Intro -- Contents -- Preface -- About the Authors -- 1 Equilibrium Electrochemistry and the Nernst Equation -- 1.1 Chemical Equilibrium -- 1.2 Electrochemical Equilibrium: Introduction -- 1.3 Electrochemical Equilibrium: Electron Transfer at the Solution-Electrode Interface -- 1.4 Electrochemical Eq...

Ausführliche Beschreibung

Bibliographische Detailangaben

Hauptverfasser:	Compton, R. G. 1955- (VerfasserIn), Banks, Craig E. (VerfasserIn)
Format:	Elektronisch E-Book
Sprache:	English
Veröffentlicht:	New Jersey ; London ; Singapore World Scientific [2018]
Ausgabe:	Third edition
Schlagworte:	Elektrochemie Voltammetrie Voltammetry-Textbooks Electronic books
Online-Zugang:	FHN01 Volltext
Zusammenfassung:	Intro -- Contents -- Preface -- About the Authors -- 1 Equilibrium Electrochemistry and the Nernst Equation -- 1.1 Chemical Equilibrium -- 1.2 Electrochemical Equilibrium: Introduction -- 1.3 Electrochemical Equilibrium: Electron Transfer at the Solution-Electrode Interface -- 1.4 Electrochemical Equilibrium: The Nernst Equation -- 1.5 Walther Hermann Nernst -- 1.6 Reference Electrodes and the Measurement of Electrode Potentials -- 1.7 The Hydrogen Electrode as a Reference Electrode -- 1.8 Standard Electrode Potentials and Formal Potentials -- 1.9 Formal Potentials and Experimental Voltammetry -- 1.10 Electrode Processes: Kinetics vs. Thermodynamics -- References -- 2 Electrode Kinetics -- 2.1 Currents and Reaction Fluxes -- 2.2 Studying Electrode Kinetics Requires Three Electrodes -- 2.3 Butler-Volmer Kinetics -- 2.4 Standard Electrochemical Rate Constants and Formal Potentials -- 2.5 The Need for Supporting Electrolyte -- 2.6 The Tafel Law -- 2.7 Julius Tafel -- 2.8 Multistep Electron Transfer Processes -- 2.9 Tafel Analysis and the Hydrogen Evolution Reaction -- 2.10 B. Stanley Pons -- 2.11 Cold Fusion -The Musical! -- 2.12 Why Are Some Standard Electrochemical Rate Constants Large but Others Slow? The Marcus Theory of Electron Transfer: An Introduction -- 2.13 Marcus Theory: Taking it Further. Inner and Outer Sphere Electron Transfer -- 2.14 Marcus Theory: Taking it Further. Adiabatic and Non-Adiabatic Reactions -- 2.15 Marcus Theory: Taking it Further. Calculating the Gibbs Energy of Activation -- 2.16 Relationship between Marcus Theory and Butler-Volmer Kinetics -- 2.17 Marcus Theory and Experiment. Success! -- 2.18 Extending Marcus-Hush Theory: The Fermi-Dirac Distribution of Electrons. Symmetric vs. Asymmetric Marcus-Hush Theory -- References -- 3 Diffusion -- 3.1 Fick's 1st Law of Diffusion -- 3.2 Fick's 2nd Law of Diffusion
Beschreibung:	Description based on publisher supplied metadata and other sources
Beschreibung:	1 Online-Ressource (xvi, 439 Seiten) Illustrationen
ISBN:	9781786345271