Biochemistry: the molecular basis of life
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York ; Oxford
Oxford University Press
[2020]
|
| Ausgabe: | International seventh edition |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | This version of the text has been adapted and customised. Not for sale in the USA or Canada. |
| Beschreibung: | xxi, 723, A-32, G-14, C-2, I-19 Seiten Illustrationen, Diagramme |
| ISBN: | 9780190847685 |
Internformat
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| 264 | 1 | |a New York ; Oxford |b Oxford University Press |c [2020] | |
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Datensatz im Suchindex
| _version_ | 1804180957580754944 |
|---|---|
| adam_text | Contents Preface xv CHAPTER 1 Biochemistry: An Introduction l 1.1 What Is Life? 2 1.2 Biomolecules 4 Nucleus 49 Mitochondria Peroxisomes Chloroplasts Cytoskeleton Functional Groups of Organic Biomolecules 5 Major Classes of Small Biomolecules 5 1.3 Biochemistry IN PERSPECTIVE Is the Living Cell a Chemical Factory? 12 Biochemical Reactions 13 Energy 18 Overview of Metabolism 19 Biological Order 20 Primary Cilia and Human Disease 61 • Biochemistry IN THE LAB Ceti Technology 62 Chapter Summary 64 Keywords 65 Review Questions 66 1.4 Systems Biology 21 Emergence 22 Robustness 22 Systems Biology Model Concepts 23 Living Organisms and Robustness 24 • Biochemistry IN THE LAB An Introduction 25 Chapter Summary 25 Keywords 26 Review Questions 26 CHAPTER 2 CHAPTER 3 Water: The Matrix of Life 68 3.1 Molecular Structure of Water 69 3.2 Noncovalent Bonding 71 Ionic Interactions 71 Hydrogen Bonds 71 Van der Waals Forces 72 3.3 Thermal Properties of Water 73 3.4 Living Cells 29 2.1 2.2 Structure of Prokaryotic Cells 35 3.5 Plasma Membrane 39 Endoplasmic Reticulum 42 Golgi Apparatus 43 Vesicular Organelles and Lysosomes: The Endocytic Pathway 46 Ionisation of Water 82 Acids, Bases, and pH 83 Buffers 84 Physiological Buffers 91 í Biochemistry IN PERSPECTIVE Cell Volume Regulation and Metabolism 93 Cell Wall 36 Plasma Membrane 37 Cytoplasm 38 Pili and Flagella 38 2.3 Structure of Eukaryotic Cells 38 Solvent Properties of Water 75 Hydrophilic Molecules, Cell Water Structuring, and Sol-Gel Transitions 75 Hydrophobic Molecules and the Hydrophobic Effect 77 Amphipathic Molecules 78 Osmotic
Pressure 79 Core Biochemistry Concepts 30 Biochemistry and Water 31 Biological Membranes 31 Self-Assembly 32 Molecular Machines 32 Macromolecular Crowding 33 Proteostasis 33 Signal Transduction 34 52 55 56 56 Chapter Summary 94 Keywords 95 Review Questions 95 CHAPTER 4 Energy 98 4.1 Thermodynamics 100 First Law of Thermodynamics 101 Second Law of Thermodynamics 103
Contents x Effects of Temperature and pH on Enzyme-Catalysed Reactions 193 Detailed Mechanisms of Enzyme Catalysis 195 4.2 Free Energy 105 Standard Free Energy Changes 105 Coupled Reactions 106 The Hydrophobic Effect Revisited 107 4.3 6.4 Michaelis-Menten Kinetics 199 Lineweaver-Burk Plots 203 Multisubstrate Reactions 204 Enzyme Inhibition 205 Enzyme Kinetics, Metabolism, and Macromolecular Crowding 210 Energy Currency Molecules 110 Energy and Reducing Power 113 • Biochemistry IN PERSPECTIVE Nonequitibrium Thermodynamics and the Evolution of Life 109 Enzyme Regulation 211 Chapter Summary 114 Keywords 114 Review Questions 114 Genetic Control 212 Covalent Modification 212 Allosteric Regulation 212 Compartmentation 214 CHAPTER 5 Amino Acids, Peptides, and Proteins ііб 5.1 • Biochemistry IN PERSPECTIVE Amino Acids 117 Alcohol Dehydrogenase: A Tale of Two Species 216 Amino Acid Classes 120 Biologically Active Amino Acids 122 Modified Amino Acids in Proteins 123 Amino Acid Stereoisomers 123 Amino Acid lonisable Side Chain Groups and pH 124 Amino Add Reactions 127 Chapter Summary 217 Keywords 217 Review Questions 218 5.2 Peptides 130 5.3 Proteins 133 Functions 133 Shape and Composition 134 Protein Structure 135 The Folding Problem 150 Fibrous Proteins 154 Globular Proteins 158 CHAPTER 7 Carbohydrates 222 7.1 7.2 Disaccharides 236 7.3 Polysaccharides 237 Homoglycans 237 Heteroglycans 240 Spider Silk and Biomimetics 163 • Biochemistry IN THE LAB 7.4 7.5 The Sugar Code 246 Lectins: Translators of the Sugar Code 247 TheGlycome 249 Chapter Summary 250 Keywords 25D Review Questions 251
CHAPTER 6 Enzymes 175 Properties of Enzymes 176 Enzyme Catalysts: The Basics 176 Enzymes·. Activation Energy and Reaction Equilibrium 177 Enzymes and Macromolecular Crowding Effects 178 Enzyme Specificity 179 6.2 6.3 CHAPTER 8 Carbohydrate Metabolism 253 8.1 Glycolysis 255 The Reactions of the Glycolytic Pathway 258 The Fates of Pyruvate 263 The Energetics of Glycolysis 266 Regulation of Glycolysis 267 Classification of Enzymes 180 Catalysis 183 Organic Reactions and the Transition State 183 Transition State Stabilisation 184 Catalytic Mechanisms 186 The Roles of Amino Acids in Enzyme Catalysis 188 The Role of Cofactors in Enzyme Catalysis 190 Glycoconjugates 242 Proteoglycans 242 Glycoproteins 244 Protein Technology 166 Chapter Summary 171 Keywords 172 Review Questions 172 Monosaccharides 223 Monosaccharide Stereoisomers 224 Cyclic Structure of Monosaccharides 224 Reactions of Monosaccharides 227 Important Monosaccharides 233 Monosaccharide Derivatives 235 © Biochemistry IN PERSPECTIVE 6.1 Enzyme Kinetics 197 8.2 Gluconeogenesis 273 Gluconeogenesis Reactions 273 Gluconeogenesis Substrates 278 Gluconeogenesis Regulation 280
Contents 8.3 The Pentose Phosphate Pathway 281 8.4 Metabolism of Other Important Sugars 285 Fructose Metabolism 285 8.5 Glycogen Metabolism 287 Gtycogenesis 288 Glycogenolysis 289 Regulation of Glycogen Metabolism 289 Antioxidant Enzyme Systems 354 The Redox Proteome 356 Antioxidant Nutrients 357 it Biochemistry IN PERSPECTIVE Myocardial Infarct: Ischemia and Reperfusion 360 Chapter Summary 361 Keywords 361 Review Questions 361 і Biochemistry IN PERSPECTIVE Saccharomyces cerevisiae and the Crabtree Effect 268 CHAPTER 11 4 Biochemistry IN PERSPECTIVE Turbo Design Can Be Dangerous 274 Chapter Summary 295 Keywords 296 Review Questions 296 CHAPTER 9 Aerobic Metabolism I: The Citric Acid Cycle 298 9.1 Oxidation-Reduction Reactions 30D Redox Coenzymes 303 Aerobic Metabolism 307 9.2 Citric Acid Cycle 307 Conversion of Pyruvate to Acetyl-CoA 309 Reactions of the Citric Acid Cycle 312 Fate of Carbon Atoms in the Citric Acid Cycle 316 The Amphibolic Citric Acid Cycle 317 Citric Acid Cycle Regulation 319 The Citric Acid Cycle and Human Disease 321 The Glyoxylate Cycle 322 Biochemistry IN PERSPECTIVE Carcinogenesis·. The Warburg Effect and Metabolic Reprogramming 324 Chapter Summary 325 Keywords 325 Review Questions 326 CHAPTER 10 Aerobic Metabolism II: Electron Transport and Oxidative Phosphorylation 328 10.1 Electron Transport 329 Electron Transport and Its Components 330 Electron Transport: The Fluid State and Solid State Models 337 Electron Transport Inhibitors 338 1D.2 Oxidative Phosphorylation 339 The Chemiosmotic Theory 339 ATP Synthesis 341 Control of Oxidative Phosphorylation
343 Creatine Kinase and Creatine 343 The Complete Oxidation of Glucose 345 Uncoupled Electron Transport 348 10.3 Oxygen, Cell Signalling, and Oxidative Stress 349 Reactive Oxygen Species 350 Lipids and Membranes 364 11.1 Lipid Classes 365 Fatty Acids 365 The Eicosanoids 368 Triacylglycerols 370 Wax Esters 371 Phospholipids 371 Phospholipases 374 Sphingolipids 375 Sphingolipid Storage Diseases 377 Isoprenoids 377 Lipoproteins 381 11.2 Membranes 384 Membrane Structure 385 Membrane Function 390 Chapter Summary 397 Keywords 398 Review Questions 398 CHAPTER 12 Lipid Metabolism 400 12.1 Fatty Acids, Triacylglerols, and the Lipoprotein Pathways 401 Dietary Fat: Digestion, Absorption, and Transport 401 Triacylglycerol Metabolism in Adipocytes 403 Fatty Acid Degradation 407 The Complete Oxidation of a Fatty Acid 411 Fatty Acid Oxidation: Double Bonds and Odd Chains 413 Fatty Acid Biosynthesis 416 Regulation of Fatty Acid Metabolism in Mammals 424 Lipoprotein Metabolism: The Endogenous Pathway 428 12.2 Membrane Lipid Metabolism 428 Phospholipid Metabolism 428 12.3 Isoprenoid Metabolism 431 Cholesterol Metabolism 431 The Cholesterol Biosynthetic Pathway and Drug Therapy 440 @ Biochemistry IN PERSPECTIVE Atherosclerosis 429 Biochemistry IN PERSPECTIVE Biotransformation 441 Chapter Summary 443 KeyWords 443 Review Questions 443
xii Contents CHAPTER 13 Photosynthesis 445 13.1 Chlorophyll and Chloroplasts 447 13.2 Light 453 13.3 Light Reactions 456 Photosystem II and Water Oxidation 458 Photosystem I and NAŪPH Synthesis 460 Photophosphorylation 462 13.4 The Light-Independent Reactions 463 The Calvin Cycle 463 Photorespiration 467 Alternatives to C3 Metabolism 468 13.5 Regulation of Photosynthesis 470 Light Control of Photosynthesis 470 Control of Ribulose-1,5-Bisphosphate Carboxylase 471 S Biochemistry IN PERSPECTIVE The Artificial Leaf: Biomimetic Photosynthesis 473 Chapter Summary 474 KeyWords 474 Review Questions 475 CHAPTER 14 Nitrogen Metabolism I: Synthesis 477 14.1 Nitrogen Fixation 478 The Nitrogen Fixation Reaction 479 Nitrogen Assimilation 481 14.2 Amino Acid Biosynthesis 482 Amino Acid Metabolism Overview 482 Reactions of Amino Groups 483 Biosynthesis of the Amino Acids 487 14.3 Biosynthetic Reactions Involving Amino Acids 493 One-Carbon Metabolism 493 Glutathione 499 Neurotransmitters 501 Nucleotides 5Û4 Haem 513 1 Biochemistry IN PERSPECTIVE Gasotransmitters 502 Chapter Summary 514 KeyWords 514 Review Questions 514 Control of the Urea Cycle 526 Catabolism of Amino Acid Carbon Skeletons 527 15.3 Nucleotide Degradation 536 Purine Catabolism 536 Pyrimidine Catabolism 538 і» Biochemistry IN PERSPECTIVE Disorders of Amino Add Catabolism 535 Chapter Summary 540 KeyWords 540 Review Questions 540 CHAPTER 16 Integration of Metabolism 542 16.1 Overview of Metabolism 543 16.2 Intercellular Communication 545 Polypeptide Signal Molecules 546 Cell-Surface Receptors 547 Enzyme-Linked Receptors 552
Nuclear Receptors 556 16.3 Metabolism in the Mammalian Body: The Feeding-Fasting Cycle 560 The Feeding Phase 561 The Fasting Phase 564 Feeding Behaviour 565 Biochemistry IN PERSPECTIVE Diabetes Mellitus 557 * Biochemistry IN PERSPECTIVE Obesity and the Metabolic Syndrome 568 Chapter Summary 569 KeyWords 570 Review Questions 570 CHAPTER 17 Nucleic Acids 573 17.1 DNA 577 DNA Structure: The Nature of Mutation 580 DNA Structure: The Genetic Material 584 DNA Structure: Variations on a Theme 585 DNÂ Supercoiling 587 Chromosomes 589 Genome Structure 595 17.2 RNA 600 CHAPTER 15 Nitrogen Metabolism II: Degradation 516 15.1 Protein Turnover 517 Ubiquitin Proteasomal System 518 Autophagy-Lysosomal System 520 15.2 Amino Acid Catabolism 521 Deamination 521 Urea Synthesis 522 Transfer RNA 604 Ribosomal RNA 611 Messenger RNA 612 Noncoding RNA 612 17.3 Viruses 614 Bacteriophage T4: A Viral Lifestyle 615 • Biochemistry IN PERSPECTIVE Epigenetics and the Epigenome: Genetic Inheritance beyond DNA Base Sequences 601
Contents • Biochemistry IN THE LAB Chapter Summary 681 Keywords 681 Review Questions 682 Nucleic Acid Methods 605 в Biochemistry IN PERSPECTIVE Forensic Investigations 610 CHAPTER 19 ® Biochemistry IN PERSPECTIVE Protein Synthesis 685 Ebola Virus 617 19.1 The Genetic Code 687 Chapter Summary 619 Keywords 619 Review Questions 620 Codon-Anticodon Interactions 689 The Aminoacyl-tRNA Synthetase Reaction 690 19.2 Protein Synthesis 692 Prokaryotic Protein Synthesis 695 Eukaryotic Protein Synthesis 701 CHAPTER 18 Genetic Information 623 18.1 Genetic Information: Replication, Repair, and Recombination DNÄ Replication 625 ONA Repair 635 DNA Recombination 640 18.2 Transcription 654 Transcription in Prokaryotes 655 RNAP and the Prokaryotic Transcription Process 656 Transcription in Eukaryotes 659 18.3 Gene Expression 668 Gene Expression in Prokaryotes 668 Gene Expression in Eukaryotes 671 • Biochemistry IN THE LAB Genomics 648 Փ Biochemistry IN THE LAB CRISPR 667 Biochemistry IN PERSPECTIVE Carcinogenesis 679 625 19.3 The Proteostasis Network 718 The Heat Shock Response 719 The Proteostasis Network and Human Disease 719 ® Biochemistry IN PERSPECTIVE Trapped Ribosomes: RNA to the Rescue! 703 # Biochemistry IN PERSPECTIVE Context-Dependent Coding Reassignment 708 • Biochemistry IN THE LAB Proteomics 720 Chapter Summary 721 Keywords 721 Review Questions 722 Appendix: Solutions A-1 Glossary G-1 Credits C-1 Index 1-1
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| isbn | 9780190847685 |
| language | English |
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| spelling | MacKee, Trudy Verfasser aut Biochemistry the molecular basis of life Trudy McKee, James R. McKee International seventh edition New York ; Oxford Oxford University Press [2020] xxi, 723, A-32, G-14, C-2, I-19 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier This version of the text has been adapted and customised. Not for sale in the USA or Canada. Biochemie (DE-588)4006777-4 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Biochemie (DE-588)4006777-4 s DE-604 MacKee, James R. Verfasser aut Digitalisierung UB Regensburg - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031828177&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | MacKee, Trudy MacKee, James R. Biochemistry the molecular basis of life Biochemie (DE-588)4006777-4 gnd |
| subject_GND | (DE-588)4006777-4 (DE-588)4123623-3 |
| title | Biochemistry the molecular basis of life |
| title_auth | Biochemistry the molecular basis of life |
| title_exact_search | Biochemistry the molecular basis of life |
| title_full | Biochemistry the molecular basis of life Trudy McKee, James R. McKee |
| title_fullStr | Biochemistry the molecular basis of life Trudy McKee, James R. McKee |
| title_full_unstemmed | Biochemistry the molecular basis of life Trudy McKee, James R. McKee |
| title_short | Biochemistry |
| title_sort | biochemistry the molecular basis of life |
| title_sub | the molecular basis of life |
| topic | Biochemie (DE-588)4006777-4 gnd |
| topic_facet | Biochemie Lehrbuch |
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