Biomass valorization: sustainable methods for the production of chemicals
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| Sprache: | English |
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Wiley-VCH
[2021]
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| Schlagworte: | |
| Online-Zugang: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34717-9/ Inhaltsverzeichnis |
| Beschreibung: | xiv, 417 Seiten Illustrationen, Karte 24.4 cm x 17 cm |
| ISBN: | 9783527347179 3527347178 |
Internformat
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| 245 | 1 | 0 | |a Biomass valorization |b sustainable methods for the production of chemicals |c edited by Davide Ravelli, Chiara Samori |
| 264 | 1 | |a Weinheim, Germany |b Wiley-VCH |c [2021] | |
| 300 | |a xiv, 417 Seiten |b Illustrationen, Karte |c 24.4 cm x 17 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Herstellung |0 (DE-588)4159653-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Grüne Chemie |0 (DE-588)7563215-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Biomasseverarbeitung |0 (DE-588)4400055-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Chemikalie |0 (DE-588)4009833-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Biomasse |0 (DE-588)4006877-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Verwertung |0 (DE-588)4188158-8 |2 gnd |9 rswk-swf |
| 653 | |a Agriculture | ||
| 653 | |a Biorenewable Resources | ||
| 653 | |a Catalysis | ||
| 653 | |a Catalysis & Chemical Reaction Engineering | ||
| 653 | |a Chemical Engineering | ||
| 653 | |a Chemie | ||
| 653 | |a Chemische Verfahrenstechnik | ||
| 653 | |a Chemistry | ||
| 653 | |a Katalyse | ||
| 653 | |a Katalyse u. Chemische Reaktionstechnik | ||
| 653 | |a Landwirtschaft | ||
| 653 | |a Nachhaltige u. Grüne Chemie | ||
| 653 | |a Nachwachsende Rohstoffe | ||
| 653 | |a Sustainable Chemistry & Green Chemistry | ||
| 653 | |a AG90: Nachwachsende Rohstoffe | ||
| 653 | |a CG03: Katalyse u. Chemische Reaktionstechnik | ||
| 653 | |a CH40: Katalyse | ||
| 653 | |a CHC0: Nachhaltige u. Grüne Chemie | ||
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| 689 | 0 | 5 | |a Biomasseverarbeitung |0 (DE-588)4400055-8 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Ravelli, Davide |d 1984- |0 (DE-588)1183819013 |4 edt | |
| 700 | 1 | |a Samorì, Chiara |4 edt | |
| 710 | 2 | |a Wiley-VCH |0 (DE-588)16179388-5 |4 pbl | |
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| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |z 978-3-527-82502-8 |
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Datensatz im Suchindex
| _version_ | 1804182916430823424 |
|---|---|
| adam_text | CONTENTS
FOREWORD
XI
PREFACE
XIII
1
ROLE
OF
BIOMASS
IN
THE
PRODUCTION
OF
CHEMICALS
1
LAYLA
FILICIOTTO,
EVAN
PFAB
AND
RAFAEL
LUQUE
1.1
INTRODUCTION
1
1.2
BIOMASS
VALORIZATION
3
1.3
LIGNOCELLULOSIC
BIOMASS
5
1.4
KEY
BIOMOLECULES
6
1.5
SOLVENTS
10
1.6
PRETREATMENT
OF
LIGNOCELLULOSES
12
1.7
CONCLUSIONS
AND
PERSPECTIVES
15
REFERENCES
15
SECTION
I
CATALYTIC
STRATEGIES
23
2
BIOMASS
PROCESSING
VIA
ACID
CATALYSIS
25
LURII
BODACHIVSKYI,
UNNIKRISHNAN
KUZHIUMPARAMBIL
AND
D.
BRADLEY
G.
WILLIAMS
2.1
INTRODUCTION
25
2.1.1
IS
AN
ACID
THE
BEST
CATALYST?
26
2.2
ACID-CATALYZED
PROCESSING
OF
CELLULOSIC
POLYSACCHARIDES
29
2.3
ACID-CATALYZED
PROCESSING
OF
LIGNIN
44
2.4
CONCLUSIONS
AND
PERSPECTIVES
47
REFERENCES
47
3
BIOMASS
PROCESSING
VIA
BASE
CATALYSIS
57
LICHEN
LIU,
MARIA
J.
CLIMENT
AND
SARA
IBORRA
3.1
INTRODUCTION
57
3.2
ALDOL
CONDENSATION
60
3.2.1
ALDOL
CONDENSATION
OF
FURANIC
ALDEHYDES
60
3.2.2
SELF-ALDOL
CONDENSATION
OF
ACETONE
63
VI
CONTENTS
3.2.3
ALDOL
CONDENSATION
BETWEEN
ALCOHOLS:
GUERBET
COUPLING
REACTION
64
3.3
KETONIZATION
REACTION
OF
CARBOXYLIC
ACIDS
65
3.4
TRANSESTERIFICATION
REACTION
68
3.4.1
BIODIESEL
PRODUCTION
68
3.4.2
HIGH
VALUE-ADDED
CHEMICALS
FROM
TRANSESTERIFICATION
REACTIONS
70
3.5
CONCLUSIONS
AND
PERSPECTIVES
73
REFERENCES
74
4
BIOMASS
PROCESSING
VIA
METAL
CATALYSIS
81
SOFIA
CAPELLI
AND
ALBERTO
VILLA
4.1
INTRODUCTION
81
4.2
SYNTHETIC
STRATEGIES
FOR
SUPPORTED
METAL
NANOPARTICLES
83
4.2.1
IMPREGNATION
83
4.2.2
PRECIPITATION
84
4.2.3
SOL
IMMOBILIZATION
85
4.3
FURFURAL
86
4.3.1
FURFURAL
HYDROGENATION
87
4.3.1.1
FURFURAL
TO
FURFURYL
ALCOHOL
87
4.3.1.2
FURFURAL
TO
TETRAHYDROFURFURYL
ALCOHOL
88
4.3.1.3
FURFURAL
TO
PENTANEDIOLS
89
4.3.1.4
FURFURAL
TO
2-METHYLFURAN
90
4.3.2
FURFURAL
OXIDATION
92
4.3.2.1
FURFURAL
TO
FUROATES
92
4.4
5-HYDROXYMETHYLFURFURAL
(HMF)
92
4.4.1
HMF
HYDROGENATION
93
4.4.1.1
HMF
TO
2,5-DIMETHYLFURAN
(DMF)
94
4.4.1.2
HMF
TO
2,5-DIHYDROXYMETHYLTETRAHYDROFURAN
(DHMTHF)
95
4.4.2
HMF
OXIDATION
96
4.4.2.1
HMF
TO
2,5-FURANDICARBOXYLIC
ACID
(FDCA)
USING
MONOMETALLIC
SYSTEMS
96
4.4.2.2
HMF
OXIDATION
OVER
BIMETALLIC
CATALYSTS
100
4.5
CONCLUSIONS
AND
PERSPECTIVES
103
REFERENCES
103
5
BIOMASS
PROCESSING
WITH
BIOCATALYSIS
113
ROGER
A.
SHELDON
5.1
INTRODUCTION
113
5.2
GENERATIONS
OF
RENEWABLE
BIOMASS:
ADVANTAGES
AND
LIMITATIONS
113
5.3
ADVANTAGES
AND
LIMITATIONS
OF
BIOCATALYSIS
116
5.4
ENZYME
DISCOVERY
AND
OPTIMIZATION
OF
ENZYME
PERFORMANCE
117
5.5
ENZYME
IMMOBILIZATION
118
5.5.1
ENZYME
IMMOBILIZATION
BY
CROSS-LINKING
ENZYME
MOLECULES
119
5.5.2
ADVANTAGES
AND
LIMITATIONS
OF
CROSS-LINKED
ENZYME
AGGREGATES
(CLEAS)
120
5.5.3
MAGNETICALLY
SEPARABLE
IMMOBILIZED
ENZYMES
120
CONTENTS
VII
5.6
5.7
5.8
5.8.1
5.9
5.10
5.10.1
5.10.2
ENZYMATIC
HYDROLYSIS
OF
STARCH
TO
GLUCOSE
121
ENZYMATIC
DEPOLYMERIZATION
OF
LIGNOCELLULOSE
122
ENZYMATIC
HYDROLYSIS
OF
CELLULOSE
AND
HEMICELLULOSE
123
MAGNETIZABLE
IMMOBILIZED
ENZYMES
IN
LIGNOCELLULOSE
CONVERSION
124
ENZYMATIC
HYDROLYSIS
OF
3RD
GENERATION
(3G)
POLYSACCHARIDES
124
COMMODITY
CHEMICALS
FROM
CARBOHYDRATES
(MONOSACCHARIDES)
126
FERMENTATIVE
PRODUCTION
OF
COMMODITY
CHEMICALS
126
DEOXYGENATION
VIA
DEHYDRATION
OF
CARBOHYDRATES
TO
FURAN
DERIVATIVES
129
5.10.3
POLYETHYLENE
FURANDICARBOXYLATE
(PEF)
AS
A
RENEWABLE
ALTERNATIVE
TO
PET
129
5.10.4
5.11
ENZYMATIC
SYNTHESIS
OF
BIO-BASED
POLYESTERS
131
ENZYMATIC
CONVERSIONS
OF
TRIGLYCERIDES:
PRODUCTION
OF
BIODIESEL
AND
BULK
CHEMICALS
132
5.12
CONCLUSIONS
AND
PERSPECTIVES
133
REFERENCES
133
SECTION
II
THERMAL
STRATEGIES
147
6
BIOMASS
PROCESSING
VIA
PYROLYSIS
149
DANIELE
FABBRI,
YUNCHAO
LI
AND
SHURONG
WANG
6.1
6.2
6.2.1
6.2.2
6.2.3
6.2.4
BRIEF
INTRODUCTION
149
CHEMICALS
FROM
CELLULOSE
PYROLYSIS
151
GENERAL
ASPECTS
151
LEVOGLUCOSAN
754
LEVOGLUCOSENONE
756
LAC,
(LR,5S)-L-HYDROXY-3,6-DIOXABICYDIOXABICYCLO-[3.2.1]OCTAN-2-ONE
757
6.3
6.4
6.4.1
6.4.1.1
6.4.1.2
6.4.1.3
6.4.1.4
6.4.2
6.4.2.1
6.4.2.2
6.4.2.3
6.4.3
6.4.4
6.4.5
6.5
CHEMICALS
FROM
LIGNIN
PYROLYSIS
760
PYROLYSIS
OF
BIOMASS
767
LEVOGLUCOSAN
767
EFFECTS
OF
METAL
OXIDES
7
62
EFFECTS
OF
ALKALI
AND
ALKALINE
EARTH
METALS
762
EFFECTS
OF
ACID
IMPREGNATION
7
62
EFFECTS
OF
OTHER
COMPONENTS
7
63
LEVOGLUCOSENONE
163
EFFECTS
OF
METAL
CHLORIDES
7
63
EFFECTS
OF
ACID
CATALYSTS
163
OTHERS
764
FURFURAL
764
AROMATIC
HYDROCARBONS
767
PHENOLIC
COMPOUNDS
769
CONCLUSIONS
AND
PERSPECTIVES
7
70
REFERENCES
777
VIII
CONTENTS
7
BIOMASS
PROCESSING
VIA
THERMOCHEMICAL
BIOLOGICAL
HYBRID
PROCESSES
181
CRISTIAN
TORRI,
ALESSANDRO
CIROLAMO
ROMBOLA,
ALISAR
KIWAN
AND
DANIELE
FABBRI
7.1
INTRODUCTION
181
7.1.1
HYBRID
THERMOCHEMICAL/BIOLOGICAL
PROCESSING
WITH
SINGLE-STRAIN
MICROORGANISMS
183
7.1.2
HYBRID
THERMOCHEMICAL/BIOLOGICAL
PROCESSING
WITH
MICROBIAL
MIXED
CONSORTIA
(MMC)
183
7.2
PYROLYSIS
PRODUCTS
(PYP)
FROM
THE
MICROORGANISM
S
STANDPOINT
185
7.2.1
WHAT
PYROLYSIS
CAN
DO
FOR
MICROORGANISMS:
YIELDS
AND
BIOAVAILABILITY
OF
PYP
186
7.2.2
VIABLE
PATHWAYS
ACCORDING
TO
THERMODYNAMICS
LAWS
188
7.2.3
RATE
OF
MMC
BIOLOGICAL
CONVERSIONS
IN
RELATIONSHIP
WITH
PYP
TREATMENT
191
7.2.4
TOXICITY
OF
PYP
TOWARD
MMC
193
7.3
CONVERSION
OF
PYP
WITH
MMC:
SURVEY
OF
EXPERIMENTAL
EVIDENCE
198
7.3.1
SYNGAS
CONVERSION
TO
METHANE
203
7.3.2
SYNGAS
CONVERSION
TO
H
2
,
VOLATILE
FATTY
ACIDS
(VFA),
AND
ALCOHOLS
203
7.3.3
CONVERSION
OF
CONDENSABLE
PYP
TO
METHANE
205
7.3.4
CONVERSION
OF
CONDENSABLE
PYP
TO
VFA
AND
OTHER
INTERMEDIATES
206
7
A
FEASIBLE
PATHWAYS
FOR
PRODUCING
CHEMICALS
FROM
PYP
WITH
MMC
207
7.4.1
HYBRID
PYROLYSIS
FERMENTATION
AND
EXTRACTION
OF
MIXED
VFA/ALCOHOLS
207
7.4.2
ALKALINE
FERMENTATION
OF
PYROLYSIS
PRODUCTS
TO
VFA
SALTS,
KETONIZATION,
AND
HYDROGENATION
TO
C3-C6
MIXED
ALCOHOLS
209
7.4.3
ALKALINE
FERMENTATION
OF
PYROLYSIS
PRODUCTS
TO
VFA
SALTS
AND
POLYHYDROXYALKANOATES
(PHA)
PRODUCTION
VIA
AEROBIC
MMC
211
7.4.4
DIRECT
ALCOHOL
PRODUCTION
BY
MEANS
OF
FERMENTATION
OF
PYP
UNDER
HIGH
HYDROGEN
PRESSURE
213
7.5
CONCLUSIONS
AND
PERSPECTIVES
215
REFERENCES
216
SECTION
III
ADVANCED/UNCONVENTIONAL
STRATEGIES
225
8
BIOMASS
PROCESSING
VIA
ELECTROCHEMICAL
MEANS
227
ROMAN
LATSUZBAIA,
ROEL
LOHANNES
MARTINUS
BISSELINK,
MARC
CROCKATT,
LAN
CORNELLS
VAN
DER
WAAL
AND
EARL
LAWRENCE
VINCENT
GOETHEER
8.1
INTRODUCTION
227
8.2
ELECTROCHEMICAL
CONVERSION
OF
BIO-BASED
MOLECULES
228
8.3
CONVERSION
OF
SUGARS
230
8.4
CONVERSION
OF
FURANICS
234
8.4.1
5-(HYDROXYMETHYL)FURFURAL
(5-HMF)
234
8.4.1.1
5-HMF
OXIDATION
235
CONTENTS
IX
8.4.1.2
5-HMF
REDUCTION
238
8.4.2
FURFURAL
240
8.5
CONVERSION
OF
LEVULINIC
ACID
244
8.6
CONVERSION
OF
GLYCEROL
246
8.7
LIGNIN
DEPOLYMERIZATION
248
8.8
SCALE-UP
OF
ELECTROSYNTHESIS
OF
BIOMASS-DERIVED
CHEMICALS
248
8.9
CONCLUSIONS
AND
PERSPECTIVES
254
REFERENCES
254
9
BIOMASS
PROCESSING
VIA
PHOTOCHEMICAL
MEANS
265
ANDREY
SHATSKIY
AND
MARKUS
D.
KARKAS
9.1
INTRODUCTION
265
9.2
FUNDAMENTAL
ASPECTS
OF
PHOTOREDOX
CATALYSIS
266
9.3
PHOTOCHEMICAL
VALORIZATION
OF
LIGNIN
267
9.3.1
STRATEGIES
FOR
C
A
-
C
()
BOND
CLEAVAGE
268
9.3.2
STRATEGIES
FOR
LIGNIN
OXIDATION
AND
C
P
-
O
BOND
CLEAVAGE
272
9.3.3
STRATEGIES
FOR
AR
-
O
BOND
CLEAVAGE
278
9.4
CONCLUSIONS
AND
PERSPECTIVES
281
REFERENCES
282
10
BIOMASS
PROCESSING
VIA
MICROWAVE
TREATMENT
289
ROBERTO
ROSA,
GIANCARLO
CRAVOTTO
AND
CRISTINA
LEONELLI
10.1
INTRODUCTION
289
10.2
MICROWAVE-MATTER
INTERACTION:
ADVANTAGES
AND
LIMITATIONS
IN
THE
PROCESSING
OF
BIOMASS
291
10.3
MICROWAVE
PYROLYSIS
296
10.4
MICROWAVE-ASSISTED
HYDROLYSIS
299
10.5
MICROWAVE-ASSISTED
EXTRACTION
OF
PHYTOCHEMICAL
COMPOUNDS
303
10.6
CONCLUSIONS
AND
PERSPECTIVES
306
REFERENCES
307
11
BIOMASS
PROCESSING
ASSISTED
BY
ULTRASOUND
315
CEZAR
A.
BIZZI,
DANIEL
SANTOS,
GABRIELLE
D.
LOP
AND
ERICO
M.
M.
FLORES
11.1
INTRODUCTION
315
11.2
ULTRASOUND
BACKGROUND
316
11.3
ULTRASOUND-ASSISTED
BIOMASS
PRETREATMENTS
319
11.4
ULTRASOUND-ASSISTED
BIOMASS
CONVERSION
322
11.4.1
THERMOCHEMICAL
CONVERSION
ASSISTED
BY
ULTRASOUND
323
11.4.2
BIOCHEMICAL
CONVERSION
ASSISTED
BY
ULTRASOUND
324
11.4.3
CHEMICAL
CONVERSION
(SYNTHESIS)
ASSISTED
BY
ULTRASOUND
325
11.5
ULTRASOUND-ASSISTED
EXTRACTION
OF
VALUE-ADDED
COMPOUNDS
326
11.5.1
ULTRASOUND
CONTRIBUTION
TO
BIOMASS
EXTRACTION
PROCESSES
326
11.5.2
USES
OF
ALTERNATIVE
APPROACHES
FOR
BIOMASS
EXTRACTIONS
ASSISTED
BY
ULTRASOUND
328
11.6
ALTERNATIVE
SOLVENTS
331
CONTENTS
11.7
CONCLUSIONS
AND
PERSPECTIVES
332
REFERENCES
333
12
BIOMASS
PROCESSING
VIA
MECHANOCHEMICAL
MEANS
343
GEORGE
MARGOUTIDIS
AND
FRANCESCA
M.
KERTON
12.1
OVERVIEW
AND
INTRODUCTION
343
12.1.1
BACKGROUND
TO
THE
METHOD
343
12.1.2
PROPERTIES
OF
A
TYPICAL
LABORATORY
MIXER/MILL
346
12.2
CRYSTALLINITY
REDUCTION
IN
BIOPOLYMERS
VIA
MECHANOCHEMISTRY
348
12.3
MECHANOCHEMICAL
TRANSFORMATIONS
OF
POLYSACCHARIDES
352
12.3.1
CELLULOSE
DEPOLYMERIZATION
352
12.3.2
CELLULOSE
MODIFICATION
TOWARD
COMPOSITE
MATERIALS
355
12.3.3
TRANSFORMATIONS
OF
CHITIN
355
12.4
MECHANOCHEMICAL
TRANSFORMATIONS
OF
AMINO
ACIDS,
NUCLEOTIDES,
AND
RELATED
MATERIALS
357
12.5
MECHANOCHEMICAL
TREATMENT
OF
LIGNIN
359
12.6
BIOMINERALS
FROM
MECHANOCHEMICAL
PROCESSING
OF
BIOMASS
360
12.7
CONCLUSIONS
AND
PERSPECTIVES
361
REFERENCES
361
SECTION
IV
CLOSING
REMARKS
367
13
INDUSTRIAL
PERSPECTIVES
OF
BIOMASS
PROCESSING
369
TOMMASO
TABANELLI
AND
FABRIZIO
CAVANI
13.1
REPLACING
EXISTING
PETROCHEMICALS
WITH
ALTERNATIVES
FROM
BIOMASS:
AN
INTRODUCTION
369
13.2
OLEOCHEMICAL
BIOREFINERY:
A
CONSOLIDATED
AND
MULTIFACETED
EXAMPLE
OF
BIOMASS
PROCESSING
371
13.2.1
BIOFUELS
AND
COPRODUCED
CHEMICALS
FROM
OILS
AND
FATS
371
13.2.2
SKELETAL
ISOMERIZATION
OF
UNSATURATED
FATTY
ACIDS
FOR
ISOSTEARIC
ACID
PRODUCTION
379
13.2.3
BIO-BASED
SYNTHESIS
OF
AZELAIC
AND
PELARGONIC
ACIDS:
A
RENEWABLE
ROUTE
TOWARD
BIO-BASED
POLYESTERS
AND
COSMETICS
382
13.3
FROM
SUGAR
TO
BIO-MONOMERS:
THE
CASE
OF
2,5-FURANDICARBOXYLIC
ACID
(FDCA)
385
13.4
FROM
BIOETHANOL
TO
RUBBER:
THE
SYNTHESIS
OF
BIO-BUTADIENE
388
13.5
CONCLUSIONS
AND
PERSPECTIVES
391
REFERENCES
391
INDEX
411
|
| adam_txt |
CONTENTS
FOREWORD
XI
PREFACE
XIII
1
ROLE
OF
BIOMASS
IN
THE
PRODUCTION
OF
CHEMICALS
1
LAYLA
FILICIOTTO,
EVAN
PFAB
AND
RAFAEL
LUQUE
1.1
INTRODUCTION
1
1.2
BIOMASS
VALORIZATION
3
1.3
LIGNOCELLULOSIC
BIOMASS
5
1.4
KEY
BIOMOLECULES
6
1.5
SOLVENTS
10
1.6
PRETREATMENT
OF
LIGNOCELLULOSES
12
1.7
CONCLUSIONS
AND
PERSPECTIVES
15
REFERENCES
15
SECTION
I
CATALYTIC
STRATEGIES
23
2
BIOMASS
PROCESSING
VIA
ACID
CATALYSIS
25
LURII
BODACHIVSKYI,
UNNIKRISHNAN
KUZHIUMPARAMBIL
AND
D.
BRADLEY
G.
WILLIAMS
2.1
INTRODUCTION
25
2.1.1
IS
AN
ACID
THE
BEST
CATALYST?
26
2.2
ACID-CATALYZED
PROCESSING
OF
CELLULOSIC
POLYSACCHARIDES
29
2.3
ACID-CATALYZED
PROCESSING
OF
LIGNIN
44
2.4
CONCLUSIONS
AND
PERSPECTIVES
47
REFERENCES
47
3
BIOMASS
PROCESSING
VIA
BASE
CATALYSIS
57
LICHEN
LIU,
MARIA
J.
CLIMENT
AND
SARA
IBORRA
3.1
INTRODUCTION
57
3.2
ALDOL
CONDENSATION
60
3.2.1
ALDOL
CONDENSATION
OF
FURANIC
ALDEHYDES
60
3.2.2
SELF-ALDOL
CONDENSATION
OF
ACETONE
63
VI
CONTENTS
3.2.3
ALDOL
CONDENSATION
BETWEEN
ALCOHOLS:
GUERBET
COUPLING
REACTION
64
3.3
KETONIZATION
REACTION
OF
CARBOXYLIC
ACIDS
65
3.4
TRANSESTERIFICATION
REACTION
68
3.4.1
BIODIESEL
PRODUCTION
68
3.4.2
HIGH
VALUE-ADDED
CHEMICALS
FROM
TRANSESTERIFICATION
REACTIONS
70
3.5
CONCLUSIONS
AND
PERSPECTIVES
73
REFERENCES
74
4
BIOMASS
PROCESSING
VIA
METAL
CATALYSIS
81
SOFIA
CAPELLI
AND
ALBERTO
VILLA
4.1
INTRODUCTION
81
4.2
SYNTHETIC
STRATEGIES
FOR
SUPPORTED
METAL
NANOPARTICLES
83
4.2.1
IMPREGNATION
83
4.2.2
PRECIPITATION
84
4.2.3
SOL
IMMOBILIZATION
85
4.3
FURFURAL
86
4.3.1
FURFURAL
HYDROGENATION
87
4.3.1.1
FURFURAL
TO
FURFURYL
ALCOHOL
87
4.3.1.2
FURFURAL
TO
TETRAHYDROFURFURYL
ALCOHOL
88
4.3.1.3
FURFURAL
TO
PENTANEDIOLS
89
4.3.1.4
FURFURAL
TO
2-METHYLFURAN
90
4.3.2
FURFURAL
OXIDATION
92
4.3.2.1
FURFURAL
TO
FUROATES
92
4.4
5-HYDROXYMETHYLFURFURAL
(HMF)
92
4.4.1
HMF
HYDROGENATION
93
4.4.1.1
HMF
TO
2,5-DIMETHYLFURAN
(DMF)
94
4.4.1.2
HMF
TO
2,5-DIHYDROXYMETHYLTETRAHYDROFURAN
(DHMTHF)
95
4.4.2
HMF
OXIDATION
96
4.4.2.1
HMF
TO
2,5-FURANDICARBOXYLIC
ACID
(FDCA)
USING
MONOMETALLIC
SYSTEMS
96
4.4.2.2
HMF
OXIDATION
OVER
BIMETALLIC
CATALYSTS
100
4.5
CONCLUSIONS
AND
PERSPECTIVES
103
REFERENCES
103
5
BIOMASS
PROCESSING
WITH
BIOCATALYSIS
113
ROGER
A.
SHELDON
5.1
INTRODUCTION
113
5.2
GENERATIONS
OF
RENEWABLE
BIOMASS:
ADVANTAGES
AND
LIMITATIONS
113
5.3
ADVANTAGES
AND
LIMITATIONS
OF
BIOCATALYSIS
116
5.4
ENZYME
DISCOVERY
AND
OPTIMIZATION
OF
ENZYME
PERFORMANCE
117
5.5
ENZYME
IMMOBILIZATION
118
5.5.1
ENZYME
IMMOBILIZATION
BY
CROSS-LINKING
ENZYME
MOLECULES
119
5.5.2
ADVANTAGES
AND
LIMITATIONS
OF
CROSS-LINKED
ENZYME
AGGREGATES
(CLEAS)
120
5.5.3
MAGNETICALLY
SEPARABLE
IMMOBILIZED
ENZYMES
120
CONTENTS
VII
5.6
5.7
5.8
5.8.1
5.9
5.10
5.10.1
5.10.2
ENZYMATIC
HYDROLYSIS
OF
STARCH
TO
GLUCOSE
121
ENZYMATIC
DEPOLYMERIZATION
OF
LIGNOCELLULOSE
122
ENZYMATIC
HYDROLYSIS
OF
CELLULOSE
AND
HEMICELLULOSE
123
MAGNETIZABLE
IMMOBILIZED
ENZYMES
IN
LIGNOCELLULOSE
CONVERSION
124
ENZYMATIC
HYDROLYSIS
OF
3RD
GENERATION
(3G)
POLYSACCHARIDES
124
COMMODITY
CHEMICALS
FROM
CARBOHYDRATES
(MONOSACCHARIDES)
126
FERMENTATIVE
PRODUCTION
OF
COMMODITY
CHEMICALS
126
DEOXYGENATION
VIA
DEHYDRATION
OF
CARBOHYDRATES
TO
FURAN
DERIVATIVES
129
5.10.3
POLYETHYLENE
FURANDICARBOXYLATE
(PEF)
AS
A
RENEWABLE
ALTERNATIVE
TO
PET
129
5.10.4
5.11
ENZYMATIC
SYNTHESIS
OF
BIO-BASED
POLYESTERS
131
ENZYMATIC
CONVERSIONS
OF
TRIGLYCERIDES:
PRODUCTION
OF
BIODIESEL
AND
BULK
CHEMICALS
132
5.12
CONCLUSIONS
AND
PERSPECTIVES
133
REFERENCES
133
SECTION
II
THERMAL
STRATEGIES
147
6
BIOMASS
PROCESSING
VIA
PYROLYSIS
149
DANIELE
FABBRI,
YUNCHAO
LI
AND
SHURONG
WANG
6.1
6.2
6.2.1
6.2.2
6.2.3
6.2.4
BRIEF
INTRODUCTION
149
CHEMICALS
FROM
CELLULOSE
PYROLYSIS
151
GENERAL
ASPECTS
151
LEVOGLUCOSAN
754
LEVOGLUCOSENONE
756
LAC,
(LR,5S)-L-HYDROXY-3,6-DIOXABICYDIOXABICYCLO-[3.2.1]OCTAN-2-ONE
757
6.3
6.4
6.4.1
6.4.1.1
6.4.1.2
6.4.1.3
6.4.1.4
6.4.2
6.4.2.1
6.4.2.2
6.4.2.3
6.4.3
6.4.4
6.4.5
6.5
CHEMICALS
FROM
LIGNIN
PYROLYSIS
760
PYROLYSIS
OF
BIOMASS
767
LEVOGLUCOSAN
767
EFFECTS
OF
METAL
OXIDES
7
62
EFFECTS
OF
ALKALI
AND
ALKALINE
EARTH
METALS
762
EFFECTS
OF
ACID
IMPREGNATION
7
62
EFFECTS
OF
OTHER
COMPONENTS
7
63
LEVOGLUCOSENONE
163
EFFECTS
OF
METAL
CHLORIDES
7
63
EFFECTS
OF
ACID
CATALYSTS
163
OTHERS
764
FURFURAL
764
AROMATIC
HYDROCARBONS
767
PHENOLIC
COMPOUNDS
769
CONCLUSIONS
AND
PERSPECTIVES
7
70
REFERENCES
777
VIII
CONTENTS
7
BIOMASS
PROCESSING
VIA
THERMOCHEMICAL
BIOLOGICAL
HYBRID
PROCESSES
181
CRISTIAN
TORRI,
ALESSANDRO
CIROLAMO
ROMBOLA,
ALISAR
KIWAN
AND
DANIELE
FABBRI
7.1
INTRODUCTION
181
7.1.1
HYBRID
THERMOCHEMICAL/BIOLOGICAL
PROCESSING
WITH
SINGLE-STRAIN
MICROORGANISMS
183
7.1.2
HYBRID
THERMOCHEMICAL/BIOLOGICAL
PROCESSING
WITH
MICROBIAL
MIXED
CONSORTIA
(MMC)
183
7.2
PYROLYSIS
PRODUCTS
(PYP)
FROM
THE
MICROORGANISM
'
S
STANDPOINT
185
7.2.1
WHAT
PYROLYSIS
CAN
DO
FOR
MICROORGANISMS:
YIELDS
AND
BIOAVAILABILITY
OF
PYP
186
7.2.2
VIABLE
PATHWAYS
ACCORDING
TO
THERMODYNAMICS
LAWS
188
7.2.3
RATE
OF
MMC
BIOLOGICAL
CONVERSIONS
IN
RELATIONSHIP
WITH
PYP
TREATMENT
191
7.2.4
TOXICITY
OF
PYP
TOWARD
MMC
193
7.3
CONVERSION
OF
PYP
WITH
MMC:
SURVEY
OF
EXPERIMENTAL
EVIDENCE
198
7.3.1
SYNGAS
CONVERSION
TO
METHANE
203
7.3.2
SYNGAS
CONVERSION
TO
H
2
,
VOLATILE
FATTY
ACIDS
(VFA),
AND
ALCOHOLS
203
7.3.3
CONVERSION
OF
CONDENSABLE
PYP
TO
METHANE
205
7.3.4
CONVERSION
OF
CONDENSABLE
PYP
TO
VFA
AND
OTHER
INTERMEDIATES
206
7
A
FEASIBLE
PATHWAYS
FOR
PRODUCING
CHEMICALS
FROM
PYP
WITH
MMC
207
7.4.1
HYBRID
PYROLYSIS
FERMENTATION
AND
EXTRACTION
OF
MIXED
VFA/ALCOHOLS
207
7.4.2
ALKALINE
FERMENTATION
OF
PYROLYSIS
PRODUCTS
TO
VFA
SALTS,
KETONIZATION,
AND
HYDROGENATION
TO
C3-C6
MIXED
ALCOHOLS
209
7.4.3
ALKALINE
FERMENTATION
OF
PYROLYSIS
PRODUCTS
TO
VFA
SALTS
AND
POLYHYDROXYALKANOATES
(PHA)
PRODUCTION
VIA
AEROBIC
MMC
211
7.4.4
DIRECT
ALCOHOL
PRODUCTION
BY
MEANS
OF
FERMENTATION
OF
PYP
UNDER
HIGH
HYDROGEN
PRESSURE
213
7.5
CONCLUSIONS
AND
PERSPECTIVES
215
REFERENCES
216
SECTION
III
ADVANCED/UNCONVENTIONAL
STRATEGIES
225
8
BIOMASS
PROCESSING
VIA
ELECTROCHEMICAL
MEANS
227
ROMAN
LATSUZBAIA,
ROEL
LOHANNES
MARTINUS
BISSELINK,
MARC
CROCKATT,
LAN
CORNELLS
VAN
DER
WAAL
AND
EARL
LAWRENCE
VINCENT
GOETHEER
8.1
INTRODUCTION
227
8.2
ELECTROCHEMICAL
CONVERSION
OF
BIO-BASED
MOLECULES
228
8.3
CONVERSION
OF
SUGARS
230
8.4
CONVERSION
OF
FURANICS
234
8.4.1
5-(HYDROXYMETHYL)FURFURAL
(5-HMF)
234
8.4.1.1
5-HMF
OXIDATION
235
CONTENTS
IX
8.4.1.2
5-HMF
REDUCTION
238
8.4.2
FURFURAL
240
8.5
CONVERSION
OF
LEVULINIC
ACID
244
8.6
CONVERSION
OF
GLYCEROL
246
8.7
LIGNIN
DEPOLYMERIZATION
248
8.8
SCALE-UP
OF
ELECTROSYNTHESIS
OF
BIOMASS-DERIVED
CHEMICALS
248
8.9
CONCLUSIONS
AND
PERSPECTIVES
254
REFERENCES
254
9
BIOMASS
PROCESSING
VIA
PHOTOCHEMICAL
MEANS
265
ANDREY
SHATSKIY
AND
MARKUS
D.
KARKAS
9.1
INTRODUCTION
265
9.2
FUNDAMENTAL
ASPECTS
OF
PHOTOREDOX
CATALYSIS
266
9.3
PHOTOCHEMICAL
VALORIZATION
OF
LIGNIN
267
9.3.1
STRATEGIES
FOR
C
A
-
C
()
BOND
CLEAVAGE
268
9.3.2
STRATEGIES
FOR
LIGNIN
OXIDATION
AND
C
P
-
O
BOND
CLEAVAGE
272
9.3.3
STRATEGIES
FOR
AR
-
O
BOND
CLEAVAGE
278
9.4
CONCLUSIONS
AND
PERSPECTIVES
281
REFERENCES
282
10
BIOMASS
PROCESSING
VIA
MICROWAVE
TREATMENT
289
ROBERTO
ROSA,
GIANCARLO
CRAVOTTO
AND
CRISTINA
LEONELLI
10.1
INTRODUCTION
289
10.2
MICROWAVE-MATTER
INTERACTION:
ADVANTAGES
AND
LIMITATIONS
IN
THE
PROCESSING
OF
BIOMASS
291
10.3
MICROWAVE
PYROLYSIS
296
10.4
MICROWAVE-ASSISTED
HYDROLYSIS
299
10.5
MICROWAVE-ASSISTED
EXTRACTION
OF
PHYTOCHEMICAL
COMPOUNDS
303
10.6
CONCLUSIONS
AND
PERSPECTIVES
306
REFERENCES
307
11
BIOMASS
PROCESSING
ASSISTED
BY
ULTRASOUND
315
CEZAR
A.
BIZZI,
DANIEL
SANTOS,
GABRIELLE
D.
LOP
AND
ERICO
M.
M.
FLORES
11.1
INTRODUCTION
315
11.2
ULTRASOUND
BACKGROUND
316
11.3
ULTRASOUND-ASSISTED
BIOMASS
PRETREATMENTS
319
11.4
ULTRASOUND-ASSISTED
BIOMASS
CONVERSION
322
11.4.1
THERMOCHEMICAL
CONVERSION
ASSISTED
BY
ULTRASOUND
323
11.4.2
BIOCHEMICAL
CONVERSION
ASSISTED
BY
ULTRASOUND
324
11.4.3
CHEMICAL
CONVERSION
(SYNTHESIS)
ASSISTED
BY
ULTRASOUND
325
11.5
ULTRASOUND-ASSISTED
EXTRACTION
OF
VALUE-ADDED
COMPOUNDS
326
11.5.1
ULTRASOUND
CONTRIBUTION
TO
BIOMASS
EXTRACTION
PROCESSES
326
11.5.2
USES
OF
ALTERNATIVE
APPROACHES
FOR
BIOMASS
EXTRACTIONS
ASSISTED
BY
ULTRASOUND
328
11.6
ALTERNATIVE
SOLVENTS
331
CONTENTS
11.7
CONCLUSIONS
AND
PERSPECTIVES
332
REFERENCES
333
12
BIOMASS
PROCESSING
VIA
MECHANOCHEMICAL
MEANS
343
GEORGE
MARGOUTIDIS
AND
FRANCESCA
M.
KERTON
12.1
OVERVIEW
AND
INTRODUCTION
343
12.1.1
BACKGROUND
TO
THE
METHOD
343
12.1.2
PROPERTIES
OF
A
TYPICAL
LABORATORY
MIXER/MILL
346
12.2
CRYSTALLINITY
REDUCTION
IN
BIOPOLYMERS
VIA
MECHANOCHEMISTRY
348
12.3
MECHANOCHEMICAL
TRANSFORMATIONS
OF
POLYSACCHARIDES
352
12.3.1
CELLULOSE
DEPOLYMERIZATION
352
12.3.2
CELLULOSE
MODIFICATION
TOWARD
COMPOSITE
MATERIALS
355
12.3.3
TRANSFORMATIONS
OF
CHITIN
355
12.4
MECHANOCHEMICAL
TRANSFORMATIONS
OF
AMINO
ACIDS,
NUCLEOTIDES,
AND
RELATED
MATERIALS
357
12.5
MECHANOCHEMICAL
TREATMENT
OF
LIGNIN
359
12.6
BIOMINERALS
FROM
MECHANOCHEMICAL
PROCESSING
OF
BIOMASS
360
12.7
CONCLUSIONS
AND
PERSPECTIVES
361
REFERENCES
361
SECTION
IV
CLOSING
REMARKS
367
13
INDUSTRIAL
PERSPECTIVES
OF
BIOMASS
PROCESSING
369
TOMMASO
TABANELLI
AND
FABRIZIO
CAVANI
13.1
REPLACING
EXISTING
PETROCHEMICALS
WITH
ALTERNATIVES
FROM
BIOMASS:
AN
INTRODUCTION
369
13.2
OLEOCHEMICAL
BIOREFINERY:
A
CONSOLIDATED
AND
MULTIFACETED
EXAMPLE
OF
BIOMASS
PROCESSING
371
13.2.1
BIOFUELS
AND
COPRODUCED
CHEMICALS
FROM
OILS
AND
FATS
371
13.2.2
SKELETAL
ISOMERIZATION
OF
UNSATURATED
FATTY
ACIDS
FOR
ISOSTEARIC
ACID
PRODUCTION
379
13.2.3
BIO-BASED
SYNTHESIS
OF
AZELAIC
AND
PELARGONIC
ACIDS:
A
RENEWABLE
ROUTE
TOWARD
BIO-BASED
POLYESTERS
AND
COSMETICS
382
13.3
FROM
SUGAR
TO
BIO-MONOMERS:
THE
CASE
OF
2,5-FURANDICARBOXYLIC
ACID
(FDCA)
385
13.4
FROM
BIOETHANOL
TO
RUBBER:
THE
SYNTHESIS
OF
BIO-BUTADIENE
388
13.5
CONCLUSIONS
AND
PERSPECTIVES
391
REFERENCES
391
INDEX
411 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author2 | Ravelli, Davide 1984- Samorì, Chiara |
| author2_role | edt edt |
| author2_variant | d r dr c s cs |
| author_GND | (DE-588)1183819013 |
| author_facet | Ravelli, Davide 1984- Samorì, Chiara |
| building | Verbundindex |
| bvnumber | BV047570455 |
| classification_rvk | ZP 3760 |
| ctrlnum | (OCoLC)1286881827 (DE-599)DNB1222296853 |
| discipline | Energietechnik |
| discipline_str_mv | Energietechnik |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV047570455 |
| illustrated | Illustrated |
| index_date | 2024-07-03T18:30:09Z |
| indexdate | 2024-07-10T09:15:09Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527347179 3527347178 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-032956090 |
| oclc_num | 1286881827 |
| open_access_boolean | |
| owner | DE-703 DE-634 |
| owner_facet | DE-703 DE-634 |
| physical | xiv, 417 Seiten Illustrationen, Karte 24.4 cm x 17 cm |
| publishDate | 2021 |
| publishDateSearch | 2021 |
| publishDateSort | 2021 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Biomass valorization sustainable methods for the production of chemicals edited by Davide Ravelli, Chiara Samori Weinheim, Germany Wiley-VCH [2021] xiv, 417 Seiten Illustrationen, Karte 24.4 cm x 17 cm txt rdacontent n rdamedia nc rdacarrier Herstellung (DE-588)4159653-5 gnd rswk-swf Grüne Chemie (DE-588)7563215-9 gnd rswk-swf Biomasseverarbeitung (DE-588)4400055-8 gnd rswk-swf Chemikalie (DE-588)4009833-3 gnd rswk-swf Biomasse (DE-588)4006877-8 gnd rswk-swf Verwertung (DE-588)4188158-8 gnd rswk-swf Agriculture Biorenewable Resources Catalysis Catalysis & Chemical Reaction Engineering Chemical Engineering Chemie Chemische Verfahrenstechnik Chemistry Katalyse Katalyse u. Chemische Reaktionstechnik Landwirtschaft Nachhaltige u. Grüne Chemie Nachwachsende Rohstoffe Sustainable Chemistry & Green Chemistry AG90: Nachwachsende Rohstoffe CG03: Katalyse u. Chemische Reaktionstechnik CH40: Katalyse CHC0: Nachhaltige u. Grüne Chemie (DE-588)4143413-4 Aufsatzsammlung gnd-content Biomasse (DE-588)4006877-8 s Verwertung (DE-588)4188158-8 s Chemikalie (DE-588)4009833-3 s Herstellung (DE-588)4159653-5 s Grüne Chemie (DE-588)7563215-9 s Biomasseverarbeitung (DE-588)4400055-8 s DE-604 Ravelli, Davide 1984- (DE-588)1183819013 edt Samorì, Chiara edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-82501-1 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-82503-5 Erscheint auch als Online-Ausgabe 978-3-527-82502-8 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34717-9/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032956090&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p vlb 20201127 DE-101 https://d-nb.info/provenance/plan#vlb |
| spellingShingle | Biomass valorization sustainable methods for the production of chemicals Herstellung (DE-588)4159653-5 gnd Grüne Chemie (DE-588)7563215-9 gnd Biomasseverarbeitung (DE-588)4400055-8 gnd Chemikalie (DE-588)4009833-3 gnd Biomasse (DE-588)4006877-8 gnd Verwertung (DE-588)4188158-8 gnd |
| subject_GND | (DE-588)4159653-5 (DE-588)7563215-9 (DE-588)4400055-8 (DE-588)4009833-3 (DE-588)4006877-8 (DE-588)4188158-8 (DE-588)4143413-4 |
| title | Biomass valorization sustainable methods for the production of chemicals |
| title_auth | Biomass valorization sustainable methods for the production of chemicals |
| title_exact_search | Biomass valorization sustainable methods for the production of chemicals |
| title_exact_search_txtP | Biomass valorization sustainable methods for the production of chemicals |
| title_full | Biomass valorization sustainable methods for the production of chemicals edited by Davide Ravelli, Chiara Samori |
| title_fullStr | Biomass valorization sustainable methods for the production of chemicals edited by Davide Ravelli, Chiara Samori |
| title_full_unstemmed | Biomass valorization sustainable methods for the production of chemicals edited by Davide Ravelli, Chiara Samori |
| title_short | Biomass valorization |
| title_sort | biomass valorization sustainable methods for the production of chemicals |
| title_sub | sustainable methods for the production of chemicals |
| topic | Herstellung (DE-588)4159653-5 gnd Grüne Chemie (DE-588)7563215-9 gnd Biomasseverarbeitung (DE-588)4400055-8 gnd Chemikalie (DE-588)4009833-3 gnd Biomasse (DE-588)4006877-8 gnd Verwertung (DE-588)4188158-8 gnd |
| topic_facet | Herstellung Grüne Chemie Biomasseverarbeitung Chemikalie Biomasse Verwertung Aufsatzsammlung |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34717-9/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032956090&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT ravellidavide biomassvalorizationsustainablemethodsfortheproductionofchemicals AT samorichiara biomassvalorizationsustainablemethodsfortheproductionofchemicals AT wileyvch biomassvalorizationsustainablemethodsfortheproductionofchemicals |