Hybrid perovskite solar cells: characteristics and operation
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| Format: | Buch |
| Sprache: | English |
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Weinheim, Germany
Wiley-VCH
[2022]
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| Beschreibung: | xix, 583 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm |
| ISBN: | 9783527347292 |
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MARC
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| 020 | |a 9783527347292 |c hbk: circa EUR 199.00 (DE) (freier Preis) |9 978-3-527-34729-2 | ||
| 024 | 3 | |a 9783527347292 | |
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| 035 | |a (OCoLC)1286869407 | ||
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| 245 | 1 | 0 | |a Hybrid perovskite solar cells |b characteristics and operation |c edited by Hiroyuki Fujiwara |
| 264 | 1 | |a Weinheim, Germany |b Wiley-VCH |c [2022] | |
| 300 | |a xix, 583 Seiten |b Illustrationen, Diagramme |c 24.4 cm x 17 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Hybridwerkstoff |0 (DE-588)4160847-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Solarzelle |0 (DE-588)4181740-0 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Perowskit |0 (DE-588)4173836-6 |2 gnd |9 rswk-swf |
| 653 | |a Components & Devices | ||
| 653 | |a EE60: Komponenten u. Bauelemente | ||
| 653 | |a EG34: Solarenergie u. Photovoltaik | ||
| 653 | |a Electrical & Electronics Engineering | ||
| 653 | |a Elektrotechnik u. Elektronik | ||
| 653 | |a Energie | ||
| 653 | |a Energy | ||
| 653 | |a Komponenten u. Bauelemente | ||
| 653 | |a MSL0: Materialien f. Energiesysteme | ||
| 653 | |a Materialien f. Energiesysteme | ||
| 653 | |a Materials Science | ||
| 653 | |a Materials for Energy Systems | ||
| 653 | |a Materialwissenschaften | ||
| 653 | |a Solar Energy & Photovoltaics | ||
| 653 | |a Solarenergie | ||
| 653 | |a Solarenergie u. Photovoltaik | ||
| 653 | |a Solarzelle | ||
| 655 | 7 | |0 (DE-588)4143413-4 |a Aufsatzsammlung |2 gnd-content | |
| 689 | 0 | 0 | |a Solarzelle |0 (DE-588)4181740-0 |D s |
| 689 | 0 | 1 | |a Perowskit |0 (DE-588)4173836-6 |D s |
| 689 | 0 | 2 | |a Hybridwerkstoff |0 (DE-588)4160847-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Fujiwara, Hiroyuki |0 (DE-588)140809872 |4 edt | |
| 710 | 2 | |a Wiley-VCH |0 (DE-588)16179388-5 |4 pbl | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-527-82584-4 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-527-82586-8 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |z 978-3-527-82585-1 |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032915460&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-032915460 | ||
Datensatz im Suchindex
| _version_ | 1804182856069545984 |
|---|---|
| adam_text | CONTENTS
PREFACE
XV
ABOUT
THE
EDITOR
XIX
1
INTRODUCTION
1
HIROYUKI
FUJIWARA
1.1
1.2
1.2.1
1.2.2
1.2.3
1.3
1.3.1
1.3.2
1.3.3
1.4
1.4.1
1.4.2
1.4.3
1.5
HYBRID
PEROVSKITE
SOLAR
CELLS
1
UNIQUE
NATURES
OF
HYBRID
PEROVSKITES
4
NOTABLE
CHARACTERISTICS
OF
HYBRID
PEROVSKITES
5
FUNDAMENTAL
PROPERTIES
OF
MAPBI
3
8
WHY
HYBRID
PEROVSKITE
SOLAR
CELLS
SHOW
HIGH
EFFICIENCY?
11
ADVANTAGES
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
12
BAND
GAP
TUNABILITY
12
HIGHLY
13
LOW
TEMPERATURE
COEFFICIENT
16
CHALLENGES
FOR
HYBRID
PEROVSKITES
16
REQUIREMENT
OF
IMPROVED
STABILITY
17
LARGE-AREA
SOLAR
CELLS
19
TOXICITY
OF
PB
AND
SN
COMPOUNDS
20
OVERVIEW
OF
THIS
BOOK
22
ACKNOWLEDGMENT
23
REFERENCES
23
2
OVERVIEW
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
29
TSUTOMU
MIYASAKA
AND
AJAY
K.
JENA
2.1
2.2
2.3
2.4
2.5
2.6
2.7
INTRODUCTION
29
HISTORICAL
BACKGROUNDS
OF
HALIDE
PEROVSKITE
PHOTOVOLTAICS
32
SEMICONDUCTOR
PROPERTIES
OF
ORGANO
LEAD
HALIDE
PEROVSKITES
34
WORKING
PRINCIPLE
OF
PEROVSKITE
PHOTOVOLTAICS
37
COMPOSITIONAL
DESIGN
OF
THE
HALIDE
PEROVSKITE
ABSORBERS
40
STRATEGY
FOR
STABILIZING
PEROVSKITE
SOLAR
CELLS
41
ALL
INORGANIC
AND
LEAD-FREE
PEROVSKITES
48
VI
CONTENTS
2.8
DEVELOPMENT
OF
HIGH-EFFICIENCY
TANDEM
SOLAR
CELLS
52
2.9
CONCLUSION
AND
PERSPECTIVES
54
REFERENCES
55
PART
I
CHARACTERISTICS
OF
HYBRID
PEROVSKITES
65
3
CRYSTAL
STRUCTURES
67
MITSUTOSHI
NISHIWAKI,
TATSUYA
NARIKURI,
AND
HIROYUKI
FUJIWARA
3.1
WHAT
IS
HYBRID
PEROVSKITE?
67
3.2
STRUCTURES
OF
HYBRID
PEROVSKITE
CRYSTALS
68
3.2.1
CRYSTAL
STRUCTURE
OF
MAPBI
3
68
3.2.2
LATTICE
PARAMETERS
OF
HYBRID
PEROVSKITES
71
3.2.3
SECONDARY
PHASE
MATERIALS
75
3.3
TOLERANCE
FACTOR
77
3.3.1
TOLERANCE
FACTOR
OF
HYBRID
PEROVSKITES
79
3.3.2
TOLERANCE
FACTOR
OF
MIXED-CATION
PEROVSKITES
82
3.4
PHASE
CHANGE
BY
TEMPERATURE
84
3.5
REFINED
STRUCTURES
OF
HYBRID
PEROVSKITES
86
3.5.1
ORIENTATION
OF
CENTER
CATIONS
86
3.5.2
RELAXATION
OF
CENTER
CATIONS
88
ACKNOWLEDGMENT
89
REFERENCES
89
4
OPTICAL
PROPERTIES
91
HIROYUKI
FUJIWARA,
YUKINORI
NISHIGAKI,
AKIO
MATSUSHITA,
AND
TAISUKE
MATSUI
4.1
INTRODUCTION
91
4.2
LIGHT
ABSORPTION
IN
MAPBI
3
93
4.2.1
VISIBLE/UV
REGION
96
4.2.2
IR
REGION
98
4.2.3
THZ
REGION
99
4.3
BAND GAP
OF
HYBRID
PEROVSKITES
101
4.3.1
BAND GAP
ANALYSIS
OF
MAPBI
3
101
4.3.2
BAND GAP
OF
BASIC
PEROVSKITES
103
4.3.3
BAND
GAP
VARIATION
IN
PEROVSKITE
ALLOYS
105
4.4
TRUE
ABSORPTION
COEFFICIENT
OF
MAPBI
3
106
4.4.1
PRINCIPLES
OF
OPTICAL
MEASUREMENTS
107
4.4.2
INTERPRETATION
OF
A
VARIATION
108
4.5
UNIVERSAL
RULES
FOR
HYBRID
PEROVSKITE
OPTICAL
PROPERTIES
111
4.5.1
VARIATION
WITH
CENTER
CATION
111
4.5.2
VARIATION
WITH
HALIDE
ANION
112
4.6
SUBGAP
ABSORPTION
CHARACTERISTICS
114
4.7
TEMPERATURE
EFFECT
ON
ABSORPTION
PROPERTIES
116
4.8
EXCITONIC
PROPERTIES
OF
HYBRID
PEROVSKITES
117
REFERENCES
119
CONTENTS
IVII
5
PHYSICAL
PROPERTIES
DETERMINED
BY
DENSITY
FUNCTIONAL
THEORY
123
HIROYUKI
FUJIWARA,
MITSUTOSHI
NISHIWAKI,
AND
YUKINORI
NISHIGAKI
5.1
INTRODUCTION
123
5.2
WHAT
IS
DFT?
124
5.2.1
BASIC
PRINCIPLES
124
5.2.2
ASSUMPTIONS
AND
LIMITATIONS
126
5.3
CRYSTAL
STRUCTURES
DETERMINED
BY
DFT
128
5.3.1
HYBRID
PEROVSKITE
STRUCTURES
128
5.3.2
ORGANIC-CENTER
CATIONS
131
5.4
BAND
STRUCTURES
132
5.4.1
BAND
STRUCTURES
OF
HYBRID
PEROVSKITES
132
5.4.2
DIRECT-INDIRECT
ISSUE
OF
HYBRID
PEROVSKITE
134
5.4.3
DENSITY
OF
STATES
139
5.4.4
EFFECTIVE
MASS
140
5.5
BAND
GAP
141
5.5.1
WHAT
DETERMINES
BAND
GAP?
142
5.5.2
EFFECT
OF
CENTER
CATION
143
5.5.3
EFFECT
OF
HALIDE
ANION
143
5.6
DEFECT
PHYSICS
144
ACKNOWLEDGMENT
147
REFERENCES
147
6
CARRIER
TRANSPORT
PROPERTIES
151
HIROYUKI
FUJIWARA
AND
YOSHITSUNE
KATO
6.1
INTRODUCTION
151
6.2
CARRIER
PROPERTIES
OF
HYBRID
PEROVSKITES
153
6.2.1
SELF-DOPING
IN
HYBRID
PEROVSKITES
153
6.2.2
EFFECT
OF
CARRIER
CONCENTRATION
ON
MOBILITY
155
6.3
CARRIER
MOBILITY
OF
MAPBI
3
155
6.3.1
VARIATION
OF
MOBILITY
WITH
CHARACTERIZATION
METHOD
156
6.3.2
TEMPERATURE
DEPENDENCE
159
6.3.3
EFFECT
OF
EFFECTIVE
MASS
160
6.3.4
WHAT
DETERMINES
MAXIMUM
MOBILITY
OF
MAPBI
3
?
161
6.4
DIFFUSION
LENGTH
164
6.5
CARRIER
TRANSPORT
IN
VARIOUS
HYBRID
PEROVSKITES
166
REFERENCES
168
7
FERROELECTRIC
PROPERTIES
173
TOBIAS
LEONHARD,
HOLGER
ROHM,
ALEXANDER
D.
SCHULZ,
AND
ALEXANDER
COLSMANN
7.1
ON
THE
IMPORTANCE
OF
FERROELECTRICITY
IN
HYBRID
PEROVSKITE
SOLAR
CELLS
173
7.2
FERROELECTRICITY
174
7.2.1
CRYSTALLOGRAPHIC
CONSIDERATIONS
174
VIII
CONTENTS
7.2.2
7.2.3
7.3
7.3.1
7.3.2
7.3.3
7.3.4
7.3.4.1
7.3.4.2
7.3.4.3
7.3.4.4
7.3.5
7.3.6
7.4
7.4.1
7.4.2
7.4.3
7.5
7.5.1
7.5.2
FERROELECTRICITY
IN
THIN
FILMS
178
CRYSTALLOGRAPHY
OF
M
APBI
3
THIN
FILMS
178
PROBING
FERROELECTRICITY
ON
THE
MICROSCALE
179
ATOMIC
FORCE
MICROSCOPY
179
PIEZORESPONSE
FORCE
MICROSCOPY
180
CHARACTERIZATION
OF
MAPBI
3
THIN
FILMS
WITH
SF-PFM
183
CORRELATIVE
DOMAIN
CHARACTERIZATION
188
TRANSMISSION
ELECTRON
MICROSCOPY
188
X-RAY
DIFFRACTION
189
ELECTRON
BACKSCATTER
DIFFRACTION
189
KELVIN
PROBE
FORCE
MICROSCOPY
191
POLARIZATION
ORIENTATION
191
FERROELASTIC
EFFECTS
IN
MAPBI
3
THIN
FILMS
193
FERROELECTRIC
POLING
OF
MAPBI
3
195
AC
POLING
OF
MAPBI
3
196
CREEPING
POLING
AND
SWITCHING
EVENTS
ON
THE
MICROSCOPIC
SCALE
197
MACROSCOPIC
EFFECTS
OF
POLING
200
IMPACT
OF
FERROELECTRICITY
ON
THE
PERFORMANCE
OF
SOLAR
CELLS
201
PITFALLS
DURING
SAMPLE
MEASUREMENTS
201
CHARGE
CARRIER
DYNAMICS
IN
SOLAR
CELLS
203
REFERENCES
203
8
PHOTOLUMINESCENCE
PROPERTIES
207
YASUHIRO
YAMADA
AND
YOSHIHIKO
KANEMITSU
8.1
8.2
8.3
8.4
8.5
8.6
8.7
8.7.1
8.7.2
8.8
INTRODUCTION
207
OVERVIEW
OF
LUMINESCENT
PROPERTIES
208
ROOM-TEMPERATURE
PL
SPECTRA
OF
A
HYBRID
PEROVSKITE
THIN
FILM
209
TIME-RESOLVED
PL
OF
A
HYBRID
PEROVSKITE
213
PL
QUANTUM
EFFICIENCY
218
TEMPERATURE-DEPENDENT
PL
220
MATERIAL
AND
DEVICE
CHARACTERIZATION
BY
PL
SPECTROSCOPY
222
DEGRADATION
AND
HEALING
OF
HYBRID
PEROVSKITES
222
CHARGE
TRANSFER
MECHANISM
IN
PEROVSKITE
SOLAR
CELL
223
CONCLUSION
224
ACKNOWLEDGMENT
225
REFERENCES
225
9
ROLE
OF
GRAIN
BOUNDARIES
229
JAE
SUNG
YUN
9.1
9.2
9.2.1
9.2.2
9.3
9.3.1
INTRODUCTION
229
ROLE
OF
GRAIN
BOUNDARIES
IN
DEVICE
PERFORMANCE
230
POTENTIAL
BARRIER
AT
GBS
AND
CHARGE
TRANSPORT
231
ENGINEERING
OF
GB
PROPERTIES
234
ION
MIGRATION
THROUGH
GRAIN
BOUNDARIES
241
ENHANCED
ION
TRANSPORT
AT
GRAIN
BOUNDARIES
241
CONTENTS
IX
9.3.2
ROLE
OF
GBS
FOR
ION
MIGRATION
244
9.4
ROLE
OF
GRAIN
BOUNDARIES
IN
STABILITY
246
9.4.1
MAPBI
3
HYDRATED
PHASE
AT
GBS
247
9.4.2
FORMATION
OF
NON-PEROVSKITE
PHASE
AT
GBS
OF
FAPBI
3
248
REFERENCES
250
10
ROLES
OF
CENTER
CATIONS
253
BIWAS
SUBEDI,
JUAN
ZUO,
MARIE
SOLANGE
TUMUSANGE,
MAXWELL
M.
JUNDA,
KIRAN
GHIMIRE,
AND
NIKOLAS
J.
PODRAZA
10.1
INTRODUCTION
253
10.2
CUBIC
PEROVSKITE
PHASE
TOLERANCE
FACTOR
256
10.3
THIN
FILM
STABILITY
258
10.4
OPTOELECTRONIC
PROPERTY
VARIATIONS
263
10.5
SOLAR
CELL
PERFORMANCE
268
REFERENCES
271
PART
II
HYBRID
PEROVSKITE
SOLAR
CELLS
275
11
OPERATIONAL
PRINCIPLES
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
277
HIROYUKI
FUJIWARA,
YOSHITSUNE
KATO,
YUJI
KADOYA,
YUKINORI
NISHIGAKI,
TOMOYA
KOBAYASHI,
AKIO
MATSUSHITA,
AND
TAISUKE
MATSUI
11.1
INTRODUCTION
277
11.2
OPERATION
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
278
11.2.1
OPERATIONAL
PRINCIPLE
AND
BASIC
STRUCTURES
278
11.2.2
BAND
ALIGNMENT
281
11.3
BAND
DIAGRAM
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
283
11.3.1
DEVICE
SIMULATION
283
11.3.2
EXPERIMENTAL
OBSERVATION
285
11.4
REFINED
ANALYSES
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
287
11.4.1
CARRIER
GENERATION
AND
LOSS
287
11.4.2
POWER
LOSS
MECHANISM
291
11.4.3
E-ARC
SOFTWARE
295
11.5
WHAT
DETERMINES
V
OC
?
295
11.5.1
EFFECT
OF
INTERFACE
297
11.5.2
EFFECT
OF
PASSIVATION
300
11.5.3
EFFECT
OF
GRAIN
BOUNDARY
303
REFERENCES
305
12
EFFICIENCY
LIMITS
OF
SINGLE
AND
TANDEM
SOLAR
CELLS
309
HIROYUKI
FUJIWARA,
YOSHITSUNE
KATO,
MASAYUKI
KOZAWA,
AKIRA
TERAKAWA,
AND
TAISUKE
MATSUI
12.1
INTRODUCTION
309
12.2
WHAT
IS
THE
SQ
LIMIT?
310
12.2.1
PHYSICAL
MODEL
311
X
CONTENTS
12.2.2
BLACKBODY
RADIATION
313
12.2.3
SQ
LIMIT
315
12.3
MAXIMUM
EFFICIENCIES
OF
PEROVSKITE
SINGLE
CELLS
319
12.3.1
CONCEPT
OF
THIN-FILM
LIMIT
319
12.3.2
EQE
CALCULATION
METHOD
321
12.3.3
MAXIMUM
EFFICIENCIES
OF
SINGLE
SOLAR
CELLS
323
12.3.4
PERFORMANCE-LIMITING
FACTORS
OF
HYBRID
PEROVSKITE
DEVICES
325
12.4
MAXIMUM
EFFICIENCY
OF
TANDEM
CELLS
327
12.4.1
OPTICAL
MODEL
AND
ASSUMPTIONS
328
12.4.2
CALCULATION
OF
TANDEM-CELL
EQE
SPECTRA
329
12.4.3
MAXIMUM
EFFICIENCIES
OF
TANDEM
DEVICES
331
12.4.4
REALISTIC
MAXIMUM
EFFICIENCY
OF
TANDEM
CELL
334
12.5
FREE
SOFTWARE
FOR
EFFICIENCY
LIMIT
CALCULATION
335
REFERENCES
336
13
MULTI-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
339
JACOB
N.
VAGOTT
AND
JUAN-PABLO
CORREA-BAENA
13.1
INTRODUCTION
339
13.2
TYPES
OF
A-SITE
MULTI-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
341
13.2.1
PB-BASED
MULTI-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
341
13.2.2
SN-BASED
MULTI-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
344
13.3
CATION
SELECTION
IN
MIXED-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
345
13.3.1
ORGANIC
A-CATIONS
345
13.3.2
INORGANIC
A-CATIONS
347
13.4
FABRICATION
OF
MIXED-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
349
13.4.1
TRADITIONAL
FABRICATION
APPROACH
349
13.4.2
EMERGING
FABRICATION
TECHNOLOGIES
350
13.5
CHARGE
TRANSPORT
MATERIALS
353
13.6
SURFACE
PASSIVATION
357
13.7
MIXED
B-CATION
HYBRID
ORGANIC-INORGANIC
PEROVSKITE
SOLAR
CELLS
361
13.8
BASIC
CHARACTERIZATION
OF
MIXED-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
362
REFERENCES
365
14
TIN
HALIDE
PEROVSKITE
SOLAR
CELLS
373
GAURAV
KAPIL
AND
SHUZI
HAYASE
14.1
INTRODUCTION
373
14.1.1
DEVICE
STRUCTURE
AND
OPERATING
PRINCIPLE
374
14.1.2
CRYSTAL
STRUCTURE
375
14.2
TIN
PEROVSKITE
SOLAR
CELLS
376
14.2.1
INTRINSIC
PROPERTIES
377
14.2.2
CARRIER
LIFETIME
AND
DIFFUSION
LENGTH
378
14.3
THE
STATUS
OF
SN
PEROVSKITE
SOLAR
CELLS
379
14.3.1
DIFFERENT
TYPE
OF
SN
PEROVSKITE
SOLAR
CELLS
380
14.3.1.1
CSSNI
3
380
CONTENTS
XI
14.3.1.2
14.3.1.3
14.3.1.4
14.3.1.5
14.3.1.6
14.3.2
14.3.2.1
14.3.2.2
14.3.2.3
14.3.2.4
14.4
14.4.1
14.4.2
14.4.2.1
14.4.2.2
14.5
14.5.1
14.5.1.1
14.5.1.2
MASNI
3
383
FASNI
3
384
FA^MA
J
-
X
S
II
I
J
385
2D/3D
FASNI
3
387
SN-GE
MIXED
PSCS
387
STRATEGIES
TO
IMPROVE
THE
EFFICIENCY
389
FILM
FABRICATION
METHODS
389
USE
OF
REDUCING
AGENTS
389
DOPING
EFFECT
OF
LARGE
ORGANIC
CATIONS
390
DEVICE
ENGINEERING
AND
LATTICE
RELAXATION
391
SN-PB
PEROVSKITE
SOLAR
CELLS
393
ANOMALOUS
BANDGAP
OF
SNPB
(THE
BOWING
EFFECT)
396
PHYSICAL
PROPERTIES
398
INTRINSIC
CARRIER
CONCENTRATION
398
CARRIER
LIFETIME
AND
DIFFUSION
LENGTH
399
THE
STATUS
OF
SN-PB
PEROVSKITE
SOLAR
CELLS
399
DIFFERENT
TYPES
OF
SN-PB
PEROVSKITE
SOLAR
CELLS
401
FIRST
KIND
OF
SN-PB
PSC
ABSORBER:
MASN^PB,
_
X
I
3
401
MULTI
CATION
SN-PB
PEROVSKITES:
(FA,
MA,
CS)
(SN,
PB)
(I,
BR,
CL)
3
401
14.5.2
14.5.2.1
14.5.2.2
14.6
STRATEGIES
TO
IMPROVE
THE
EFFICIENCY
403
USE
OF
ADDITIVES
403
DEVICE
ENGINEERING
404
CONCLUSION
AND
OUTLOOK
406
REFERENCES
406
15
STABILITY
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
411
SEIGO
ITO
15.1
15.2
15.3
15.4
INTRODUCTION:
TRIGGER
OF
THE
DEGRADATION
411
CRYSTAL
QUALITY
FOR
STABLE
PEROVSKITE
SOLAR
CELLS
413
WATER-STABLE
AND
MA-FREE
PEROVSKITES
415
DEFECTS
AND
GRAIN-SURFACE
ION
MIGRATION,
AND
PASSIVATION
(INCLUDING
2-D
CRYSTAL)
417
15.5
15.6
DEGRADATION
AT
INTERFACE
WITH
METAL
OXIDES
420
POROUS
CARBON
ELECTRODE
TO
BE
VERY
STABLE
MULTIPOROUS-LAYERED
ELECTRODE
PEROVSKITE
SOLAR
CELLS
(MPLE-PSC)
420
15.7
15.8
DAMP
HEAT
TESTS
421
CONCLUSION
422
REFERENCES
425
16
HYSTERESIS
IN
J-V
CHARACTERISTICS
429
WOLFGANG
TRESS
16.1
16.2
16.3
INTRODUCTION
AND
DEFINITIONS:
WHAT
DO
WE
MEAN
BY
HYSTERESIS?
429
THE
JV
CURVE
OF
A
SOLAR
CELL:
WHAT
DOES
IT
TELL?
431
CHARACTERISTICS
OF
HYSTERESIS:
WHAT
DOES
IT
DEPEND
ON?
437
XII
CONTENTS
16.4
MECHANISTIC
AND
MICROSCOPIC
ORIGIN
OF
HYSTERESIS:
WHAT
CHANGES
SLOWLY?
442
16.5
16.6
ISSUES
WITH
HYSTERESIS:
HOW
TO
TUNE/AVOID/SUPPRESS?
453
CONCLUSION
AND
OPEN
QUESTIONS
453
REFERENCES
454
17
PEROVSKITE-BASED
TANDEM
SOLAR
CELLS
463
KLAUS
JAGER
AND
STEVE
ALBRECHT
17.1
17.2
17.2.1
17.2.2
17.2.3
17.2.4
17.3
17.3.1
17.3.2
17.3.3
17.4
17.5
17.5.1
17.5.2
17.6
17.6.1
17.6.2
17.6.3
17.6.4
17.6.5
17.7
INTRODUCTION
463
ARCHITECTURES
OF
TANDEM
SOLAR
CELLS
465
MONOLITHIC
TWO-TERMINAL
SOLAR
CELLS
466
FOUR-TERMINAL
TANDEM
SOLAR
CELLS
467
OTHER
CONCEPTS
468
BIFACIAL
SOLAR
CELLS
469
EFFICIENCY
LIMITS
OF
MULTI-JUNCTION
SOLAR
CELLS
469
EFFICIENCY
LIMIT
FOR
FOUR-TERMINAL
TANDEM
SOLAR
CELLS
470
EFFICIENCY
LIMIT
FOR
TWO-TERMINAL
TANDEM
SOLAR
CELLS
472
EFFICIENCY
LIMIT
FOR
CELLS
WITH
MORE
JUNCTIONS
474
PEROVSKITES
AS
TANDEM
SOLAR
CELL
MATERIALS
474
EXPERIMENTAL
RESULTS
ON
PEROVSKITE-BASED
TANDEM
SOLAR
CELLS
477
PEROVSKITE/SILICON
TANDEM
SOLAR
CELLS
482
PEROVSKITE
CHALCOGENIDE
TANDEM
SOLAR
CELLS
489
ENERGY
YIELD
CALCULATIONS
493
ILLUMINATION
MODEL
494
OPTICAL
MODEL
494
ELECTRICAL
MODEL
496
TEMPERATURE
MODEL
498
ENERGY
YIELD
CALCULATION
498
CONCLUSIONS
AND
OUTLOOK
499
ACKNOWLEDGMENTS
500
REFERENCES
500
18
ALL
PEROVSKITE
TANDEM
SOLAR
CELLS
509
ZHAONING
SONG
AND
YANFA
YAN
18.1
18.2
18.2.1
18.2.2
18.2.3
18.3
18.3.1
18.3.2
18.3.3
18.4
18.4.1
INTRODUCTION
509
WORKING
PRINCIPLES
OF
TANDEM
SOLAR
CELLS
511
WHY
TO
U
SE
TANDEM
SOLAR
CELLS
511
TANDEM
DEVICE
ARCHITECTURES
513
PCE
OF
TANDEM
SOLAR
CELLS
514
WIDE-BANDGAP
PEROVSKITE
SOLAR
CELLS
516
WIDE-BANDGAP
MIXED
I-BR
PEROVSKITES
516
CURRENT
STATE
OF
WIDE-BANDGAP
PEROVSKITE
SOLAR
CELLS
518
CRITICAL
ISSUES
OF
WIDE-BANDGAP
PEROVSKITE
CELLS
519
LOW-BANDGAP
PEROVSKITE
SOLAR
CELLS
520
LOW-BANDGAP
MIXED
SN-PB
PEROVSKITES
520
CONTENTS
XIII
18.4.2
18.4.3
18.5
18.5.1
18.5.2
18.5.3
18.6
CURRENT
STATE
OF
LOW-BANDGAP
PEROVSKITE
SOLAR
CELLS
524
CRITICAL
ISSUES
OF
LOW-BANDGAP
PEROVSKITE
CELLS
525
ALL-PEROVSKITE
TANDEM
SOLAR
CELLS
527
4-T
ALL-PEROVSKITE
TANDEM
SOLAR
CELLS
527
2-T
ALL-PEROVSKITE
TANDEM
SOLAR
CELLS
528
LIMITATIONS
AND
CHALLENGES
OF
ALL-PEROVSKITE
TANDEM
SOLAR
CELLS
533
CONCLUSION
AND
OUTLOOKS
534
ACKNOWLEDGMENTS
535
REFERENCES
535
A
OPTICAL
CONSTANTS
OF
HYBRID
PEROVSKITE
MATERIALS
541
YUKINORI
NISHIGAKI,
AKIO
MATSUSHITA,
ALVARO
TEJADA,
TAISUKE
MATSUI,
AND
HIROYUKI
FUJIWARA
REFERENCES
562
B
NUMERICAL
VALUES
OF
SHOCKLEY-QUEISSER
LIMIT
563
YOSHITSUNE
KATO
AND
HIROYUKI
FUJIWARA
INDEX
567
|
| adam_txt |
CONTENTS
PREFACE
XV
ABOUT
THE
EDITOR
XIX
1
INTRODUCTION
1
HIROYUKI
FUJIWARA
1.1
1.2
1.2.1
1.2.2
1.2.3
1.3
1.3.1
1.3.2
1.3.3
1.4
1.4.1
1.4.2
1.4.3
1.5
HYBRID
PEROVSKITE
SOLAR
CELLS
1
UNIQUE
NATURES
OF
HYBRID
PEROVSKITES
4
NOTABLE
CHARACTERISTICS
OF
HYBRID
PEROVSKITES
5
FUNDAMENTAL
PROPERTIES
OF
MAPBI
3
8
WHY
HYBRID
PEROVSKITE
SOLAR
CELLS
SHOW
HIGH
EFFICIENCY?
11
ADVANTAGES
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
12
BAND
GAP
TUNABILITY
12
HIGHLY
13
LOW
TEMPERATURE
COEFFICIENT
16
CHALLENGES
FOR
HYBRID
PEROVSKITES
16
REQUIREMENT
OF
IMPROVED
STABILITY
17
LARGE-AREA
SOLAR
CELLS
19
TOXICITY
OF
PB
AND
SN
COMPOUNDS
20
OVERVIEW
OF
THIS
BOOK
22
ACKNOWLEDGMENT
23
REFERENCES
23
2
OVERVIEW
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
29
TSUTOMU
MIYASAKA
AND
AJAY
K.
JENA
2.1
2.2
2.3
2.4
2.5
2.6
2.7
INTRODUCTION
29
HISTORICAL
BACKGROUNDS
OF
HALIDE
PEROVSKITE
PHOTOVOLTAICS
32
SEMICONDUCTOR
PROPERTIES
OF
ORGANO
LEAD
HALIDE
PEROVSKITES
34
WORKING
PRINCIPLE
OF
PEROVSKITE
PHOTOVOLTAICS
37
COMPOSITIONAL
DESIGN
OF
THE
HALIDE
PEROVSKITE
ABSORBERS
40
STRATEGY
FOR
STABILIZING
PEROVSKITE
SOLAR
CELLS
41
ALL
INORGANIC
AND
LEAD-FREE
PEROVSKITES
48
VI
CONTENTS
2.8
DEVELOPMENT
OF
HIGH-EFFICIENCY
TANDEM
SOLAR
CELLS
52
2.9
CONCLUSION
AND
PERSPECTIVES
54
REFERENCES
55
PART
I
CHARACTERISTICS
OF
HYBRID
PEROVSKITES
65
3
CRYSTAL
STRUCTURES
67
MITSUTOSHI
NISHIWAKI,
TATSUYA
NARIKURI,
AND
HIROYUKI
FUJIWARA
3.1
WHAT
IS
HYBRID
PEROVSKITE?
67
3.2
STRUCTURES
OF
HYBRID
PEROVSKITE
CRYSTALS
68
3.2.1
CRYSTAL
STRUCTURE
OF
MAPBI
3
68
3.2.2
LATTICE
PARAMETERS
OF
HYBRID
PEROVSKITES
71
3.2.3
SECONDARY
PHASE
MATERIALS
75
3.3
TOLERANCE
FACTOR
77
3.3.1
TOLERANCE
FACTOR
OF
HYBRID
PEROVSKITES
79
3.3.2
TOLERANCE
FACTOR
OF
MIXED-CATION
PEROVSKITES
82
3.4
PHASE
CHANGE
BY
TEMPERATURE
84
3.5
REFINED
STRUCTURES
OF
HYBRID
PEROVSKITES
86
3.5.1
ORIENTATION
OF
CENTER
CATIONS
86
3.5.2
RELAXATION
OF
CENTER
CATIONS
88
ACKNOWLEDGMENT
89
REFERENCES
89
4
OPTICAL
PROPERTIES
91
HIROYUKI
FUJIWARA,
YUKINORI
NISHIGAKI,
AKIO
MATSUSHITA,
AND
TAISUKE
MATSUI
4.1
INTRODUCTION
91
4.2
LIGHT
ABSORPTION
IN
MAPBI
3
93
4.2.1
VISIBLE/UV
REGION
96
4.2.2
IR
REGION
98
4.2.3
THZ
REGION
99
4.3
BAND GAP
OF
HYBRID
PEROVSKITES
101
4.3.1
BAND GAP
ANALYSIS
OF
MAPBI
3
101
4.3.2
BAND GAP
OF
BASIC
PEROVSKITES
103
4.3.3
BAND
GAP
VARIATION
IN
PEROVSKITE
ALLOYS
105
4.4
TRUE
ABSORPTION
COEFFICIENT
OF
MAPBI
3
106
4.4.1
PRINCIPLES
OF
OPTICAL
MEASUREMENTS
107
4.4.2
INTERPRETATION
OF
A
VARIATION
108
4.5
UNIVERSAL
RULES
FOR
HYBRID
PEROVSKITE
OPTICAL
PROPERTIES
111
4.5.1
VARIATION
WITH
CENTER
CATION
111
4.5.2
VARIATION
WITH
HALIDE
ANION
112
4.6
SUBGAP
ABSORPTION
CHARACTERISTICS
114
4.7
TEMPERATURE
EFFECT
ON
ABSORPTION
PROPERTIES
116
4.8
EXCITONIC
PROPERTIES
OF
HYBRID
PEROVSKITES
117
REFERENCES
119
CONTENTS
IVII
5
PHYSICAL
PROPERTIES
DETERMINED
BY
DENSITY
FUNCTIONAL
THEORY
123
HIROYUKI
FUJIWARA,
MITSUTOSHI
NISHIWAKI,
AND
YUKINORI
NISHIGAKI
5.1
INTRODUCTION
123
5.2
WHAT
IS
DFT?
124
5.2.1
BASIC
PRINCIPLES
124
5.2.2
ASSUMPTIONS
AND
LIMITATIONS
126
5.3
CRYSTAL
STRUCTURES
DETERMINED
BY
DFT
128
5.3.1
HYBRID
PEROVSKITE
STRUCTURES
128
5.3.2
ORGANIC-CENTER
CATIONS
131
5.4
BAND
STRUCTURES
132
5.4.1
BAND
STRUCTURES
OF
HYBRID
PEROVSKITES
132
5.4.2
DIRECT-INDIRECT
ISSUE
OF
HYBRID
PEROVSKITE
134
5.4.3
DENSITY
OF
STATES
139
5.4.4
EFFECTIVE
MASS
140
5.5
BAND
GAP
141
5.5.1
WHAT
DETERMINES
BAND
GAP?
142
5.5.2
EFFECT
OF
CENTER
CATION
143
5.5.3
EFFECT
OF
HALIDE
ANION
143
5.6
DEFECT
PHYSICS
144
ACKNOWLEDGMENT
147
REFERENCES
147
6
CARRIER
TRANSPORT
PROPERTIES
151
HIROYUKI
FUJIWARA
AND
YOSHITSUNE
KATO
6.1
INTRODUCTION
151
6.2
CARRIER
PROPERTIES
OF
HYBRID
PEROVSKITES
153
6.2.1
SELF-DOPING
IN
HYBRID
PEROVSKITES
153
6.2.2
EFFECT
OF
CARRIER
CONCENTRATION
ON
MOBILITY
155
6.3
CARRIER
MOBILITY
OF
MAPBI
3
155
6.3.1
VARIATION
OF
MOBILITY
WITH
CHARACTERIZATION
METHOD
156
6.3.2
TEMPERATURE
DEPENDENCE
159
6.3.3
EFFECT
OF
EFFECTIVE
MASS
160
6.3.4
WHAT
DETERMINES
MAXIMUM
MOBILITY
OF
MAPBI
3
?
161
6.4
DIFFUSION
LENGTH
164
6.5
CARRIER
TRANSPORT
IN
VARIOUS
HYBRID
PEROVSKITES
166
REFERENCES
168
7
FERROELECTRIC
PROPERTIES
173
TOBIAS
LEONHARD,
HOLGER
ROHM,
ALEXANDER
D.
SCHULZ,
AND
ALEXANDER
COLSMANN
7.1
ON
THE
IMPORTANCE
OF
FERROELECTRICITY
IN
HYBRID
PEROVSKITE
SOLAR
CELLS
173
7.2
FERROELECTRICITY
174
7.2.1
CRYSTALLOGRAPHIC
CONSIDERATIONS
174
VIII
CONTENTS
7.2.2
7.2.3
7.3
7.3.1
7.3.2
7.3.3
7.3.4
7.3.4.1
7.3.4.2
7.3.4.3
7.3.4.4
7.3.5
7.3.6
7.4
7.4.1
7.4.2
7.4.3
7.5
7.5.1
7.5.2
FERROELECTRICITY
IN
THIN
FILMS
178
CRYSTALLOGRAPHY
OF
M
APBI
3
THIN
FILMS
178
PROBING
FERROELECTRICITY
ON
THE
MICROSCALE
179
ATOMIC
FORCE
MICROSCOPY
179
PIEZORESPONSE
FORCE
MICROSCOPY
180
CHARACTERIZATION
OF
MAPBI
3
THIN
FILMS
WITH
SF-PFM
183
CORRELATIVE
DOMAIN
CHARACTERIZATION
188
TRANSMISSION
ELECTRON
MICROSCOPY
188
X-RAY
DIFFRACTION
189
ELECTRON
BACKSCATTER
DIFFRACTION
189
KELVIN
PROBE
FORCE
MICROSCOPY
191
POLARIZATION
ORIENTATION
191
FERROELASTIC
EFFECTS
IN
MAPBI
3
THIN
FILMS
193
FERROELECTRIC
POLING
OF
MAPBI
3
195
AC
POLING
OF
MAPBI
3
196
CREEPING
POLING
AND
SWITCHING
EVENTS
ON
THE
MICROSCOPIC
SCALE
197
MACROSCOPIC
EFFECTS
OF
POLING
200
IMPACT
OF
FERROELECTRICITY
ON
THE
PERFORMANCE
OF
SOLAR
CELLS
201
PITFALLS
DURING
SAMPLE
MEASUREMENTS
201
CHARGE
CARRIER
DYNAMICS
IN
SOLAR
CELLS
203
REFERENCES
203
8
PHOTOLUMINESCENCE
PROPERTIES
207
YASUHIRO
YAMADA
AND
YOSHIHIKO
KANEMITSU
8.1
8.2
8.3
8.4
8.5
8.6
8.7
8.7.1
8.7.2
8.8
INTRODUCTION
207
OVERVIEW
OF
LUMINESCENT
PROPERTIES
208
ROOM-TEMPERATURE
PL
SPECTRA
OF
A
HYBRID
PEROVSKITE
THIN
FILM
209
TIME-RESOLVED
PL
OF
A
HYBRID
PEROVSKITE
213
PL
QUANTUM
EFFICIENCY
218
TEMPERATURE-DEPENDENT
PL
220
MATERIAL
AND
DEVICE
CHARACTERIZATION
BY
PL
SPECTROSCOPY
222
DEGRADATION
AND
HEALING
OF
HYBRID
PEROVSKITES
222
CHARGE
TRANSFER
MECHANISM
IN
PEROVSKITE
SOLAR
CELL
223
CONCLUSION
224
ACKNOWLEDGMENT
225
REFERENCES
225
9
ROLE
OF
GRAIN
BOUNDARIES
229
JAE
SUNG
YUN
9.1
9.2
9.2.1
9.2.2
9.3
9.3.1
INTRODUCTION
229
ROLE
OF
GRAIN
BOUNDARIES
IN
DEVICE
PERFORMANCE
230
POTENTIAL
BARRIER
AT
GBS
AND
CHARGE
TRANSPORT
231
ENGINEERING
OF
GB
PROPERTIES
234
ION
MIGRATION
THROUGH
GRAIN
BOUNDARIES
241
ENHANCED
ION
TRANSPORT
AT
GRAIN
BOUNDARIES
241
CONTENTS
IX
9.3.2
ROLE
OF
GBS
FOR
ION
MIGRATION
244
9.4
ROLE
OF
GRAIN
BOUNDARIES
IN
STABILITY
246
9.4.1
MAPBI
3
HYDRATED
PHASE
AT
GBS
247
9.4.2
FORMATION
OF
NON-PEROVSKITE
PHASE
AT
GBS
OF
FAPBI
3
248
REFERENCES
250
10
ROLES
OF
CENTER
CATIONS
253
BIWAS
SUBEDI,
JUAN
ZUO,
MARIE
SOLANGE
TUMUSANGE,
MAXWELL
M.
JUNDA,
KIRAN
GHIMIRE,
AND
NIKOLAS
J.
PODRAZA
10.1
INTRODUCTION
253
10.2
CUBIC
PEROVSKITE
PHASE
TOLERANCE
FACTOR
256
10.3
THIN
FILM
STABILITY
258
10.4
OPTOELECTRONIC
PROPERTY
VARIATIONS
263
10.5
SOLAR
CELL
PERFORMANCE
268
REFERENCES
271
PART
II
HYBRID
PEROVSKITE
SOLAR
CELLS
275
11
OPERATIONAL
PRINCIPLES
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
277
HIROYUKI
FUJIWARA,
YOSHITSUNE
KATO,
YUJI
KADOYA,
YUKINORI
NISHIGAKI,
TOMOYA
KOBAYASHI,
AKIO
MATSUSHITA,
AND
TAISUKE
MATSUI
11.1
INTRODUCTION
277
11.2
OPERATION
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
278
11.2.1
OPERATIONAL
PRINCIPLE
AND
BASIC
STRUCTURES
278
11.2.2
BAND
ALIGNMENT
281
11.3
BAND
DIAGRAM
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
283
11.3.1
DEVICE
SIMULATION
283
11.3.2
EXPERIMENTAL
OBSERVATION
285
11.4
REFINED
ANALYSES
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
287
11.4.1
CARRIER
GENERATION
AND
LOSS
287
11.4.2
POWER
LOSS
MECHANISM
291
11.4.3
E-ARC
SOFTWARE
295
11.5
WHAT
DETERMINES
V
OC
?
295
11.5.1
EFFECT
OF
INTERFACE
297
11.5.2
EFFECT
OF
PASSIVATION
300
11.5.3
EFFECT
OF
GRAIN
BOUNDARY
303
REFERENCES
305
12
EFFICIENCY
LIMITS
OF
SINGLE
AND
TANDEM
SOLAR
CELLS
309
HIROYUKI
FUJIWARA,
YOSHITSUNE
KATO,
MASAYUKI
KOZAWA,
AKIRA
TERAKAWA,
AND
TAISUKE
MATSUI
12.1
INTRODUCTION
309
12.2
WHAT
IS
THE
SQ
LIMIT?
310
12.2.1
PHYSICAL
MODEL
311
X
CONTENTS
12.2.2
BLACKBODY
RADIATION
313
12.2.3
SQ
LIMIT
315
12.3
MAXIMUM
EFFICIENCIES
OF
PEROVSKITE
SINGLE
CELLS
319
12.3.1
CONCEPT
OF
THIN-FILM
LIMIT
319
12.3.2
EQE
CALCULATION
METHOD
321
12.3.3
MAXIMUM
EFFICIENCIES
OF
SINGLE
SOLAR
CELLS
323
12.3.4
PERFORMANCE-LIMITING
FACTORS
OF
HYBRID
PEROVSKITE
DEVICES
325
12.4
MAXIMUM
EFFICIENCY
OF
TANDEM
CELLS
327
12.4.1
OPTICAL
MODEL
AND
ASSUMPTIONS
328
12.4.2
CALCULATION
OF
TANDEM-CELL
EQE
SPECTRA
329
12.4.3
MAXIMUM
EFFICIENCIES
OF
TANDEM
DEVICES
331
12.4.4
REALISTIC
MAXIMUM
EFFICIENCY
OF
TANDEM
CELL
334
12.5
FREE
SOFTWARE
FOR
EFFICIENCY
LIMIT
CALCULATION
335
REFERENCES
336
13
MULTI-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
339
JACOB
N.
VAGOTT
AND
JUAN-PABLO
CORREA-BAENA
13.1
INTRODUCTION
339
13.2
TYPES
OF
A-SITE
MULTI-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
341
13.2.1
PB-BASED
MULTI-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
341
13.2.2
SN-BASED
MULTI-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
344
13.3
CATION
SELECTION
IN
MIXED-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
345
13.3.1
ORGANIC
A-CATIONS
345
13.3.2
INORGANIC
A-CATIONS
347
13.4
FABRICATION
OF
MIXED-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
349
13.4.1
TRADITIONAL
FABRICATION
APPROACH
349
13.4.2
EMERGING
FABRICATION
TECHNOLOGIES
350
13.5
CHARGE
TRANSPORT
MATERIALS
353
13.6
SURFACE
PASSIVATION
357
13.7
MIXED
B-CATION
HYBRID
ORGANIC-INORGANIC
PEROVSKITE
SOLAR
CELLS
361
13.8
BASIC
CHARACTERIZATION
OF
MIXED-CATION
HYBRID
PEROVSKITE
SOLAR
CELLS
362
REFERENCES
365
14
TIN
HALIDE
PEROVSKITE
SOLAR
CELLS
373
GAURAV
KAPIL
AND
SHUZI
HAYASE
14.1
INTRODUCTION
373
14.1.1
DEVICE
STRUCTURE
AND
OPERATING
PRINCIPLE
374
14.1.2
CRYSTAL
STRUCTURE
375
14.2
TIN
PEROVSKITE
SOLAR
CELLS
376
14.2.1
INTRINSIC
PROPERTIES
377
14.2.2
CARRIER
LIFETIME
AND
DIFFUSION
LENGTH
378
14.3
THE
STATUS
OF
SN
PEROVSKITE
SOLAR
CELLS
379
14.3.1
DIFFERENT
TYPE
OF
SN
PEROVSKITE
SOLAR
CELLS
380
14.3.1.1
CSSNI
3
380
CONTENTS
XI
14.3.1.2
14.3.1.3
14.3.1.4
14.3.1.5
14.3.1.6
14.3.2
14.3.2.1
14.3.2.2
14.3.2.3
14.3.2.4
14.4
14.4.1
14.4.2
14.4.2.1
14.4.2.2
14.5
14.5.1
14.5.1.1
14.5.1.2
MASNI
3
383
FASNI
3
384
FA^MA
J
-
X
S
II
I
J
385
2D/3D
FASNI
3
387
SN-GE
MIXED
PSCS
387
STRATEGIES
TO
IMPROVE
THE
EFFICIENCY
389
FILM
FABRICATION
METHODS
389
USE
OF
REDUCING
AGENTS
389
DOPING
EFFECT
OF
LARGE
ORGANIC
CATIONS
390
DEVICE
ENGINEERING
AND
LATTICE
RELAXATION
391
SN-PB
PEROVSKITE
SOLAR
CELLS
393
ANOMALOUS
BANDGAP
OF
SNPB
(THE
BOWING
EFFECT)
396
PHYSICAL
PROPERTIES
398
INTRINSIC
CARRIER
CONCENTRATION
398
CARRIER
LIFETIME
AND
DIFFUSION
LENGTH
399
THE
STATUS
OF
SN-PB
PEROVSKITE
SOLAR
CELLS
399
DIFFERENT
TYPES
OF
SN-PB
PEROVSKITE
SOLAR
CELLS
401
FIRST
KIND
OF
SN-PB
PSC
ABSORBER:
MASN^PB,
_
X
I
3
401
MULTI
CATION
SN-PB
PEROVSKITES:
(FA,
MA,
CS)
(SN,
PB)
(I,
BR,
CL)
3
401
14.5.2
14.5.2.1
14.5.2.2
14.6
STRATEGIES
TO
IMPROVE
THE
EFFICIENCY
403
USE
OF
ADDITIVES
403
DEVICE
ENGINEERING
404
CONCLUSION
AND
OUTLOOK
406
REFERENCES
406
15
STABILITY
OF
HYBRID
PEROVSKITE
SOLAR
CELLS
411
SEIGO
ITO
15.1
15.2
15.3
15.4
INTRODUCTION:
TRIGGER
OF
THE
DEGRADATION
411
CRYSTAL
QUALITY
FOR
STABLE
PEROVSKITE
SOLAR
CELLS
413
WATER-STABLE
AND
MA-FREE
PEROVSKITES
415
DEFECTS
AND
GRAIN-SURFACE
ION
MIGRATION,
AND
PASSIVATION
(INCLUDING
2-D
CRYSTAL)
417
15.5
15.6
DEGRADATION
AT
INTERFACE
WITH
METAL
OXIDES
420
POROUS
CARBON
ELECTRODE
TO
BE
VERY
STABLE
MULTIPOROUS-LAYERED
ELECTRODE
PEROVSKITE
SOLAR
CELLS
(MPLE-PSC)
420
15.7
15.8
DAMP
HEAT
TESTS
421
CONCLUSION
422
REFERENCES
425
16
HYSTERESIS
IN
J-V
CHARACTERISTICS
429
WOLFGANG
TRESS
16.1
16.2
16.3
INTRODUCTION
AND
DEFINITIONS:
WHAT
DO
WE
MEAN
BY
HYSTERESIS?
429
THE
JV
CURVE
OF
A
SOLAR
CELL:
WHAT
DOES
IT
TELL?
431
CHARACTERISTICS
OF
HYSTERESIS:
WHAT
DOES
IT
DEPEND
ON?
437
XII
CONTENTS
16.4
MECHANISTIC
AND
MICROSCOPIC
ORIGIN
OF
HYSTERESIS:
WHAT
CHANGES
SLOWLY?
442
16.5
16.6
ISSUES
WITH
HYSTERESIS:
HOW
TO
TUNE/AVOID/SUPPRESS?
453
CONCLUSION
AND
OPEN
QUESTIONS
453
REFERENCES
454
17
PEROVSKITE-BASED
TANDEM
SOLAR
CELLS
463
KLAUS
JAGER
AND
STEVE
ALBRECHT
17.1
17.2
17.2.1
17.2.2
17.2.3
17.2.4
17.3
17.3.1
17.3.2
17.3.3
17.4
17.5
17.5.1
17.5.2
17.6
17.6.1
17.6.2
17.6.3
17.6.4
17.6.5
17.7
INTRODUCTION
463
ARCHITECTURES
OF
TANDEM
SOLAR
CELLS
465
MONOLITHIC
TWO-TERMINAL
SOLAR
CELLS
466
FOUR-TERMINAL
TANDEM
SOLAR
CELLS
467
OTHER
CONCEPTS
468
BIFACIAL
SOLAR
CELLS
469
EFFICIENCY
LIMITS
OF
MULTI-JUNCTION
SOLAR
CELLS
469
EFFICIENCY
LIMIT
FOR
FOUR-TERMINAL
TANDEM
SOLAR
CELLS
470
EFFICIENCY
LIMIT
FOR
TWO-TERMINAL
TANDEM
SOLAR
CELLS
472
EFFICIENCY
LIMIT
FOR
CELLS
WITH
MORE
JUNCTIONS
474
PEROVSKITES
AS
TANDEM
SOLAR
CELL
MATERIALS
474
EXPERIMENTAL
RESULTS
ON
PEROVSKITE-BASED
TANDEM
SOLAR
CELLS
477
PEROVSKITE/SILICON
TANDEM
SOLAR
CELLS
482
PEROVSKITE
CHALCOGENIDE
TANDEM
SOLAR
CELLS
489
ENERGY
YIELD
CALCULATIONS
493
ILLUMINATION
MODEL
494
OPTICAL
MODEL
494
ELECTRICAL
MODEL
496
TEMPERATURE
MODEL
498
ENERGY
YIELD
CALCULATION
498
CONCLUSIONS
AND
OUTLOOK
499
ACKNOWLEDGMENTS
500
REFERENCES
500
18
ALL
PEROVSKITE
TANDEM
SOLAR
CELLS
509
ZHAONING
SONG
AND
YANFA
YAN
18.1
18.2
18.2.1
18.2.2
18.2.3
18.3
18.3.1
18.3.2
18.3.3
18.4
18.4.1
INTRODUCTION
509
WORKING
PRINCIPLES
OF
TANDEM
SOLAR
CELLS
511
WHY
TO
U
SE
TANDEM
SOLAR
CELLS
511
TANDEM
DEVICE
ARCHITECTURES
513
PCE
OF
TANDEM
SOLAR
CELLS
514
WIDE-BANDGAP
PEROVSKITE
SOLAR
CELLS
516
WIDE-BANDGAP
MIXED
I-BR
PEROVSKITES
516
CURRENT
STATE
OF
WIDE-BANDGAP
PEROVSKITE
SOLAR
CELLS
518
CRITICAL
ISSUES
OF
WIDE-BANDGAP
PEROVSKITE
CELLS
519
LOW-BANDGAP
PEROVSKITE
SOLAR
CELLS
520
LOW-BANDGAP
MIXED
SN-PB
PEROVSKITES
520
CONTENTS
XIII
18.4.2
18.4.3
18.5
18.5.1
18.5.2
18.5.3
18.6
CURRENT
STATE
OF
LOW-BANDGAP
PEROVSKITE
SOLAR
CELLS
524
CRITICAL
ISSUES
OF
LOW-BANDGAP
PEROVSKITE
CELLS
525
ALL-PEROVSKITE
TANDEM
SOLAR
CELLS
527
4-T
ALL-PEROVSKITE
TANDEM
SOLAR
CELLS
527
2-T
ALL-PEROVSKITE
TANDEM
SOLAR
CELLS
528
LIMITATIONS
AND
CHALLENGES
OF
ALL-PEROVSKITE
TANDEM
SOLAR
CELLS
533
CONCLUSION
AND
OUTLOOKS
534
ACKNOWLEDGMENTS
535
REFERENCES
535
A
OPTICAL
CONSTANTS
OF
HYBRID
PEROVSKITE
MATERIALS
541
YUKINORI
NISHIGAKI,
AKIO
MATSUSHITA,
ALVARO
TEJADA,
TAISUKE
MATSUI,
AND
HIROYUKI
FUJIWARA
REFERENCES
562
B
NUMERICAL
VALUES
OF
SHOCKLEY-QUEISSER
LIMIT
563
YOSHITSUNE
KATO
AND
HIROYUKI
FUJIWARA
INDEX
567 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author2 | Fujiwara, Hiroyuki |
| author2_role | edt |
| author2_variant | h f hf |
| author_GND | (DE-588)140809872 |
| author_facet | Fujiwara, Hiroyuki |
| building | Verbundindex |
| bvnumber | BV047514666 |
| classification_rvk | ZP 3730 VN 6050 |
| ctrlnum | (OCoLC)1286869407 (DE-599)DNB1231093811 |
| discipline | Chemie / Pharmazie Energietechnik |
| discipline_str_mv | Chemie / Pharmazie Energietechnik |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV047514666 |
| illustrated | Illustrated |
| index_date | 2024-07-03T18:22:55Z |
| indexdate | 2024-07-10T09:14:11Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527347292 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-032915460 |
| oclc_num | 1286869407 |
| open_access_boolean | |
| owner | DE-29T DE-703 DE-384 |
| owner_facet | DE-29T DE-703 DE-384 |
| physical | xix, 583 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm |
| publishDate | 2022 |
| publishDateSearch | 2022 |
| publishDateSort | 2022 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Hybrid perovskite solar cells characteristics and operation edited by Hiroyuki Fujiwara Weinheim, Germany Wiley-VCH [2022] xix, 583 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm txt rdacontent n rdamedia nc rdacarrier Hybridwerkstoff (DE-588)4160847-1 gnd rswk-swf Solarzelle (DE-588)4181740-0 gnd rswk-swf Perowskit (DE-588)4173836-6 gnd rswk-swf Components & Devices EE60: Komponenten u. Bauelemente EG34: Solarenergie u. Photovoltaik Electrical & Electronics Engineering Elektrotechnik u. Elektronik Energie Energy Komponenten u. Bauelemente MSL0: Materialien f. Energiesysteme Materialien f. Energiesysteme Materials Science Materials for Energy Systems Materialwissenschaften Solar Energy & Photovoltaics Solarenergie Solarenergie u. Photovoltaik Solarzelle (DE-588)4143413-4 Aufsatzsammlung gnd-content Solarzelle (DE-588)4181740-0 s Perowskit (DE-588)4173836-6 s Hybridwerkstoff (DE-588)4160847-1 s DE-604 Fujiwara, Hiroyuki (DE-588)140809872 edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-82584-4 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-82586-8 Erscheint auch als Online-Ausgabe 978-3-527-82585-1 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032915460&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hybrid perovskite solar cells characteristics and operation Hybridwerkstoff (DE-588)4160847-1 gnd Solarzelle (DE-588)4181740-0 gnd Perowskit (DE-588)4173836-6 gnd |
| subject_GND | (DE-588)4160847-1 (DE-588)4181740-0 (DE-588)4173836-6 (DE-588)4143413-4 |
| title | Hybrid perovskite solar cells characteristics and operation |
| title_auth | Hybrid perovskite solar cells characteristics and operation |
| title_exact_search | Hybrid perovskite solar cells characteristics and operation |
| title_exact_search_txtP | Hybrid perovskite solar cells characteristics and operation |
| title_full | Hybrid perovskite solar cells characteristics and operation edited by Hiroyuki Fujiwara |
| title_fullStr | Hybrid perovskite solar cells characteristics and operation edited by Hiroyuki Fujiwara |
| title_full_unstemmed | Hybrid perovskite solar cells characteristics and operation edited by Hiroyuki Fujiwara |
| title_short | Hybrid perovskite solar cells |
| title_sort | hybrid perovskite solar cells characteristics and operation |
| title_sub | characteristics and operation |
| topic | Hybridwerkstoff (DE-588)4160847-1 gnd Solarzelle (DE-588)4181740-0 gnd Perowskit (DE-588)4173836-6 gnd |
| topic_facet | Hybridwerkstoff Solarzelle Perowskit Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032915460&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT fujiwarahiroyuki hybridperovskitesolarcellscharacteristicsandoperation AT wileyvch hybridperovskitesolarcellscharacteristicsandoperation |