OF
CS[AU
'
X2][AU"LY4]
(X,
Y
=
C1,
BR,
I)
228
ISOMER
SHIFT
OF
AU
1
IN
CS
2
[
AU
'
X,
]
[AU"Y4]
228
ISOMER
SHIFT
OF
AUYY
IN
CS[AU
'
X2][AU"LY4]
230
QUADRUPOLE
SPLITTING
OF
AU
1
IN
CS[AU
'
X2I[AU"Y4]
230
QUADRUPOLE
SPLITTING
OF
AUYY
IN
CS[AUYYX ][AUYYY4]
231
SINGLE
CRYSTAL
197
AU
MDSSBAUER
SPECTRA
OF
CS[AU
'
1,][AUYY1]
231
COMPARISON
OF
197
AU
MDSSBAUER
SPECTRA
BETWEEN
SINGLE
CRYSTAL
AND
POWDER
CRYSTAL
231
8.8.2
8.9
SIGN
OF
EFG
FOR
AU
1
IN
[AU
1
^]
-
AND
AUYY
IN
[AUMX,]
234
197
AU
MDSSBAUER
SPECTRA
OF
CS[AU
'
X,][AU"X,]
(X
=
C1,1)
UNDER
HIGH
PRESSURES
235
8.9.1
8.9.2
8.93
8.10
PHASE
DIAGRAM
OF
CS[AU
'
X2][AU"X,]
(X
=
C1,
BR,
I)
235
ORIGIN
OF
METALLIC
MIXED-VALENCE
STATE
IN
CS[AU
'
C12][AU"CI]
236
AU
VALENCE
TRANSITION
IN
CS
2
[AU
I
I
2
][AU
III
I
4
]
239
197
AU
MDSSBAUER
SPECTRA
OF
[NH
3
(CH
2
)
N
NH
3
]
2
[(AUYY1,)(AUL1,)(1,)2]
(N
=
7,8)
241
8.11
CONCLUSION
243
ACKNOWLEDGMENTS
244
REFERENCES
245
9
TEMPERATURE
AND
PHOTO-INDUCED
SPIN-CROSSOVER
IN
MOLECULE-BASED
MAGNETS
251
HIROKO
TOKORO,
KENTA
IMOTO,
AND
SHIN-ICHI
OHKOSHI
9.1
9.2
INTRODUCTION
251
SPIN-CROSSOVER
PHENOMENA
IN
CESIUM
IRON
HEXACYANIDOCHROMATE
PRUSSIAN
BLUE
ANALOG
252
93
LIGHT-INDUCED
SPIN-CROSSOVER
MAGNET
IN
IRON
OCTACYANIDONIOBATE
BIMETAL
ASSEMBLY
254
X
I
CONTENTS
9.4
CHIRAL
PHOTOMAGNETISM
AND
LIGHT-CONTROLLABLE
SECOND
HARMONIC
LIGHT
IN
IRON
OCTACYANIDONIOBATE
BIMETAL
ASSEMBLY
258
9.5
CONCLUSION
AND
PERSPECTIVE
265
REFERENCES
265
10
DEVELOPING
A
METHODOLOGY
TO
OBTAIN
NEW
PHOTOSWITCHABLE
FE(LL)
SPIN
CROSSOVER
COMPLEXES
271
VARUN
KUMAR
AND
YANN
GARCIA
10.1
INTRODUCTION
AND
CONTEXT
271
10.2
INTRODUCTION
TO
A
NEW
PHOTO-RESPONSIVE
ANION:
PSCA
275
10.3
COMBINING
FE(II)
AND
PSCA
TOGETHER
IN
A
SINGLE
COMPOUND
276
10.4
FE(II)
MONONUCLEAR
COMPLEXES
WITH
DMPP
AND
PSCA
LIGANDS
278
10.5
1D
FE(II)
COORDINATION
POLYMER
WITH
PSCA
AS
NON-COORDINATED
ANIONS
281
10.6
CONCLUSIONS
AND
PERSPECTIVES
284
REFERENCES
285
11
57
FE
MDSSBAUER
SPECTROSCOPY
AS
A
PRIME
TOOL
TO
EXPLORE
A
NEW
FAMILY
OF
COLORIMETRIC
SENSORS
291
LI
SUN,
WEIYANG
LI,
AND
YANN
GARCIA
11.1
INTRODUCTION
AND
GENERAL
CONTEXT
291
11.2
COLORIMETRIC
GAS
SENSORS
BASED
ON
FE(II)
COMPLEXES
292
11.3
CONCLUSIONS
AND
PERSPECTIVES
306
REFERENCES
306
INDEX
311 |
adam_txt |
CONTENTS
PREFACE
XI
1
APPLICATION
OF
MDSSBAUER
SPECTROSCOPY
TO
ENERGY
MATERIALS
1
PIERRE-EMMANUEL
LIPPENS,
JEAN-CLAUDE
JUMAS,
AND
JOSETTE
OLIVIER-FOURCADE
1.1
INTRODUCTION
1
1.2
MDSSBAUER
SPECTROSCOPY
FOR
LI-ION
AND
NA-ION
BATTERIES
2
1.2.1
CHARACTERIZATION
OF
ELECTRODE
MATERIALS
AND
ELECTROCHEMICAL
REACTIONS
2
1.2.2
TIN-BASED
NEGATIVE
ELECTRODE
MATERIALS
FOR
LI-ION
BATTERIES
3
1.2.2.1
ELECTROCHEMICAL
REACTIONS
OF
LITHIUM
WITH
TIN
3
1.2.2.2
TIN
OXIDES
7
1.2.2.3
TIN
BOROPHOSPHATES
10
1.2.2.4
TIN-BASED
INTERMETALLICS
13
1.2.3
IRON-BASED
ELECTRODE
MATERIALS
17
1.2.3.1
LIFEPO
4
AS
POSITIVE
ELECTRODE
MATERIAL
FOR
LI-ION
BATTERIES
17
1.2.3.2
FE,
19PO4(OH)
57(H2O).43/C
AS
POSITIVE
ELECTRODE
MATERIAL
FOR
LI-ION
BATTERIES
IS
1.2.3.3
NA,
5
FE
0
5TI,
S(PO,)3/C
AS
ELECTRODE
MATERIAL
FOR
NA-ION
BATTERIES
19
1.3
MOSSBAUER
SPECTROSCOPY
OF
TIN-BASED
CATALYSTS
21
1.3.1
REFORMING
CATALYSIS
21
1.3.2
REDOX
PROPERTIES
OF
PT-SN
BASED
CATALYSTS
22
1.3.3
TRIMETALLIC
PT-SN-IN
BASED
CATALYSTS
24
1.4
CONCLUSION
26
ACKNOWLEDGMENTS
27
REFERENCES
27
2
MDSSBAUER
SPECTRAL
STUDIES
OF
IRON
PHOSPHATE
CONTAINING
MINERALS
AND
COMPOUNDS
33
GARY
J.
LONG
AND
FERNANDE
GRANDJEAN
2.1
INTRODUCTION
33
2.2
THERMODYNAMIC
PROPERTIES
OF
IRON
PHOSPHATE
CONTAINING
COMPOUNDS
34
VI
CONTENTS
2.3
ROOM
TEMPERATURE
MOSSBAUER
SPECTRA
OF
IRON
PHOSPHATE
CONTAINING
MINERALS
37
2.4
2.5
ANALYSIS
OF
MAGNETICALLY
ORDERED
MDSSBAUER
SPECTRA
50
STRUCTURAL
AND
THERMODYNAMIC
PROPERTIES
OF
THE
POLYMORPHS
OF
FEPO
4
53
2.5.1
2.6
2.7
POLYMORPHS
OF
FEPO
4
53
MDSSBAUER
SPECTRA
OF
A-FEPO4
55
MAGNETIC
STRUCTURE
OF
A-FEPO4,
OBTAINED
BY
MDSSBAUER
SPECTROSCOPY
57
2.7.1
2.8
2.9
2.9.1
2.9.2
MAGNETIC
STRUCTURE
OF
A-FEPO4
57
TEMPERATURE
DEPENDENCE
OF
THE
A-FEPO4
STRUCTURE
TILT
ANGLE
60
MDSSBAUER
SPECTRAL
STUDIES
ON
METASTABLE
POLYMORPHS
OF
FEPO
4
62
CRYSTALLOGRAPHIC
STRUCTURES
OF
TWO
POLYMORPHS
OF
FEPO42H,O
62
PREPARATION
AND
CRYSTALLOGRAPHIC
STRUCTURES OF
THE
TWO
POLYMORPHS,
Y-FEPO,
AND
Z-FEPO,
62
2.9.3
2.9.4
MDSSBAUER
SPECTRAL
STUDIES
OF
FEPO
4
METASTABLE
POLYMORPHS
64
PREPARATION
AND
MDSSBAUER
SPECTRA
OF
SYNTHETIC
HETEROSITE,
(FE,MN)PO
4
67
2.9.5
2.10
2.10.1
2.10.2
2.10.3
2.10.4
FITS
OF
THE
MAGNETIC
MDSSBAUER
SPECTRA
OF
N-FE
.
MN,
1PO4
68
MDSSBAUER
SPECTRAL
STUDIES
OF
VARIOUS
IRON
PHOSPHATE
COMPOUNDS
73
MDSSBAUER
SPECTRAL
PROPERTIES
OF
A-FE,(PO,)O
74
MDSSBAUER
SPECTRAL
PROPERTIES
OF
FE
3
(PO
4
)O
3
79
PREPARATION
AND
STRUCTURAL
PROPERTIES
OF
FE
9
(PO
4
)O
8
80
MDSSBAUER
SPECTRAL
PROPERTIES
OF
FE
9
(PO
4
)O
8
81
ACKNOWLEDGMENTS
85
REFERENCES
AND
NOTES
85
3
MDSSBAUER
SPECTROSCOPIC
INVESTIGATION
OF
FE-BASED
SILICIDES
93
XIAO
CHEN,
JUNHU
WANG,
AND
CHANGHAI
LIANG
3.1
3.2
INTRODUCTION
93
MDSSBAUER
SPECTROSCOPIC
INVESTIGATION
OF
IRON
SILICIDES
PREPARED
BY
MECHANICAL
ALLOYING
AND
HEAT
TREATMENT
95
3.3
MDSSBAUER
SPECTRA
OF
IRON
SILICIDE
ON
SILICA
PREPARED
BY
PYROLYSIS
OF
FERROCENE-POLYDIMETHYLSILANE
COMPOSITES
99
3.4
SYNTHESIS
AND
MDSSBAUER
SPECTRA
OF
IRON
SILICIDES
BY
TEMPERATURE-PROGRAMMED
SILICIFICATION
102
3.5
3.6
MDSSBAUER
SPECTROSCOPIC
INVESTIGATION
OF
DOPED
IRON
SILICIDES
104
CONCLUSION
AND
PERSPECTIVE
107
REFERENCES
108
4
MDSSBAUER
SPECTROSCOPY
OF
CATALYSTS
113
KAROLY
LAZAR
4.1
4.2
INTRODUCTION
113
PRINCIPLES
OF
THE
MDSSBAUER
EFFECT
AND
OUTLOOK
OF
ITS
APPLICATION
FOR
CATALYST
STUDIES
116
CONTENTS
VII
4.2.1
4.2.2
BRIEF
OVERVIEW
OF
THE
BASICS
OF
MDSSBAUER
SPECTROSCOPY
116
MDSSBAUER
SPECTROSCOPY
FROM
THE
POINT
OF
VIEW
OF
CATALYST
STUDIES
-
PARTICULAR
FEATURES
117
4.2.3
4.2.4
4.2.4.1
4.2.4.2
4.2.4.3
4.2.5
4.3
4.3.1
THE
PROBABILITY
OF
THE
MDSSBAUER
EFFECT
-
F-FACTOR
AND
SIZE
EFFECTS
118
VARIANTS
OF
THE
TECHNIQUE
120
57
CO
EMISSION
SPECTROSCOPY
120
SYNCHROTRON-BASED
NFS
(NUCLEAR
FORWARD
SCATTERING)
122
CONVERSION
ELECTRON
MDSSBAUER
SPECTROSCOPY
122
TECHNICAL
IMPLEMENTATIONS
-
EXPERIMENTAL
CONDITIONS
123
HETEROGENEOUS
CATALYSTS
124
SITES
ON
SUPPORTED
PARTICLES
WITH
DIFFERENT
PARTICIPATION
IN
CATALYTIC
PROCESSES
124
4.3.2
4.3.3
4.3.3.1
4.3.3.2
4.3.3.3
4.4
4.5
4.5.1
COLLECTIVE
EFFECTS
IN
PARTICLES
(MAGNETISM)
125
CASE
STUDIES
126
METALS
AND
ALLOYS
126
OXIDE
CATALYSTS
130
CATALYSTS
WITH
FE-N,
FE-C,
AND
FE-N-C
CENTERS
133
BIOCATALYSTS
-
ENZYMES
135
HOMOGENEOUS
CATALYSTS
-
FROZEN
SOLUTIONS
135
STUDIES
ON
REACTION
INTERMEDIATES
-
TIME-RESOLVED
FREEZE-QUENCHED
SPECTRA
136
4.6
CONCLUSIONS
137
ACKNOWLEDGMENT
137
REFERENCES
138
5
APPLICATION
OF
MDSSBAUER
SPECTROSCOPY
IN
STUDYING
CATALYSTS
FOR
CO
OXIDATION
AND
PREFERENTIAL
OXIDATION
OF
CO
IN
H2
145
KUO
LIU,
JUNHU
WANG,
AND
TOO
ZHANG
5.1
5.2
5.2.1
5.2.2
5.2.3
5.2.4
5.3
5.3.1
5.3.2
5.3.3
5.3.3.1
5.3.3.2
5.3.4
5.4
INTRODUCTION
145
APPLICATION
OF
MDSSBAUER
SPECTROSCOPY
IN
CO
OXIDATION
147
57
FE
MDSSBAUER
SPECTROSCOPY
147
119
SN
MDSSBAUER
SPECTROSCOPY
150
197
AU
MDSSBAUER
SPECTROSCOPY
151
193
IR
MDSSBAUER
SPECTROSCOPY
152
APPLICATION
OF
MDSSBAUER
SPECTROSCOPY
IN
PROX
153
PTFE
CONTAINING
CATALYSTS
153
AU-BASED
CATALYSTS
155
IRFE-CONTAINING
CATALYSTS
158
POROUS
CARBON
SUPPORTED
IRFE
CATALYSTS
158
SIO
2
AND
AL,O,
SUPPORTED
IRFE
CATALYSTS
159
CUO/CEO
2
WITH
FE
2
O
3
ADDITIVE
165
CONCLUDING
REMARKS
165
ACKNOWLEDGMENTS
166
REFERENCES
166
VIII
CONTENTS
6
APPLICATION
OF
57
FE
MOSSBAUER
SPECTROSCOPY
IN
STUDYING
FE-N-C
CATALYSTS
FOR
OXYGEN
REDUCTION
REACTION
IN
PROTON
EXCHANGE
MEMBRANE
FUEL
CELLS
171
XINLONG
XU,
JUNHU
WANG,
SULI
WANG,
AND
GONGQUAN
SUN
6.1
6.2
6.2.1
6.2.2
INTRODUCTION
171
ADVANCED
57
FE
MDSSBAUER
SPECTROSCOPY
TECHNIQUE
173
ROOM
TEMPERATURE
57
FE
MDSSBAUER
SPECTROSCOPY
173
LOW
TEMPERATURE
AND
COMPUTATIONAL
57
FE
MDSSBAUER
SPECTROSCOPY
174
6.2.3
6.3
6.3.1
6.3.2
6.3.3
6.3.3.1
6.3.3.2
6.4
IN
SITU
ELECTROCHEMICAL
57
FE
MDSSBAUER
SPECTROSCOPY
175
CHARACTERIZATION
OF
FE-N-C
USING
57
FE
MDSSBAUER
SPECTROSCOPY
177
IDENTIFICATION
OF
ACTIVE
SITES
177
INVESTIGATION
OF
DEGRADATION
MECHANISM
180
OPTIMIZATION
FOR
SYNTHESIS
OF
FE-N-C
184
PRECURSOR
COMPOSITION
184
HEAT
TREATMENT
185
SUMMARY
AND
PERSPECTIVE
187
ACKNOWLEDGMENTS
188
REFERENCES
188
7
197
AU
MDSSBAUER
SPECTROSCOPY
OF
THIOLATE-PROTECTED
GOLD
CLUSTERS
195
NORIMICHI
KOJIMA,
YASUHIRO
KOBAQYASHI,
AND
MAKOTO
SETO
7.1
7.2
7.3
7.3.1
7.3.2
7.3.3
7.3.4
7.3.5
INTRODUCTION
195
SYNTHESIS
OF
THIOLATE
PROTECTED
GOLD
CLUSTERS
197
197
AU
MDSSBAUER
SPECTROSCOPY
OF
GOLD
NANO-CLUSTERS
198
EXPERIMENTAL
PROCEDURE
OF
197
AU
MDSSBAUER
SPECTROSCOPY
198
197
AU
MDSSBAUER
SPECTRA
OF
AU
N
(SG)
M
(N
=
10^55)
198
MOLECULAR
STRUCTURE
AND
197
AU
MDSSBAUER
SPECTRA
OF
AU
10
(SG)
10
198
MOLECULAR
STRUCTURE
AND
197
AU
MDSSBAUER
SPECTRA
OF
AU
25
(SG)
18
200
STRUCTURAL
EVOLUTION
OF
AUYY(SG)M
(N
=
10^55)
BASED
ON
197
AU
MDSSBAUER
SPECTROSCOPY
201
7.3.6
7.3.7
7.4
197
AU
MDSSBAUER
SPECTRA
OF
AU
2
4PD
1
(SC
12
H25)
18
204
197
AU
MDSSBAUER
SPECTRA
OF
AUYY(SC12H25)M
205
CONCLUSION
208
ACKNOWLEDGMENTS
208
REFERENCES
209
8
197
AU
MDSSBAUER
SPECTROSCOPY
OF
GOLD
MIXED-VALENCE
COMPLEXES,
CS2[AU
'
X2][AU"Y,](X,
Y
=
CL,
BR,
1)
AND
[NH;
(CH,)YYNH]2[(AU
'
12)(AU"4)
(13)21
(N
=
7,
8)
213
NORIMICHI
KOJIMA,
YASUHIRO
KOBAQYASHI,
AND
MAKOTO
SETO
8.1
8.2
8.2.1
INTRODUCTION
213
EXPERIMENTAL
PROCEDURE
216
SYNTHESIS
AND
CHARACTERIZATION
216
CONTENTS
IX
8.2.1.1
8.2.1.2
8.2.2
8.3
8.4
8.5
8.5.1
CS[AU
'
X,][AU"Y4]
(X,
Y
=
C1,
BR,
I)
216
[NH,(CH,),NHA]2[(AU
'
T,)(AUYY1)(1,)21
(N
=
7,
8)
217
197
AU
MDSSBAUER
SPECTROSCOPY
217
CRYSTAL
STRUCTURE
OF
CS[AU
'
X2][AUYYY4]
(X,
Y
=
C1,
BR,
I)
218
CHEMICAL
BOND
OF
AU-X
IN
[AU
I
X
2
]
"
AND
[AU"X,]
221
MDSSBAUER
PARAMETERS
OF
197
AU
IN
[AUTX]
AND
[AUYYX4]
223
MDSSBAUER
PARAMETERS
OF
197
AU
IN
(C
4
H
9
)
4
N[AU
I
X
2
]
AND
(C,H,),N[AU"X,]
224
8.5.1.1
8.5.1.2
8.5.2
ISOMER
SHIFT
224
QUADRUPOLE
SPLITTING
224
MDSSBAUER
PARAMETERS
OF
197
AU
IN
CS
[AUX
][AU"X4]
(X
=
CL,BR,I)
225
8.5.2.1
8.5.2.2
8.5.23
8.6
8.7
8.7.1
8.7.2
8.73
8.7.4
8.8
8.8.1
ISOMER
SHIFT
225
QUADRUPOLE
SPLITTING
226
ANALYSIS
OF
197
AU
MDSSBAUER
PARAMETERS
FOR
CS,[AU
'
X2][AU"X4]
226
CHARGE
TRANSFER
INTERACTION
IN
CS[AU
'
X,][AU"X,]
(X
=
C1,
BR,
I)
227
197
AU
MDSSBAUER
SPECTRA
OF
CS[AU
'
X2][AU"LY4]
(X,
Y
=
C1,
BR,
I)
228
ISOMER
SHIFT
OF
AU
1
IN
CS
2
[
AU
'
X,
]
[AU"Y4]
228
ISOMER
SHIFT
OF
AUYY
IN
CS[AU
'
X2][AU"LY4]
230
QUADRUPOLE
SPLITTING
OF
AU
1
IN
CS[AU
'
X2I[AU"Y4]
230
QUADRUPOLE
SPLITTING
OF
AUYY
IN
CS[AUYYX ][AUYYY4]
231
SINGLE
CRYSTAL
197
AU
MDSSBAUER
SPECTRA
OF
CS[AU
'
1,][AUYY1]
231
COMPARISON
OF
197
AU
MDSSBAUER
SPECTRA
BETWEEN
SINGLE
CRYSTAL
AND
POWDER
CRYSTAL
231
8.8.2
8.9
SIGN
OF
EFG
FOR
AU
1
IN
[AU
1
^]
-
AND
AUYY
IN
[AUMX,]
234
197
AU
MDSSBAUER
SPECTRA
OF
CS[AU
'
X,][AU"X,]
(X
=
C1,1)
UNDER
HIGH
PRESSURES
235
8.9.1
8.9.2
8.93
8.10
PHASE
DIAGRAM
OF
CS[AU
'
X2][AU"X,]
(X
=
C1,
BR,
I)
235
ORIGIN
OF
METALLIC
MIXED-VALENCE
STATE
IN
CS[AU
'
C12][AU"CI]
236
AU
VALENCE
TRANSITION
IN
CS
2
[AU
I
I
2
][AU
III
I
4
]
239
197
AU
MDSSBAUER
SPECTRA
OF
[NH
3
(CH
2
)
N
NH
3
]
2
[(AUYY1,)(AUL1,)(1,)2]
(N
=
7,8)
241
8.11
CONCLUSION
243
ACKNOWLEDGMENTS
244
REFERENCES
245
9
TEMPERATURE
AND
PHOTO-INDUCED
SPIN-CROSSOVER
IN
MOLECULE-BASED
MAGNETS
251
HIROKO
TOKORO,
KENTA
IMOTO,
AND
SHIN-ICHI
OHKOSHI
9.1
9.2
INTRODUCTION
251
SPIN-CROSSOVER
PHENOMENA
IN
CESIUM
IRON
HEXACYANIDOCHROMATE
PRUSSIAN
BLUE
ANALOG
252
93
LIGHT-INDUCED
SPIN-CROSSOVER
MAGNET
IN
IRON
OCTACYANIDONIOBATE
BIMETAL
ASSEMBLY
254
X
I
CONTENTS
9.4
CHIRAL
PHOTOMAGNETISM
AND
LIGHT-CONTROLLABLE
SECOND
HARMONIC
LIGHT
IN
IRON
OCTACYANIDONIOBATE
BIMETAL
ASSEMBLY
258
9.5
CONCLUSION
AND
PERSPECTIVE
265
REFERENCES
265
10
DEVELOPING
A
METHODOLOGY
TO
OBTAIN
NEW
PHOTOSWITCHABLE
FE(LL)
SPIN
CROSSOVER
COMPLEXES
271
VARUN
KUMAR
AND
YANN
GARCIA
10.1
INTRODUCTION
AND
CONTEXT
271
10.2
INTRODUCTION
TO
A
NEW
PHOTO-RESPONSIVE
ANION:
PSCA
275
10.3
COMBINING
FE(II)
AND
PSCA
TOGETHER
IN
A
SINGLE
COMPOUND
276
10.4
FE(II)
MONONUCLEAR
COMPLEXES
WITH
DMPP
AND
PSCA
LIGANDS
278
10.5
1D
FE(II)
COORDINATION
POLYMER
WITH
PSCA
AS
NON-COORDINATED
ANIONS
281
10.6
CONCLUSIONS
AND
PERSPECTIVES
284
REFERENCES
285
11
57
FE
MDSSBAUER
SPECTROSCOPY
AS
A
PRIME
TOOL
TO
EXPLORE
A
NEW
FAMILY
OF
COLORIMETRIC
SENSORS
291
LI
SUN,
WEIYANG
LI,
AND
YANN
GARCIA
11.1
INTRODUCTION
AND
GENERAL
CONTEXT
291
11.2
COLORIMETRIC
GAS
SENSORS
BASED
ON
FE(II)
COMPLEXES
292
11.3
CONCLUSIONS
AND
PERSPECTIVES
306
REFERENCES
306
INDEX
311 |
any_adam_object | 1 |
any_adam_object_boolean | 1 |
author2 | Garcia, Yann Wang, Junhu Zhang, Tao |
author2_role | edt edt edt |
author2_variant | y g yg j w jw t z tz |
author_GND | (DE-588)1260237060 (DE-588)1315449897 |
author_facet | Garcia, Yann Wang, Junhu Zhang, Tao |
building | Verbundindex |
bvnumber | BV049047893 |
classification_rvk | VG 8950 |
ctrlnum | (OCoLC)1403382591 (DE-599)DNB1280080701 |
discipline | Chemie / Pharmazie |
discipline_str_mv | Chemie / Pharmazie |
format | Book |
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genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
genre_facet | Aufsatzsammlung |
id | DE-604.BV049047893 |
illustrated | Illustrated |
index_date | 2024-07-03T22:20:45Z |
indexdate | 2024-07-20T09:04:40Z |
institution | BVB |
institution_GND | (DE-588)16179388-5 |
isbn | 9783527346912 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-034310300 |
oclc_num | 1403382591 |
open_access_boolean | |
owner | DE-29T DE-11 DE-19 DE-BY-UBM |
owner_facet | DE-29T DE-11 DE-19 DE-BY-UBM |
physical | xiii, 316 Seiten Illustrationen 24.4 cm x 17 cm |
publishDate | 2024 |
publishDateSearch | 2024 |
publishDateSort | 2024 |
publisher | Wiley-VCH |
record_format | marc |
spelling | Mössbauer spectroscopy applications in chemistry and materials science edited by Yann Garcia, Junhu Wang, and Tao Zhang Weinheim Wiley-VCH [2024] © 2024 xiii, 316 Seiten Illustrationen 24.4 cm x 17 cm txt rdacontent n rdamedia nc rdacarrier Mößbauer-Spektroskopie (DE-588)4170352-2 gnd rswk-swf Analyse u. Charakterisierung von Nanosystemen Analysis/Characterization of Nanosystems CH15: Spektroskopie Chemie Chemistry MSA0: Werkstoffprüfung Materials Characterization Materials Science Materialwissenschaften NT80: Analyse u. Charakterisierung von Nanosystemen Nanotechnologie Nanotechnology Spectroscopy Spektroskopie Werkstoffprüfung (DE-588)4143413-4 Aufsatzsammlung gnd-content Mößbauer-Spektroskopie (DE-588)4170352-2 s DE-604 Garcia, Yann (DE-588)1260237060 edt Wang, Junhu (DE-588)1315449897 edt Zhang, Tao edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-82494-6 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-82493-9 Erscheint auch als Online-Ausgabe, oBook 978-3-527-82495-3 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34691-2/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034310300&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Mössbauer spectroscopy applications in chemistry and materials science Mößbauer-Spektroskopie (DE-588)4170352-2 gnd |
subject_GND | (DE-588)4170352-2 (DE-588)4143413-4 |
title | Mössbauer spectroscopy applications in chemistry and materials science |
title_auth | Mössbauer spectroscopy applications in chemistry and materials science |
title_exact_search | Mössbauer spectroscopy applications in chemistry and materials science |
title_exact_search_txtP | Mössbauer spectroscopy applications in chemistry and materials science |
title_full | Mössbauer spectroscopy applications in chemistry and materials science edited by Yann Garcia, Junhu Wang, and Tao Zhang |
title_fullStr | Mössbauer spectroscopy applications in chemistry and materials science edited by Yann Garcia, Junhu Wang, and Tao Zhang |
title_full_unstemmed | Mössbauer spectroscopy applications in chemistry and materials science edited by Yann Garcia, Junhu Wang, and Tao Zhang |
title_short | Mössbauer spectroscopy |
title_sort | mossbauer spectroscopy applications in chemistry and materials science |
title_sub | applications in chemistry and materials science |
topic | Mößbauer-Spektroskopie (DE-588)4170352-2 gnd |
topic_facet | Mößbauer-Spektroskopie Aufsatzsammlung |
url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34691-2/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034310300&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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