Verfügbarkeit: Organosilicon chemistry

Organosilicon chemistry: novel approaches and reactions

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Bibliographische Detailangaben
Weitere Verfasser:	Hiyama, Tamejirō 1946- (HerausgeberIn), Oestreich, Martin 1971- (HerausgeberIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Weinheim Wiley-VCH [2019]
Schlagworte:	Siliciumorganische Verbindungen Hardback Chemie Chemistry Homogene Katalyse Homogeneous Catalysis Industrial Chemistry Methods - Synthesis & Techniques Organische Chemie / Methoden, Synthesen, Verfahren Technische u. Industrielle Chemie CH30: Technische u. Industrielle Chemie CH42: Homogene Katalyse CH81: Organische Chemie / Methoden, Synthesen, Verfahren 1654: Hardcover, Softcover / Chemie/Organische Chemie Aufsatzsammlung
Online-Zugang:	http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34453-6/ Inhaltsverzeichnis
Beschreibung:	xv, 550 Seiten Illustrationen
ISBN:	9783527344536

Internformat

MARC


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245	1	0	\|a Organosilicon chemistry \|b novel approaches and reactions \|c edited by Tamejiro Hiyama, Martin Oestreich
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653			\|a Chemistry
653			\|a Homogene Katalyse
653			\|a Homogeneous Catalysis
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653			\|a Methods - Synthesis & Techniques
653			\|a Organische Chemie / Methoden, Synthesen, Verfahren
653			\|a Technische u. Industrielle Chemie
653			\|a CH30: Technische u. Industrielle Chemie
653			\|a CH42: Homogene Katalyse
653			\|a CH81: Organische Chemie / Methoden, Synthesen, Verfahren
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Datensatz im Suchindex

_version_	1804180726546956288
adam_text	V CONTENTS FOREWORD XIII PREFACE XV 1 CATALYTIC GENERATION OF SILICON NUCLEOPHILES 1 KOJI KUBOTA AND HAJIME ITO 1.1 1.2 1.2.1 1.2.1.1 1.2.1.2 1.2.1.3 1.2.2 1.2.2.1 1.2.2.2 1.2.2.3 1.2.2.4 1.2.2.5 1.2.2.6 1.2.2.7 1.2.2.8 1.2.2.9 1.2.2.10 1.2.2.11 1.2.2.12 1.2.2.13 1.2.2.14 1.2.3 1.3 1.3.1 1.3.2 INTRODUCTION 1 SILICON NUCLEOPHILES WITH COPPER CATALYSTS 2 COPPER-CATALYZED NUCLEOPHILIC SILYLATION WITH DISILANES 2 SILYLATION OF A,P-UNSATURATED CARBONYL COMPOUNDS 2 SILYLATION OF ALKYLIDENE MALONATES 3 SILYLATION OF ALLYLIC CARBAMATES 3 COPPER-CATALYZED NUCLEOPHILIC SILYLATION WITH SILYLBORONATE 4 SILICON-BORON BOND ACTIVATION WITH COPPER ALKOXIDE 4 SILYLATION OF A,P-UNSATURATED CARBONYL COMPOUNDS 4 CATALYTIC ALLYLIC SILYLATION 7 CATALYTIC SILYLATION OF IMINES 9 CATALYTIC SILYLATION OF ALDEHYDES 9 CATALYTIC SYNTHESIS OF ACYLSILANES 11 SILYLATIVE CARBOXYLATION WITH CO 2 11 CO2 REDUCTION VIA SILYLATION 13 SILYL SUBSTITUTION OF ALKYL ELECTROPHILES 13 DECARBOXYLATIVE SILYLATION 14 SILYLATIVE CYCLIZATION 15 SILYLATIVE ALLYLATION OF KETONES 15 SILYLATION OF ALKYNES 16 PROPARGYLIC SUBSTITUTION 1 9 COPPER-CATALYZED NUCLEOPHILIC SILYLATION WITH SILYLZINCS 20 SILICON NUCLEOPHILES WITH RHODIUM CATALYSTS 21 RHODIUM-CATALYZED NUCLEOPHILIC SILYLATION WITH DISILANES 21 RHODIUM-CATALYZED NUCLEOPHILIC SILYLATION WITH SILYLBORONATES 21 1.3.2.1 1.3.2.2 CONJUGATE SILYLATION 21 COUPLING BETWEEN PROPARGYLIC CARBONATES TO FORM ALLENYLSILANES 22 1.4 SILICON NUCLEOPHILES WITH NICKEL CATALYSTS 22 VI CONTENTS 1.4.1 NICKEL-CATALYZED NUCLEOPHILIC SILYLATION WITH ALKYL ELECTROPHILES 22 1.5 1.5.1 SILICON NUCLEOPHILES WITH LEWIS BASE CATALYSTS 23 N-HETEROCYCLIC CARBENE-CATALYZED NUCLEOPHILIC 1,4-SILYLATION 23 1.5.2 1.5.3 1.6 ALKOXIDE BASE-CATALYZED 1,2-SILABORATION 24 PHOSPHINE-CATALYZED 1,2-SILABORATION 24 CLOSING REMARKS 25 ABBREVIATIONS 25 REFERENCES 26 2 SI * H BOND ACTIVATION BY MAIN-GROUP LEWIS ACIDS 33 DIETER WEBER AND MICHEL R. GAGNE 2.1 2.1.1 2.1.2 2.1.3 2.1.4 2.2 2.2.1 2.2.2 INTRODUCTION TO SILANES AND THE SI * H BOND 33 OVERVIEW OF THE DISCOVERY AND THE HISTORY OF SILANES 33 A COMPARISON OF HYDROCARBONS AND HYDROSILICONS 34 STABILITY OF THE SILICON-HYDROGEN BOND 35 THE SILYLIUM ION 35 THE ACTIVATION OF SI * H BONDS BY BORON LEWIS ACIDS 36 TRIS(PENTAFLUOROPHENYL)BORANE (BCE) 36 THE CATALYTIC ACTIVATION OF SI * H BONDS BY BCE AND OTHER BORANES 36 2.2.2.1 THE MECHANISM OF BORANE-CATALYZED SI * H BOND ACTIVATION 36 2.2.2.2 2.2.3 ADDITIONAL MECHANISTIC ASPECTS 38 CATEGORIZING REDUCTION TYPES OF N AND O BONDS INVOLVING THE RP-EBJ-H-FSI] ADDUCT 40 2.2.3.1 2.2.3.2 2.2.3.3 2.2.3.4 2.2.3.5 2.2.3.6 2.3 TYPE I: THE REDUCTION OF POLAR N BONDS (EL=NU/EL=NU) 40 TYPE II: THE REDUCTION OF POLAR O BONDS (EL-NU) 45 TYPE III: THE REDUCTION OF NONPOLAR N BONDS (A=A/A=A) 55 TYPE IV: THE REDUCTION OF NONPOLAR O BONDS (A * A) 58 COMBINATION OF REDUCTION TYPES 61 MECHANISTIC VARIATION OF REDUCTION TYPES 66 THE ACTIVATION OF SI * H BONDS BY ALUMINUM LEWIS ACIDS 72 2.4 2.4.1 2.4.2 2.4.3 THE ACTIVATION OF SI * H BONDS BY GROUP 14 LEWIS ACIDS 73 INTRODUCTION 73 CARBOCATIONS AS LEWIS ACIDS 73 CATIONIC TRI-COORDINATE SILYLIUM IONS AND NEUTRAL SI(IV) LEWIS ACIDS 74 2.5 THE ACTIVATION OF SI * H BONDS BY PHOSPHOROUS-BASED LEWIS ACIDS 75 2.5.1 2.5.2 2.6 P(III) LEWIS ACIDS 75 P(V) LEWIS ACIDS 76 SUMMARY AND CONCLUSIONS 76 ACKNOWLEDGMENTS 77 REFERENCES 77 CONTENTS VII 3 SI * H BOND ACTIVATION BY TRANSITION-METAL LEWIS ACIDS 87 GEORGII 1. NIKONOV REFERENCES 111 4 METAL-LIGAND COOPERATIVE SI * H BOND ACTIVATION 115 FRANCIS FORSTER AND MARTIN OESTREICH 4.1 4.2 INTRODUCTION 115 COOPERATIVE SI * H BOND ACTIVATION WITH CARBENE COMPLEXES ACROSS M * C DOUBLE BONDS 116 4.3 4.4 4.5 4.5.1 4.5.2 COOPERATIVE SI * H BOND ACTIVATION AT M * N BONDS 116 COOPERATIVE SI * H BOND ACTIVATION AT M * O BONDS 117 COOPERATIVE SI * H BOND ACTIVATION AT M * S BONDS 118 INTRODUCTION 118 SEMINAL RESULTS IN COOPERATIVE SI * H BOND ACTIVATION ACROSS M S BONDS 119 4.5.3 4.5.4 4.5.5 DEHYDROGENATIVE C H SILYLATION 123 COMPETING DEHYDROGENATIVE COUPLING AND HYDROSILYLATION 125 C * H SILYLATION BY HYDROSILYLATION/DEHYDROGENATIVE SILYLATION/ RETRO-HYDROSILYLATION 126 4.6 SUMMARY 127 REFERENCES 128 5 CATIONIC SILICON-BASED LEWIS ACIDS IN CATALYSIS 131 POLINA SHAYKHUTDINOVA, SEBASTIAN KEESS, AND MARTIN OESTREICH 5.1 5.2 5.2.1 5.2.2 5.3 5.3.1 5.3.2 INTRODUCTION 131 DEOXYGENATION AND HYDROSILYLATION OF C=X MULTIPLE BONDS 131 DEOXYGENATION OF C=O BONDS 131 HYDROSILYLATION OF C=O, C=N, C=C, AND C=C BONDS 133 C * F BOND ACTIVATION 137 HYDRODEFLUORINATION 137 DEFLUORINATION COUPLED WITH ELECTROPHILIC AROMATIC SUBSTITUTION (S E AR) 144 5.4 5.5 5.6 FRIEDEL-CRAFTS C-H SILYLATION 149 DIELS-ALDER REACTIONS 153 MUKAIYAMA ALDOL AND RELATED REACTIONS 163 REFERENCES 167 6 TRANSITION-METAL-CATALYZED C * H BOND SILYLATION 171 YOSHIYA FUKUMOTO AND NAOTO CHATANI 6.1 6.2 6.3 C(SP) * H BOND SILYLATION 171 C(SP 2 ) * H BOND SILYLATION 174 C(SP 3 ) * H BOND SILYLATION 198 REFERENCES 207 7 TRANSITION-METAL-FREE CATALYTIC C H BOND SILYLATION 213 DAVID P. SCHUMAN, WEN-BO LIU, NASRI NESNAS, AND BRIAN M. STOLTZ 7.1 INTRODUCTION 213 VIII I CONTENTS 7.2 7.2.1 7.2.2 7.2.3 7.3 7.4 7.4.1 7.4.2 7.4.3 7.5 7.5.1 7.5.2 7.5.2.1 7.5.2.2 LEWIS ACID 213 BC1 3 CATALYST 213 B(C 6 F 5 ) 3 , A FRUSTRATED * LEWIS ACID CATALYST 214 LEWIS ACID CONCLUSIONS 222 BRONSTED ACID 222 BRONSTED BASE 224 EARLY EXAMPLE OF CATALYTIC C-H SILYLATION BY BRONSTED BASE 224 FLUORIDE/BASE CATALYSIS 224 BRONSTED BASE-CATALYZED C-H SILYLATION OF ALKYNES 226 RADICAL DEHYDROSILYLATION 229 * ELECTRON * AS A C-H SILYLATION CATALYST 229 DISCOVERY OF UNUSUAL KO-BU-CATALYZED C-H SILYLATION 231 KOT-BU-CATALYZED C-H SILYLATION METHODOLOGY 232 MECHANISTIC INVESTIGATIONS OF KOZ-BU-CATALYZED C-H SILYLATION AND RELATED CHEMISTRY 234 7.6 7.7 C(SP 3 )-H SILYLATION 238 CONCLUSION 238 REFERENCES 239 8 SILYL-HECK, SILYL-NEGISHI, AND RELATED REACTIONS 241 SARAH B. KRAUSE AND DONALD A. WATSON 8.1 8.1.1 8.1.1.1 8.1.1.2 8.1.1.3 8.2 8.2.1 8.2.2 8.2.3 8.2.4 8.2.5 8.2.6 INTRODUCTION 241 ACTIVATION OF SILICON-HALOGEN BONDS 241 OXIDATIVE ADDITION TO PLATINUM COMPLEXES 242 OXIDATIVE ADDITION TO PALLADIUM COMPLEXES 242 OXIDATIVE ADDITION TO IRIDIUM AND RHODIUM COMPLEXES 243 SILYL-HECK REACTIONS 244 EARLY SILYL-HECK STUDIES 245 MULTICOMPONENT COUPLING 246 IMPROVED SILYL-HECK REACTION CONDITIONS 247 MECHANISTIC CONSIDERATIONS 252 PRE-CATALYST INVESTIGATIONS 254 THE FORMATION OF SILYL ETHERS AND DISILOXANES VIA THE SILYL-HECK REACTION 258 8.2.7 8.3 8.4 8.5 THE NICKEL-CATALYZED SILYL-HECK REACTION 260 SILYL-NEGISHI REACTIONS 263 SILYL-KUMADA-CORRIU REACTIONS 267 SUMMARY AND CONCLUSIONS 268 REFERENCES 269 9 TRANSITION-METAL-CATALYZED CROSS-COUPLING OF ORGANOSILICON COMPOUNDS 271 TAMEJIRO HIYAMA, YASUNORI MINAMI, ANDATSUNORI MORI 9.1 9.1.1 INTRODUCTION 271 HISTORICAL BACKGROUND OF THE CROSS-COUPLING WITH ORGANOSILICON REAGENTS 271 CONTENTS IX 9.2 IMPROVEMENTS IN THE CROSS-COUPLING REACTION OF ORGANOSILICON COMPOUNDS 275 9.2.1 9.2.2 9.2.3 9.2.4 LIGAND DESIGN FOR THE PALLADIUM CATALYST 275 VARIATION OF PALLADIUM CATALYSTS AND ADDITIVE SYSTEMS 276 ALTERNATIVE ELECTROPHILES AND METAL CATALYSTS 278 CROSS-COUPLING REACTION OF FUNCTIONALIZED ORGANOSILICON REAGENTS 284 9.2.5 CROSS-COUPLING REACTION OF ORGANOSILANES THROUGH DIRECTED C * H BOND ACTIVATION 285 9.2.6 9.3 TANDEM REACTION INVOLVING SILICON-BASED CROSS-COUPLING 288 CROSS-COUPLING OF SILANOLS, SILANOLATES, OLIGOSILOXANES, AND POLYSILOXANES 289 9.3.1 9.3.2 9.4 9.4.1 9.4.2 9.4.3 9.4.4 9.5 SILANOLS AND SILANOLATES 289 DISILOXANES, OLIGOSILOXANES, AND POLYSILOXANES 294 CROSS-COUPLING OF ALLYLSILANE, ARYLSILANES, AND TRIALKYLSILANES 296 SILACYCLOBUTYL, ALLYLSILANES, AND BENZYLSILANES 296 ARYLSILANES 300 TRIALKYLSILANES 304 2 - HYDROXYMETHYLPHENYL (DIALKYL) SILANES 313 SUMMARY 323 REFERENCES 323 10 LEWIS BASE ACTIVATION OF SILICON LEWIS ACIDS 333 SERGIO ROSSI AND SCOTT E. DENMARK 10.1 10.2 INTRODUCTION 333 DIRECT TRANSFER OF A SILICON LIGAND TO A SUBSTRATE NOT COORDINATED TO THE SILICON ATOM 338 10.2.1 TRANSFER OF HYDRIDE: REDUCTION OF C=O AND C=N DOUBLE BONDS PROMOTED BY TRICHLOROSILANE 338 10.2.2 REDUCTION OF NITROAROMATIC COMPOUNDS BY TRICHLOROSILANE 351 10.3 DIRECT TRANSFER OF A SILICON SUBSTITUENT TO THE SILICON-COORDINATED SUBSTRATE 353 10.3.1 10.3.1.1 OPENING OF EPOXIDES 353 LEWIS BASE-CATALYZED EPOXIDE OPENING WITH CHLOROTRIMETHYLSILANE 353 10.3.1.2 LEWIS BASE-CATALYZED EPOXIDE OPENING WITH SILICON TETRACHLORIDE 355 10.3.2 10.3.2.1 10.3.2.2 10.3.3 10.4 ALLYLATION OF SUBSTRATES USING ALLYLIC TRICHLOROSILANES 359 ALLYLATION OF C=N BONDS 359 ALLYLATION OF C=O BONDS 361 ALDOL REACTIONS INVOLVING PREFORMED ENOXYSILANE DERIVATIVES 371 INTERACTION OF THE SILICON-ACTIVATED SUBSTRATE WITH AN EXTERNAL NON-COORDINATED NUCLEOPHILE 375 10.4.1 10.4.2 ALLYLATION OF ALDEHYDES MEDIATED BY SILICON TETRACHLORIDE 376 ALDOL REACTIONS INVOLVING TRIALKYLSILYL ENOL DERIVATIVES 378 X CONTENTS 10.4.2.1 10.4.2.2 10.4.2.3 10.4.3 10.4.4 10.4.5 10.5 ALDOL REACTIONS INVOLVING TRIALKYLSILYL ENOL ETHER DERIVATIVES 378 ALDOL REACTIONS INVOLVING TRIALKYLSILYL KETENE ACETALS 379 VINYLOGOUS ALDOL ADDITION 382 SYNTHESIS OF NITRILE DERIVATIVES FROM SILYL KETENE IMINES 385 PASSERINI REACTION 387 PHOSPHONYLATION OF ALDEHYDES WITH TRIETHYL PHOSPHITE 388 INTERACTION OF THE ACTIVATED SUBSTRATE WITH AN EXTERNALLY COORDINATED NUCLEOPHILE 390 10.5.1 10.5.1.1 10.5.2 10.5.3 DIRECT ALDOL REACTIONS AND DOUBLE ALDOL REACTION 390 DIRECT ALDOL ADDITION OF ACTIVATED THIOESTERS 395 ENANTIOSELECTIVE MORITA-BAYLIS-HILLMAN REACTION 396 OUTLOOK AND PERSPECTIVE 397 ACKNOWLEDGMENT 398 REFERENCES 398 11 HYDROSILYLATION CATALYZED BY BASE METALS 417 YUSUKE SUNADA AND HIDEO NAGASHIMA 11.1 11.2 INTRODUCTION 417 BASE-METAL CATALYSTS FOR HYDROSILYLATION OF ALKENES WITH ALKOXYHYDROSILANES AND HYDROSILOXANES 418 11.2.1 11.2.1.1 IRON AND COBALT CATALYSTS 419 CATALYSTS BEARING TRIDENTATE NITROGEN REDOX-ACTIVE LIGANDS AND RELATED CATALYSTS 419 11.2.1.2 11.2.1.3 11.2.2 11.3 CATALYSTS CONTAINING CO, CNR, AND NHC LIGANDS 421 MISCELLANEOUS 425 NICKEL CATALYSTS 426 HYDROSILYLATION OF ALKENES WITH PRIMARY AND SECONDARY HYDROSILANES BY BASE-METAL CATALYSTS 427 11.4 CONCLUSION AND FUTURE OUTLOOK 434 REFERENCES 434 12 SILYLENES AS LIGANDS IN CATALYSIS 439 YU-PENG ZHOU AND MATTHIAS DRIESS 12.1 12.2 12.2.1 12.2.2 12.2.3 12.3 INTRODUCTION 439 APPLICATIONS OF SILYLENE LIGANDS IN CATALYSIS 439 CARBON-CARBON BOND-FORMING REACTIONS 439 CARBON-HETEROATOM BOND-FORMING REACTIONS 445 REDUCTION REACTIONS 451 SUMMARY AND OUTLOOK 456 ACKNOWLEDGMENT 457 REFERENCES 457 13 ENANTIOSELECTIVE SYNTHESIS OF SILYL ETHERS THROUGH CATALYTIC SI* O BOND FORMATION 459 AMIR H. HOVEYDA AND MARC L. SNAPPER 13.1 INTRODUCTION 459 CONTENTS XI 13.2 LEWIS BASE-CATALYZED ENANTIOSELECTIVE SILYLATIONS OF ALCOHOLS 460 13.2.1 EARLY LEWIS BASE-MEDIATED ENANTIOSELECTIVE SILYLATIONS OF ALCOHOLS 460 13.2.2 LEWIS- AND BRONSTED BASE-CATALYZED ENANTIOSELECTIVE SILYLATIONS OF POLYOLS 461 13.2.3 DIRECTED LEWIS BASE-CATALYZED ENANTIOSELECTIVE SILYLATIONS OF POLYOLS 469 13.2.4 LEWIS BASE-CATALYZED ENANTIOSELECTIVE SILYLATIONS OF MONO-ALCOHOLS 473 13.2.5 LEWIS BASE-MEDIATED ENANTIOSELECTIVE DESILYLATIONS OF MONO-ALCOHOLS 478 13.3 BRONSTED ACID-CATALYZED ENANTIOSELECTIVE SILYLATIONS OF ALCOHOLS 479 13.4 13.4.1 HYDROXYL GROUP SILYLATIONS WITH ORGANOMETALLIC COMPLEXES 481 DIRECTED, CATALYTIC ENANTIOSELECTIVE HYDROXYL GROUP SILYLATIONS WITH CHIRAL SILANES 482 13.4.2 METAL-CATALYZED ENANTIOSELECTIVE HYDROXY GROUP SILYLATIONS WITH CHIRAL SILANES 486 13.4.3 DIRECTED, ENANTIOSELECTIVE CATALYTIC HYDROXY GROUP SILYLATIONS WITH ACHIRAL SILANES 487 13.4.4 ENANTIOSELECTIVE CATALYTIC HYDROXYL GROUP SILYLATIONS WITH ACHIRAL SILANES 488 13.5 CONCLUSIONS 490 REFERENCES 491 14 CHIRAL SILICON MOLECULES 495 KAZUNOBU IGAWA AND KATSUHIKO TOMOOKA 14.1 14.1.1 14.1.2 14.2 14.2.1 INTRODUCTION 495 GENERAL BACKGROUND OF CHIRAL SILICON MOLECULES 495 HISTORY OF CHIRAL SILICON MOLECULES 496 PREPARATION OF ENANTIOENRICHED CHIRAL SILICON MOLECULES 497 CLASSIFICATION OF PREPARATION METHODS FOR ENANTIOENRICHED CHIRAL SILICON MOLECULES 497 14.2.2 14.2.2.1 SEPARATION OF STEREOISOMERS OF CHIRAL SILICON MOLECULES 498 CLASSIFICATION OF SEPARATION METHODS FOR STEREOISOMERS OF CHIRAL SILICON MOLECULES 498 14.2.2.2 14.2.2.3 SEPARATION OF SILICON EPIMERS OF CHIRAL SILICON MOLECULES 499 KINETIC RESOLUTION OF ENANTIOMERS OF CHIRAL SILICON MOLECULES 500 14.2.3 14.2.3.1 ASYMMETRIC SYNTHESIS OF CHIRAL SILICON MOLECULES 503 CLASSIFICATION OF ASYMMETRIC SYNTHETIC METHODS FOR CHIRAL SILICON MOLECULES 503 14.2.3.2 DESYMMETRIZATION OF PROCHIRAL SILICON ATOMS BY SUBSTITUTION OF A HETEROATOM SUBSTITUENT 503 14.2.3.3 DESYMMETRIZATION OF DIHYDROSILANE 506 XII CONTENTS INDEX 533 14.2.3.4 DESYMMETRIZATION OF PROCHIRAL SILICON ATOMS BY ENANTIOSELECTIVE SUBSTITUTION OF A CARBON SUBSTITUENT 507 14.2.3.5 DESYMMETRIZATION OF PROCHIRAL SILICON ATOMS BY TRANSFORMATIONS OF CARBON SUBSTITUENT(S) WITHOUT SI * C BOND CLEAVAGE 513 14.3 STEREOSELECTIVE TRANSFORMATION OF ENANTIOENRICHED CHIRAL SILICON MOLECULES 515 14.3.1 CLASSIFICATION OF STEREOSELECTIVE TRANSFORMATION OF CHIRAL SILICON MOLECULES 515 14.3.2 14.3.3 14.3.4 14.3.4.1 14.3.4.2 14.3.5 14.4 14.4.1 14.4.2 14.4.3 14.4.3.1 14.4.3.2 14.4.4 14.5 NUCLEOPHILIC SUBSTITUTION AT A CHIRAL SILICON CENTER 515 ELECTROPHILIC SUBSTITUTION AT CHIRAL SILICON CENTER 518 OXIDATION AT CHIRAL SILICON CENTER 519 OXIDATION OF HYDROSILANE 519 OXIDATION OF ALKENYLSILANE 521 MULTISTEP FUNCTIONALIZATION OF CHIRAL SILICON MOLECULES 521 APPLICATION OF ENANTIOENRICHED CHIRAL SILICON MOLECULES 523 CLASSIFICATION OF APPLICATIONS OF CHIRAL SILICON MOLECULES 523 APPLICATION AS CHIRAL REAGENTS 523 APPLICATION AS CHIRAL MATERIALS 525 CHIRAL SILICON POLYMER 525 CIRCULAR POLARIZED LUMINESCENCE OF CHIRAL SILICON MOLECULES 527 APPLICATIONS AS BIOACTIVE MOLECULES 527 SUMMARY AND CONCLUSIONS 528 REFERENCES 528
any_adam_object	1
author2	Hiyama, Tamejirō 1946- Oestreich, Martin 1971-
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author_GND	(DE-588)121605191 (DE-588)121126323
author_facet	Hiyama, Tamejirō 1946- Oestreich, Martin 1971-
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discipline	Chemie / Pharmazie
format	Book
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genre	(DE-588)4143413-4 Aufsatzsammlung gnd-content
genre_facet	Aufsatzsammlung
id	DE-604.BV046278202
illustrated	Illustrated
indexdate	2024-07-10T08:40:21Z
institution	BVB
institution_GND	(DE-588)16179388-5
isbn	9783527344536
language	English
oai_aleph_id	oai:aleph.bib-bvb.de:BVB01-031655879
oclc_num	1096284778
open_access_boolean
owner	DE-11 DE-92
owner_facet	DE-11 DE-92
physical	xv, 550 Seiten Illustrationen
publishDate	2019
publishDateSearch	2019
publishDateSort	2019
publisher	Wiley-VCH
record_format	marc
spelling	Organosilicon chemistry novel approaches and reactions edited by Tamejiro Hiyama, Martin Oestreich Weinheim Wiley-VCH [2019] © 2019 xv, 550 Seiten Illustrationen txt rdacontent n rdamedia nc rdacarrier Siliciumorganische Verbindungen (DE-588)4077449-1 gnd rswk-swf Hardback Chemie Chemistry Homogene Katalyse Homogeneous Catalysis Industrial Chemistry Methods - Synthesis & Techniques Organische Chemie / Methoden, Synthesen, Verfahren Technische u. Industrielle Chemie CH30: Technische u. Industrielle Chemie CH42: Homogene Katalyse CH81: Organische Chemie / Methoden, Synthesen, Verfahren 1654: Hardcover, Softcover / Chemie/Organische Chemie (DE-588)4143413-4 Aufsatzsammlung gnd-content Siliciumorganische Verbindungen (DE-588)4077449-1 s DE-604 Hiyama, Tamejirō 1946- (DE-588)121605191 edt Oestreich, Martin 1971- (DE-588)121126323 edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-81475-6 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-81477-0 Erscheint auch als Online-Ausgabe, oBook 978-3-527-81478-7 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34453-6/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031655879&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Organosilicon chemistry novel approaches and reactions Siliciumorganische Verbindungen (DE-588)4077449-1 gnd
subject_GND	(DE-588)4077449-1 (DE-588)4143413-4
title	Organosilicon chemistry novel approaches and reactions
title_auth	Organosilicon chemistry novel approaches and reactions
title_exact_search	Organosilicon chemistry novel approaches and reactions
title_full	Organosilicon chemistry novel approaches and reactions edited by Tamejiro Hiyama, Martin Oestreich
title_fullStr	Organosilicon chemistry novel approaches and reactions edited by Tamejiro Hiyama, Martin Oestreich
title_full_unstemmed	Organosilicon chemistry novel approaches and reactions edited by Tamejiro Hiyama, Martin Oestreich
title_short	Organosilicon chemistry
title_sort	organosilicon chemistry novel approaches and reactions
title_sub	novel approaches and reactions
topic	Siliciumorganische Verbindungen (DE-588)4077449-1 gnd
topic_facet	Siliciumorganische Verbindungen Aufsatzsammlung
url	http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34453-6/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031655879&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT hiyamatamejiro organosiliconchemistrynovelapproachesandreactions AT oestreichmartin organosiliconchemistrynovelapproachesandreactions AT wileyvch organosiliconchemistrynovelapproachesandreactions

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