Bioinorganic chemistry: some new facets
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| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin ; Boston
De Gruyter
[2021]
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| Schriftenreihe: | De Gruyter graduate
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| Schlagworte: | |
| Online-Zugang: | https://www.degruyter.com/books/9783110727296 Inhaltsverzeichnis |
| Beschreibung: | XV, 395 Seiten Illustrationen, Diagramme |
| ISBN: | 3110727293 9783110727296 |
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| 100 | 1 | |a Maurya, R. C. |e Verfasser |0 (DE-588)1195475543 |4 aut | |
| 245 | 1 | 0 | |a Bioinorganic chemistry |b some new facets |c Ram Charitra Maurya |
| 264 | 1 | |a Berlin ; Boston |b De Gruyter |c [2021] | |
| 264 | 4 | |c © 2021 | |
| 300 | |a XV, 395 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a De Gruyter graduate | |
| 650 | 0 | 7 | |a Bioanorganische Chemie |0 (DE-588)4126727-8 |2 gnd |9 rswk-swf |
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| 689 | 0 | 0 | |a Bioanorganische Chemie |0 (DE-588)4126727-8 |D s |
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| 710 | 2 | |a Walter de Gruyter GmbH & Co. KG |0 (DE-588)10095502-2 |4 pbl | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-11-072730-2 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-11-072741-8 |
| 856 | 4 | 2 | |m X:MVB |u https://www.degruyter.com/books/9783110727296 |
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Datensatz im Suchindex
| _version_ | 1804182675302383616 |
|---|---|
| adam_text | CONTENTS
PREFACE
-
VII
CHAPTER
I
COORDINATION
CHEMISTRY
OF
CHLOROPHYLLS/BACTERIOCHLOROPHYTLS
AND
ITS
FUNCTIONAL
ASPECTS
IN
PHOTOSYNTHESIS
----
1
1.1
INTRODUCTION
-
1
1.2
DIVERSE
PHOTOSYNTHETIC
ORGANISMS
----
2
1.2.1
PHOTOSYNTHETIC
ORGANISMS:
DEPENDENCE
ON
DIFFERENT
HYDROGEN
DONORS
----
3
1.3
LIGHT
AND
DARK
REACTIONS
IN
PHOTOSYNTHESIS
----
4
1.3.1
PHOTO-PHASE
OR
LIGHT
REACTION
----
5
1.3.2
SYNTHESIS-PHASE
OR
DARK
REACTIONS
-
5
1.4
CHLOROPLASTS:
THE
PHOTOSYNTHESIS
LOCATION
-
7
1.5
LIGHT-HARVESTING
PIGMENTS:
CHLOROPHYLLS
-
8
1.5.1
ACCESSORY
PIGMENTS
IN
THYLAKOIDS
(PHOTOSYNTHETIC
CELLS)
-
10
1.6
CHLOROPHYLLS
IN
PHOTOSYNTHETIC
LIGHT
ABSORPTION:
ABSORPTION
SPECTRA
OF
VARIOUS
PHOTOSYNTHETIC
PIGMENTS
AND
THEIR
FUNCTIONS
----
13
1.7
THE
ROLE
OF
MG(LL)
IN
CHLOROPHYLLS
-
16
1.8
HILL
REACTIONS:
ILLUMINATED
CHLOROPLASTS
EVOLVE
O
2
AND
REDUCE
ELECTRON
ACCEPTORS
----
17
1.9
PHOTOSYSTEMS
I
AND
II
IN
PHOTOSYNTHESIS
BY
GREEN
PLANTS
----
19
1.9.1
RED
DROP
-
20
1.9.2
PHOTOSYSTEM
I
(ALSO
CALLED
PS-1
OR
P-700,
P
STANDS
FOR
PIGMENT)
-
21
1.9.3
PHOTOSYSTEM
II
(ABBREVIATED
AS
PS-II
OR
P-680)
-
21
1.9.4
PHOTOSYSTEM
I
----
21
1.9.5
WATER
SPLITTING
REACTIONS
ASSISTED
BY
A
WATER
SPLITTING
COMPLEX
(MN
4
CLUSTER)
----
23
1.9.6
DARK
REACTION
----
27
1.9.7
CYCLIC
PHOTOPHOSPHORYLATION
IN
PHOTOSYNTHESIS
----
27
1.10
ANTENNA
CHLOROPHYLLS
AND
REACTION
CENTRES
IN
CHLOROPLASTS
-
28
REFERENCE
----
30
EXERCISES
-
30
X
-
CONTENTS
CHAPTER
II
COMPLEXES
CONTAINING
NITRIC
OXIDE:
SYNTHESIS,
REACTIVITY,
STRUCTURE,
BONDING
AND
THERAPEUTIC
ASPECTS
OF
NITRIC
OXIDE-RELEASING
MOLECULES
(NORMS)
IN
HUMAN
BEINGS
AND
PLANTS
----
35
2.1
INTRODUCTION
----
35
2.1.1
DISCOVERY
OF
NITRIC
OXIDE
(NO)
----
35
2.1.2
IMPORTANCE
OF
NITRIC
OXIDE
COMPLEXES
-----
35
2.2
METAL
NITROSYL
COMPLEXES?
----
37
2.3
SYNTHETIC
METHODS
OF
METAL
NITROSYLS
-
38
2.3.1
NITRIC
OXIDE
GAS
AS
THE
NITROSYLATING
AGENT
----
38
2.3.2
NO
+
AS
THE
NITROSYLATING
AGENT
----
42
2.3.3
NITROSYL
HALIDE
(NOX)
AS
THE
NITROSYLATING
AGENT
----
43
2.3.4
N-NITROSOAMIDES
AS
THE
NITROSYLATING
AGENTS
----
45
2.3.5
COORDINATED
NO
AS
THE
NITROSYLATING
AGENTS
----
46
2.3.6
HYDROXYLAMINE
(NH
2
OH)
AS
THE
NITROSYLATING
AGENTS
-----46
2.3.7
ACIDIC
SOLUTION
OF
NITRITE
SALTS
(NO
2
~/H
+
)
AS
THE
NITROSYLATING
AGENTS
-
49
2.3.8
ALKYL
NITRITES
AS
THE
NITROSYLATING
AGENTS
----
50
2.3.9
NITRIC
ACID
AS
THE
NITROSYLATING
AGENT
----
50
2.3.10
SYNTHESIS
OF
NITROSYL
COMPLEXES
USING
REDOX
REACTION
-
51
2.3.11
SYNTHESIS
OF
METAL
NITROSYL
BY
SUBSTITUTION
OF
CYANO
GROUPS
IN
PARENT
CYANONITROSYL
COMPLEX
----
52
2.4
THE
{M(N0)
M
}
FORMALISM
FOR
METAL
NITROSYL
COMPLEXES
-
52
2.4.1
LIMITATIONS
OF
THE
{M(N0)
M
}
N
FORMALISM
---
54
2.5
ALTERNATIVE
FORMALISM/NOTATION
FOR
METAL
NITROSYL
COMPLEXES
----
55
2.6
SIMPLIFIED
PROCEDURE
FOR
CALCULATION
OF
EAN
OF
METAL
NITROSYL
COMPLEXES
----
60
2.7
NEW
NOTATION
WITH
THE
FORMAL
CHARGES
ON
THE
NITROSYL
LIGAND
AND
THE
FORMAL
METAL
OXIDATION
STATE
----
61
2.8
TRANSITION
METAL
NITROSYL
COMPLEXES:
BONDING
----
62
2.8.1
STRUCTURAL
STUDIES:
X-RAY
STUDY
----
62
2.8.2
M.O.
CALCULATIONS
OF
BONDING
IN
METAL
NITROSYLS:
LINEAR
TO
BENT
MNO
BOND
ANGLE
TRANSFORMATION
IN
HEXA
AND
PENTA-COORDINATED
NITRIC
OXIDE
COMPLEXES
----
72
2.8.3
MOLECULAR
ORBITAL
CALCULATIONS:
DENSITY
FUNCTIONAL
THEORY
APPROACH
----
77
2.8.4
LINEAR
VERSUS
BENT
NITROSYL
LIGANDS:
ENEMARK-FELTHAM
APPROACH
----
79
2.9
CHARACTERIZATION
OF
METAL
NITROSYL
COMPLEXES
USING
SPECTROSCOPIC
AND
OTHER
PHYSICAL
METHODS
-----83
2.9.1
VIBRATIONAL
SPECTRAL
STUDIES
----
83
2.9.2
ELECTRONIC
SPECTRAL
STUDIES
----
89
CONTENTS
-
XI
2.9.3
MAGNETIC
PROPERTIES
----
97
2.9.4
ELECTRON
SPIN
RESONANCE
(ESR)
STUDIES
----
101
2.9.5
NUCLEAR
MAGNETIC
RESONANCE
(NMR)
SPECTRAL
STUDIES
----
106
2.9.6
X-RAY
PHOTOELECTRON
SPECTROSCOPY
OR
ESCA
STUDIES
----
107
2.9.7
MDSSBAUER
(MB)
SPECTRAL
STUDIES
----
110
2.9.8
KINETIC
STUDIES
----
115
2.9.9
NUCLEAR
RESONANCE
VIBRATIONAL
SPECTROSCOPIC
STUDIES
----
117
2.9.10
MASS
SPECTRAL
STUDIES
-
118
2.10
REACTIVITY
OF
NITRIC
OXIDE
COORDINATED
TO
TRANSITION
METALS
----
121
2.10.1
NUCLEOPHILIC
ATTACK
----
123
2.10.2
ELECTROPHILIC
ATTACK
OF
COORDINATED
NO
-
125
2.10.3
REDUCTION
REACTIONS
----
126
2.10.4
OXYGENATION
REACTIONS
IN
METAL
NITROSYLS
----
127
2.11
OTHER
REACTIONS
-
129
2.11.1
NITRIC
OXIDE
(NO):
INSERTION
REACTIONS
-
129
2.11.2
TRANSFER
OF
COORDINATED
NO
TO
THE
OTHER
METALS
-
129
2.12
TRANSITION
METAL
NITROSYLS:
ORGANIC
SYNTHESIS
AND
IN
POLLUTION
CONTROL
----
130
2.12.1
TRANSITION
METAL
NITROSYLS:
ORGANIC
SYNTHESIS
-
130
2.12.2
COORDINATED
NO
GROUP:
SOME
REACTIONS
----
135
2.12.3
METAL
NITROSYLS
AS
DEPOLLUTING
AGENTS
-
136
2.13
APPLICATIONS
OF
METAL
NITROSYLS
----
141
2.13.1
BIOMEDICAL
SCIENCE
-
142
2.14
NO
NEWS
IS
GOOD
NEWS
FOR
EYES:
NO
DONORS
FOR
THE
TREATMENT
OF
EYE
DISEASES
-
166
2.14.1
BIOSYNTHESIS
OF
NITRIC
OXIDE
-
167
2.14.2
ROLES
OF
NITRIC
OXIDE
IN
EYES
----
168
2.14.3
USE
OF
NORMS
IN
THE
TREATMENT
OF
EYE
DEFECTS
----
170
2.14.4
MECHANISM
OF
ACTION
OF
NO
IN
IOP
LOWERING
----
176
2.15
ROLE
OF
NO
AND
EXOGENOUS
NO
DONORS
IN
PLANTS
----
177
2.15.1
BIOSYNTHESIS
OF
NITRIC
OXIDE
----
177
2.15.2
NITRIC
OXIDE
ACTION
IN
PLANTS
-
179
2.16
CONCLUSIONS
-
186
REFERENCES
-
186
EXERCISES
-
198
XII
-
CONTENTS
CHAPTER
III
COMPLEXES
CONTAINING
CARBON
MONOXIDE:
SYNTHESIS,
REACTIVITY,
STRUCTURE,
BONDING
AND
THERAPEUTIC
ASPECTS
OF
CARBON
MONOXIDE-RELEASING
MOLECULES
(CORMS)
IN
HUMAN
BEINGS
AND
PLANTS
----
205
3.1
INTRODUCTION
----
205
3.2
METAL
CARBONYLS
----
206
3.3
SYNTHESIS
OF
METAL
CARBONYLS
-------
207
3.4
PHYSICAL
PROPERTIES
----
211
3.5
CHEMICAL
PROPERTIES/REACTIVITY
OF
METAL
CARBONYLS
----
211
3.5.1
DISPLACEMENT
OR
SUBSTITUTION
REACTIONS
----
211
3.5.2
FORMATION
OF
CATIONIC
CARBONYL
COMPLEXES:
CARBONYLATE
CATIONS
----
212
3.5.3
FORMATION
OF
ANIONIC
CARBONYL
COMPLEXES:
CARBONYLATE
ANIONS
----
213
3.5.4
REDOX
REACTIONS
INCLUDING
THE
FORMATION
AND
CLEAVAGE
OF
METAL
METAL
BONDS
-----
214
3.5.5
REACTION
WITH
NO
----
214
3.5.6
ACTION
OF
HEAT
----
214
3.5.7
INSERTION
REACTIONS
----
215
3.5.8
NUCLEOPHILIC
ATTACK
ON
COORDINATED
CO----
216
3.5.9
ELECTROPHILIC
ADDITION
TO
THE
CARBONYL
OXYGEN
----
217
3.5.10
DISPROPORTIONATION
REACTION
-----
217
3.5.11
COLLMAN
S
REAGENT
----
217
3.5.12
OXIDATIVE
DECARBONYLATION
---
218
3.5.13
PHOTOCHEMICAL
SUBSTITUTION
-----
218
3.6
CATALYTIC
ASPECT
OF
METAL
CARBONYLS
-----
219
3.6.1
HYDROGENATION
OF
ALKENES
----
219
3.6.2
HYDROFORMYLATION
REACTION
---
221
3.6.3
MANUFACTURING
OF
CH
3
COOH
BY
CARBONYLATION
OF
CH
3
OH
USING
METAL
CARBONYL
AS
CATALYST
---
224
3.6.4
MANUFACTURING
OF
ACETIC
ANHYDRIDE
BY
CARBONYLATION
OF
CH
3
COOCH
3
----
228
3.6.5
IMPORTANCE
OF
ACETIC
ANHYDRIDE
----
229
3.6.6
MANUFACTURING
OF
ACETIC
ACID
BY
BP
CATIVA
PROCESS
USING
IRIDIUM
CARBONYL
AS
A
CATALYST
----
230
3.6.7
CARBONYLATION
OF
OLEFINS
AND
ACETYLENES
TO
CARBOXYLIC
ACIDS
OR
ESTERS
OR
ALCOHOLS
USING
METAL
CARBONYLS
AS
A
CATALYST
-
231
3.7
METAL
CARBONYLS:
EFFECTIVE
ATOMIC
NUMBER
(EAN)
RULE
----
233
3.7.1
MONONUCLEAR
CARBONYLS
HAVING
METALLIC
ATOM
WITH
EVEN
ATOMIC
NUMBERS
----
234
3.7.2
MONONUCLEAR
CARBONYLS
HAVING
METALLIC
ATOM
WITH
ODD
ATOMIC
NUMBERS
----
234
CONTENTS
-
XIII
3.7.3
POLYNUCLEAR
CARBONYLS
-
235
3.7.4
UTILITY
OF
EAN
RULE
----
238
3.8
EIGHTEEN-ELECTRON
RULE
FOR
METAL
CARBONYLS
-
240
3.8.1
EIGHTEEN-ELECTRON
RULE:
SQUARE
PLANAR
COMPLEXES
----
244
3.9
TYPES
OF
BOND
PRESENT
IN
METAL
CARBONYLS
----
245
3.10
STRUCTURE
OF
METAL
CARBONYLS:
VALENCE
BOND
(VB)
APPROACH
-
247
3.11
BONDING
IN
METAL
CARBONYLS:
NATURE
OF
M-C
AND
C-0
BONDS
IN
METAL
CARBONYLS
-
261
3.11.1
FORMATION
OF
OC
-
M
A-BOND:
VALENCE
BOND
THEORY
(VBT)
APPROACH
----
262
3.11.2
FORMATION
OF
OC
-----
M
O-BOND
AND
M
----
CO
N
BOND:
MOLECULAR
ORBITAL
THEORY
(MOT)
APPROACH
-
263
3.11.3
BONDING
IN
METAL
CARBONYL
VERSUS
N-COMPLEXES
OF
UNSATURATED
ORGANIC
LIGANDS
-
265
3.11.4
METAL
CARBONYLS
AND
IR
SPECTRA
-
265
3.12
METAL
CARBONYL
COMPOUNDS:
A
NEW
CLASS
OF
METALLOPHARMACEUTICALS
----
270
3.12.1
INTRODUCTION
----
270
3.12.2
SOURCES
OF
CO
IN
THE
HUMAN
BODY
-
271
3.12.3
GENERATED
CO
IN
MAMMALS:
TARGET
SITES
----
274
3.13
CO
SIGNALLING
IN
ANTI-INFLAMMATORY
RESPONSES
----
277
3.14
THERAPEUTIC
SCOPE
OF
CO
----
279
3.14.1
WAYS
OF
CO
DELIVERY
IN
HUMAN
BODY
AS
A
THERAPEUTIC
AGENT
----
279
3.14.2
REQUIREMENT
OF
EXOGENOUS
ENDEAVOUR,
WHY?
----
281
3.15
THERAPEUTIC
APPLICATIONS
OF
CO
AND
CO
RESEALING
MOLECULES/
MATERIALS
----
282
3.15.1
ROLE
OF
EXOGENOUSLY
APPLIED
CO
GAS
-
283
3.15.2
CARBON
MONOXIDE-RELEASING
MOLECULES
(CORMS)
AND
PHOTOACTIVE
CORMS
OR
PHOTOCORMS----
285
3.16
CO
AS
A
SIGNALLING
MOLECULE
IN
PLANTS:
A
VEGETATION
ECHO
OF
CO
----
297
3.16.1
INTRODUCTION
---
297
3.16.2
SYNTHESIS
OF
CO
IN
PLANTS
----
298
3.16.3
ROLE
OF
CO
IN
PLANT
GROWTH
AND
DEVELOPMENT
----
299
3.16.4
ROLE
OF
CO
IN
ABIOTIC
STRESSES
----
303
3.17
CROSS-TALK
BETWEEN
CO
AND
OTHER
SIGNALLING
MOLECULES
-----
305
3.17.1
CROSS-TALK
BETWEEN
CO
AND
NO
--------
306
3.17.2
CROSS-TALK
BETWEEN
CO
AND
PHYTOHORMONE
----
307
3.17.3
CROSS-TALK
BETWEEN
CO
AND
OTHER
SMALL
SIGNALLING
MOLECULES
-
307
XIV
-
CONTENTS
3.18
CONCLUDING
REMARKS
----
308
REFERENCES
----
309
EXERCISES
----
318
CHAPTER
IV
ADVANTAGEOUS
ROLE
OF
GASEOUS
SIGNALLING
MOLECULE,
H
2
S:
HYDROGEN
SULPHIDE
AND
THEIR
RESPECTIVE
DONORS,
IN
OPHTHALMIC
DISEASES
AND
PHYSIOLOGICAL
IMPLICATIONS
IN
PLANTS
----
325
4.1
4.2
INTRODUCTION
----
325
INTRODUCTORY
VIEW
OF
GASOTRANSMITTERS:
ENDOGENOUS
SIGNALLING
MOLECULES
-
327
4.3
4.3.1
4.3.2
4.4
4.5
4.5.1
4.5.2
4.5.3
4.5.4
4.5.5
4.5.6
4.6
4.6.1
4.6.2
4.6.3
BIOSYNTHESIS
OF
H
2
S
----
328
IN
OCULAR
TISSUES
----
328
IN
PLANTS
----
330
BIOLOGICAL
CHEMISTRY
OF
H
2
S
----
331
IMPLICATIONS
OF
H
2
S
IN
OPHTHALMIC
DISEASES
----
333
INTRODUCTION
----
333
OCULAR
DRUG
DELIVERY
----
334
OCULAR
BIOAVAILABILITY
----
334
H
2
S
AND
GLAUCOMA
----
336
H
2
S
AND
DIABETIC
RETINOPATHY
----
339
H
2
S
AND
RETINAL
DEGENERATION
----
342
PHYSIOLOGICAL
FUNCTIONS
OF
H
2
S
IN
PLANTS
----
343
INTRODUCTION
----
343
IMPROVEMENT
IN
SEED
GERMINATION
AND
PLANT
GROWTH
----
344
H
2
S
IN
FRUIT
RIPENING
AND
POST-HARVEST
DAMAGE
TO
FRESH
PRODUCE
----
345
4.6.4
4.6.5
4.6.6
4.6.7
4.7
ABIOTIC
STRESSES
IN
PLANTS
----
345
CROP
PLANTS
AND
BIOTIC
STRESS
----
349
EXOGENOUSLY
APPLIED
NAHS:
ACTIVATION
OF
H
2
S
SIGNALLING
-
349
CROSS-ADAPTATION:
PERSUADED
BY
H
2
S
----
350
CONCLUSIONS
----
354
REFERENCES
----
354
EXERCISES
----
363
CONTENTS
-----
XV
APPENDIX
I
THE
INTERNATIONAL
SYSTEM
OF
UNITS,
FUNDAMENTAL
PHYSICAL
CONSTANTS
AND
CONVERSION
FACTORS
----
367
APPENDIX
II
BODY
MASS
INDEX
(BMI):
AN
INDICATOR
OF
OUR
BODY
FAT
----
373
APPENDIX
III
AMINO
ACIDS,
THE
BUILDING
BLOCKS
OF
PROTEINS:
NAMES,
SYMBOLS,
STRUCTURES,
PROPERTIES
AND
SOME
PHYSICAL
CONSTANTS
-
375
BIBLIOGRAPHY
----
387
INDEX
----
391
|
| adam_txt |
CONTENTS
PREFACE
-
VII
CHAPTER
I
COORDINATION
CHEMISTRY
OF
CHLOROPHYLLS/BACTERIOCHLOROPHYTLS
AND
ITS
FUNCTIONAL
ASPECTS
IN
PHOTOSYNTHESIS
----
1
1.1
INTRODUCTION
-
1
1.2
DIVERSE
PHOTOSYNTHETIC
ORGANISMS
----
2
1.2.1
PHOTOSYNTHETIC
ORGANISMS:
DEPENDENCE
ON
DIFFERENT
HYDROGEN
DONORS
----
3
1.3
LIGHT
AND
DARK
REACTIONS
IN
PHOTOSYNTHESIS
----
4
1.3.1
PHOTO-PHASE
OR
LIGHT
REACTION
----
5
1.3.2
SYNTHESIS-PHASE
OR
DARK
REACTIONS
-
5
1.4
CHLOROPLASTS:
THE
PHOTOSYNTHESIS
LOCATION
-
7
1.5
LIGHT-HARVESTING
PIGMENTS:
CHLOROPHYLLS
-
8
1.5.1
ACCESSORY
PIGMENTS
IN
THYLAKOIDS
(PHOTOSYNTHETIC
CELLS)
-
10
1.6
CHLOROPHYLLS
IN
PHOTOSYNTHETIC
LIGHT
ABSORPTION:
ABSORPTION
SPECTRA
OF
VARIOUS
PHOTOSYNTHETIC
PIGMENTS
AND
THEIR
FUNCTIONS
----
13
1.7
THE
ROLE
OF
MG(LL)
IN
CHLOROPHYLLS
-
16
1.8
HILL
REACTIONS:
ILLUMINATED
CHLOROPLASTS
EVOLVE
O
2
AND
REDUCE
ELECTRON
ACCEPTORS
----
17
1.9
PHOTOSYSTEMS
I
AND
II
IN
PHOTOSYNTHESIS
BY
GREEN
PLANTS
----
19
1.9.1
RED
DROP
-
20
1.9.2
PHOTOSYSTEM
I
(ALSO
CALLED
PS-1
OR
P-700,
P
STANDS
FOR
PIGMENT)
-
21
1.9.3
PHOTOSYSTEM
II
(ABBREVIATED
AS
PS-II
OR
P-680)
-
21
1.9.4
PHOTOSYSTEM
I
----
21
1.9.5
WATER
SPLITTING
REACTIONS
ASSISTED
BY
A
WATER
SPLITTING
COMPLEX
(MN
4
CLUSTER)
----
23
1.9.6
DARK
REACTION
----
27
1.9.7
CYCLIC
PHOTOPHOSPHORYLATION
IN
PHOTOSYNTHESIS
----
27
1.10
ANTENNA
CHLOROPHYLLS
AND
REACTION
CENTRES
IN
CHLOROPLASTS
-
28
REFERENCE
----
30
EXERCISES
-
30
X
-
CONTENTS
CHAPTER
II
COMPLEXES
CONTAINING
NITRIC
OXIDE:
SYNTHESIS,
REACTIVITY,
STRUCTURE,
BONDING
AND
THERAPEUTIC
ASPECTS
OF
NITRIC
OXIDE-RELEASING
MOLECULES
(NORMS)
IN
HUMAN
BEINGS
AND
PLANTS
----
35
2.1
INTRODUCTION
----
35
2.1.1
DISCOVERY
OF
NITRIC
OXIDE
(NO)
----
35
2.1.2
IMPORTANCE
OF
NITRIC
OXIDE
COMPLEXES
-----
35
2.2
METAL
NITROSYL
COMPLEXES?
----
37
2.3
SYNTHETIC
METHODS
OF
METAL
NITROSYLS
-
38
2.3.1
NITRIC
OXIDE
GAS
AS
THE
NITROSYLATING
AGENT
----
38
2.3.2
NO
+
AS
THE
NITROSYLATING
AGENT
----
42
2.3.3
NITROSYL
HALIDE
(NOX)
AS
THE
NITROSYLATING
AGENT
----
43
2.3.4
N-NITROSOAMIDES
AS
THE
NITROSYLATING
AGENTS
----
45
2.3.5
COORDINATED
NO
AS
THE
NITROSYLATING
AGENTS
----
46
2.3.6
HYDROXYLAMINE
(NH
2
OH)
AS
THE
NITROSYLATING
AGENTS
-----46
2.3.7
ACIDIC
SOLUTION
OF
NITRITE
SALTS
(NO
2
~/H
+
)
AS
THE
NITROSYLATING
AGENTS
-
49
2.3.8
ALKYL
NITRITES
AS
THE
NITROSYLATING
AGENTS
----
50
2.3.9
NITRIC
ACID
AS
THE
NITROSYLATING
AGENT
----
50
2.3.10
SYNTHESIS
OF
NITROSYL
COMPLEXES
USING
REDOX
REACTION
-
51
2.3.11
SYNTHESIS
OF
METAL
NITROSYL
BY
SUBSTITUTION
OF
CYANO
GROUPS
IN
PARENT
CYANONITROSYL
COMPLEX
----
52
2.4
THE
{M(N0)
M
}"
FORMALISM
FOR
METAL
NITROSYL
COMPLEXES
-
52
2.4.1
LIMITATIONS
OF
THE
{M(N0)
M
}
N
FORMALISM
---
54
2.5
ALTERNATIVE
FORMALISM/NOTATION
FOR
METAL
NITROSYL
COMPLEXES
----
55
2.6
SIMPLIFIED
PROCEDURE
FOR
CALCULATION
OF
EAN
OF
METAL
NITROSYL
COMPLEXES
----
60
2.7
NEW
NOTATION
WITH
THE
FORMAL
CHARGES
ON
THE
NITROSYL
LIGAND
AND
THE
FORMAL
METAL
OXIDATION
STATE
----
61
2.8
TRANSITION
METAL
NITROSYL
COMPLEXES:
BONDING
----
62
2.8.1
STRUCTURAL
STUDIES:
X-RAY
STUDY
----
62
2.8.2
M.O.
CALCULATIONS
OF
BONDING
IN
METAL
NITROSYLS:
LINEAR
TO
BENT
MNO
BOND
ANGLE
TRANSFORMATION
IN
HEXA
AND
PENTA-COORDINATED
NITRIC
OXIDE
COMPLEXES
----
72
2.8.3
MOLECULAR
ORBITAL
CALCULATIONS:
DENSITY
FUNCTIONAL
THEORY
APPROACH
----
77
2.8.4
LINEAR
VERSUS
BENT
NITROSYL
LIGANDS:
ENEMARK-FELTHAM
APPROACH
----
79
2.9
CHARACTERIZATION
OF
METAL
NITROSYL
COMPLEXES
USING
SPECTROSCOPIC
AND
OTHER
PHYSICAL
METHODS
-----83
2.9.1
VIBRATIONAL
SPECTRAL
STUDIES
----
83
2.9.2
ELECTRONIC
SPECTRAL
STUDIES
----
89
CONTENTS
-
XI
2.9.3
MAGNETIC
PROPERTIES
----
97
2.9.4
ELECTRON
SPIN
RESONANCE
(ESR)
STUDIES
----
101
2.9.5
NUCLEAR
MAGNETIC
RESONANCE
(NMR)
SPECTRAL
STUDIES
----
106
2.9.6
X-RAY
PHOTOELECTRON
SPECTROSCOPY
OR
ESCA
STUDIES
----
107
2.9.7
MDSSBAUER
(MB)
SPECTRAL
STUDIES
----
110
2.9.8
KINETIC
STUDIES
----
115
2.9.9
NUCLEAR
RESONANCE
VIBRATIONAL
SPECTROSCOPIC
STUDIES
----
117
2.9.10
MASS
SPECTRAL
STUDIES
-
118
2.10
REACTIVITY
OF
NITRIC
OXIDE
COORDINATED
TO
TRANSITION
METALS
----
121
2.10.1
NUCLEOPHILIC
ATTACK
----
123
2.10.2
ELECTROPHILIC
ATTACK
OF
COORDINATED
NO
-
125
2.10.3
REDUCTION
REACTIONS
----
126
2.10.4
OXYGENATION
REACTIONS
IN
METAL
NITROSYLS
----
127
2.11
OTHER
REACTIONS
-
129
2.11.1
NITRIC
OXIDE
(NO):
INSERTION
REACTIONS
-
129
2.11.2
TRANSFER
OF
COORDINATED
NO
TO
THE
OTHER
METALS
-
129
2.12
TRANSITION
METAL
NITROSYLS:
ORGANIC
SYNTHESIS
AND
IN
POLLUTION
CONTROL
----
130
2.12.1
TRANSITION
METAL
NITROSYLS:
ORGANIC
SYNTHESIS
-
130
2.12.2
COORDINATED
NO
GROUP:
SOME
REACTIONS
----
135
2.12.3
METAL
NITROSYLS
AS
DEPOLLUTING
AGENTS
-
136
2.13
APPLICATIONS
OF
METAL
NITROSYLS
----
141
2.13.1
BIOMEDICAL
SCIENCE
-
142
2.14
NO
NEWS
IS
GOOD
NEWS
FOR
EYES:
NO
DONORS
FOR
THE
TREATMENT
OF
EYE
DISEASES
-
166
2.14.1
BIOSYNTHESIS
OF
NITRIC
OXIDE
-
167
2.14.2
ROLES
OF
NITRIC
OXIDE
IN
EYES
----
168
2.14.3
USE
OF
NORMS
IN
THE
TREATMENT
OF
EYE
DEFECTS
----
170
2.14.4
MECHANISM
OF
ACTION
OF
NO
IN
IOP
LOWERING
----
176
2.15
ROLE
OF
NO
AND
EXOGENOUS
NO
DONORS
IN
PLANTS
----
177
2.15.1
BIOSYNTHESIS
OF
NITRIC
OXIDE
----
177
2.15.2
NITRIC
OXIDE
ACTION
IN
PLANTS
-
179
2.16
CONCLUSIONS
-
186
REFERENCES
-
186
EXERCISES
-
198
XII
-
CONTENTS
CHAPTER
III
COMPLEXES
CONTAINING
CARBON
MONOXIDE:
SYNTHESIS,
REACTIVITY,
STRUCTURE,
BONDING
AND
THERAPEUTIC
ASPECTS
OF
CARBON
MONOXIDE-RELEASING
MOLECULES
(CORMS)
IN
HUMAN
BEINGS
AND
PLANTS
----
205
3.1
INTRODUCTION
----
205
3.2
METAL
CARBONYLS
----
206
3.3
SYNTHESIS
OF
METAL
CARBONYLS
-------
207
3.4
PHYSICAL
PROPERTIES
----
211
3.5
CHEMICAL
PROPERTIES/REACTIVITY
OF
METAL
CARBONYLS
----
211
3.5.1
DISPLACEMENT
OR
SUBSTITUTION
REACTIONS
----
211
3.5.2
FORMATION
OF
CATIONIC
CARBONYL
COMPLEXES:
CARBONYLATE
CATIONS
----
212
3.5.3
FORMATION
OF
ANIONIC
CARBONYL
COMPLEXES:
CARBONYLATE
ANIONS
----
213
3.5.4
REDOX
REACTIONS
INCLUDING
THE
FORMATION
AND
CLEAVAGE
OF
METAL
METAL
BONDS
-----
214
3.5.5
REACTION
WITH
NO
----
214
3.5.6
ACTION
OF
HEAT
----
214
3.5.7
INSERTION
REACTIONS
----
215
3.5.8
NUCLEOPHILIC
ATTACK
ON
COORDINATED
CO----
216
3.5.9
ELECTROPHILIC
ADDITION
TO
THE
CARBONYL
OXYGEN
----
217
3.5.10
DISPROPORTIONATION
REACTION
-----
217
3.5.11
COLLMAN
'
S
REAGENT
----
217
3.5.12
OXIDATIVE
DECARBONYLATION
---
218
3.5.13
PHOTOCHEMICAL
SUBSTITUTION
-----
218
3.6
CATALYTIC
ASPECT
OF
METAL
CARBONYLS
-----
219
3.6.1
HYDROGENATION
OF
ALKENES
----
219
3.6.2
HYDROFORMYLATION
REACTION
---
221
3.6.3
MANUFACTURING
OF
CH
3
COOH
BY
CARBONYLATION
OF
CH
3
OH
USING
METAL
CARBONYL
AS
CATALYST
---
224
3.6.4
MANUFACTURING
OF
ACETIC
ANHYDRIDE
BY
CARBONYLATION
OF
CH
3
COOCH
3
----
228
3.6.5
IMPORTANCE
OF
ACETIC
ANHYDRIDE
----
229
3.6.6
MANUFACTURING
OF
ACETIC
ACID
BY
BP
CATIVA
PROCESS
USING
IRIDIUM
CARBONYL
AS
A
CATALYST
----
230
3.6.7
CARBONYLATION
OF
OLEFINS
AND
ACETYLENES
TO
CARBOXYLIC
ACIDS
OR
ESTERS
OR
ALCOHOLS
USING
METAL
CARBONYLS
AS
A
CATALYST
-
231
3.7
METAL
CARBONYLS:
EFFECTIVE
ATOMIC
NUMBER
(EAN)
RULE
----
233
3.7.1
MONONUCLEAR
CARBONYLS
HAVING
METALLIC
ATOM
WITH
EVEN
ATOMIC
NUMBERS
----
234
3.7.2
MONONUCLEAR
CARBONYLS
HAVING
METALLIC
ATOM
WITH
ODD
ATOMIC
NUMBERS
----
234
CONTENTS
-
XIII
3.7.3
POLYNUCLEAR
CARBONYLS
-
235
3.7.4
UTILITY
OF
EAN
RULE
----
238
3.8
EIGHTEEN-ELECTRON
RULE
FOR
METAL
CARBONYLS
-
240
3.8.1
EIGHTEEN-ELECTRON
RULE:
SQUARE
PLANAR
COMPLEXES
----
244
3.9
TYPES
OF
BOND
PRESENT
IN
METAL
CARBONYLS
----
245
3.10
STRUCTURE
OF
METAL
CARBONYLS:
VALENCE
BOND
(VB)
APPROACH
-
247
3.11
BONDING
IN
METAL
CARBONYLS:
NATURE
OF
M-C
AND
C-0
BONDS
IN
METAL
CARBONYLS
-
261
3.11.1
FORMATION
OF
OC
-
M
A-BOND:
VALENCE
BOND
THEORY
(VBT)
APPROACH
----
262
3.11.2
FORMATION
OF
OC
-----
M
O-BOND
AND
M
----
CO
N
BOND:
MOLECULAR
ORBITAL
THEORY
(MOT)
APPROACH
-
263
3.11.3
BONDING
IN
METAL
CARBONYL
VERSUS
N-COMPLEXES
OF
UNSATURATED
ORGANIC
LIGANDS
-
265
3.11.4
METAL
CARBONYLS
AND
IR
SPECTRA
-
265
3.12
METAL
CARBONYL
COMPOUNDS:
A
NEW
CLASS
OF
METALLOPHARMACEUTICALS
----
270
3.12.1
INTRODUCTION
----
270
3.12.2
SOURCES
OF
CO
IN
THE
HUMAN
BODY
-
271
3.12.3
GENERATED
CO
IN
MAMMALS:
TARGET
SITES
----
274
3.13
CO
SIGNALLING
IN
ANTI-INFLAMMATORY
RESPONSES
----
277
3.14
THERAPEUTIC
SCOPE
OF
CO
----
279
3.14.1
WAYS
OF
CO
DELIVERY
IN
HUMAN
BODY
AS
A
THERAPEUTIC
AGENT
----
279
3.14.2
REQUIREMENT
OF
EXOGENOUS
ENDEAVOUR,
WHY?
----
281
3.15
THERAPEUTIC
APPLICATIONS
OF
CO
AND
CO
RESEALING
MOLECULES/
MATERIALS
----
282
3.15.1
ROLE
OF
EXOGENOUSLY
APPLIED
CO
GAS
-
283
3.15.2
CARBON
MONOXIDE-RELEASING
MOLECULES
(CORMS)
AND
PHOTOACTIVE
CORMS
OR
PHOTOCORMS----
285
3.16
CO
AS
A
SIGNALLING
MOLECULE
IN
PLANTS:
A
VEGETATION
ECHO
OF
CO
----
297
3.16.1
INTRODUCTION
---
297
3.16.2
SYNTHESIS
OF
CO
IN
PLANTS
----
298
3.16.3
ROLE
OF
CO
IN
PLANT
GROWTH
AND
DEVELOPMENT
----
299
3.16.4
ROLE
OF
CO
IN
ABIOTIC
STRESSES
----
303
3.17
CROSS-TALK
BETWEEN
CO
AND
OTHER
SIGNALLING
MOLECULES
-----
305
3.17.1
CROSS-TALK
BETWEEN
CO
AND
NO
--------
306
3.17.2
CROSS-TALK
BETWEEN
CO
AND
PHYTOHORMONE
----
307
3.17.3
CROSS-TALK
BETWEEN
CO
AND
OTHER
SMALL
SIGNALLING
MOLECULES
-
307
XIV
-
CONTENTS
3.18
CONCLUDING
REMARKS
----
308
REFERENCES
----
309
EXERCISES
----
318
CHAPTER
IV
ADVANTAGEOUS
ROLE
OF
GASEOUS
SIGNALLING
MOLECULE,
H
2
S:
HYDROGEN
SULPHIDE
AND
THEIR
RESPECTIVE
DONORS,
IN
OPHTHALMIC
DISEASES
AND
PHYSIOLOGICAL
IMPLICATIONS
IN
PLANTS
----
325
4.1
4.2
INTRODUCTION
----
325
INTRODUCTORY
VIEW
OF
GASOTRANSMITTERS:
ENDOGENOUS
SIGNALLING
MOLECULES
-
327
4.3
4.3.1
4.3.2
4.4
4.5
4.5.1
4.5.2
4.5.3
4.5.4
4.5.5
4.5.6
4.6
4.6.1
4.6.2
4.6.3
BIOSYNTHESIS
OF
H
2
S
----
328
IN
OCULAR
TISSUES
----
328
IN
PLANTS
----
330
BIOLOGICAL
CHEMISTRY
OF
H
2
S
----
331
IMPLICATIONS
OF
H
2
S
IN
OPHTHALMIC
DISEASES
----
333
INTRODUCTION
----
333
OCULAR
DRUG
DELIVERY
----
334
OCULAR
BIOAVAILABILITY
----
334
H
2
S
AND
GLAUCOMA
----
336
H
2
S
AND
DIABETIC
RETINOPATHY
----
339
H
2
S
AND
RETINAL
DEGENERATION
----
342
PHYSIOLOGICAL
FUNCTIONS
OF
H
2
S
IN
PLANTS
----
343
INTRODUCTION
----
343
IMPROVEMENT
IN
SEED
GERMINATION
AND
PLANT
GROWTH
----
344
H
2
S
IN
FRUIT
RIPENING
AND
POST-HARVEST
DAMAGE
TO
FRESH
PRODUCE
----
345
4.6.4
4.6.5
4.6.6
4.6.7
4.7
ABIOTIC
STRESSES
IN
PLANTS
----
345
CROP
PLANTS
AND
BIOTIC
STRESS
----
349
EXOGENOUSLY
APPLIED
NAHS:
ACTIVATION
OF
H
2
S
SIGNALLING
-
349
CROSS-ADAPTATION:
PERSUADED
BY
H
2
S
----
350
CONCLUSIONS
----
354
REFERENCES
----
354
EXERCISES
----
363
CONTENTS
-----
XV
APPENDIX
I
THE
INTERNATIONAL
SYSTEM
OF
UNITS,
FUNDAMENTAL
PHYSICAL
CONSTANTS
AND
CONVERSION
FACTORS
----
367
APPENDIX
II
BODY
MASS
INDEX
(BMI):
AN
INDICATOR
OF
OUR
BODY
FAT
----
373
APPENDIX
III
AMINO
ACIDS,
THE
BUILDING
BLOCKS
OF
PROTEINS:
NAMES,
SYMBOLS,
STRUCTURES,
PROPERTIES
AND
SOME
PHYSICAL
CONSTANTS
-
375
BIBLIOGRAPHY
----
387
INDEX
----
391 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Maurya, R. C. |
| author_GND | (DE-588)1195475543 |
| author_facet | Maurya, R. C. |
| author_role | aut |
| author_sort | Maurya, R. C. |
| author_variant | r c m rc rcm |
| building | Verbundindex |
| bvnumber | BV047409208 |
| classification_rvk | VH 9750 |
| ctrlnum | (OCoLC)1269390363 (DE-599)DNB1231460911 |
| discipline | Chemie / Pharmazie |
| discipline_str_mv | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV047409208 |
| illustrated | Illustrated |
| index_date | 2024-07-03T17:54:59Z |
| indexdate | 2024-07-10T09:11:19Z |
| institution | BVB |
| institution_GND | (DE-588)10095502-2 |
| isbn | 3110727293 9783110727296 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-032810129 |
| oclc_num | 1269390363 |
| open_access_boolean | |
| owner | DE-29T DE-92 DE-634 DE-11 DE-19 DE-BY-UBM |
| owner_facet | DE-29T DE-92 DE-634 DE-11 DE-19 DE-BY-UBM |
| physical | XV, 395 Seiten Illustrationen, Diagramme |
| publishDate | 2021 |
| publishDateSearch | 2021 |
| publishDateSort | 2021 |
| publisher | De Gruyter |
| record_format | marc |
| series2 | De Gruyter graduate |
| spelling | Maurya, R. C. Verfasser (DE-588)1195475543 aut Bioinorganic chemistry some new facets Ram Charitra Maurya Berlin ; Boston De Gruyter [2021] © 2021 XV, 395 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier De Gruyter graduate Bioanorganische Chemie (DE-588)4126727-8 gnd rswk-swf TB: Textbook Bioanorganische Chemie (DE-588)4126727-8 s DE-604 Walter de Gruyter GmbH & Co. KG (DE-588)10095502-2 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-11-072730-2 Erscheint auch als Online-Ausgabe, EPUB 978-3-11-072741-8 X:MVB https://www.degruyter.com/books/9783110727296 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032810129&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Maurya, R. C. Bioinorganic chemistry some new facets Bioanorganische Chemie (DE-588)4126727-8 gnd |
| subject_GND | (DE-588)4126727-8 |
| title | Bioinorganic chemistry some new facets |
| title_auth | Bioinorganic chemistry some new facets |
| title_exact_search | Bioinorganic chemistry some new facets |
| title_exact_search_txtP | Bioinorganic chemistry some new facets |
| title_full | Bioinorganic chemistry some new facets Ram Charitra Maurya |
| title_fullStr | Bioinorganic chemistry some new facets Ram Charitra Maurya |
| title_full_unstemmed | Bioinorganic chemistry some new facets Ram Charitra Maurya |
| title_short | Bioinorganic chemistry |
| title_sort | bioinorganic chemistry some new facets |
| title_sub | some new facets |
| topic | Bioanorganische Chemie (DE-588)4126727-8 gnd |
| topic_facet | Bioanorganische Chemie |
| url | https://www.degruyter.com/books/9783110727296 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032810129&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT mauryarc bioinorganicchemistrysomenewfacets AT walterdegruytergmbhcokg bioinorganicchemistrysomenewfacets |