Neue Konzepte in der asymmetrischen Goldkatalyse:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | German English |
| Veröffentlicht: |
Heidelberg
[2019]
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Inhaltsverzeichnis |
| Beschreibung: | VI, 427 Seiten Illustrationen, Diagramme 30 cm |
Internformat
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| 245 | 1 | 0 | |a Neue Konzepte in der asymmetrischen Goldkatalyse |c vorgelegt von M. Sc. Jürgen Schulmeister ; Gutachter: Prof. Dr. A. Stephen K. Hashmi, Prof. Dr. Uwe H. F. Bunz |
| 264 | 1 | |a Heidelberg |c [2019] | |
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| 546 | |a Text Deutsch, experimenteller Teil in englischer Sprache | ||
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Datensatz im Suchindex
| _version_ | 1804181711629582336 |
|---|---|
| adam_text | INHALTSVERZEICHNIS
1
VEROEFFENTLICHUNGEN
...........................................................................................................................
I
2
ABKUERZUNGSVERZEICHNIS
..................................................................................................................
II
3
KURZZUSAMMENFASSUNG
..................................................................................................................
V
4
ABSTRACT
...........................................................................................................................................
VI
5
EINLEITUNG
.........................................................................................................................................
1
6
KENNTNISSTAND
.................................................................................................................................
3
6.1
SUBSTRATKONTROLLE
......................................................................................................................
3
6.2
REAGENZKONTROLLE
.....................................................................................................................
5
6.2.1
CHIRALE
PHOSPHAN-LIGANDEN
...............................................................................................................
6
6.2.2 CHIRALE
GEGENANIONEN
.......................................................................................................................
11
6.2.3 CHIRALE
CARBEN-LIGANDEN
...................................................................................................................
13
6.2.4 CHIRALE
GOLD(LLL)-KOMPLEXE
................................................................................................................
17
7
ERGEBNISSE
UND
DISKUSSION
.........................................................................................................
19
7.1
MOTIVATION
..............................................................................................................................
19
7.2
AUFBAU
DER
KATALYSATOR-BIBLIOTHEK
.........................................................................................
26
7.2.1
SYNTHESE
VON
SS-AMINOSAEUREESTERN
2
UEBER
DIE
PICTET-SPENGLER-REAKTION
.........................................
26
7.2.2
SYNTHESE
VON
NHOC
GOLD(L--KOMPLEXEN
6
........................................................................................
34
7.2.3 SYNTHESE
VON
ENOLDERIVATEN
DER
NHOC-GOLD(L)-KOMPLEXE
8
...........................................................
41
7.2.4 SYNTHESE
VON
SS-AMINOALKOHOLEN
3
....................................................................................................
44
7.2.5
SYNTHESE
VON
HYDROXY-NAC
GOLD(L)-KOMPLEXEN
4
............................................................................
46
7.2.6
SYNTHESE
VON
HYDROXY-GESCHUETZTEN
DERIVATEN
DER
NAC
GOLD(L)-KOMPLEXE
7
...................................
53
7.2.7 SYNTHESE
VON
NHC
GOLD(L)-KOMPLEXEN
5
..........................................................................................
55
7.3
QUANTENCHEMISCHE
BERECHNUNG
DER
NMR
VERSCHIEBUNGEN
ZUR
BESTIMMUNG
DER
ABSOLUTEN
KONFIGURATION
.......................................................................................................................................
66
7.4
ZWISCHENRESUEMEE
...................................................................................................................
78
7.5
ASYMMETRISCHE
GOLDKATALYSE
................................................................................................
81
8
ZUSAMMENFASSUNG
UND
AUSBLICK
................................................................................................
92
9
EXPERIMENTELLER
TEIL
/
EXPERIMENTAL
SECTION
.............................................................................
96
9.1
GENERAL
REMARKS
.....................................................................................................................
96
9.2
SYNTHESIS
OF
TRYPTOPHAN-BASED
GOLD(L)
CARBENE
COMPLEXES
...................................................
99
9.2.1
LABELING
.............................................................................................................................................
99
9.2.2
SYNTHESIS
OF
SS-AMINO
ACID
ESTERS
2
..................................................................................................
102
9.2.3
SYNTHESIS
OF
SS-AMINO
ALCOHOLS
3
......................................................................................................
145
9.2.4
SYNTHESIS
OF
HYDROXYL-NAC
GOLD(L)
COMPLEXES
4
.............................................................................
183
9.2.5
SYNTHESIS
OF
NHC
GOLD(L)
COMPLEXES
5
(WITH
A
SATURATED
BACKBONE)
..............................................
221
9.2.6
SYNTHESIS
OF
NHOC
GOLD(L)
COMPLEXES
6
.........................................................................................
275
9.2.7
SYNTHESIS
OF
HYDROXYL-PROTECTED
NAC
GOLD(L)
COMPLEXES
7
............................................................
292
9.2.8
SYNTHESIS
OF
THE
ENOLIZED
NHOC
GOLD(L)
COMPLEX
8C
S
A
..................................................................
304
9.2.9
MISCELLANEOUS
SYNTHESIZED
COMPOUNDS
...........................................................................................
309
9.3
ASYMMETRIE
GOLD
CATALYSIS
....................................................................................................
321
9.3.1
SUBSTRATE
A
(REARRANGEMENT
OF
PROPARGYL
PIVALATES)
.....................................................................
321
9.3.2
SUBSTRATE
*B
(CYCLOISOMERIZATION
OF
1
,6-ENYNES)
.............................................................................
353
9.3.3
SUBSTRATE
C
(CYCLOPROPANATION)
.......................................................................................................
371
9.3.4
SUBSTRATE
D
(METHOXYCYCLIZATION
OF
1
,6-ENYNES)
.............................................................................
393
9.3.5
SUBSTRATE
(HYDROXYCARBOXYLATION
OF
ALLENES)
...............................................................................
411
10
DANKSAGUNG
............................................................................................................................
420
11
ANHANG
....................................................................................................................................
422
12
LITERATURVERZEICHNIS
...............................................................................................................
423
|
| adam_txt |
INHALTSVERZEICHNIS
1
VEROEFFENTLICHUNGEN
.
I
2
ABKUERZUNGSVERZEICHNIS
.
II
3
KURZZUSAMMENFASSUNG
.
V
4
ABSTRACT
.
VI
5
EINLEITUNG
.
1
6
KENNTNISSTAND
.
3
6.1
SUBSTRATKONTROLLE
.
3
6.2
REAGENZKONTROLLE
.
5
6.2.1
CHIRALE
PHOSPHAN-LIGANDEN
.
6
6.2.2 CHIRALE
GEGENANIONEN
.
11
6.2.3 CHIRALE
CARBEN-LIGANDEN
.
13
6.2.4 CHIRALE
GOLD(LLL)-KOMPLEXE
.
17
7
ERGEBNISSE
UND
DISKUSSION
.
19
7.1
MOTIVATION
.
19
7.2
AUFBAU
DER
KATALYSATOR-BIBLIOTHEK
.
26
7.2.1
SYNTHESE
VON
SS-AMINOSAEUREESTERN
2
UEBER
DIE
PICTET-SPENGLER-REAKTION
.
26
7.2.2
SYNTHESE
VON
NHOC
GOLD(L--KOMPLEXEN
6
.
34
7.2.3 SYNTHESE
VON
ENOLDERIVATEN
DER
NHOC-GOLD(L)-KOMPLEXE
8
.
41
7.2.4 SYNTHESE
VON
SS-AMINOALKOHOLEN
3
.
44
7.2.5
SYNTHESE
VON
HYDROXY-NAC
GOLD(L)-KOMPLEXEN
4
.
46
7.2.6
SYNTHESE
VON
HYDROXY-GESCHUETZTEN
DERIVATEN
DER
NAC
GOLD(L)-KOMPLEXE
7
.
53
7.2.7 SYNTHESE
VON
NHC
GOLD(L)-KOMPLEXEN
5
.
55
7.3
QUANTENCHEMISCHE
BERECHNUNG
DER
NMR
VERSCHIEBUNGEN
ZUR
BESTIMMUNG
DER
ABSOLUTEN
KONFIGURATION
.
66
7.4
ZWISCHENRESUEMEE
.
78
7.5
ASYMMETRISCHE
GOLDKATALYSE
.
81
8
ZUSAMMENFASSUNG
UND
AUSBLICK
.
92
9
EXPERIMENTELLER
TEIL
/
EXPERIMENTAL
SECTION
.
96
9.1
GENERAL
REMARKS
.
96
9.2
SYNTHESIS
OF
TRYPTOPHAN-BASED
GOLD(L)
CARBENE
COMPLEXES
.
99
9.2.1
LABELING
.
99
9.2.2
SYNTHESIS
OF
SS-AMINO
ACID
ESTERS
2
.
102
9.2.3
SYNTHESIS
OF
SS-AMINO
ALCOHOLS
3
.
145
9.2.4
SYNTHESIS
OF
HYDROXYL-NAC
GOLD(L)
COMPLEXES
4
.
183
9.2.5
SYNTHESIS
OF
NHC
GOLD(L)
COMPLEXES
5
(WITH
A
SATURATED
BACKBONE)
.
221
9.2.6
SYNTHESIS
OF
NHOC
GOLD(L)
COMPLEXES
6
.
275
9.2.7
SYNTHESIS
OF
HYDROXYL-PROTECTED
NAC
GOLD(L)
COMPLEXES
7
.
292
9.2.8
SYNTHESIS
OF
THE
ENOLIZED
NHOC
GOLD(L)
COMPLEX
8C
S
A
.
304
9.2.9
MISCELLANEOUS
SYNTHESIZED
COMPOUNDS
.
309
9.3
ASYMMETRIE
GOLD
CATALYSIS
.
321
9.3.1
SUBSTRATE
A
(REARRANGEMENT
OF
PROPARGYL
PIVALATES)
.
321
9.3.2
SUBSTRATE
*B
(CYCLOISOMERIZATION
OF
1
,6-ENYNES)
.
353
9.3.3
SUBSTRATE
C
(CYCLOPROPANATION)
.
371
9.3.4
SUBSTRATE
D
(METHOXYCYCLIZATION
OF
1
,6-ENYNES)
.
393
9.3.5
SUBSTRATE
(HYDROXYCARBOXYLATION
OF
ALLENES)
.
411
10
DANKSAGUNG
.
420
11
ANHANG
.
422
12
LITERATURVERZEICHNIS
.
423 |
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| author_GND | (DE-588)1140648020 (DE-588)101199576X |
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| building | Verbundindex |
| bvnumber | BV046866793 |
| ctrlnum | (OCoLC)1193287164 (DE-599)KXP1680637150 |
| discipline | Chemie / Pharmazie |
| discipline_str_mv | Chemie / Pharmazie |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV046866793 |
| illustrated | Illustrated |
| index_date | 2024-07-03T15:14:30Z |
| indexdate | 2024-07-10T08:56:00Z |
| institution | BVB |
| institution_GND | (DE-588)2024349-2 |
| language | German English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-032275359 |
| oclc_num | 1193287164 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR |
| owner_facet | DE-355 DE-BY-UBR |
| physical | VI, 427 Seiten Illustrationen, Diagramme 30 cm |
| publishDate | 2019 |
| publishDateSearch | 2019 |
| publishDateSort | 2019 |
| record_format | marc |
| spelling | Schulmeister, Jürgen Verfasser (DE-588)1140648020 aut Neue Konzepte in der asymmetrischen Goldkatalyse vorgelegt von M. Sc. Jürgen Schulmeister ; Gutachter: Prof. Dr. A. Stephen K. Hashmi, Prof. Dr. Uwe H. F. Bunz Heidelberg [2019] VI, 427 Seiten Illustrationen, Diagramme 30 cm txt rdacontent n rdamedia nc rdacarrier Dissertation Ruprecht-Karls-Universität Heidelberg 2019 Text Deutsch, experimenteller Teil in englischer Sprache 1\p Gold (DE-588)4157819-3 gnd 2\p Hydroxide (DE-588)4072684-8 gnd (DE-588)4113937-9 Hochschulschrift gnd-content Hashmi, A. Stephen K. 1963- (DE-588)101199576X dgs Universität Heidelberg (DE-588)2024349-2 dgg B:DE-101 application/pdf https://d-nb.info/1199653195/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032275359&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p maschinell gebildet 0,21502 20191121 DE-101 2\p maschinell gebildet 0,01946 20191121 DE-101 |
| spellingShingle | Schulmeister, Jürgen Neue Konzepte in der asymmetrischen Goldkatalyse 1\p Gold (DE-588)4157819-3 gnd 2\p Hydroxide (DE-588)4072684-8 gnd |
| subject_GND | (DE-588)4157819-3 (DE-588)4072684-8 (DE-588)4113937-9 |
| title | Neue Konzepte in der asymmetrischen Goldkatalyse |
| title_auth | Neue Konzepte in der asymmetrischen Goldkatalyse |
| title_exact_search | Neue Konzepte in der asymmetrischen Goldkatalyse |
| title_exact_search_txtP | Neue Konzepte in der asymmetrischen Goldkatalyse |
| title_full | Neue Konzepte in der asymmetrischen Goldkatalyse vorgelegt von M. Sc. Jürgen Schulmeister ; Gutachter: Prof. Dr. A. Stephen K. Hashmi, Prof. Dr. Uwe H. F. Bunz |
| title_fullStr | Neue Konzepte in der asymmetrischen Goldkatalyse vorgelegt von M. Sc. Jürgen Schulmeister ; Gutachter: Prof. Dr. A. Stephen K. Hashmi, Prof. Dr. Uwe H. F. Bunz |
| title_full_unstemmed | Neue Konzepte in der asymmetrischen Goldkatalyse vorgelegt von M. Sc. Jürgen Schulmeister ; Gutachter: Prof. Dr. A. Stephen K. Hashmi, Prof. Dr. Uwe H. F. Bunz |
| title_short | Neue Konzepte in der asymmetrischen Goldkatalyse |
| title_sort | neue konzepte in der asymmetrischen goldkatalyse |
| topic | 1\p Gold (DE-588)4157819-3 gnd 2\p Hydroxide (DE-588)4072684-8 gnd |
| topic_facet | Gold Hydroxide Hochschulschrift |
| url | https://d-nb.info/1199653195/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032275359&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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