CO2 as a building block in organic synthesis:
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Weinheim
Wiley-VCH
[2020]
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Schlagworte: | |
Online-Zugang: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34613-4/ Inhaltsverzeichnis |
Beschreibung: | Die 2 im Titel ist tiefgestellt |
Beschreibung: | x, 453 Seiten Illustrationen |
ISBN: | 9783527346134 |
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020 | |a 9783527346134 |9 978-3-527-34613-4 | ||
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245 | 1 | 0 | |a CO2 as a building block in organic synthesis |c edited by Shoubhik Das |
264 | 1 | |a Weinheim |b Wiley-VCH |c [2020] | |
264 | 4 | |c © 2020 | |
300 | |a x, 453 Seiten |b Illustrationen | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
500 | |a Die 2 im Titel ist tiefgestellt | ||
650 | 0 | 7 | |a Kohlendioxid |0 (DE-588)4031648-8 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Carboxylierung |0 (DE-588)4205211-7 |2 gnd |9 rswk-swf |
653 | |a Anorganische Chemie | ||
653 | |a Chemie | ||
653 | |a Chemistry | ||
653 | |a CO2 | ||
653 | |a Inorganic Chemistry | ||
653 | |a Kohlendioxid | ||
653 | |a Methods - Synthesis & Techniques | ||
653 | |a Organische Chemie / Methoden, Synthesen, Verfahren | ||
653 | |a Pharmaceutical & Medicinal Chemistry | ||
653 | |a Pharmazeutische u. Medizinische Chemie | ||
653 | |a CH60: Pharmazeutische u. Medizinische Chemie | ||
653 | |a CH70: Anorganische Chemie | ||
653 | |a CH81: Organische Chemie / Methoden, Synthesen, Verfahren | ||
655 | 7 | |0 (DE-588)4143413-4 |a Aufsatzsammlung |2 gnd-content | |
689 | 0 | 0 | |a Kohlendioxid |0 (DE-588)4031648-8 |D s |
689 | 0 | 1 | |a Carboxylierung |0 (DE-588)4205211-7 |D s |
689 | 0 | |5 DE-604 | |
700 | 1 | |a Das, Shoubhik |d 1980- |0 (DE-588)1018978429 |4 edt | |
710 | 2 | |a Wiley-VCH |0 (DE-588)16179388-5 |4 pbl | |
776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-527-82194-5 |
776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-527-82196-9 |
776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, OBOOK |z 978-3-527-82195-2 |
856 | 4 | 2 | |m X:MVB |u http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34613-4/ |
856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032295695&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
999 | |a oai:aleph.bib-bvb.de:BVB01-032295695 |
Datensatz im Suchindex
_version_ | 1804181746752684032 |
---|---|
adam_text | CONTENTS
1
PHOTOCHEMICAL
AND
SUBSTRATE-DRIVEN
CO
2
CONVERSION
1
BART
LIMBURG,
CRISTINA
MAQUILON,
AND
ARJAN
W.
KLEIJ
1.1
1.2
1.3
INTRODUCTION
1
IODINE
ACTIVATION
OF
(HOMO)ALLYLIC
SUBSTRATES
3
SUBSTRATE
ACTIVATION
VIA
RADICAL
ADDITION/PHOTOCHEMICAL
OXIDATION
PROCESSES
9
1.4
1.5
1.6
SUBSTRATE-INDUCED
ACTIVATION
OF
OXIRANES
12
SUBSTRATE-INVOLVED ACTIVATION
OF
OXETANES
AND
AZETIDINES
21
CONCLUDING
REMARKS
21
REFERENCES
22
2
C-H
CARBOXYLATIONS
WITH
CO
2
29
UTTAM
DHAWA,
ISAAC
CHOI,
AND
LUTZ
ACKERMANN
2.1
2.2
2.2.1
2.2.2
2.2.3
2.2.4
2.2.5
2.2.6
2.2.7
2.2.8
2.2.9
2.2.10
2.2.11
2.3
2.3.1
2.3.2
2.3.3
2.3.4
2.4
2.5
INTRODUCTION
29
TRANSITION-METAL-CATALYZED
C-H
CARBOXYLATION
30
COPPER-CATALYZED
C-H
CARBOXYLATION
30
COBALT-CATALYZED
C-H
CARBOXYLATION
36
NICKEL-CATALYZED
C-H
CARBOXYLATION
36
MOLYBDENUM-CATALYZED
C-H
CARBOXYLATION
38
RUTHENIUM-CATALYZED
C-H
CARBOXYLATION
38
RHODIUM-CATALYZED
C-H
CARBOXYLATION
39
PALLADIUM-CATALYZED
C-H
CARBOXYLATION
41
SILVER-CATALYZED
C-H
CARBOXYLATION
42
IRIDIUM-CATALYZED
C-H
CARBOXYLATION
45
GOLD-CATALYZED
C-H
CARBOXYLATION
45
NEODYMIUM-CATALYZED
C-H
CARBOXYLATION
45
METAL-FREE
C-H
CARBOXYLATION
46
BASE-MEDIATED
C-H
CARBOXYLATION
46
ELECTRO-CATALYZED
C-H
CARBOXYLATION
49
LEWIS
ACID-MEDIATED
CARBOXYLATION
49
LIGHT-DRIVEN
CARBOXYLATION
50
CO
2
CARBOXYLATION
PROMOTED
BY
TRANSITION
METAL
COMPLEXES
52
CONCLUSIONS
53
REFERENCES
53
VI
3
TRANSITION-METAL-CATALYZED
C-H
CARBOXYLATION
59
JOAQUIM
CAN
ER
AND
NOBUHARU
IWASAWA
3.1
INTRODUCTION
59
3.2
DIRECT
C-H
CARBOXYLATION
OF
ELECTRON-DEFICIENT
ARENES
AND
(HETERO)
ARENES
CATALYZED
BY
BASIC
COMPLEXES
59
3.3
DIRECT
CARBOXYLATION
OF
INERT
CSP
2
H
BONDS
66
3.3.1
RHODIUM-CATALYZED
C-H
CARBOXYLATION
REACTIONS
66
3.3.2
PALLADIUM-CATALYZED
C-H
CARBOXYLATION
REACTIONS
76
3.4
DIRECT
CARBOXYLATION
OF
CSP
3
-
H
BONDS
85
3.5
SUMMARY
AND
OUTLOOK
89
REFERENCES
90
4
FIXATION
OF
CO
2
IN
ORGANIC
MOLECULES
WITH
HETEROGENEOUS
CATALYSTS
95
DONGCHENG
HE,
HONGLI
WANG,
AND
FENG
SHI
4.1
INTRODUCTION
95
4.2
CO
2
CYCLOADDITION
TO
EPOXIDE
96
4.2.1
OXIDES
96
4.2.2
ZEOLITE
CATALYSTS
97
4.2.3
SUPPORTED
NANOPARTICLE
AND
LEWIS
ACID
CATALYSTS
98
4.2.4
CARBON
AND
ITS
DERIVATIVES
99
4.2.5
SALEN,
PORPHYRIN,
AND
PHTHALOCYANINE
CATALYST
101
4.2.6
IONIC
LIQUID
CATALYST
103
4.2.7
METAL-ORGANIC
FRAMEWORK
(MOF)
CATALYST
108
4.2.8
BIFUNCTIONAL
CATALYST
112
4.2.9
OTHER
CATALYSTS
120
4.3
REACTIONS
OF
AZIRIDINES
AND
CO2
120
4.4
REACTIONS
OF
POLYALCOHOLS/OLEFINS
AND
CO2
121
4.5
REACTION
OF
PROPARGYL
ALCOHOLS/PROPARGYL
AMINES
AND
CO
2
124
4.6
REACTIONS
OF
TERMINAL
ALKYNES
AND
CO2
125
4.7
FORMYLATION
OF
AMINES
AND
CO2
127
4.8
METHYLATION
OF
AMINES
AND
CO2
130
4.9
OTHER
REACTIONS
OF
AMINES
AND
CO2
131
4.10
HYDROFORMYLATION
OF
CO2
AND
OLEFINS
INTO
ALCOHOLS
133
4.11
REACTIONS
OF
AROMATIC
HALIDES
AND
CO2
134
4.12
REACTIONS
OF
2
AMINOBENZONITRILES
AND
CO2
136
4.13
CONCLUSIONS
137
REFERENCES
138
5
CO
2
FIXATION
INTO
ORGANIC
MOLECULES
VIA
CARBON-HETEROATOM
BOND
FORMATION
155
YU-NONG
LI,
HONG-RU
LI
AND
LIANG-NIAN
HE
5.1
INTRODUCTION
155
5.2
CO2
CONVERSION
WITH
C
-
N
BOND
FORMATION
157
5.2.1
SYNTHESIS
OF
OXAZOLIDINONES
157
5.2.1.1
OXAZOLIDINONE
SYNTHESIS
FROM
AZIRIDINE
AND
CO2
158
VII
5.2.1.2
OXAZOLIDINONE
SYNTHESIS
FROM
OLEFIN,
A
NITROGEN
SOURCE,
ANDCO2
163
5.2.1.3
5.2.1.4
OXAZOLIDINONE
SYNTHESIS
FROM
AMINO
ALCOHOLS
AND
CO2
164
OXAZOLIDINONE
SYNTHESIS
FROM
CARBOXYLATIVE
CYCLIZATION
OF
PROPARGYL
AMINES
WITH
CO2
165
5.2.1.5
OXAZOLIDINONE
SYNTHESIS
FROM
PROPARGYL
ALCOHOL,
ALIPHATIC
AMINES/
2
-AMINOETHANOLS,
AND
CO
2
167
5.2.1.6
PHOTOINDUCED
RADICAL-INITIATED
CARBOXYLATIVE
CYCLIZATION
OF
ALLYL
AMINES WITH
CO2
170
5.2.2
5.2.3
5.2.4
5.3
5.3.1
5.3.1.1
5.3.1.2
SYNTHESIS
OF
ISOCYANATES
AND
LINEAR
CARBAMATES
172
SYNTHESIS
OF
UREA
DERIVATIVES
174
SYNTHESIS
OF
QUINAZOLINES
175
CO2
CONVERSION
WITH
C
-
O
BOND
FORMATION
178
SYNTHESIS
OF
CYCLIC
CARBONATES
178
CYCLIC
CARBONATE
SYNTHESIS
FROM
EPOXIDE
AND
CO2
178
A-ALKYLIDENE
CYCLIC
CARBONATE
SYNTHESIS
FROM
CARBOXYLATIVE
CYCLIZATION
OF
PROPARGYL
ALCOHOLS
WITH
CO2
181
5.3.1.3
CYCLIC
CARBONATE
SYNTHESIS
FROM
CARBOXYLATIVE
CYCLIZATION
OF
1,2-DIOLS
WITH
CO2
182
5.3.1.4
ONE-POT
STEPWISE
SYNTHESIS
OF
CYCLIC
CARBONATES
DIRECTLY
FROM
OLEFINS
OR
VICINAL
HALOHYDRINS
WITH
CO2
183
5.3.2
5.4
5.4.1
5.4.2
5.4.3
5.5
SYNTHESIS
OF
LINEAR
CARBONATES
185
CO2
CONVERSION
WITH
C
-
S
BOND
FORMATION
187
SYNTHESIS
OF
DITHIOACETALS
187
SYNTHESIS
OF
BENZOTHIAZOLONES
188
SYNTHESIS
OF
BENZOTHIAZOLES
189
CARBON-HETEROATOM
BOND
FORMATION
FROM
THE
CAPTURED
CO2
OR
CO2
DERIVATIVES
190
5.6
CONCLUSIONS
191
ABBREVIATIONS
192
REFERENCES
193
6
CARBONYL-ENE
REACTIONS
OF
ALKENES
WITH
CARBON
DIOXIDE
199
YASUYUKI
MORI
AND
MASANARI
KIMURA
6.1
6.2
6.2.1
INTRODUCTION
199
CARBONYL-ENE
REACTIONS
OF
ALKENES
WITH
CO2
199
ORGANOALUMINUM
AND
PYRIDINE
DERIVATIVE-MEDIATED
COUPLING
REACTION
199
6.2.2
LIGHT-INDUCED
COPPER-CATALYZED
CARBOXYLATION
OF
ALLYLIC
C
-
H
BONDS
204
6.2.3
COPPER
AND
ALUMINUM
ATE
COMPOUND
SYSTEM
FOR
CARBOXYLATION
OF
ALLYLIC
C
-
H
BOND
OF
ALKENES
208
6.2.4
COBALT-CATALYZED
CARBOXYLATION
OF
ALLYLIC
C
-
H
BOND
OF
TERMINAL
ALKENES
272
6.2.5
NICKEL-CATALYZED
CARBONYL-ENE-TYPE
REACTION
OF
TERMINAL
ALKENES
WITH
CO
2
277
REFERENCES
223
VIII
J
7
RECENT
ADVANCES
IN
ELECTROCHEMICAL
CARBOXYLATION
OF
ORGANIC
COMPOUNDS
FOR
CO
2
VALORIZATION
225
LUCA
DELL AMICO,
MARCELLA
BONCHIO,
AND
XAVIER
COMPANYO
7.1
INTRODUCTION
225
7.2
ELECTROCHEMICAL
CARBOXYLATION
OF
UNSATURATED
COMPOUNDS
228
73
ELECTROCHEMICAL
CARBOXYLATION
OF
ORGANIC
HALIDES
236
7.4
STEREOSELECTIVE
ELECTROCHEMICAL
CARBOXYLATIONS
245
7.5
CONCLUSIONS
249
REFERENCES
250
8
PHOTOCATALYSIS
AS
A
POWERFUL
TOOL
FOR
THE
UTILIZATION
OF
CO
2
IN
ORGANIC
SYNTHESIS
253
DANIEL
RIEMER
AND
SHOUBHIK
DAS
8.1
KEY
INTERMEDIATE
INVOLVING
SUBSTRATE
WITH
LATE-STAGE
CO
2
ADDITION/
INSERTION
254
8.1.1
UNSATURATED
SUBSTRATES
254
8.1.2
ARYL
HALIDES
264
8.1.3
BENZYLIC
C
-
H
BONDS
267
8.2
CO
2
SUBSTRATE
ADDUCT
AS
THE
KEY
INTERMEDIATE
269
8.3
CO2
RADICAL
ANION
AS
A
KEY
INTERMEDIATE
276
8.4
HYDROXYCARBONYL
RADICAL
AS
A
KEY
INTERMEDIATE
282
8.5
CONCLUSION
AND
OUTLOOK
284
REFERENCES
285
9
DIRECT
CARBOXYLATION
OF
ALKENES
AND
ALKYNES
291
MARTIN
PICHETTE
DRAPEAU,
JOHANNES
SCHRANCK,
AND
AN
IS
TLILI
9.1
INTRODUCTION
291
9.2
CARBOXYLATION
OF
ALKENES
291
9.2.1
STOICHIOMETRIC
CARBOXYLATION
OF
ALKENES
291
9.2.2
CATALYTIC
HYDROCARBOXYLATION
OF
ALKENES
295
9.2.3
PHOTOINDUCED
HYDROCARBOXYLATION
OF
ALKENES
300
9.2.4
DIFUNCTIONALIZATION
OF
ALKENES
WITH
CARBON
DIOXIDE
304
9.3
CARBOXYLATION
OF
ALKYNES
305
9.3.1
CARBOXYLATION
OF
TERMINAL
ALKYNES
305
9.3.1.1
SYNTHESIS
OF
PROPIOLIC
ESTERS
305
9.3.1.2
SYNTHESIS
OF
PROPIOLIC
ACIDS
308
9.3.2
SYNTHESIS
OF
ACRYLIC
ACID
DERIVATIVES
316
9.3.2.1
HYDROCARBOXYLATION
316
93.2.2
ALKYL
AND
ARYLCARBOXYLATIONS
321
93,23
SILA
AND
BORACARBOXYLATIONS
323
9.3.3
CARBOXYLATION
LEADING
TO
CYCLIZATION
PRODUCTS
324
9.4
CONCLUSIONS
326
REFERENCES
327
IX
10
HOMOGENEOUS
IRON
CATALYSTS
FOR
THE
SYNTHESIS
OF
USEFUL
MOLECULES
FROM
CO
2
331
FRANCESCO
DELLA
MONICA
AND
CARMINE
CAPACCHIONE
10.1
10.2
10.2.1
10.2.2
10.2.3
10.3
10.3.1
INTRODUCTION
331
REDUCTIVE
PROCESSES
332
HYDROGENATION
332
HYDROSILYLATION
AND
HYDROBORATION
335
MECHANISTIC
DETAILS
336
NONREDUCTIVE
PROCESSES
337
CYCLIC
ORGANIC
CARBONATES
AND
ALIPHATIC
POLYCARBONATES
FROM
CO
2
AND
EPOXIDES
337
10.3.2
10.3.3
10.3.4
10.4
MECHANISTIC
DETAILS
346
STEREOCHEMISTRY
OF
CYCLIC
ORGANIC
CARBONATES
354
OXAZOLIDINONES
358
CONCLUSIONS
360
REFERENCES
360
11
NHC-CATALYZED
CO
2
FIXATIONS
IN
ORGANIC
SYNTHESIS
367
VLSHAKHA
GOYAL,
NAINA
SARKI,
ANAND
NARANI,
AND
KISHORE
NATTE
11.1
11.2
11.2.1
11.2.2
11.2.3
11.3
11.4
11.4.1
11.4.2
11.4.3
11.4.4
11.5
11.5.1
11.5.2
11.6
11.7
INTRODUCTION
367
DIRECT
C-H
ACTIVATION
WITH
CO
2
369
C-H
ACTIVATION
OF
TERMINAL
ALKYNES
369
CARBOXYLATION
OF
ARENES
AND
HETEROARENES
373
CARBOXYLATION
OF
ALKENES
AND
ORGANOBORONIC
ESTERS
376
OXIDATION
OF
ALDEHYDES
WITH
CO
2
376
CYCLIZATION
REACTIONS
WITH
CO
2
379
SYNTHESIS
OF
CYCLIC
CARBONATES
FROM
CO
2
AND
EPOXIDES
379
CYCLIZATION
OF
CO
2
IN
PRESENCE
OF
NHC-CO
2
ADDUCTS
380
CYCLIZATION
OF
CO
2
IN
PRESENCE
OF
METAL
NHCS
COMPLEXES
382
CYCLIZATION
OF
PROPARGYLIC
AMINES
385
ALKYLATION
WITH
CO
2
387
N-METHYLATION
387
N-FORMYLATION
388
MISCELLANEOUS
390
SUMMARY
393
REFERENCES
393
12
SILVER-CATALYZED
CO
2
FIXATION
397
KODAI
SAITO
AND
TOHRU
YAMADA
12.1
12.2
INTRODUCTION
397
HISTORICAL
BACKGROUND
OF
CARBON
DIOXIDE
FIXATION
INTO
ORGANOSILVER
COMPLEXES
398
12.3
12.4
12.5
CARBOXYLATION
OF
TERMINAL
ALKYNES
399
CASCADE
CARBOXYLATIVE CYCLIZATION
404
SILVER-CATALYZED
SEQUENTIAL
CARBOXYLATIVE
CYCLIZATION
OF
PROPARGYL
ALCOHOLS
405
12.6
SYNTHESIS
OF
CYCLIC
CARBONATE
405
12.7
CATALYTIC
ASYMMETRIC
SYNTHESIS
OF
CYCLIC
CARBONATE
411
12.8
THREE-COMPONENT
REACTION
OF
PROPARGYL
ALCOHOLS,
CARBON
DIOXIDE,
AND
NUCLEOPHILES
411
12.9
CCVMEDIATED
TRANSFORMATION
OF
PROPARGYL
ALCOHOLS
412
12.10
TRANSFORMATION
OF
AMINE
DERIVATIVES
417
12.11
CASCADE
CARBOXYLATION
AND
CYCLIZATION
OF
UNSATURATED
AMINE
DERIVATIVES
417
12.11.1
BENZOXAZINE-2-ONE
FROM
O-ALKYNYLANILINE
AND
CARBON
DIOXIDE
418
12.11.2
CASCADE
CARBOXYLATION
-
ADDITION
TO
ALLENES
418
12.11.3
THREE-COMPONENT
REACTION
OF
CARBON
DIOXIDE,
AMINES,
AND
ARYLOXYALLENS
419
12.12
DOMINO
CARBOXYLATION
-
CYCLIZATION
-
MIGRATION
OF
UNSATURATED
AMINES
421
12.12.1
CARBOXYLATION
INVOLVING
C
-
C
BOND
FORMATION
-
SEQUENTIAL
CYCLIZATION
423
12.12.2
CARBOXYLATION
OF
ENOLATE
-
SEQUENTIAL
CYCLIZATION
423
12.12.3
CARBON
DIOXIDE
INCORPORATION
REACTION
USING
OTHER
CARBANIONS
427
12.13
CARBOXYLATION
OF
ARYLBORONIC
ESTERS
428
12.13.1
FUNCTIONALIZATION
OF
TERMINAL
EPOXIDES
431
12.14
CONCLUSION
432
REFERENCES
433
INDEX
437
|
adam_txt |
CONTENTS
1
PHOTOCHEMICAL
AND
SUBSTRATE-DRIVEN
CO
2
CONVERSION
1
BART
LIMBURG,
CRISTINA
MAQUILON,
AND
ARJAN
W.
KLEIJ
1.1
1.2
1.3
INTRODUCTION
1
IODINE
ACTIVATION
OF
(HOMO)ALLYLIC
SUBSTRATES
3
SUBSTRATE
ACTIVATION
VIA
RADICAL
ADDITION/PHOTOCHEMICAL
OXIDATION
PROCESSES
9
1.4
1.5
1.6
SUBSTRATE-INDUCED
ACTIVATION
OF
OXIRANES
12
SUBSTRATE-INVOLVED ACTIVATION
OF
OXETANES
AND
AZETIDINES
21
CONCLUDING
REMARKS
21
REFERENCES
22
2
C-H
CARBOXYLATIONS
WITH
CO
2
29
UTTAM
DHAWA,
ISAAC
CHOI,
AND
LUTZ
ACKERMANN
2.1
2.2
2.2.1
2.2.2
2.2.3
2.2.4
2.2.5
2.2.6
2.2.7
2.2.8
2.2.9
2.2.10
2.2.11
2.3
2.3.1
2.3.2
2.3.3
2.3.4
2.4
2.5
INTRODUCTION
29
TRANSITION-METAL-CATALYZED
C-H
CARBOXYLATION
30
COPPER-CATALYZED
C-H
CARBOXYLATION
30
COBALT-CATALYZED
C-H
CARBOXYLATION
36
NICKEL-CATALYZED
C-H
CARBOXYLATION
36
MOLYBDENUM-CATALYZED
C-H
CARBOXYLATION
38
RUTHENIUM-CATALYZED
C-H
CARBOXYLATION
38
RHODIUM-CATALYZED
C-H
CARBOXYLATION
39
PALLADIUM-CATALYZED
C-H
CARBOXYLATION
41
SILVER-CATALYZED
C-H
CARBOXYLATION
42
IRIDIUM-CATALYZED
C-H
CARBOXYLATION
45
GOLD-CATALYZED
C-H
CARBOXYLATION
45
NEODYMIUM-CATALYZED
C-H
CARBOXYLATION
45
METAL-FREE
C-H
CARBOXYLATION
46
BASE-MEDIATED
C-H
CARBOXYLATION
46
ELECTRO-CATALYZED
C-H
CARBOXYLATION
49
LEWIS
ACID-MEDIATED
CARBOXYLATION
49
LIGHT-DRIVEN
CARBOXYLATION
50
CO
2
CARBOXYLATION
PROMOTED
BY
TRANSITION
METAL
COMPLEXES
52
CONCLUSIONS
53
REFERENCES
53
VI
3
TRANSITION-METAL-CATALYZED
C-H
CARBOXYLATION
59
JOAQUIM
CAN
ER
AND
NOBUHARU
IWASAWA
3.1
INTRODUCTION
59
3.2
DIRECT
C-H
CARBOXYLATION
OF
ELECTRON-DEFICIENT
ARENES
AND
(HETERO)
ARENES
CATALYZED
BY
BASIC
COMPLEXES
59
3.3
DIRECT
CARBOXYLATION
OF
INERT
CSP
2
"
H
BONDS
66
3.3.1
RHODIUM-CATALYZED
C-H
CARBOXYLATION
REACTIONS
66
3.3.2
PALLADIUM-CATALYZED
C-H
CARBOXYLATION
REACTIONS
76
3.4
DIRECT
CARBOXYLATION
OF
CSP
3
-
H
BONDS
85
3.5
SUMMARY
AND
OUTLOOK
89
REFERENCES
90
4
FIXATION
OF
CO
2
IN
ORGANIC
MOLECULES
WITH
HETEROGENEOUS
CATALYSTS
95
DONGCHENG
HE,
HONGLI
WANG,
AND
FENG
SHI
4.1
INTRODUCTION
95
4.2
CO
2
CYCLOADDITION
TO
EPOXIDE
96
4.2.1
OXIDES
96
4.2.2
ZEOLITE
CATALYSTS
97
4.2.3
SUPPORTED
NANOPARTICLE
AND
LEWIS
ACID
CATALYSTS
98
4.2.4
CARBON
AND
ITS
DERIVATIVES
99
4.2.5
SALEN,
PORPHYRIN,
AND
PHTHALOCYANINE
CATALYST
101
4.2.6
IONIC
LIQUID
CATALYST
103
4.2.7
METAL-ORGANIC
FRAMEWORK
(MOF)
CATALYST
108
4.2.8
BIFUNCTIONAL
CATALYST
112
4.2.9
OTHER
CATALYSTS
120
4.3
REACTIONS
OF
AZIRIDINES
AND
CO2
120
4.4
REACTIONS
OF
POLYALCOHOLS/OLEFINS
AND
CO2
121
4.5
REACTION
OF
PROPARGYL
ALCOHOLS/PROPARGYL
AMINES
AND
CO
2
124
4.6
REACTIONS
OF
TERMINAL
ALKYNES
AND
CO2
125
4.7
FORMYLATION
OF
AMINES
AND
CO2
127
4.8
METHYLATION
OF
AMINES
AND
CO2
130
4.9
OTHER
REACTIONS
OF
AMINES
AND
CO2
131
4.10
HYDROFORMYLATION
OF
CO2
AND
OLEFINS
INTO
ALCOHOLS
133
4.11
REACTIONS
OF
AROMATIC
HALIDES
AND
CO2
134
4.12
REACTIONS
OF
2
AMINOBENZONITRILES
AND
CO2
136
4.13
CONCLUSIONS
137
REFERENCES
138
5
CO
2
FIXATION
INTO
ORGANIC
MOLECULES
VIA
CARBON-HETEROATOM
BOND
FORMATION
155
YU-NONG
LI,
HONG-RU
LI
AND
LIANG-NIAN
HE
5.1
INTRODUCTION
155
5.2
CO2
CONVERSION
WITH
C
-
N
BOND
FORMATION
157
5.2.1
SYNTHESIS
OF
OXAZOLIDINONES
157
5.2.1.1
OXAZOLIDINONE
SYNTHESIS
FROM
AZIRIDINE
AND
CO2
158
VII
5.2.1.2
OXAZOLIDINONE
SYNTHESIS
FROM
OLEFIN,
A
NITROGEN
SOURCE,
ANDCO2
163
5.2.1.3
5.2.1.4
OXAZOLIDINONE
SYNTHESIS
FROM
AMINO
ALCOHOLS
AND
CO2
164
OXAZOLIDINONE
SYNTHESIS
FROM
CARBOXYLATIVE
CYCLIZATION
OF
PROPARGYL
AMINES
WITH
CO2
165
5.2.1.5
OXAZOLIDINONE
SYNTHESIS
FROM
PROPARGYL
ALCOHOL,
ALIPHATIC
AMINES/
2
-AMINOETHANOLS,
AND
CO
2
167
5.2.1.6
PHOTOINDUCED
RADICAL-INITIATED
CARBOXYLATIVE
CYCLIZATION
OF
ALLYL
AMINES WITH
CO2
170
5.2.2
5.2.3
5.2.4
5.3
5.3.1
5.3.1.1
5.3.1.2
SYNTHESIS
OF
ISOCYANATES
AND
LINEAR
CARBAMATES
172
SYNTHESIS
OF
UREA
DERIVATIVES
174
SYNTHESIS
OF
QUINAZOLINES
175
CO2
CONVERSION
WITH
C
-
O
BOND
FORMATION
178
SYNTHESIS
OF
CYCLIC
CARBONATES
178
CYCLIC
CARBONATE
SYNTHESIS
FROM
EPOXIDE
AND
CO2
178
A-ALKYLIDENE
CYCLIC
CARBONATE
SYNTHESIS
FROM
CARBOXYLATIVE
CYCLIZATION
OF
PROPARGYL
ALCOHOLS
WITH
CO2
181
5.3.1.3
CYCLIC
CARBONATE
SYNTHESIS
FROM
CARBOXYLATIVE
CYCLIZATION
OF
1,2-DIOLS
WITH
CO2
182
5.3.1.4
ONE-POT
STEPWISE
SYNTHESIS
OF
CYCLIC
CARBONATES
DIRECTLY
FROM
OLEFINS
OR
VICINAL
HALOHYDRINS
WITH
CO2
183
5.3.2
5.4
5.4.1
5.4.2
5.4.3
5.5
SYNTHESIS
OF
LINEAR
CARBONATES
185
CO2
CONVERSION
WITH
C
-
S
BOND
FORMATION
187
SYNTHESIS
OF
DITHIOACETALS
187
SYNTHESIS
OF
BENZOTHIAZOLONES
188
SYNTHESIS
OF
BENZOTHIAZOLES
189
CARBON-HETEROATOM
BOND
FORMATION
FROM
THE
CAPTURED
CO2
OR
CO2
DERIVATIVES
190
5.6
CONCLUSIONS
191
ABBREVIATIONS
192
REFERENCES
193
6
CARBONYL-ENE
REACTIONS
OF
ALKENES
WITH
CARBON
DIOXIDE
199
YASUYUKI
MORI
AND
MASANARI
KIMURA
6.1
6.2
6.2.1
INTRODUCTION
199
CARBONYL-ENE
REACTIONS
OF
ALKENES
WITH
CO2
199
ORGANOALUMINUM
AND
PYRIDINE
DERIVATIVE-MEDIATED
COUPLING
REACTION
199
6.2.2
LIGHT-INDUCED
COPPER-CATALYZED
CARBOXYLATION
OF
ALLYLIC
C
-
H
BONDS
204
6.2.3
COPPER
AND
ALUMINUM
ATE
COMPOUND
SYSTEM
FOR
CARBOXYLATION
OF
ALLYLIC
C
-
H
BOND
OF
ALKENES
208
6.2.4
COBALT-CATALYZED
CARBOXYLATION
OF
ALLYLIC
C
-
H
BOND
OF
TERMINAL
ALKENES
272
6.2.5
NICKEL-CATALYZED
CARBONYL-ENE-TYPE
REACTION
OF
TERMINAL
ALKENES
WITH
CO
2
277
REFERENCES
223
VIII
J
7
RECENT
ADVANCES
IN
ELECTROCHEMICAL
CARBOXYLATION
OF
ORGANIC
COMPOUNDS
FOR
CO
2
VALORIZATION
225
LUCA
DELL'AMICO,
MARCELLA
BONCHIO,
AND
XAVIER
COMPANYO
7.1
INTRODUCTION
225
7.2
ELECTROCHEMICAL
CARBOXYLATION
OF
UNSATURATED
COMPOUNDS
228
73
ELECTROCHEMICAL
CARBOXYLATION
OF
ORGANIC
HALIDES
236
7.4
STEREOSELECTIVE
ELECTROCHEMICAL
CARBOXYLATIONS
245
7.5
CONCLUSIONS
249
REFERENCES
250
8
PHOTOCATALYSIS
AS
A
POWERFUL
TOOL
FOR
THE
UTILIZATION
OF
CO
2
IN
ORGANIC
SYNTHESIS
253
DANIEL
RIEMER
AND
SHOUBHIK
DAS
8.1
KEY
INTERMEDIATE
INVOLVING
SUBSTRATE
WITH
LATE-STAGE
CO
2
ADDITION/
INSERTION
254
8.1.1
UNSATURATED
SUBSTRATES
254
8.1.2
ARYL
HALIDES
264
8.1.3
BENZYLIC
C
-
H
BONDS
267
8.2
CO
2
SUBSTRATE
ADDUCT
AS
THE
KEY
INTERMEDIATE
269
8.3
CO2
RADICAL
ANION
AS
A
KEY
INTERMEDIATE
276
8.4
HYDROXYCARBONYL
RADICAL
AS
A
KEY
INTERMEDIATE
282
8.5
CONCLUSION
AND
OUTLOOK
284
REFERENCES
285
9
DIRECT
CARBOXYLATION
OF
ALKENES
AND
ALKYNES
291
MARTIN
PICHETTE
DRAPEAU,
JOHANNES
SCHRANCK,
AND
AN
IS
TLILI
9.1
INTRODUCTION
291
9.2
CARBOXYLATION
OF
ALKENES
291
9.2.1
STOICHIOMETRIC
CARBOXYLATION
OF
ALKENES
291
9.2.2
CATALYTIC
HYDROCARBOXYLATION
OF
ALKENES
295
9.2.3
PHOTOINDUCED
HYDROCARBOXYLATION
OF
ALKENES
300
9.2.4
DIFUNCTIONALIZATION
OF
ALKENES
WITH
CARBON
DIOXIDE
304
9.3
CARBOXYLATION
OF
ALKYNES
305
9.3.1
CARBOXYLATION
OF
TERMINAL
ALKYNES
305
9.3.1.1
SYNTHESIS
OF
PROPIOLIC
ESTERS
305
9.3.1.2
SYNTHESIS
OF
PROPIOLIC
ACIDS
308
9.3.2
SYNTHESIS
OF
ACRYLIC
ACID
DERIVATIVES
316
9.3.2.1
HYDROCARBOXYLATION
316
93.2.2
ALKYL
AND
ARYLCARBOXYLATIONS
321
93,23
SILA
AND
BORACARBOXYLATIONS
323
9.3.3
CARBOXYLATION
LEADING
TO
CYCLIZATION
PRODUCTS
324
9.4
CONCLUSIONS
326
REFERENCES
327
IX
10
HOMOGENEOUS
IRON
CATALYSTS
FOR
THE
SYNTHESIS
OF
USEFUL
MOLECULES
FROM
CO
2
331
FRANCESCO
DELLA
MONICA
AND
CARMINE
CAPACCHIONE
10.1
10.2
10.2.1
10.2.2
10.2.3
10.3
10.3.1
INTRODUCTION
331
REDUCTIVE
PROCESSES
332
HYDROGENATION
332
HYDROSILYLATION
AND
HYDROBORATION
335
MECHANISTIC
DETAILS
336
NONREDUCTIVE
PROCESSES
337
CYCLIC
ORGANIC
CARBONATES
AND
ALIPHATIC
POLYCARBONATES
FROM
CO
2
AND
EPOXIDES
337
10.3.2
10.3.3
10.3.4
10.4
MECHANISTIC
DETAILS
346
STEREOCHEMISTRY
OF
CYCLIC
ORGANIC
CARBONATES
354
OXAZOLIDINONES
358
CONCLUSIONS
360
REFERENCES
360
11
NHC-CATALYZED
CO
2
FIXATIONS
IN
ORGANIC
SYNTHESIS
367
VLSHAKHA
GOYAL,
NAINA
SARKI,
ANAND
NARANI,
AND
KISHORE
NATTE
11.1
11.2
11.2.1
11.2.2
11.2.3
11.3
11.4
11.4.1
11.4.2
11.4.3
11.4.4
11.5
11.5.1
11.5.2
11.6
11.7
INTRODUCTION
367
DIRECT
C-H
ACTIVATION
WITH
CO
2
369
C-H
ACTIVATION
OF
TERMINAL
ALKYNES
369
CARBOXYLATION
OF
ARENES
AND
HETEROARENES
373
CARBOXYLATION
OF
ALKENES
AND
ORGANOBORONIC
ESTERS
376
OXIDATION
OF
ALDEHYDES
WITH
CO
2
376
CYCLIZATION
REACTIONS
WITH
CO
2
379
SYNTHESIS
OF
CYCLIC
CARBONATES
FROM
CO
2
AND
EPOXIDES
379
CYCLIZATION
OF
CO
2
IN
PRESENCE
OF
NHC-CO
2
ADDUCTS
380
CYCLIZATION
OF
CO
2
IN
PRESENCE
OF
METAL
NHCS
COMPLEXES
382
CYCLIZATION
OF
PROPARGYLIC
AMINES
385
ALKYLATION
WITH
CO
2
387
N-METHYLATION
387
N-FORMYLATION
388
MISCELLANEOUS
390
SUMMARY
393
REFERENCES
393
12
SILVER-CATALYZED
CO
2
FIXATION
397
KODAI
SAITO
AND
TOHRU
YAMADA
12.1
12.2
INTRODUCTION
397
HISTORICAL
BACKGROUND
OF
CARBON
DIOXIDE
FIXATION
INTO
ORGANOSILVER
COMPLEXES
398
12.3
12.4
12.5
CARBOXYLATION
OF
TERMINAL
ALKYNES
399
CASCADE
CARBOXYLATIVE CYCLIZATION
404
SILVER-CATALYZED
SEQUENTIAL
CARBOXYLATIVE
CYCLIZATION
OF
PROPARGYL
ALCOHOLS
405
12.6
SYNTHESIS
OF
CYCLIC
CARBONATE
405
12.7
CATALYTIC
ASYMMETRIC
SYNTHESIS
OF
CYCLIC
CARBONATE
411
12.8
THREE-COMPONENT
REACTION
OF
PROPARGYL
ALCOHOLS,
CARBON
DIOXIDE,
AND
NUCLEOPHILES
411
12.9
CCVMEDIATED
TRANSFORMATION
OF
PROPARGYL
ALCOHOLS
412
12.10
TRANSFORMATION
OF
AMINE
DERIVATIVES
417
12.11
CASCADE
CARBOXYLATION
AND
CYCLIZATION
OF
UNSATURATED
AMINE
DERIVATIVES
417
12.11.1
BENZOXAZINE-2-ONE
FROM
O-ALKYNYLANILINE
AND
CARBON
DIOXIDE
418
12.11.2
CASCADE
CARBOXYLATION
-
ADDITION
TO
ALLENES
418
12.11.3
THREE-COMPONENT
REACTION
OF
CARBON
DIOXIDE,
AMINES,
AND
ARYLOXYALLENS
419
12.12
DOMINO
CARBOXYLATION
-
CYCLIZATION
-
MIGRATION
OF
UNSATURATED
AMINES
421
12.12.1
CARBOXYLATION
INVOLVING
C
-
C
BOND
FORMATION
-
SEQUENTIAL
CYCLIZATION
423
12.12.2
CARBOXYLATION
OF
ENOLATE
-
SEQUENTIAL
CYCLIZATION
423
12.12.3
CARBON
DIOXIDE
INCORPORATION
REACTION
USING
OTHER
CARBANIONS
427
12.13
CARBOXYLATION
OF
ARYLBORONIC
ESTERS
428
12.13.1
FUNCTIONALIZATION
OF
TERMINAL
EPOXIDES
431
12.14
CONCLUSION
432
REFERENCES
433
INDEX
437 |
any_adam_object | 1 |
any_adam_object_boolean | 1 |
author2 | Das, Shoubhik 1980- |
author2_role | edt |
author2_variant | s d sd |
author_GND | (DE-588)1018978429 |
author_facet | Das, Shoubhik 1980- |
building | Verbundindex |
bvnumber | BV046885778 |
classification_rvk | VK 5500 VK 6000 |
ctrlnum | (OCoLC)1289788406 (DE-599)DNB1207012084 |
discipline | Chemie / Pharmazie |
discipline_str_mv | Chemie / Pharmazie |
format | Book |
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genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
genre_facet | Aufsatzsammlung |
id | DE-604.BV046885778 |
illustrated | Illustrated |
index_date | 2024-07-03T15:19:30Z |
indexdate | 2024-07-10T08:56:33Z |
institution | BVB |
institution_GND | (DE-588)16179388-5 |
isbn | 9783527346134 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-032295695 |
oclc_num | 1289788406 |
open_access_boolean | |
owner | DE-11 DE-29T DE-19 DE-BY-UBM |
owner_facet | DE-11 DE-29T DE-19 DE-BY-UBM |
physical | x, 453 Seiten Illustrationen |
publishDate | 2020 |
publishDateSearch | 2020 |
publishDateSort | 2020 |
publisher | Wiley-VCH |
record_format | marc |
spelling | CO2 as a building block in organic synthesis edited by Shoubhik Das Weinheim Wiley-VCH [2020] © 2020 x, 453 Seiten Illustrationen txt rdacontent n rdamedia nc rdacarrier Die 2 im Titel ist tiefgestellt Kohlendioxid (DE-588)4031648-8 gnd rswk-swf Carboxylierung (DE-588)4205211-7 gnd rswk-swf Anorganische Chemie Chemie Chemistry CO2 Inorganic Chemistry Kohlendioxid Methods - Synthesis & Techniques Organische Chemie / Methoden, Synthesen, Verfahren Pharmaceutical & Medicinal Chemistry Pharmazeutische u. Medizinische Chemie CH60: Pharmazeutische u. Medizinische Chemie CH70: Anorganische Chemie CH81: Organische Chemie / Methoden, Synthesen, Verfahren (DE-588)4143413-4 Aufsatzsammlung gnd-content Kohlendioxid (DE-588)4031648-8 s Carboxylierung (DE-588)4205211-7 s DE-604 Das, Shoubhik 1980- (DE-588)1018978429 edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-82194-5 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-82196-9 Erscheint auch als Online-Ausgabe, OBOOK 978-3-527-82195-2 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34613-4/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032295695&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | CO2 as a building block in organic synthesis Kohlendioxid (DE-588)4031648-8 gnd Carboxylierung (DE-588)4205211-7 gnd |
subject_GND | (DE-588)4031648-8 (DE-588)4205211-7 (DE-588)4143413-4 |
title | CO2 as a building block in organic synthesis |
title_auth | CO2 as a building block in organic synthesis |
title_exact_search | CO2 as a building block in organic synthesis |
title_exact_search_txtP | CO2 as a building block in organic synthesis |
title_full | CO2 as a building block in organic synthesis edited by Shoubhik Das |
title_fullStr | CO2 as a building block in organic synthesis edited by Shoubhik Das |
title_full_unstemmed | CO2 as a building block in organic synthesis edited by Shoubhik Das |
title_short | CO2 as a building block in organic synthesis |
title_sort | co2 as a building block in organic synthesis |
topic | Kohlendioxid (DE-588)4031648-8 gnd Carboxylierung (DE-588)4205211-7 gnd |
topic_facet | Kohlendioxid Carboxylierung Aufsatzsammlung |
url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34613-4/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032295695&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT dasshoubhik co2asabuildingblockinorganicsynthesis AT wileyvch co2asabuildingblockinorganicsynthesis |