Chemistry of the non-metals: syntheses, structures, bonding, applications
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De Gruyter
[2020]
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| 245 | 1 | 0 | |a Chemistry of the non-metals |b syntheses, structures, bonding, applications |c Ralf Steudel ; in cooperation with David Scheschkewitz |
| 250 | |a 2nd edition | ||
| 263 | |a 201910 | ||
| 264 | 1 | |a Berlin ; Boston |b De Gruyter |c [2020] | |
| 264 | 4 | |c © 2020 | |
| 300 | |a XVIII, 723 Seiten |b Illustrationen, Diagramme |c 24 cm x 17 cm | ||
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Datensatz im Suchindex
| _version_ | 1804180674210430976 |
|---|---|
| adam_text | CONTENTS
PREFACE * V
PART I: CHEMICAL BONDS AND PROPERTIES OF MOLECULES
1 INTRODUCTION * 3
2 THE CHEMICAL BOND *11
2.1 THE IONIC BOND *13
2.1.1 GENERAL *13
2.1.2 THE IONIZATION ENERGY I *13
2.1.3 THE ELECTRON AFFINITY
EEA
*15
2.1.4 IONIC CRYSTALS AND IONIC RADII *17
2.1.5 LATTICE ENERGY AND LATTICE ENTHALPY *19
2.1.6 DETERMINATION OF LATTICE ENERGIES AND ENTHALPIES * 21
2.1.7 SIGNIFICANCE OF THE LATTICE ENTHALPY * 23
2.1.7.1 COMPLEX FORMATION OF METAL HALIDES * 26
2.1.7.2 WEAKLY COORDINATING ANIONS * 27
2.1.8 POLARIZATION OF ANIONS BY CATIONS * 27
2.2 MOLECULAR GEOMETRY * 30
2.2.1 STRUCTURE DETERMINATION-30
2.2.2 THE VSEPR MODEL FOR ESTIMATION OF MOLECULAR GEOMETRIES
2.2.2.1 LONE ELECTRON PAIRS * 38
2.2.2.2 SINGLE ELECTRON DOMAINS-40
2.2.2.3 SUBSTITUENTS OF DIFFERING ELECTRONEGATIVITY * 40
2.2.2.4 MULTIPLE BONDS-41
2.2.2.5 FINAL REMARKS ON THE VSEPR MODEL * 41
2.3 MOLECULAR SYMMETRY AND POINT GROUP SYMBOLS * 43
2.4 THE COVALENT BOND * 48
2.4.1 THE MOLECULAR ION [H2]+ * 49
2.4.1.1 THE LCAO APPROXIMATION * 50
2.4.2 THE MOLECULE H2-57
2.4.2.1 THE CATION [HE2]+ * 59
2.4.2.2 THE ROLE OF ANTIBONDING MOLECULAR ORBITALS-59
2.4.3 HOMONUCLEAR DIATOMIC MOLECULES * 60
2.4.4 PHOTOELECTRON SPECTROSCOPY OF SMALL MOLECULES * 68
2.4.5 HETERONUCLEAR DIATOMIC MOLECULES * 70
2.4.5.1 GENERAL RULES FOR THE CONSTRUCTION OF MOS * 72
2.4.6 THREE-ATOMIC MOLECULES OF SYMMETRY * 73
2.4.6.1 THE MOLECULE BEH2-75
BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/1182482201
VIII
CONTENTS
2.4.6.2 THE MOLECULE C02-76
2.4.7 THREE-ATOMIC MOLECULES OF C2V SYMMETRY
**
2.4.8 FOUR-ATOMIC MOLECULES OF D3H SYMMETRY -
2.4.9 FOUR-ATOMIC MOLECULES OF C3V SYMMETRY -
2.4.10 FIVE-ATOMIC MOLECULES-87
2.5 THE COORDINATE BOND-89
2.6 HYPERCOORDINATE MOLECULES-93
-77
*80
83
3
VAN DER WAALS
INTERACTION-101
3.1 THE DIPOLE EFFECT-101
3.2 INDUCED DIPOLE EFFECT-104
3.3 THE DISPERSION EFFECT-104
3.4 VAN
DER
WAALS RADII *107
3.5
VAN
DER
WAALS
MOLECULES *109
4 BOND PROPERTIES-113
4.1 INTRODUCTION-113
4.2 BOND ENTHALPY AND DISSOCIATION ENTHALPY-114
4.2.1 DIATOMIC MOLECULES-114
4.2.2 POLYATOMIC MOLECULES-117
4.2.3 WHY IS OXYGEN A GAS AND SULFUR A SOLID?-122
4.3 THE INTERNUCLEAR DISTANCE-124
4.4 THE VALENCE FORCE CONSTANT-127
4.4.1 DIATOMIC MOLECULES-127
4.4.2 DIATOMIC GROUPS-128
4.4.3 THREE-ATOMIC MOLECULES-129
4.5 RELATIONSHIPS BETWEEN DIFFERENT BOND PROPERTIES-132
4.6 POLARITY OF COVALENT BONDS AND ELECTRONEGATIVITY-134
4.6.1 INTRODUCTION-134
4.6.2 ELECTRONEGATIVITIES (X)-136
4.6.2.1 THERMODYNAMIC ELECTRONEGATIVITIES BY PAULING *136
4.6.2.2 ELECTRONEGATIVITIES ACCORDING TO ALLRED AND ROCHOW-138
4.6.2.3 SPECTROSCOPIC ELECTRONEGATIVITIES ACCORDING TO ALLEN-141
4.6.2.4 GROUP ELECTRONEGATIVITIES-142
4.6.3 THE DIPOLE MOMENT-143
4.7 ELECTRON DENSITY DISTRIBUTION IN MOLECULES AND CRYSTALS-147
4.7.1 PROMOLECULE AND DEFORMATION DENSITY-147
4.7.2 HALOGEN BONDING-149
CONTENTS
IX
PART II: CHEMISTRY OF THE NON-METALS
5
5.1
5.1.1
5
.
1.2
5.1.3
5.2
5.3
5.3.1
5.3.2
5.3.3
5.4
5.5
5.5.1
5.5.1.1
5.5.1.2
5.5.2
5.6
5.6.1
5.6.2
5.6.3
5.6.3.1
5.6.3.2
5.6.3.3
5.6.4
5.6.4.1
5.6.4.2
5.6.4.3
5.6.4.4
5.6.5
5.7
5.7.1
5.7.2
5.7.2.1
5.7.3
5.7.4
5.7.5
5.7.5.1
HYDROGEN *157
ELEMENTAL HYDROGEN *157
PRODUCTION AND USES *157
ISOTOPES OF HYDROGEN *161
PROPERTIES OF HYDROGEN *164
HYDROGEN IONS H+ *165
ACIDS *168
OXONIUM SALTS *169
LIQUID AMMONIA *171
ANHYDROUS SULFURIC ACID *172
BASES *172
THE RELATIVE STRENGTH OF ACIDS AND BASES *174
DILUTE SOLUTIONS *174
BINARY COVALENT HYDRIDES *175
OXOACIDS *176
CONCENTRATED AND NONAQUEOUS ACIDS *177
HYDROGEN BONDS (H-BONDS) *181
INTRODUCTION *181
GENERAL PROPERTIES OF HYDROGEN BONDS *182
EXPERIMENTAL DETECTION OF HYDROGEN BONDS *183
PHYSICAL CONSTANTS *183
STRUCTURE DETERMINATION *185
MOLECULAR SPECTROSCOPY *185
EXAMPLES OF SPECIAL HYDROGEN BONDS *187
HYDROGEN FLUORIDE *187
ICE AND WATER *188
GAS HYDRATES AND CLATHRATE HYDRATES *194
AMMONIA AND AMINES *195
THEORY OF HYDROGEN BOND FORMATION *198
HYDROGEN COMPOUNDS (HYDRIDES) * 202
INTRODUCTION * 202
COVALENT HYDRIDES * 203
ACTIVATION OF H2 MOLECULES * 203
H2 AS LIGAND IN COORDINATION COMPOUNDS * 204
SALT-LIKE HYDRIDES * 206
METAL- AND ALLOY-LIKE HYDRIDES (INSERTION HYDRIDES) * 209
BONDING OF HYDROGEN IN ALLOY-LIKE HYDRIDES * 211
X **- CONTENTS
6
6.1
6.2
6
.
2.1
6.2.2
6.2.3
6.3
6.3.1
6.3.2
6.3.3
6.4
6.4.1
6.4.2
6.5
6.5.1
6.5.2
6.5.3
6.5.3.1
6.5.3.2
6.5.4
6.6
6.7
6.8
6
.
8.1
6.8.2
6.9
6.9.1
6.9.2
6.9.3
6.10
6
.
10.1
6
.
10.2
6.10.3
6.10.4
6.10.5
BORON-215
INTRODUCTION * 215
BONDING SITUATION * 216
LEWIS
ACIDITY AND ADDUCT FORMATION * 216
COORDINATION NUMBERS AND MULTIPLE BONDS * 219
SIMILARITIES AND DIFFERENCES TO OTHER NON-METALS * 221
ELEMENTAL BORON * 222
PREPARATION OF ELEMENTAL BORON-223
SOLID-STATE STRUCTURES OF ELEMENTAL BORON * 224
BONDING IN ELEMENTAL BORON * 226
BORIDES AND BORON CARBIDES * 228
BORIDES-228
BORON CARBIDES-230
BORANES AND HYDROBORATES * 231
INTRODUCTION * 231
DIBORANE(6) * 232
HIGHER BORANES * 234
PREPARATION * 234
STRUCTURES * 235
HYDROBORATES * 237
ORGANOBORANES * 241
CARBORANES * 243
BORON HALIDES * 246
TRIHALIDES (BX3)-246
SUBHALIDES * 248
BORON-OXYGEN SPECIES * 250
INTRODUCTION-250
BORON TRIOXIDE AND BORIC ACIDS * 251
BORATES-254
BORON-NITROGEN COMPOUNDS * 256
BONDING SITUATION * 256
AMMONIA-BORANE-257
BORAZINE * 259
BORON NITRIDE * 261
NITRIDOBORATES * 264
7 CARBON * 265
7.1 INTRODUCTION * 265
7.2 BONDING SITUATION IN GROUP 14-266
7.3 CARBON ALLOTROPES-271
7.3.1 GRAPHITE AND GRAPHENE * 272
7.3.1.1 GRAPHENE-274
7.3.2 DIAMOND * 275
7.3.3 FULLERENES * 279
7.3.3.1 PREPARATION * 280
7.3.3.2 STRUCTURES * 280
7333
PROPERTIES * 281
7.3.3.4 REACTIVITY * 281
7.3.4 CARBON NANOTUBES * 283
7.4 GRAPHITE COMPOUNDS * 285
7.4.1 COVALENT GRAPHITE COMPOUNDS * 285
7.4.1.1 SURFACE COMPOUNDS * 286
7.4.2 IONIC GRAPHITE COMPOUNDS * 288
7.5 CARBON BLACK, COAL AND COKE * 291
7.6 CARBON HALIDES * 293
7.7 CARBON CHALCOGENIDES * 294
7.7.1 OXIDES * 294
7.7.1.1 CARBON MONOXIDE * 295
7.7.1.2 CARBON DIOXIDE * 297
7.7.1.3 OTHER CARBON OXIDES * 298
7.7.2 SULFIDES, SELENIDES AND TELLURIDES * 299
7.7.3 CARBONIC ACID AND CARBONATES * 301
7.7.3.1 CARBONIC PERACIDS * 304
7.8 CARBON NITRIDES * 305
7.8.1 HYDROGEN CYANIDE AND CYANIDES * 305
7.8.2 BINARY CARBON-NITROGEN SPECIES * 307
8 SILICON AND GERMANIUM * 309
8.1 INTRODUCTION * 309
8.2 BONDING SITUATION * 310
8.3 THE ELEMENTS SILICON AND GERMANIUM * 318
8.4 SILICIDES AND GERMANIDES * 322
8.5 HYDRIDES OF SILICON AND GERMANIUM * 325
8.5.1 PREPARATION OF HYDRIDES * 326
8.5.2 REACTIONS OF SILANES AND GERMANES * 328
8.6 HALIDES OF SILICON AND GERMANIUM * 329
8.6.1 FLUORIDES * 330
8.6.2 CHLORIDES * 331
8.6.3 OTHER SILICON HALIDES * 333
8.7 OXIDES OF SILICON AND GERMANIUM * 334
8.7.1 SILICON DIOXIDE * 334
8.7.2 SILICON MONOXIDE * 336
8.7.3 GERMANIUM OXIDES * 337
8.8 OXOACIDS, SILICATES AND GERMANATES * 338
XII * CONTENTS
8.8.1 SILICIC ACID AND SILOXANES-338
8.8.2 SILICATES-341
8.8.3 GERMANATES-347
8.9 GLASSES-348
8.10 SILICON-NITROGEN COMPOUNDS-351
8.11 ORGANOSILICON COMPOUNDS-353
8.11.1 ORGANOSILANES-353
8.11.2 UNSATURATED ORGANOSILICON AND ORGANOGERMANIUM
COMPOUNDS-357
8.11.3 ORGANOSILOXANES-362
8.12 OTHER SILICON COMPOUNDS-363
8.12.1 SILICON CARBIDE-363
8.12.2 SILICON NITRIDE-364
8.12.3 SILICON SULFIDES-365
9 NITROGEN-367
9.1 ELEMENTAL NITROGEN-367
9.2 N2 AS COMPLEX LIGAND-369
9.3 BONDING IN NITROGEN COMPOUNDS-372
9.3.1 BOND ENTHALPIES AND FORMATION ENTHALPIES-376
9.4 NITROGEN HYDRIDES-379
9.4.1 INTRODUCTION-379
9.4.2 AMMONIA (NH3)-380
9.4.3 HYDRAZINE (N2H4)-384
9.4.4 DIAZENE (DIIMINE), N2H2-386
9.4.5 HYDROGEN AZIDE (HN3) AND AZIDES-387
9.4.6 TETRAZENE(2) (N4H4)-390
9.4.7 HYDROXYLAMINE (NH2OH)-391
9.4.8 WATER-LIKE SOLVENTS-392
9.4.8.1 SOLUBILITIES IN LIQUID AMMONIA-393
9.4.8.2 AUTODISSOCIATION OF LIQUID AMMONIA-393
9.4.8.3 AMMONOLYSIS-394
9.4.8.4 SOLVATED ELECTRONS IN LIQUID AMMONIA-394
9.4.8.5 REACTIONS OF SOLVATED ELECTRONS IN LIQUID AMMONIA-398
9.4.8.6 SOLVATED ELECTRONS IN WATER-399
9.5 HALIDES AND OXOHALIDES OF NITROGEN-402
9.5.1 HALIDES-402
9.5.2 OXOHALIDES OF NITROGEN-405
9.6 OXIDES OF NITROGEN-406
9.6.1 INTRODUCTION-406
9.6.2 DINITROGEN OXIDE (N20)-407
9.6.3 NITROGEN MONOXIDE (NO) AND DINITROGEN DIOXIDE (N202)-408
CONTENTS XIII
9.6.4 DLNITROGEN TRIOXIDE (N203)-412
9.6.5 NITROGEN DIOXIDE (NO
2
) AND DINITROGEN TETROXIDE (N204)-413
9.6.6 DINITROGEN PENTOXIDE (N205) * 414
9.7 OXOACIDS OF NITROGEN * 415
9.7.1 INTRODUCTION-415
9.7.2 NITRIC ACID (HN03 OR HONO^-417
9.7.3 PEROXONITRIC ACID (HN04 OR H00N02)-419
9.7.4 NITROUS ACID (HN02 OR HONO)-419
9.7.5 PEROXONITROUS ACID (HOONO)-421
9.7.6 HYPONITROUS ACID (H0N)2 AND NITRAMIDE (H2NN02) * 422
10 PHOSPHORUS AND ARSENIC-425
10.1 INTRODUCTION-425
10.2 BONDING SITUATION IN P AND AS COMPOUNDS-425
10.3 PHOSPHORUS AND ARSENIC AS ELEMENTS * 429
10.3.1 PRODUCTION OF THE ELEMENTS * 430
10.3.2 MODIFICATIONS OF PHOSPHORUS AND ARSENIC * 431
10.3.2.1 STRUCTURES OF P AND AS MODIFICATIONS * 432
10.4 HYDRIDES OF PHOSPHORUS AND ARSENIC * 437
10.4.1 PHOSPHANE AND ARSANE * 438
10.4.2 DIPHOSPHANE(4)-440
10.5 PHOSPHIDES-441
10.6 ORGANOPHOSPHANES * 443
10.7 DIPHOSPHENES AND PHOSPHAALKYNES-445
10.8 HALIDES OF PHOSPHORUS AND ARSENIC * 447
10.8.1 TRIHALIDES (EX3. E = P, AS)-448
10.8.2 TETRAHALIDES (E2X4; E = P, AS)-450
10.8.3 PENTAHALIDES (EX5. E = P, AS)-451
10.8.4 STRONG
LEWIS
ACIDS-453
10.9 PHOSPHORANES AND ARSORANES * 455
10.10 OXIDES OF PHOSPHORUS AND ARSENIC-458
10.10.1 PHOSPHORUS(LLL) OXIDES * 458
10.10.2 PHOSPHORUS(V) OXIDES-459
10.10.3 PHOSPHORUS(LLL,V) OXIDES * 461
10.10.4 ARSENIC OXIDES-462
10.11 SULFIDES OF PHOSPHORUS AND ARSENIC * 463
10.12 OXOACIDS OF PHOSPHORUS AND ARSENIC AND THEIR DERIVATIVES * 465
10.12.1 OXOACIDS WITH ONE P ATOM-465
10.12.1.1 ORTHOPHOSPHORIC ACID AND ORTHOPHOSPHATES * 467
10.12.1.2 PHOSPHONIC ACID (H3P03 OR HPOCOH)^-469
10.12.1.3 PHOSPHINIC OR HYPOPHOSPHOROUS ACID (H^O^ * 470
10.12.1.4 PHOSPHINOUS ACID (H3PO) AND HYDROXOPHOSPHANE (H2P0H)-470
XIV *- CONTENTS
10.12.2 CONDENSED PHOSPHORIC ACIDS-470
10.12.3 PEROXOPHOSPHORIC ACIDS-472
10.12.4 THIOPHOSPHORIC ACIDS-473
10.12.5 HALOGENO- AND AMIDOPHOSPHORIC ACIDS-473
10.12.6 OXO* AND THIOACIDS OF ARSENIC AND THEIR SALTS-473
10.13 PHOSPHORUS(V) NITRIDES AND NITRIDOPHOSPHATES-474
10.14 PHOSPHAZENES * 476
10.14.1 BONDING SITUATION-478
10.14.2 POLYPHOSPHAZENES * 479
11 OXYGEN-481
11.1 ELEMENTAL OXYGEN * 481
11.1.1 MOLECULAR OXYGEN, 02-481
11.1.1.1 SINGLET DIOXYGEN C02)-483
11.1.1.2 COMPLEXES WITH 02 AS A LIGAND * 485
11.1.2 ATOMIC OXYGEN-490
11.1.3 OZONE, 03 * 491
11.2 IONIC AND COVALENT OXYGEN COMPOUNDS-497
11.2.1 OXIDES-497
11.2.1.1 IONIC OXIDES-497
11.2.1.2 COVALENT OXIDES-498
11.2.2 PEROXIDES * 500
11.2.2.1 IONIC PEROXIDES-500
11.2.2.2 COVALENT PEROXIDES-501
11.2.3 SUPEROXIDES-502
11.2.4 OZONIDES-503
11.2.5 DIOXYGENYL COMPOUNDS-504
11.2.6 BOND PROPERTIES OF THE IONS [02] +, [02]*~ AND [02]2--505
11.3 HYDRIDES OF OXYGEN AND PEROXO COMPOUNDS-506
11.3.1 INTRODUCTION-506
11.3.2 WATER * 507
11.3.3 HYDROGEN PEROXIDE, H202-509
11.3.3.1 PREPARATION-509
11.3.3.2 PROPERTIES AND STRUCTURE OF H202-510
11.3.3.3 REACTIONS OF H202-511
11.3.4 HYDROGEN TRIOXIDE, H203-513
11.3.5 HYDROXYL RADICAL, OH -514
11.4 FLUORIDES OF OXYGEN-516
11.4.1 INTRODUCTION-516
11.4.2 OXYGEN DIFLUORIDE, OF2 * 517
11.4.3 DIOXYGEN DIFLUORIDE, 02F2-518
11.5 BONDING SITUATION IN OXYGEN HYDRIDES AND FLUORIDES-518
CONTENTS
XV
12 SULFUR, SELENIUM AND TELLURIUM * 521
12.1 INTRODUCTION * 521
12.2 BONDING SITUATIONS AND TENDENCIES IN GROUP 16 * 522
12.3 PREPARATION OF THE ELEMENTS * 525
12.3.1 PRODUCTION OF SULFUR * 525
12.3.2 PRODUCTION AND USES OF SELENIUM AND TELLURIUM * 528
12.4 ALLOTROPES OF THE CHALCOGENS * 529
12.4.1 SULFUR-529
12.4.1.1 THERMAL BEHAVIOR OF SULFUR * 530
12.4.1.2 MONOTROPIC SULFUR ALLOTROPES * 534
12.4.2 ALLOTROPES OF SELENIUM AND TELLURIUM * 538
12.5 HOMOATOMIC CHALCOGEN CATIONS * 541
12.6 CHAIN GROWTH AND DEGRADATION REACTIONS * 543
12.7 CHALCOGEN HYDRIDES * 545
12.7.1 HYDRIDES H2E (E = S, SE, TE)-545
12.7.2 POLYSULFANES, H2S* (N 1)-547
12.7.2.1 SYNTHESIS OF POLYSULFANES * 548
12.8 METAL CHALCOGENIDES * 549
12.8.1 CHALCOGENIDES OF ALKALI METALS * 550
12.8.2 POLYCHALOGENIDES * 551
12.8.3 STRUCTURES OF POLYCHALCOGENIDE ANIONS * 552
12.9 ORGANO POLYSULFANES R2S* * 554
12.10 CHALCOGEN OXIDES-555
12.10.1 DIOXIDES-556
12.10.1.1 SELENIUM AND TELLURIUM OXIDES * 558
12.10.2 TRIOXIDES * 559
12.10.2.1 ALLOTROPES OF S03-560
12.10.2.2 REACTIONS OF SULFUR TRIOXIDE * 561
12.10.2.3 SELENIUM TRIOXIDE-563
12.10.2.4 TELLURIUM TRIOXIDE-563
12.10.3 LOWER SULFUR OXIDES * 563
12.11 OXO-, THIO- AND HALO-ACIDS OF THE CHALCOGENS * 564
12.11.1 INTRODUCTION * 564
12.11.2 SULFUROUS ACID, H2S03-566
12.11.3 SELENOUS ACID (H2SE03) AND TELLUROUS ACID (H2TE03)-569
12.11.4 SULFURIC ACID (H2S04) AND POLYSULFURIC ACIDS (H2SRT03/J+1) * 569
12.11.5 SELENIC ACID (H2SEOJ AND TELLURIC ACIDS [H2TE04 AND
TE(OH)6]-571
12.11.6 PEROXOSULFURIC ACIDS (H2S05 H2S208) * 573
12.11.7 HALOSULFURIC ACIDS, HSN05NX * 573
12.11.8 THIOSULFURIC ACID (H2S203) AND SULFANE DISULFONIC ACIDS
(H2S*06)-574
XVI ** CONTENTS
12.11.9 DITHIONLC ACID, H2S206-576
12.11.10 DITHIONOUS ACID, H2S204-577
12.11.11 DISULFANE DITHIONOUS ACID, H2S404 * 578
12.12 HALIDES AND OXOHALIDES OF THE CHALCOGENS * 578
12.12.1 INTRODUCTION-578
12.12.2 SULFUR HALIDES-580
12.12.2.1 FLUORIDES-580
12.12.2.2 LOWER SULFUR FLUORIDES-582
12.12.2.3 CHLORIDES, BROMIDES AND IODIDES * 583
12.12.3 SULFUR OXOHALIDES-585
12.12.4 SELENIUM AND TELLURIUM HALIDES-587
12.12.4.1 FLUORIDES-587
12.12.4.2 SELENIUM CHLORIDES AND BROMIDES * 587
12.12.4.3 TELLURIUM CHLORIDES AND BROMIDES * 588
12.12.4.4 POLYMERIC TELLURIUM HALIDES WITH TE-TE BONDS * 589
12.12.4.5 HALOCHALCOGENATE ANIONS-590
12.12.4.6 BONDING IN SELENIUM AND TELLURIUM HALIDES * 591
12.13 SULFUR-NITROGEN COMPOUNDS-591
13 THE HALOGENS-599
13.1 INTRODUCTION-599
13.2 ELEMENTAL FLUORINE, CHLORINE, BROMINE AND IODINE * 600
13.2.1 HALOGEN MOLECULES-600
13.2.2 HALOGEN ATOMS-602
13.2.3 REACTIVITY-602
13.3 BONDING SITUATIONS-603
13.3.1 HALIDE IONS * 603
13.3.2 COVALENT COMPOUNDS-604
13.3.3 HALONIUM IONS-605
13.3.4 HALOGEN BONDS-606
13.4 FLUORINE-607
13.4.1 PREPARATION OF FLUORINE -* 607
13.4.2 PROPERTIES OF FLUORINE-609
13.4.3 PREPARATION OF FLUORIDES * 610
13.4.4 APPLICATIONS OF FLUORINE COMPOUNDS-612
13.4.4.1 LIQUID HYDROGEN FLUORIDE-612
13.4.4.2 URANIUM HEXAFLUORIDE-612
13.4.4.3 FLUORIDE ATE-COMPLEXES * 612
13.4.4.4 FLUORINATED HYDRO- AND CHLOROCARBONS-613
13.4.4.5 FLUORINATED POLYMERS-613
13.4.4.6 FLUORINE COMPOUNDS FOR ENERGY STORAGE AND CONVERSION * 614
13.4.4.7 FLUORINATED COMPOUNDS IN SEMICONDUCTOR INDUSTRY-614
CONTENTS * XVII
13.4.4.8 LIQUID CRYSTALS * 615
13.4.4.9 FLUORINATED PHARMACOLOGICALLY AND AGROCHEMICALLY ACTIVE
SUBSTANCES * 615
13.4.5 BONDING SITUATION IN FLUORIDES * 616
13.4.6 STABILIZATION OF LOW OXIDATION STATES * 617
13.4.7 STABILIZATION OF HIGH OXIDATION STATES * 619
13.5 CHLORINE, BROMINE AND IODINE * 620
13.5.1 PREPARATION AND PROPERTIES OF THE ELEMENTS * 620
13.5.1.1 CHLORINE * 620
13.5.1.2 BROMINE * 623
13.5.1.3 IODINE * 624
13.5.2 HALIDES * 625
13.5.2.1 HYDROGEN HALIDES HCL, HBR AND HI * 625
13.5.3 POLYHALIDE IONS * 627
13.5.4 POSITIVE HALOGEN IONS * 631
13.5.5 INTERHALOGEN COMPOUNDS * 633
13.5.6 OXYGEN COMPOUNDS OF CHLORINE, BROMINE AND IODINE * 636
13.5.6.1 OXIDES * 636
13.5.6.2 CHLORINE OXIDES * 637
13.5.6.3 BROMINE OXIDES * 640
13.5.6.4 IODINE OXIDES * 640
13.5.6.5 OXOACIDS OF THE HALOGENS * 641
13.5.6.6 OXOACIDS OF CHLORINE * 641
13.5.6.7 OXOACIDS OF BROMINE * 645
13.5.6.8 OXOACIDS OF IODINE * 645
13.5.6.9 ACID HALIDES * 646
13.5.6.10 HALOGEN DERIVATIVES OF OXOACIDS OF OTHER NONMETALS * 648
13.6 PSEUDOHALOGENS * 650
14 THE NOBLE GASES * 653
14.1 INTRODUCTION * 653
14.2 OCCURRENCE, RECOVERY AND APPLICATIONS * 654
14.3 XENON COMPOUNDS * 656
14.3.1 XENON FLUORIDES*657
14.3.2 REACTIVITY OF XENON FLUORIDES * 658
14.3.2.1 REDOX REACTIONS * 659
14.3.2.2 FLUORIDE TRANSFER REACTIONS * 659
14.3.3 OXIDES AND OXOSALTS OF XENON * 661
14.3.4 XENON OXYFLUORIDES * 663
14.3.5 OTHER XENON COMPOUNDS * 664
14.4 COMPOUNDS OF OTHER NOBLE GASES * 666
14.4.1 ARGON * 666
XVIII
CONTENTS
14.4.2
14.4.3
14.5
14.6
14.6.1
14.6.2
14.6.3
KRYPTON * 667
RADON * 667
ELECTRONEGATIVITIES OF NOBLE GASES * 667
BONDING SITUATION IN NOBLE GAS COMPOUNDS * 669
DIATOMIC MOLECULES AND IONS * 669
POLYATOMIC MOLECULES AND IONS * 669
EXISTENCE AND NONEXISTENCE OF NOBLE GAS COMPOUNDS
INDEX * 675
|
| any_adam_object | 1 |
| author | Steudel, Ralf 1937-2021 |
| author_GND | (DE-588)106016075 (DE-588)1048646793 |
| author_facet | Steudel, Ralf 1937-2021 |
| author_role | aut |
| author_sort | Steudel, Ralf 1937-2021 |
| author_variant | r s rs |
| building | Verbundindex |
| bvnumber | BV046249152 |
| classification_rvk | VH 7901 VH 5700 |
| classification_tum | CHE 325f |
| ctrlnum | (OCoLC)1145253729 (DE-599)DNB1182482201 |
| discipline | Chemie / Pharmazie Chemie |
| edition | 2nd edition |
| format | Book |
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| genre | (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Lehrbuch |
| id | DE-604.BV046249152 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T08:39:31Z |
| institution | BVB |
| institution_GND | (DE-588)10095502-2 |
| isbn | 9783110578058 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-031627403 |
| oclc_num | 1145253729 |
| open_access_boolean | |
| owner | DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-92 DE-11 DE-573 |
| owner_facet | DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-92 DE-11 DE-573 |
| physical | XVIII, 723 Seiten Illustrationen, Diagramme 24 cm x 17 cm |
| publishDate | 2020 |
| publishDateSearch | 2020 |
| publishDateSort | 2020 |
| publisher | De Gruyter |
| record_format | marc |
| series2 | De Gruyter STEM |
| spelling | Steudel, Ralf 1937-2021 Verfasser (DE-588)106016075 aut Chemistry of the non-metals syntheses, structures, bonding, applications Ralf Steudel ; in cooperation with David Scheschkewitz 2nd edition 201910 Berlin ; Boston De Gruyter [2020] © 2020 XVIII, 723 Seiten Illustrationen, Diagramme 24 cm x 17 cm txt rdacontent n rdamedia nc rdacarrier De Gruyter STEM Nichtmetall (DE-588)4042114-4 gnd rswk-swf Chemie (DE-588)4009816-3 gnd rswk-swf Nichtmetallverbindungen (DE-588)4347153-5 gnd rswk-swf Paperback / softback Allgemein SCI013030 GTG: General studies PNK: Inorganic chemistry Anorganische Chemie Nichtmetall Chemische Bindung 1653: Hardcover, Softcover / Chemie/Anorganische Chemie (DE-588)4123623-3 Lehrbuch gnd-content Chemie (DE-588)4009816-3 s Nichtmetallverbindungen (DE-588)4347153-5 s DE-604 Nichtmetall (DE-588)4042114-4 s 1\p DE-604 Scheschkewitz, David 1971- (DE-588)1048646793 oth Walter de Gruyter GmbH & Co. KG (DE-588)10095502-2 pbl Erscheint auch als Online-Ausgabe, EPUB 978-3-11-057831-7 Erscheint auch als Online-Ausgabe, PDF 978-3-11-057806-5 X:MVB http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110578058&searchTitles=true DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031627403&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Steudel, Ralf 1937-2021 Chemistry of the non-metals syntheses, structures, bonding, applications Nichtmetall (DE-588)4042114-4 gnd Chemie (DE-588)4009816-3 gnd Nichtmetallverbindungen (DE-588)4347153-5 gnd |
| subject_GND | (DE-588)4042114-4 (DE-588)4009816-3 (DE-588)4347153-5 (DE-588)4123623-3 |
| title | Chemistry of the non-metals syntheses, structures, bonding, applications |
| title_auth | Chemistry of the non-metals syntheses, structures, bonding, applications |
| title_exact_search | Chemistry of the non-metals syntheses, structures, bonding, applications |
| title_full | Chemistry of the non-metals syntheses, structures, bonding, applications Ralf Steudel ; in cooperation with David Scheschkewitz |
| title_fullStr | Chemistry of the non-metals syntheses, structures, bonding, applications Ralf Steudel ; in cooperation with David Scheschkewitz |
| title_full_unstemmed | Chemistry of the non-metals syntheses, structures, bonding, applications Ralf Steudel ; in cooperation with David Scheschkewitz |
| title_short | Chemistry of the non-metals |
| title_sort | chemistry of the non metals syntheses structures bonding applications |
| title_sub | syntheses, structures, bonding, applications |
| topic | Nichtmetall (DE-588)4042114-4 gnd Chemie (DE-588)4009816-3 gnd Nichtmetallverbindungen (DE-588)4347153-5 gnd |
| topic_facet | Nichtmetall Chemie Nichtmetallverbindungen Lehrbuch |
| url | http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110578058&searchTitles=true http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031627403&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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