Homogeneous hydrogenation with non-precious catalysts:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2020
|
| Schlagworte: | |
| Online-Zugang: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34439-0/ Inhaltsverzeichnis |
| Beschreibung: | x, 298 Seiten Illustrationen |
| ISBN: | 9783527344390 352734439X |
Internformat
MARC
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| 245 | 1 | 0 | |a Homogeneous hydrogenation with non-precious catalysts |c edited by Johannes F. Teichert |
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| 653 | |a Nachhaltige u. Grüne Chemie | ||
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Datensatz im Suchindex
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| adam_text | V
CONTENTS
PREFACE
IX
PRELUDE
-
A
CRITICAL
ASSESSMENT
FROM
AN
INDUSTRIAL
POINT
OF
VIEW
1
HANS-ULRICH
BLASER
1
1.1
SOME
INTRODUCTORY
REMARKS
1
WHAT
IS
THE
MOTIVATION
FOR
DEVELOPING
NON-NOBLE
METAL
CATALYSTS?
2
1.2
1.2.1
1.2.2
2
2.1
CRUCIAL
PARAMETERS
FOR
PROCESS
DEVELOPMENT
3
THE
CATALYST:
METAL
COMPLEX,
(CHIRAL)
LIGAND
4
THE
PROCESS
5
COMPARISON
WITH
THE
ESTABLISHED
CATALYSTS
5
CHEMOSELECTIVE
HYDROGENATIONS:
ALTERNATIVES
TO
HETEROGENEOUS
CATALYSTS
6
2.1.1
2.1.2
2.1.3
2.2
2.3
3
HYDROGENATION
OF
ESTERS
6
E-SELECTIVE
HYDROGENATION
OF
ALKYNES
7
SELECTIVE
C=O
REDUCTION
OF
UNSATURATED
CARBONYL
GROUPS
7
ENANTIOSELECTIVE
HYDROGENATIONS
8
A
FEW
REMARKABLE
TRANSFORMATIONS
USING
CU
AND
CO
COMPLEXES
9
EPILOGUE
10
REFERENCES
13
1
IRON-CATALYZED
HOMOGENEOUS
HYDROGENATION
REACTIONS
15
THOMAS
ZELL
AND
ROBERT
LANGER
1.1
1.2
1.3
1.3.1
1.3.2
1.3.3
1.4
1.4.1
1.4.2
1.5
1.5.1
INTRODUCTION
15
FUNDAMENTAL
DIFFERENCES BETWEEN
NOBLE
AND
3D
METAL
COMPLEXES
17
MECHANISTIC
SCENARIOS
AND
THE
ROLE
OF
SUBSTRATES
22
NONPOLAR
SUBSTRATES
22
POLAR
SUBSTRATES
24
EXCEPTIONS
25
IRON-CATALYZED
HYDROGENATION
OF
C
*
C
MULTIPLE
BONDS
26
HYDROGENATION
OF
OLEFINS
26
HYDROGENATION
OF
ALKYNES
27
IRON-CATALYZED
HYDROGENATION
OF
C
*
O
MULTIPLE
BONDS
28
HYDROGENATION
OF
ALDEHYDES
AND
KETONES
29
VI
CONTENTS
1.5.2
HYDROGENATION
OF
ESTERS
31
1.5.3
HYDROGENATION
OF
AMIDES
32
1.6
IRON-CATALYZED
HYDROGENATION
OF
C
*
N
MULTIPLE
BONDS
32
1.7
CONCLUSION
34
ABBREVIATIONS
35
REFERENCES
35
2
COBALT-CATALYZED
HYDROGENATIONS
39
FELICIA
WEBER
AND
GERHARD
HILT
2.1
INTRODUCTION
39
2.2
HYDROGENATION
REACTIONS
39
2.2.1
ACTIVATION
OF
MOLECULAR
HYDROGEN-DIHYDROGEN
COMPLEXES
VS.
DIHYDRIDE
COMPLEXES
39
2.2.2
HYDROGENATION
OF
CO
2
,
CARBOXYLIC
ACIDS,
CARBOXYLIC
ESTERS,
AND
NITRILES
40
2.2.3
HYDROGENATION
OF
C=O,
C=N,
C=C,
C=C,
AND
(HETERO)ARENES
46
2.3
CONCLUSION
57
REFERENCES
57
3
HOMOGENEOUS
NICKEL-CATALYZED
HYDROGENATIONS
63
MARLENE
BOLDL
AND
IVANA
FLEISCHER
3.1
INTRODUCTION
63
3.2
HYDROGENATION
OF
ALKENES
65
3.2.1
HYDROGENATION
OF
ALKYL-
AND
ARYL-SUBSTITUTED
ALKENES
65
3.2.2
HYDROGENATION
OF
ELECTRON-DEFICIENT
ALKENES
76
3.3
HYDROGENATION
OF
ALKYNES
78
3.4
HYDROGENATION
OF
CARBONYL
GROUPS
79
3.4.1
HYDROGENATION
OF
KETONES
79
3.4.2
HYDROGENATION
OF
CARBON
DIOXIDE
81
3.5
CONCLUSIONS
83
REFERENCES
83
4
HOMOGENEOUS
HYDROGENATION
WITH
COPPER
CATALYSTS
87
NIKLAS
0.
THIEL,
FELIX
PAPE,
AND
JOHANNES
F.
TEICHERT
4.1
INTRODUCTION
87
4.1.1
EARLY
STUDIES
ON
COPPER-CATALYZED
HYDROGENATIONS
87
4.2
HYDROGENATION
OF
(A,P-UNSATURATED)
CARBONYL
AND
CARBOXYL
COMPOUNDS
88
4.2.1
CONJUGATE
REDUCTION
88
4.2.2
1,2-HYDROGENATION
OF
A,|3-UNSATURATED
KETONES
AND
ALDEHYDES
91
4.2.3
ASYMMETRIC
1,2-HYDROGENATION
OF
SIMPLE
(NONCONJUGATED)
KETONES
AND
ALDEHYDES
92
4.3
CO
2
REDUCTION
TO
FORMATE
93
4.4
ALLYLIC
SUBSTITUTIONS
WITH
A
HYDRIDE
NUCLEOPHILE
GENERATED
FROM
H
2
95
4.5
Z-SELECTIVE
ALKYNE
SEMIHYDROGENATION
98
CONTENTS
VII
4.6
ALKYNE
TRANSFER
SEMIHYDROGENATION
AND
TRANSFER
CONJUGATE
REDUCTION
WITH
AMMONIA
BORANE
104
4.7
DIHYDROGEN-MEDIATED
CROSS-COUPLING
OF
INTERNAL
ALKYNES
AND
ARYL
IODIDES
105
4.8
CONCLUSIONS
AND
PERSPECTIVES
106
REFERENCES
107
5
HYDROGENATION
REACTIONS
USING
GROUP
III
TO
GROUP
VII
TRANSITION
METALS
111
MATTHEW
L.
CLARKE
AND
MAGNUS
B.
WIDEGREN
5.1
5.2
5.3
5.3.1
INTRODUCTION
111
GROUP
III
METALS:
SCANDIUM
AND
YTTRIUM
111
GROUP
IV
METALS:
TITANIUM,
ZIRCONIUM,
AND
HAFNIUM
112
ASYMMETRIC
HYDROGENATION
USING
TITANIUM AND
ZIRCONIUM
CATALYSTS
115
5.4
5.5
5.6
5.7
GROUP
V
METALS:
VANADIUM,
NIOBIUM,
AND
TANTALUM
119
GROUP
VI
METALS:
CHROMIUM,
MOLYBDENUM,
AND
TUNGSTEN
121
GROUP
VII
METALS:
MANGANESE
AND
RHENIUM
122
SUMMARY
AND
CONCLUSIONS
137
REFERENCES
137
6
EARLY
MAIN
GROUP
METAL
CATALYZED
HYDROGENATION
141
HEIKO
BAUER
AND
SJOERD
HARDER
6.1
6.2
6.3
6.4
6.5
INTRODUCTION
141
HYDROGENATION
OF
C=C
DOUBLE
BONDS
144
HYDROGENATION
OF
C=N
DOUBLE
BONDS
153
HYDROGENATION
OF
C-O
DOUBLE
BONDS
157
SUMMARY
AND
PERSPECTIVES
160
REFERENCES
163
7
FRUSTRATED
LEWIS
PAIR-CATALYZED
REDUCTIONS
USING
MOLECULAR
HYDROGEN
167
JAN
PARODIES
AND
SEBASTIAN
TUSSING
7.1
7.2
7.3
INTRODUCTION
167
MECHANISTIC
CONSIDERATIONS
168
INFLUENCE
OF
THE
LEWIS
ACID
AND
LEWIS
BASE
ON
HYDROGENATION
REACTIVITY
171
7.3.1
7.4
7.4.1
7.4.2
7.4.3
7.4.4
7.4.5
7.5
7.5.1
CHOICE
OF
LEWIS
ACID
172
BALANCE
BETWEEN
LEWIS
ACIDITY
AND
LEWIS
BASICITY
173
HYDROGENATION
OF
OLEFINS
178
DEHYDROGENATIVE
COUPLING
179
ACCEPTORLESS
DEHYDROGENATION
180
INTRAMOLECULAR
FRUSTRATED
LEWIS
PAIRS
181
AIR-STABLE
FLPS
184
APPLICATION
OF
FRUSTRATED
LEWIS
PAIRS
IN
HYDROGENATIONS
187
HYDROGENATION
OF
ALDIMINES
AND
KETIMINES
187
VIII
CONTENTS
INDEX
285
7.5.2
7.5.3
7.5.4
7.6
7.7
HYDROGENATION
OF
ENAMINES
AND
SILYLENOL
ETHERS
193
HYDROGENATION
OF
KETONES
198
REDUCTIVE
DEOXYGENATIONS
198
HYDROGENATION
OF
HETEROCYCLES
201
HYDROGENATION
OF
ENONES,
ALKYLIDENE
MALONATES,
AND
NITROOLEFINS
207
7.8
HYDROGENATION
OF
UNPOLARIZED
OLEFINS
AND
POLYCYCLIC
AROMATIC
HYDROCARBONS
211
7.9
7.10
ELECTROPHILIC
PHOSPHONIUM
CATIONS
(EPCS)
215
SUMMARY
217
ABBREVIATIONS
217
REFERENCES
218
8
RECENT
ADVANCES
IN
SELECTIVE
BIOCATALYTIC
(HYDROGEN
TRANSFER)
REDUCTIONS
227
GONZALO
DE
GONZALO
AND
IVAN
LAVANDERA
8.1
8.2
8.2.1
8.2.2
8.2.3
8.2.4
INTRODUCTION
227
KETOREDUCTASES
228
ALCOHOL
DEHYDROGENASES
IN
*
NONCONVENTIONAL
*
MEDIA
229
DYNAMIC
PROCESSES
EMPLOYING
KETOREDUCTASES
230
ALCOHOL
DEHYDROGENASES
IN
MULTICATALYTIC
PROCESSES
232
APPLICATION
OF
KETOREDUCTASES
TO
THE
SYNTHESIS
OF
VALUABLE
COMPOUNDS
236
8.3
8.3.1
8.3.2
8.4
8.5
8.6
8.7
ENE-REDUCTASES
241
SUBSTRATE
SCOPE
OF
ENE-REDUCTASES
242
ENE-REDUCTASES
IN
MULTICATALYTIC
PROCESSES
244
IMINE
REDUCTASES
248
CARBOXYLIC
ACID
REDUCTASES
249
EMERGING
ENZYMES:
NITRILE
REDUCTASES
AND
NITROREDUCTASES
250
SUMMARY
AND
OUTLOOK
251
ABBREVIATIONS
252
REFERENCES
253
9
ORGANOCATALYTIC
TRANSFER
HYDROGENATION
261
LIE
WANG
AND
YONG-GUL
ZHOU
9.1
9.2
9.3
9.4
9.5
9.6
INTRODUCTION
261
ASYMMETRIC
TRANSFER
HYDROGENATION
OF
C=C
BONDS
262
ASYMMETRIC
TRANSFER
HYDROGENATION
OF
C=N
BONDS
266
ASYMMETRIC
TRANSFER
HYDROGENATION
OF
C=O
BONDS
273
ASYMMETRIC
TRANSFER
HYDROGENATION
OF
HETEROAROMATICS
274
SUMMARY
AND
OUTLOOK
280
ABBREVIATIONS
280
REFERENCES
281
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV046312110 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T08:41:20Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527344390 352734439X |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-031689263 |
| oclc_num | 1137731170 |
| open_access_boolean | |
| owner | DE-11 |
| owner_facet | DE-11 |
| physical | x, 298 Seiten Illustrationen |
| publishDate | 2020 |
| publishDateSearch | 2020 |
| publishDateSort | 2020 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Homogeneous hydrogenation with non-precious catalysts edited by Johannes F. Teichert Weinheim Wiley-VCH 2020 © 2020 x, 298 Seiten Illustrationen txt rdacontent n rdamedia nc rdacarrier Katalyse (DE-588)4029921-1 gnd rswk-swf Hydrierung (DE-588)4160891-4 gnd rswk-swf Homogene Reaktion (DE-588)4160582-2 gnd rswk-swf Hardback Biochemie Biochemie u. Chemische Biologie Catalysis Chemie Chemistry Katalyse Methods - Synthesis & Techniques Nachhaltige u. Grüne Chemie Organische Chemie Organische Chemie / Methoden, Synthesen, Verfahren Sustainable Chemistry & Green Chemistry CH40: Katalyse CH81: Organische Chemie / Methoden, Synthesen, Verfahren CHB0: Biochemie u. Chemische Biologie CHC0: Nachhaltige u. Grüne Chemie 1654: Hardcover, Softcover / Chemie/Organische Chemie (DE-588)4143413-4 Aufsatzsammlung gnd-content Hydrierung (DE-588)4160891-4 s Homogene Reaktion (DE-588)4160582-2 s Katalyse (DE-588)4029921-1 s DE-604 Teichert, Johannes Florian 1980- (DE-588)132282836 edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, ePDF 978-3-527-81422-0 Erscheint auch als Online-Ausgabe, oBook 978-3-527-81423-7 Erscheint auch als Online-Ausgabe, ePub 978-3-527-81420-6 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34439-0/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031689263&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Homogeneous hydrogenation with non-precious catalysts Katalyse (DE-588)4029921-1 gnd Hydrierung (DE-588)4160891-4 gnd Homogene Reaktion (DE-588)4160582-2 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4160891-4 (DE-588)4160582-2 (DE-588)4143413-4 |
| title | Homogeneous hydrogenation with non-precious catalysts |
| title_auth | Homogeneous hydrogenation with non-precious catalysts |
| title_exact_search | Homogeneous hydrogenation with non-precious catalysts |
| title_full | Homogeneous hydrogenation with non-precious catalysts edited by Johannes F. Teichert |
| title_fullStr | Homogeneous hydrogenation with non-precious catalysts edited by Johannes F. Teichert |
| title_full_unstemmed | Homogeneous hydrogenation with non-precious catalysts edited by Johannes F. Teichert |
| title_short | Homogeneous hydrogenation with non-precious catalysts |
| title_sort | homogeneous hydrogenation with non precious catalysts |
| topic | Katalyse (DE-588)4029921-1 gnd Hydrierung (DE-588)4160891-4 gnd Homogene Reaktion (DE-588)4160582-2 gnd |
| topic_facet | Katalyse Hydrierung Homogene Reaktion Aufsatzsammlung |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34439-0/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031689263&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT teichertjohannesflorian homogeneoushydrogenationwithnonpreciouscatalysts AT wileyvch homogeneoushydrogenationwithnonpreciouscatalysts |