Solid oxide fuel cells: from electrolyte-based to electrolyte-free devices
Gespeichert in:
| Weitere Verfasser: | , , , |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
[2020]
|
| Schlagworte: | |
| Online-Zugang: | Buchcover Inhaltsverzeichnis |
| Beschreibung: | xiv, 471 Seiten Illustrationen, Diagramme (teilweise farbig) |
| ISBN: | 9783527344116 |
Internformat
MARC
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| 245 | 1 | 0 | |a Solid oxide fuel cells |b from electrolyte-based to electrolyte-free devices |c edited by Bin Zhu, Rizwan Raza, Liangdong Fan, Chunwen Sun |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c [2020] | |
| 264 | 4 | |c © 2020 | |
| 300 | |a xiv, 471 Seiten |b Illustrationen, Diagramme (teilweise farbig) | ||
| 336 | |b txt |2 rdacontent | ||
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| 653 | |a Hardback | ||
| 653 | |a Batterien u. Brennstoffzellen | ||
| 653 | |a Batteries & Fuel Cells | ||
| 653 | |a Brennstoffzelle | ||
| 653 | |a Chemie | ||
| 653 | |a Chemistry | ||
| 653 | |a Energie | ||
| 653 | |a Energy | ||
| 653 | |a Festoxidbrennstoffzelle | ||
| 653 | |a Hydrogen, Batteries & Fuel Cells | ||
| 653 | |a Materialien f. Energiesysteme | ||
| 653 | |a Materials for Energy Systems | ||
| 653 | |a Materials Science | ||
| 653 | |a Materialwissenschaften | ||
| 653 | |a Wasserstoff | ||
| 653 | |a Wasserstoff, Batterien u. Brennstoffzellen | ||
| 653 | |a CHA1: Batterien u. Brennstoffzellen | ||
| 653 | |a EG32: Wasserstoff, Batterien u. Brennstoffzellen | ||
| 653 | |a MSL0: Materialien f. Energiesysteme | ||
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| 700 | 1 | |a Zhu, Bin |4 edt | |
| 700 | 1 | |a Raza, Rizwan |0 (DE-588)1208847074 |4 edt | |
| 700 | 1 | |a Fan, Liangdong |0 (DE-588)120884797X |4 edt | |
| 700 | 1 | |a Sun, Chunwen |0 (DE-588)1184344337 |4 edt | |
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Datensatz im Suchindex
| _version_ | 1804181461137358848 |
|---|---|
| adam_text | CONTENTS
PREFACE
XIII
PART
1
SOLID
OXIDE
FUEL
CELL
WITH
IONIC
CONDUCTING
ELECTROLYTE
1
1
INTRODUCTION
3
BIN
ZHU
AND
PETER
D.
LUND
1.1
1.2
1.3
1.4
1.4.1
1.5
AN
INTRODUCTION
TO
THE
PRINCIPLES
OF
FUEL
CELLS
3
MATERIALS
AND
TECHNOLOGIES
5
NEW
ELECTROLYTE
DEVELOPMENTS
ON
LTSOFC
10
BEYOND
THE
STATE
OF
THE
ART:
THE
ELECTROLYTE-FREE
FUEL
CELL
(EFFC)
20
FUNDAMENTAL
ISSUES
23
BEYOND
THE
SOFC
25
REFERENCES
28
2
SOLID-STATE
ELECTROLYTES
FOR
SOFC
35
LIANGDONG
FAN
2.1
2.2
2.2.1
2.2.1.1
2.2.1.2
2.2.1.3
2.2.2
INTRODUCTION
35
SINGLE-PHASE
SOFC
ELECTROLYTES
37
OXYGEN
IONIC
CONDUCTING
ELECTROLYTE
37
STABILIZED
ZIRCONIA
37
DOPED
CERIA
39
SRO-
AND
MGO-DOPED
LANTHANUM
GALLATES
(LSGM)
42
PROTON-CONDUCTING
ELECTROLYTE
AND
MIXED
IONIC
CONDUCTING
ELECTROLYTE
42
2.2.3
2.3
2.4
2.4.1
2.4.2
2.4.2.1
2.4.2.2
2.4.3
ALTERNATIVE
NEW
ELECTROLYTES
AND
RESEARCH
INTERESTS
44
ION
CONDUCTION/TRANSPORTATION
IN
ELECTROLYTES
49
COMPOSITE
ELECTROLYTES
52
OXIDE-OXIDE
ELECTROLYTE
52
OXIDE-CARBONATE
COMPOSITE
53
MATERIALS
FABRICATION
54
PERFORMANCE
AND
STABILITY
OPTIMIZATION
57
OTHER
OXIDE-SALT
COMPOSITE
ELECTROLYTES
60
VI
CONTENTS
2.4.4
IONIC
CONDUCTION
MECHANISM
STUDIES
OF
CERIA-CARBONATE
COMPOSITE
62
2.5
2.6
NANOCOFC
AND
MATERIAL
DESIGN
PRINCIPLE
66
CONCLUDING
REMARKS
67
ACKNOWLEDGMENTS
69
REFERENCES
69
3
CATHODES
FOR
SOLID
OXIDE
FUEL
CELL
79
TIANMIN
HE,
QINGJUN
ZHOU,
AND
FANGJUN
JIN
3.1
3.2
3.3
3.3.1
3.3.1.1
3.3.1.2
3.3.1.3
3.3.1.4
3.3.2
3.4
3.4.1
3.4.2
3.5
INTRODUCTION
79
OVERVIEW
OF
CATHODE
REACTION
MECHANISM
80
DEVELOPMENT
OF
CATHODE
MATERIALS
82
PEROVSKITE
CATHODE
MATERIALS
82
MN-BASED
PEROVSKITE
CATHODES
83
CO-BASED
PEROVSKITE
CATHODES
85
FE-BASED
PEROVSKITE
CATHODES
88
NI-BASED
PEROVSKITE
CATHODES
89
DOUBLE
PEROVSKITE
CATHODE
MATERIALS
89
MICROSTRUCTURE
OPTIMIZATION
OF
CATHODE
MATERIALS
94
NANOSTRUCTURED
CATHODES
94
COMPOSITE
CATHODES
97
SUMMARY
102
REFERENCES
103
4ANODES
FOR
SOLID
OXIDE
FUEL
CELL
113
CHUNWEN
SUN
4.1
4.2
4.2.1
4.2.1.1
4.3
4.3.1
4.3.2
4.3.2.1
4.3.2.2
4.3.3
4.4
INTRODUCTION
113
OVERVIEW
OF
ANODE
REACTION
MECHANISM
114
BASIC
OPERATING
PRINCIPLES
OF
A
SOFC
114
THE
ANODE
THREE-PHASE
BOUNDARY
115
DEVELOPMENT
OF
ANODE
MATERIALS
117
NI-YSZ
CERMET
ANODE
MATERIALS
117
ALTERNATIVE
ANODE
MATERIALS
118
FLUORITE
ANODE
MATERIALS
118
PEROVSKITE
ANODE
MATERIALS
120
SULFUR-TOLERANT
ANODE
MATERIALS
124
DEVELOPMENT
OF
KINETICS,
REACTION
MECHANISM,
AND
MODEL
OF
THE
ANODE
126
4.5
SUMMARY
AND
OUTLOOK
135
ACKNOWLEDGMENTS
137
REFERENCES
137
5
DESIGN
AND
DEVELOPMENT
OF
SOFC
STACKS
145
WAN
BI
NG
GUAN
5.1
5.2
5.2.1
INTRODUCTION
145
CHANGE
OF
CELL
OUTPUT
PERFORMANCE
UNDER
2D
INTERFACE
CONTACT
145
DESIGN
OF
2D
INTERFACE
CONTACT
MODE
145
CONTENTS
VII
5.2.2
5.2.3
VARIATIONS
OF
CELL
OUTPUT
PERFORMANCE
UNDER
2D
CONTACT
MODE
147
2D
INTERFACE
STRUCTURE
IMPROVEMENTS
AND
ENHANCEMENT
OF
CELL
OUTPUT
PERFORMANCE
149
5.2.4
5.2.5
CONTRIBUTIONS
OF
3D
CONTACT
IN
2D
INTERFACE
CONTACT
151
MECHANISM
OF
PERFORMANCE
ENHANCEMENT
AFTER
THE
TRANSITION
FROM
2D
TO
3D
INTERFACE
153
5.3
CONTROL
DESIGN
OF
TRANSITION FROM
2D
TO
3D
INTERFACE
CONTACT
AND
THEIR
QUANTITATIVE
CONTRIBUTION
DIFFERENTIATION
156
5.3.1
5.3.2
CONTROL
DESIGN
OF
2D
AND
3D
INTERFACE
CONTACT
156
QUANTITATIVE
EFFECTS
OF
2D
CONTACT
ON
THE
TRANSIENT
OUTPUT
PERFORMANCE
OF
A
CELL
158
5.3.3
QUANTITATIVE
EFFECTS
OF
2D
CONTACT
ON
THE
STEADY-STATE
OUTPUT
PERFORMANCE
OF
THE
CELL
161
5.3.4
QUANTITATIVE
EFFECTS
OF
3D
CONTACT
ON
CELL
TRANSIENT
PERFORMANCE
163
5.3.5
QUANTITATIVE
EFFECTS
OF
3D
CONTACT
ON
THE
STEADY-STATE
PERFORMANCE
OF
A
CELL
166
5.3.6
5.4
DIFFERENCES
BETWEEN
2D
AND
3D
INTERFACE
CONTACTS
769
CONCLUSIONS
7
77
REFERENCES
7
72
PART
II
ELECTROLYTE-FREE
FUEL
CELLS:
MATERIALS,
TECHNOLOGIES,
AND
WORKING
PRINCIPLES
173
6
ELECTROLYTE-FREE
SOFCS:
MATERIALS,
TECHNOLOGIES,
AND
WORKING
PRINCIPLES
175
BIN
ZHU,
LIANGDONG
FAN,
JUNG-SIK
KIM,
AND
PETER
D.
LUND
6.1
6.2
6.3
6.4
6.5
6.6
CONCEPT
OF
THE
ELECTROLYTE-FREE
FUEL
CELL
7
75
SLFC
USING
THE
IONIC
CONDUCTOR-BASED
ELECTROLYTE
7
77
DEVELOPMENTS
ON
ADVANCED
SLFC
7
79
FROM
SLFCS
TO
SEMICONDUCTOR-IONIC
FUEL
CELLS
(SIFCS)
184
THE
SLFC
WORKING
PRINCIPLE
7
96
REMARKS
204
ACKNOWLEDGMENTS
207
REFERENCES
207
7
CERIA
FLUORITE
ELECTROLYTES
FROM
IONIC
TO
MIXED
ELECTRONIC
AND
IONIC
MEMBRANES
213
BAOYUAN
WANG,
LIANGDONG
FAN,
YANYAN
LIU,
AND
BIN
ZHU
7.1
7.2
INTRODUCTION
273
DOPED
CERIA
AS
THE
ELECTROLYTE
FOR
INTERMEDIATE
TEMPERATURE
SOFCS
214
7.3
7.4
SURFACE
DOPING
FOR
LOW
TEMPERATURE
SOFCS
276
NON-DOPED
CERIA
FOR
ADVANCED
LOW
TEMPERATURE
SOFCS
222
REFERENCES
235
VIII
I
CONTENTS
8
CHARGE
TRANSFER
IN
OXIDE
SOLID
FUEL
CELLS
239
JING
SHI
AND
SINING
YUN
8.1
OXYGEN
DIFFUSION
IN
PEROVSKITE
OXIDES
239
8.1.1
OXYGEN VACANCY
FORMATION
239
8.1.2
OXYGEN
DIFFUSION
MECHANISMS
242
8.1.3
ANISOTROPY
OXYGEN
TRANSPORT
IN
LAYERED
PEROVSKITES
244
8.1.3.1
OXYGEN
TRANSPORT
IN
RUDDLESDEN-POPPER
(RP)
PEROVSKITES
244
8.1.3.2
OXYGEN
TRANSPORT
IN
A-SITE
ORDERED
DOUBLE
PEROVSKITES
244
8.1.4
OXYGEN
ION
DIFFUSION
AT
GRAIN
BOUNDARY
246
8.1.5
FACTORS
CONTROLLING
OXYGEN
MIGRATION
BARRIERS
IN
PEROVSKITES
248
8.2
PROTON
DIFFUSION
IN
PEROVSKITE-TYPE
OXIDES
249
8.2.1
PROTON
DIFFUSION
MECHANISMS
249
8.2.2
PROTON-DOPANT
INTERACTION
253
8.2.2.1
INFLUENCE
OF
DOPANTS
IN
A-SITE
253
8.2.2.2
INFLUENCE
OF
DOPANTS
IN
B-SITE
254
8.2.3
LONG-RANGE
PROTON
CONDUCTION
PATHWAYS
IN
PEROVSKITES
255
8.2.4
HYDROGEN-INDUCED
INSULATION
256
8.3
ENHANCED
ION
CONDUCTIVITY
IN
OXIDE
HETEROSTRUCTURES
259
8.3.1
ENHANCED
IONIC
CONDUCTION
BY
STRAIN
259
8.3.2
ENHANCED
IONIC
CONDUCTIVITY
BY
BAND
BENDING
263
8.3.2.1
SURFACE
STATE-INDUCED
BAND
BENDING
263
8.3.2.2
BAND
BENDING
IN
P-N
HETEROJUNCTIONS
265
8.3.2.3
P-N
HETEROJUNCTION
STRUCTURES
IN
SOFC
265
8.4
SUMMARY
266
ACKNOWLEDGMENTS
267
REFERENCES
267
9
MATERIAL
DEVELOPMENT
II:
NATURAL
MATERIAL-BASED
COMPOSITES
FOR
ELECTROLYTE
LAYER-FREE
FUEL
CELLS
275
CHEN
XIA
AND
YANYAN
LIU
9.1
INTRODUCTION
275
9.1.1
MATERIALS
DEVELOPMENT
FOR
EFFCS
275
9.1.2
NATURAL
MATERIALS
AS
POTENTIAL
ELECTROLYTES
276
9.2
INDUSTRIAL-GRADE
RARE
EARTH
FOR
EFFCS
279
9.2.1
RARE-EARTH
OXIDE
LCP
280
9.2.2
SEMICONDUCTING-IONIC
COMPOSITE
BASED
ON
LCP
281
9.2.2.1
LCP-LSCF
282
9.2.2.2
LCP-ZNO
284
9.2.3
STABILITY
OPERATION
AND
SCHOTTKY
JUNCTION
OF
EFFC
288
9.2.3.1
PERFORMANCE
STABILITY
288
9.23.2
IN
SITU
SCHOTTKY
JUNCTION
EFFECT
288
9.2.4
SUMMARY
290
9.3
NATURAL
HEMATITE
FOR
EFFCS
291
9.3.1
NATURAL
HEMATITE
292
9.3.2
SEMICONDUCTING-IONIC
COMPOSITE
BASED
ON
HEMATITE
295
CONTENTS
IX
9.3.2.1
HEMATITE-LSCF
295
93.2.2
HEMATITE/LCP-LSCF
297
9.3.3
SUMMARY
300
9.4
NATURAL
CUFE
OXIDE
MINERALS
FOR
EFFCS
302
9.4.1
NATURAL
CUFE
2
O
4
MINERAL
FOR
EFFC
302
9.4.2
NATURAL
DELAFOSSITE
CUFEO
2
FOR
EFFC
305
9.4.3
SUMMARY
308
9.5
BIO-DERIVED
CALCITE
FOR
EFFC
308
9.5.1
BIO-DERIVED
CALCITE FOR
EFFC
309
9.5.2
SUMMARY
312
REFERENCES
314
10
CHARGE
TRANSFER,
TRANSPORTATION,
AND
SIMULATION
319
MUHAMMAD
AFZAL,
MUSTAFA
ANWAR,
MUHAMMAD
I.
ASGHAR,
PETER
D.
LUND,
NAVEED
JHAMAT,
RIZWAN
RAZA,
AND
BIN
ZHU
10.1
PHYSICAL
ASPECTS
319
10.2
ELECTROCHEMICAL
ASPECTS
320
10.3
IONIC
CONDUCTION
ENHANCEMENT
IN
HETEROSTRUCTURE
COMPOSITES
321
10.4
CHARGE
TRANSPORTATION
MECHANISM
AND
COUPLING
EFFECTS
326
10.5
SURFACE
AND
INTERFACIAL
STATE-INDUCED
SUPERIONIC
CONDUCTION
AND
TRANSPORTATION
330
10.6
IONIC
TRANSPORT
NUMBER
MEASUREMENTS
331
10.7
DETERMINATION
OF
ELECTRON
AND
IONIC
CONDUCTIVITIES
IN
EFFCS
332
10.8
EIS
ANALYSIS
334
10.9
SEMICONDUCTOR
BAND
EFFECTS
ON
THE
IONIC
CONDUCTION
DEVICE
PERFORMANCE
335
10.10
SIMULATIONS
339
ACKNOWLEDGMENTS
343
REFERENCES
343
11
ELECTROLYTE-FREE
FUEL
CELL:
PRINCIPLES
AND
CROSSLINK
RESEARCH
347
YAN
WU,
LIANGDONG
FAN,
NAVEED
MUSHTAQ,
BIN
ZHU,
MUHAMMAD
AFZAL,
MUHAMMAD
SAJID,
RIZWAN
RAZA,
JUNG-SIK
KIM,
WEN-FENG
LIN,
AND
PETER
D.
LUND
11.1
INTRODUCTION
347
11.2
FUNDAMENTAL
CONSIDERATIONS
OF
FUEL
CELL
SEMICONDUCTOR
ELECTROCHEMISTRY
353
11.2.1
PHYSICS
AND
ELECTROCHEMISTRY
AT
INTERFACES
353
11.2.2
ELECTROCHEMISTRY
VS.
SEMICONDUCTOR
PHYSICS
355
11.3
WORKING
PRINCIPLE
OF
SEMICONDUCTOR-BASED
FUEL
CELLS
AND
CROSSING
LINK
SCIENCES
356
11.4
EXTENDING
APPLICATIONS
BY
COUPLING
DEVICES
367
11.5
FINAL
REMARKS
368
ACKNOWLEDGMENTS
372
REFERENCES
373
X
CONTENTS
PART
III
FUEL
CELLS:
FROM
TECHNOLOGY
TO
APPLICATIONS
377
12
SCALING
UP
MATERIALS
AND
TECHNOLOGY
FOR
SLFC
379
KANG
YUAN,
ZHIGANG
ZHU,
MUHAMMAD
AFZAL,
AND
BIN
ZHU
12.1
12.2
SINGLE-LAYER
FUEL
CELL
(SLFC)
ENGINEERING
MATERIALS
379
SCALING
UP
SINGLE-LAYER
FUEL
CELL
DEVICES:
TAPE
CASTING
AND
HOT
PRESSING
383
12.3
SCALING
UP
SINGLE-LAYER
FUEL
CELL
DEVICES:
THERMAL
SPRAY
COATING
TECHNOLOGY
386
12.3.1
12.3.2
TRADITIONAL
PLASMA
SPRAY
COATING
TECHNOLOGY
387
NEW
DEVELOPED
LOW-PRESSURE
PLASMA
SPRAY
(LPPS)
COATING
TECHNOLOGY
388
12.4
12.4.1
12.4.2
12.4.3
12.5
12.6
12.7
12.8
12.9
SHORT
STACK
395
SLFC
CELLS
395
BIPOLAR
PLATE
DESIGN
396
SEALING
AND
SEALANT-FREE
SHORT
STACK
396
TESTS
AND
EVALUATIONS
397
DURABILITY
TESTING
399
A
CASE
STUDY
FOR
THE
CELL
DEGRADATION
MECHANISM
400
CONTINUOUS
EFFORTS
AND
FUTURE
DEVELOPMENTS
404
CONCLUDING
REMARKS
409
REFERENCES
411
13
PLANAR
SOFC
STACK
DESIGN
AND
DEVELOPMENT
415
SHAORONG
WANG,
YIXIANG
SHI,
NAVEED
MUSHTAQ,
AND
BIN
ZHU
13.1
13.2
13.3
13.4
13.4.1
13.4.2
13.4.3
13.5
13.5.1
13.5.2
13.6
13.7
13.8
INTERNAL
MANIFOLD
AND
EXTERNAL
MANIFOLD
415
INTERFACE
BETWEEN
AN
INTERCONNECT
PLATE
AND
A
SINGLE
CELL
416
ANTIOXIDATION
COATING
OF
THE
INTERCONNECT
PLATE
418
DESIGN
THE
FLOW
FIELD
OF
INTERCONNECT
PLATE
419
MATHEMATICAL
SIMULATION
420
EFFECT
OF
CO-FLOW,
CROSSFLOW,
AND
COUNTERFLOW
422
AIR
FLOW
DISTRIBUTION
BETWEEN
LAYERS
IN
A
STACK
424
THE
IMPORTANCE
OF
SEALING
424
THERMAL
CYCLING
OF
THE
SEALING
428
DURABILITY
OF
SEALING
428
THE
LIFE
OF
THE
STACK:
THE
CHEMICAL
PROBLEMS
ON
THE
INTERFACE
429
TOWARD
MARKET
PRODUCTS
431
CONCLUDING
REMARKS
443
REFERENCES
443
14
ENERGY
SYSTEM
INTEGRATION
AND
FUTURE
PERSPECTIVES
447
GHAZANFAR
ABBAS,
MUHAMMAD
AH
BABAR,
FIDA
HUSSAIN,
AND
RIZWAN
RAZA
14.1
14.2
14.3
14.4
14.5
SOLAR
CELL
AND
FUEL
CELL
447
FUEL
CELL-SOLAR
CELL
INTEGRATION
450
SOLAR
ELECTROLYSIS-FUEL
CELL
INTEGRATION
452
FUEL
CELL-BIOMASS
INTEGRATION
453
THE
FUEL
CELL
SYSTEM
MODELING
USING
BIOGAS
454
CONTENTS
XI
14.5.1
ACTIVATION
LOSS
457
14.5.2
OHMIC
LOSS
457
14.5.3
CONCENTRATION
VOLTAGE
LOSS
458
14.6
THE
FUEL
CELL
SYSTEM
EFFICIENCY
(HEATING
AND
ELECTRICAL)
458
14.6.1
THE
EFFECT
OF
DIFFERENT
TEMPERATURES
ON
SYSTEM
EFFICIENCY
458
14.6.2
THE
FUEL
UTILIZATION
FACTOR
AND
EFFICIENCIES
OF
THE
SYSTEM
458
14.6.3
THE
SYSTEM
EFFICIENCIES
AND
OPERATING
PRESSURE
460
14.7
INTEGRATED
NEW
CLEAN
ENERGY
SYSTEM
460
14.8
SUMMARY
462
REFERENCES
462
INDEX
465
|
| adam_txt |
CONTENTS
PREFACE
XIII
PART
1
SOLID
OXIDE
FUEL
CELL
WITH
IONIC
CONDUCTING
ELECTROLYTE
1
1
INTRODUCTION
3
BIN
ZHU
AND
PETER
D.
LUND
1.1
1.2
1.3
1.4
1.4.1
1.5
AN
INTRODUCTION
TO
THE
PRINCIPLES
OF
FUEL
CELLS
3
MATERIALS
AND
TECHNOLOGIES
5
NEW
ELECTROLYTE
DEVELOPMENTS
ON
LTSOFC
10
BEYOND
THE
STATE
OF
THE
ART:
THE
ELECTROLYTE-FREE
FUEL
CELL
(EFFC)
20
FUNDAMENTAL
ISSUES
23
BEYOND
THE
SOFC
25
REFERENCES
28
2
SOLID-STATE
ELECTROLYTES
FOR
SOFC
35
LIANGDONG
FAN
2.1
2.2
2.2.1
2.2.1.1
2.2.1.2
2.2.1.3
2.2.2
INTRODUCTION
35
SINGLE-PHASE
SOFC
ELECTROLYTES
37
OXYGEN
IONIC
CONDUCTING
ELECTROLYTE
37
STABILIZED
ZIRCONIA
37
DOPED
CERIA
39
SRO-
AND
MGO-DOPED
LANTHANUM
GALLATES
(LSGM)
42
PROTON-CONDUCTING
ELECTROLYTE
AND
MIXED
IONIC
CONDUCTING
ELECTROLYTE
42
2.2.3
2.3
2.4
2.4.1
2.4.2
2.4.2.1
2.4.2.2
2.4.3
ALTERNATIVE
NEW
ELECTROLYTES
AND
RESEARCH
INTERESTS
44
ION
CONDUCTION/TRANSPORTATION
IN
ELECTROLYTES
49
COMPOSITE
ELECTROLYTES
52
OXIDE-OXIDE
ELECTROLYTE
52
OXIDE-CARBONATE
COMPOSITE
53
MATERIALS
FABRICATION
54
PERFORMANCE
AND
STABILITY
OPTIMIZATION
57
OTHER
OXIDE-SALT
COMPOSITE
ELECTROLYTES
60
VI
CONTENTS
2.4.4
IONIC
CONDUCTION
MECHANISM
STUDIES
OF
CERIA-CARBONATE
COMPOSITE
62
2.5
2.6
NANOCOFC
AND
MATERIAL
DESIGN
PRINCIPLE
66
CONCLUDING
REMARKS
67
ACKNOWLEDGMENTS
69
REFERENCES
69
3
CATHODES
FOR
SOLID
OXIDE
FUEL
CELL
79
TIANMIN
HE,
QINGJUN
ZHOU,
AND
FANGJUN
JIN
3.1
3.2
3.3
3.3.1
3.3.1.1
3.3.1.2
3.3.1.3
3.3.1.4
3.3.2
3.4
3.4.1
3.4.2
3.5
INTRODUCTION
79
OVERVIEW
OF
CATHODE
REACTION
MECHANISM
80
DEVELOPMENT
OF
CATHODE
MATERIALS
82
PEROVSKITE
CATHODE
MATERIALS
82
MN-BASED
PEROVSKITE
CATHODES
83
CO-BASED
PEROVSKITE
CATHODES
85
FE-BASED
PEROVSKITE
CATHODES
88
NI-BASED
PEROVSKITE
CATHODES
89
DOUBLE
PEROVSKITE
CATHODE
MATERIALS
89
MICROSTRUCTURE
OPTIMIZATION
OF
CATHODE
MATERIALS
94
NANOSTRUCTURED
CATHODES
94
COMPOSITE
CATHODES
97
SUMMARY
102
REFERENCES
103
4ANODES
FOR
SOLID
OXIDE
FUEL
CELL
113
CHUNWEN
SUN
4.1
4.2
4.2.1
4.2.1.1
4.3
4.3.1
4.3.2
4.3.2.1
4.3.2.2
4.3.3
4.4
INTRODUCTION
113
OVERVIEW
OF
ANODE
REACTION
MECHANISM
114
BASIC
OPERATING
PRINCIPLES
OF
A
SOFC
114
THE
ANODE
THREE-PHASE
BOUNDARY
115
DEVELOPMENT
OF
ANODE
MATERIALS
117
NI-YSZ
CERMET
ANODE
MATERIALS
117
ALTERNATIVE
ANODE
MATERIALS
118
FLUORITE
ANODE
MATERIALS
118
PEROVSKITE
ANODE
MATERIALS
120
SULFUR-TOLERANT
ANODE
MATERIALS
124
DEVELOPMENT
OF
KINETICS,
REACTION
MECHANISM,
AND
MODEL
OF
THE
ANODE
126
4.5
SUMMARY
AND
OUTLOOK
135
ACKNOWLEDGMENTS
137
REFERENCES
137
5
DESIGN
AND
DEVELOPMENT
OF
SOFC
STACKS
145
WAN
BI
NG
GUAN
5.1
5.2
5.2.1
INTRODUCTION
145
CHANGE
OF
CELL
OUTPUT
PERFORMANCE
UNDER
2D
INTERFACE
CONTACT
145
DESIGN
OF
2D
INTERFACE
CONTACT
MODE
145
CONTENTS
VII
5.2.2
5.2.3
VARIATIONS
OF
CELL
OUTPUT
PERFORMANCE
UNDER
2D
CONTACT
MODE
147
2D
INTERFACE
STRUCTURE
IMPROVEMENTS
AND
ENHANCEMENT
OF
CELL
OUTPUT
PERFORMANCE
149
5.2.4
5.2.5
CONTRIBUTIONS
OF
3D
CONTACT
IN
2D
INTERFACE
CONTACT
151
MECHANISM
OF
PERFORMANCE
ENHANCEMENT
AFTER
THE
TRANSITION
FROM
2D
TO
3D
INTERFACE
153
5.3
CONTROL
DESIGN
OF
TRANSITION FROM
2D
TO
3D
INTERFACE
CONTACT
AND
THEIR
QUANTITATIVE
CONTRIBUTION
DIFFERENTIATION
156
5.3.1
5.3.2
CONTROL
DESIGN
OF
2D
AND
3D
INTERFACE
CONTACT
156
QUANTITATIVE
EFFECTS
OF
2D
CONTACT
ON
THE
TRANSIENT
OUTPUT
PERFORMANCE
OF
A
CELL
158
5.3.3
QUANTITATIVE
EFFECTS
OF
2D
CONTACT
ON
THE
STEADY-STATE
OUTPUT
PERFORMANCE
OF
THE
CELL
161
5.3.4
QUANTITATIVE
EFFECTS
OF
3D
CONTACT
ON
CELL
TRANSIENT
PERFORMANCE
163
5.3.5
QUANTITATIVE
EFFECTS
OF
3D
CONTACT
ON
THE
STEADY-STATE
PERFORMANCE
OF
A
CELL
166
5.3.6
5.4
DIFFERENCES
BETWEEN
2D
AND
3D
INTERFACE
CONTACTS
769
CONCLUSIONS
7
77
REFERENCES
7
72
PART
II
ELECTROLYTE-FREE
FUEL
CELLS:
MATERIALS,
TECHNOLOGIES,
AND
WORKING
PRINCIPLES
173
6
ELECTROLYTE-FREE
SOFCS:
MATERIALS,
TECHNOLOGIES,
AND
WORKING
PRINCIPLES
175
BIN
ZHU,
LIANGDONG
FAN,
JUNG-SIK
KIM,
AND
PETER
D.
LUND
6.1
6.2
6.3
6.4
6.5
6.6
CONCEPT
OF
THE
ELECTROLYTE-FREE
FUEL
CELL
7
75
SLFC
USING
THE
IONIC
CONDUCTOR-BASED
ELECTROLYTE
7
77
DEVELOPMENTS
ON
ADVANCED
SLFC
7
79
FROM
SLFCS
TO
SEMICONDUCTOR-IONIC
FUEL
CELLS
(SIFCS)
184
THE
SLFC
WORKING
PRINCIPLE
7
96
REMARKS
204
ACKNOWLEDGMENTS
207
REFERENCES
207
7
CERIA
FLUORITE
ELECTROLYTES
FROM
IONIC
TO
MIXED
ELECTRONIC
AND
IONIC
MEMBRANES
213
BAOYUAN
WANG,
LIANGDONG
FAN,
YANYAN
LIU,
AND
BIN
ZHU
7.1
7.2
INTRODUCTION
273
DOPED
CERIA
AS
THE
ELECTROLYTE
FOR
INTERMEDIATE
TEMPERATURE
SOFCS
214
7.3
7.4
SURFACE
DOPING
FOR
LOW
TEMPERATURE
SOFCS
276
NON-DOPED
CERIA
FOR
ADVANCED
LOW
TEMPERATURE
SOFCS
222
REFERENCES
235
VIII
I
CONTENTS
8
CHARGE
TRANSFER
IN
OXIDE
SOLID
FUEL
CELLS
239
JING
SHI
AND
SINING
YUN
8.1
OXYGEN
DIFFUSION
IN
PEROVSKITE
OXIDES
239
8.1.1
OXYGEN VACANCY
FORMATION
239
8.1.2
OXYGEN
DIFFUSION
MECHANISMS
242
8.1.3
ANISOTROPY
OXYGEN
TRANSPORT
IN
LAYERED
PEROVSKITES
244
8.1.3.1
OXYGEN
TRANSPORT
IN
RUDDLESDEN-POPPER
(RP)
PEROVSKITES
244
8.1.3.2
OXYGEN
TRANSPORT
IN
A-SITE
ORDERED
DOUBLE
PEROVSKITES
244
8.1.4
OXYGEN
ION
DIFFUSION
AT
GRAIN
BOUNDARY
246
8.1.5
FACTORS
CONTROLLING
OXYGEN
MIGRATION
BARRIERS
IN
PEROVSKITES
248
8.2
PROTON
DIFFUSION
IN
PEROVSKITE-TYPE
OXIDES
249
8.2.1
PROTON
DIFFUSION
MECHANISMS
249
8.2.2
PROTON-DOPANT
INTERACTION
253
8.2.2.1
INFLUENCE
OF
DOPANTS
IN
A-SITE
253
8.2.2.2
INFLUENCE
OF
DOPANTS
IN
B-SITE
254
8.2.3
LONG-RANGE
PROTON
CONDUCTION
PATHWAYS
IN
PEROVSKITES
255
8.2.4
HYDROGEN-INDUCED
INSULATION
256
8.3
ENHANCED
ION
CONDUCTIVITY
IN
OXIDE
HETEROSTRUCTURES
259
8.3.1
ENHANCED
IONIC
CONDUCTION
BY
STRAIN
259
8.3.2
ENHANCED
IONIC
CONDUCTIVITY
BY
BAND
BENDING
263
8.3.2.1
SURFACE
STATE-INDUCED
BAND
BENDING
263
8.3.2.2
BAND
BENDING
IN
P-N
HETEROJUNCTIONS
265
8.3.2.3
P-N
HETEROJUNCTION
STRUCTURES
IN
SOFC
265
8.4
SUMMARY
266
ACKNOWLEDGMENTS
267
REFERENCES
267
9
MATERIAL
DEVELOPMENT
II:
NATURAL
MATERIAL-BASED
COMPOSITES
FOR
ELECTROLYTE
LAYER-FREE
FUEL
CELLS
275
CHEN
XIA
AND
YANYAN
LIU
9.1
INTRODUCTION
275
9.1.1
MATERIALS
DEVELOPMENT
FOR
EFFCS
275
9.1.2
NATURAL
MATERIALS
AS
POTENTIAL
ELECTROLYTES
276
9.2
INDUSTRIAL-GRADE
RARE
EARTH
FOR
EFFCS
279
9.2.1
RARE-EARTH
OXIDE
LCP
280
9.2.2
SEMICONDUCTING-IONIC
COMPOSITE
BASED
ON
LCP
281
9.2.2.1
LCP-LSCF
282
9.2.2.2
LCP-ZNO
284
9.2.3
STABILITY
OPERATION
AND
SCHOTTKY
JUNCTION
OF
EFFC
288
9.2.3.1
PERFORMANCE
STABILITY
288
9.23.2
IN
SITU
SCHOTTKY
JUNCTION
EFFECT
288
9.2.4
SUMMARY
290
9.3
NATURAL
HEMATITE
FOR
EFFCS
291
9.3.1
NATURAL
HEMATITE
292
9.3.2
SEMICONDUCTING-IONIC
COMPOSITE
BASED
ON
HEMATITE
295
CONTENTS
IX
9.3.2.1
HEMATITE-LSCF
295
93.2.2
HEMATITE/LCP-LSCF
297
9.3.3
SUMMARY
300
9.4
NATURAL
CUFE
OXIDE
MINERALS
FOR
EFFCS
302
9.4.1
NATURAL
CUFE
2
O
4
MINERAL
FOR
EFFC
302
9.4.2
NATURAL
DELAFOSSITE
CUFEO
2
FOR
EFFC
305
9.4.3
SUMMARY
308
9.5
BIO-DERIVED
CALCITE
FOR
EFFC
308
9.5.1
BIO-DERIVED
CALCITE FOR
EFFC
309
9.5.2
SUMMARY
312
REFERENCES
314
10
CHARGE
TRANSFER,
TRANSPORTATION,
AND
SIMULATION
319
MUHAMMAD
AFZAL,
MUSTAFA
ANWAR,
MUHAMMAD
I.
ASGHAR,
PETER
D.
LUND,
NAVEED
JHAMAT,
RIZWAN
RAZA,
AND
BIN
ZHU
10.1
PHYSICAL
ASPECTS
319
10.2
ELECTROCHEMICAL
ASPECTS
320
10.3
IONIC
CONDUCTION
ENHANCEMENT
IN
HETEROSTRUCTURE
COMPOSITES
321
10.4
CHARGE
TRANSPORTATION
MECHANISM
AND
COUPLING
EFFECTS
326
10.5
SURFACE
AND
INTERFACIAL
STATE-INDUCED
SUPERIONIC
CONDUCTION
AND
TRANSPORTATION
330
10.6
IONIC
TRANSPORT
NUMBER
MEASUREMENTS
331
10.7
DETERMINATION
OF
ELECTRON
AND
IONIC
CONDUCTIVITIES
IN
EFFCS
332
10.8
EIS
ANALYSIS
334
10.9
SEMICONDUCTOR
BAND
EFFECTS
ON
THE
IONIC
CONDUCTION
DEVICE
PERFORMANCE
335
10.10
SIMULATIONS
339
ACKNOWLEDGMENTS
343
REFERENCES
343
11
ELECTROLYTE-FREE
FUEL
CELL:
PRINCIPLES
AND
CROSSLINK
RESEARCH
347
YAN
WU,
LIANGDONG
FAN,
NAVEED
MUSHTAQ,
BIN
ZHU,
MUHAMMAD
AFZAL,
MUHAMMAD
SAJID,
RIZWAN
RAZA,
JUNG-SIK
KIM,
WEN-FENG
LIN,
AND
PETER
D.
LUND
11.1
INTRODUCTION
347
11.2
FUNDAMENTAL
CONSIDERATIONS
OF
FUEL
CELL
SEMICONDUCTOR
ELECTROCHEMISTRY
353
11.2.1
PHYSICS
AND
ELECTROCHEMISTRY
AT
INTERFACES
353
11.2.2
ELECTROCHEMISTRY
VS.
SEMICONDUCTOR
PHYSICS
355
11.3
WORKING
PRINCIPLE
OF
SEMICONDUCTOR-BASED
FUEL
CELLS
AND
CROSSING
LINK
SCIENCES
356
11.4
EXTENDING
APPLICATIONS
BY
COUPLING
DEVICES
367
11.5
FINAL
REMARKS
368
ACKNOWLEDGMENTS
372
REFERENCES
373
X
CONTENTS
PART
III
FUEL
CELLS:
FROM
TECHNOLOGY
TO
APPLICATIONS
377
12
SCALING
UP
MATERIALS
AND
TECHNOLOGY
FOR
SLFC
379
KANG
YUAN,
ZHIGANG
ZHU,
MUHAMMAD
AFZAL,
AND
BIN
ZHU
12.1
12.2
SINGLE-LAYER
FUEL
CELL
(SLFC)
ENGINEERING
MATERIALS
379
SCALING
UP
SINGLE-LAYER
FUEL
CELL
DEVICES:
TAPE
CASTING
AND
HOT
PRESSING
383
12.3
SCALING
UP
SINGLE-LAYER
FUEL
CELL
DEVICES:
THERMAL
SPRAY
COATING
TECHNOLOGY
386
12.3.1
12.3.2
TRADITIONAL
PLASMA
SPRAY
COATING
TECHNOLOGY
387
NEW
DEVELOPED
LOW-PRESSURE
PLASMA
SPRAY
(LPPS)
COATING
TECHNOLOGY
388
12.4
12.4.1
12.4.2
12.4.3
12.5
12.6
12.7
12.8
12.9
SHORT
STACK
395
SLFC
CELLS
395
BIPOLAR
PLATE
DESIGN
396
SEALING
AND
SEALANT-FREE
SHORT
STACK
396
TESTS
AND
EVALUATIONS
397
DURABILITY
TESTING
399
A
CASE
STUDY
FOR
THE
CELL
DEGRADATION
MECHANISM
400
CONTINUOUS
EFFORTS
AND
FUTURE
DEVELOPMENTS
404
CONCLUDING
REMARKS
409
REFERENCES
411
13
PLANAR
SOFC
STACK
DESIGN
AND
DEVELOPMENT
415
SHAORONG
WANG,
YIXIANG
SHI,
NAVEED
MUSHTAQ,
AND
BIN
ZHU
13.1
13.2
13.3
13.4
13.4.1
13.4.2
13.4.3
13.5
13.5.1
13.5.2
13.6
13.7
13.8
INTERNAL
MANIFOLD
AND
EXTERNAL
MANIFOLD
415
INTERFACE
BETWEEN
AN
INTERCONNECT
PLATE
AND
A
SINGLE
CELL
416
ANTIOXIDATION
COATING
OF
THE
INTERCONNECT
PLATE
418
DESIGN
THE
FLOW
FIELD
OF
INTERCONNECT
PLATE
419
MATHEMATICAL
SIMULATION
420
EFFECT
OF
CO-FLOW,
CROSSFLOW,
AND
COUNTERFLOW
422
AIR
FLOW
DISTRIBUTION
BETWEEN
LAYERS
IN
A
STACK
424
THE
IMPORTANCE
OF
SEALING
424
THERMAL
CYCLING
OF
THE
SEALING
428
DURABILITY
OF
SEALING
428
THE
LIFE
OF
THE
STACK:
THE
CHEMICAL
PROBLEMS
ON
THE
INTERFACE
429
TOWARD
MARKET
PRODUCTS
431
CONCLUDING
REMARKS
443
REFERENCES
443
14
ENERGY
SYSTEM
INTEGRATION
AND
FUTURE
PERSPECTIVES
447
GHAZANFAR
ABBAS,
MUHAMMAD
AH
BABAR,
FIDA
HUSSAIN,
AND
RIZWAN
RAZA
14.1
14.2
14.3
14.4
14.5
SOLAR
CELL
AND
FUEL
CELL
447
FUEL
CELL-SOLAR
CELL
INTEGRATION
450
SOLAR
ELECTROLYSIS-FUEL
CELL
INTEGRATION
452
FUEL
CELL-BIOMASS
INTEGRATION
453
THE
FUEL
CELL
SYSTEM
MODELING
USING
BIOGAS
454
CONTENTS
XI
14.5.1
ACTIVATION
LOSS
457
14.5.2
OHMIC
LOSS
457
14.5.3
CONCENTRATION
VOLTAGE
LOSS
458
14.6
THE
FUEL
CELL
SYSTEM
EFFICIENCY
(HEATING
AND
ELECTRICAL)
458
14.6.1
THE
EFFECT
OF
DIFFERENT
TEMPERATURES
ON
SYSTEM
EFFICIENCY
458
14.6.2
THE
FUEL
UTILIZATION
FACTOR
AND
EFFICIENCIES
OF
THE
SYSTEM
458
14.6.3
THE
SYSTEM
EFFICIENCIES
AND
OPERATING
PRESSURE
460
14.7
INTEGRATED
NEW
CLEAN
ENERGY
SYSTEM
460
14.8
SUMMARY
462
REFERENCES
462
INDEX
465 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author2 | Zhu, Bin Raza, Rizwan Fan, Liangdong Sun, Chunwen |
| author2_role | edt edt edt edt |
| author2_variant | b z bz r r rr l f lf c s cs |
| author_GND | (DE-588)1208847074 (DE-588)120884797X (DE-588)1184344337 |
| author_facet | Zhu, Bin Raza, Rizwan Fan, Liangdong Sun, Chunwen |
| building | Verbundindex |
| bvnumber | BV046720844 |
| classification_rvk | VN 6050 ZN 8750 |
| ctrlnum | (OCoLC)1155083805 (DE-599)DNB1198425814 |
| discipline | Chemie / Pharmazie Elektrotechnik / Elektronik / Nachrichtentechnik |
| discipline_str_mv | Chemie / Pharmazie Elektrotechnik / Elektronik / Nachrichtentechnik |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV046720844 |
| illustrated | Illustrated |
| index_date | 2024-07-03T14:33:36Z |
| indexdate | 2024-07-10T08:52:01Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527344116 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-032131066 |
| oclc_num | 1155083805 |
| open_access_boolean | |
| owner | DE-29T DE-83 DE-703 DE-11 |
| owner_facet | DE-29T DE-83 DE-703 DE-11 |
| physical | xiv, 471 Seiten Illustrationen, Diagramme (teilweise farbig) |
| publishDate | 2020 |
| publishDateSearch | 2020 |
| publishDateSort | 2020 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Solid oxide fuel cells from electrolyte-based to electrolyte-free devices edited by Bin Zhu, Rizwan Raza, Liangdong Fan, Chunwen Sun Weinheim Wiley-VCH [2020] © 2020 xiv, 471 Seiten Illustrationen, Diagramme (teilweise farbig) txt rdacontent n rdamedia nc rdacarrier Brennstoffzelle (DE-588)4008195-3 gnd rswk-swf Hardback Batterien u. Brennstoffzellen Batteries & Fuel Cells Brennstoffzelle Chemie Chemistry Energie Energy Festoxidbrennstoffzelle Hydrogen, Batteries & Fuel Cells Materialien f. Energiesysteme Materials for Energy Systems Materials Science Materialwissenschaften Wasserstoff Wasserstoff, Batterien u. Brennstoffzellen CHA1: Batterien u. Brennstoffzellen EG32: Wasserstoff, Batterien u. Brennstoffzellen MSL0: Materialien f. Energiesysteme 1650: Hardcover, Softcover / Chemie (DE-588)4143413-4 Aufsatzsammlung gnd-content Brennstoffzelle (DE-588)4008195-3 s DE-604 Zhu, Bin edt Raza, Rizwan (DE-588)1208847074 edt Fan, Liangdong (DE-588)120884797X edt Sun, Chunwen (DE-588)1184344337 edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-81278-3 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-81280-6 Erscheint auch als Online-Ausgabe, oBook 978-3-527-81279-0 SWB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032131066&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Buchcover DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032131066&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Solid oxide fuel cells from electrolyte-based to electrolyte-free devices Brennstoffzelle (DE-588)4008195-3 gnd |
| subject_GND | (DE-588)4008195-3 (DE-588)4143413-4 |
| title | Solid oxide fuel cells from electrolyte-based to electrolyte-free devices |
| title_auth | Solid oxide fuel cells from electrolyte-based to electrolyte-free devices |
| title_exact_search | Solid oxide fuel cells from electrolyte-based to electrolyte-free devices |
| title_exact_search_txtP | Solid oxide fuel cells from electrolyte-based to electrolyte-free devices |
| title_full | Solid oxide fuel cells from electrolyte-based to electrolyte-free devices edited by Bin Zhu, Rizwan Raza, Liangdong Fan, Chunwen Sun |
| title_fullStr | Solid oxide fuel cells from electrolyte-based to electrolyte-free devices edited by Bin Zhu, Rizwan Raza, Liangdong Fan, Chunwen Sun |
| title_full_unstemmed | Solid oxide fuel cells from electrolyte-based to electrolyte-free devices edited by Bin Zhu, Rizwan Raza, Liangdong Fan, Chunwen Sun |
| title_short | Solid oxide fuel cells |
| title_sort | solid oxide fuel cells from electrolyte based to electrolyte free devices |
| title_sub | from electrolyte-based to electrolyte-free devices |
| topic | Brennstoffzelle (DE-588)4008195-3 gnd |
| topic_facet | Brennstoffzelle Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032131066&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032131066&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT zhubin solidoxidefuelcellsfromelectrolytebasedtoelectrolytefreedevices AT razarizwan solidoxidefuelcellsfromelectrolytebasedtoelectrolytefreedevices AT fanliangdong solidoxidefuelcellsfromelectrolytebasedtoelectrolytefreedevices AT sunchunwen solidoxidefuelcellsfromelectrolytebasedtoelectrolytefreedevices AT wileyvch solidoxidefuelcellsfromelectrolytebasedtoelectrolytefreedevices |