Alkene polymerization reactions with transition metal catalysts:
During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unpreceden...
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam London
Elsevier
2008
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| Schriftenreihe: | Studies in surface science and catalysis
173 |
| Schlagworte: | |
| Online-Zugang: | FLA01 Volltext Volltext |
| Zusammenfassung: | During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006 |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | 1 online resource (xiv, 592 pages) illustrations |
| ISBN: | 9780444532152 0444532153 9781435628755 1435628756 0080557996 9780080557991 |
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| 520 | |a During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. | ||
| 520 | |a These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. | ||
| 520 | |a The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006 | ||
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Datensatz im Suchindex
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| dewey-full | 541.39 |
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| dewey-ones | 541 - Physical chemistry |
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| id | DE-604.BV046124671 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T08:35:50Z |
| institution | BVB |
| isbn | 9780444532152 0444532153 9781435628755 1435628756 0080557996 9780080557991 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-031505125 |
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| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | Elsevier |
| record_format | marc |
| series2 | Studies in surface science and catalysis |
| spelling | Kissin, Y. V. Verfasser aut Alkene polymerization reactions with transition metal catalysts Yury V. Kissin Amsterdam London Elsevier 2008 1 online resource (xiv, 592 pages) illustrations txt rdacontent c rdamedia cr rdacarrier Studies in surface science and catalysis 173 Includes bibliographical references and index During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006 SCIENCE / Chemistry / Physical & Theoretical bisacsh Polymerization fast Transition metal catalysts fast Polymerization Transition metal catalysts Polymerisation (DE-588)4046704-1 gnd rswk-swf Katalyse (DE-588)4029921-1 gnd rswk-swf Alkene (DE-588)4001207-4 gnd rswk-swf Übergangsmetall (DE-588)4078494-0 gnd rswk-swf Alkene (DE-588)4001207-4 s Polymerisation (DE-588)4046704-1 s Katalyse (DE-588)4029921-1 s Übergangsmetall (DE-588)4078494-0 s 1\p DE-604 http://www.sciencedirect.com/science/book/9780444532152 Verlag URL des Erstveröffentlichers Volltext http://www.sciencedirect.com/science/bookseries/01672991/173 Verlag URL des Erstveröffentlichers Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Kissin, Y. V. Alkene polymerization reactions with transition metal catalysts SCIENCE / Chemistry / Physical & Theoretical bisacsh Polymerization fast Transition metal catalysts fast Polymerization Transition metal catalysts Polymerisation (DE-588)4046704-1 gnd Katalyse (DE-588)4029921-1 gnd Alkene (DE-588)4001207-4 gnd Übergangsmetall (DE-588)4078494-0 gnd |
| subject_GND | (DE-588)4046704-1 (DE-588)4029921-1 (DE-588)4001207-4 (DE-588)4078494-0 |
| title | Alkene polymerization reactions with transition metal catalysts |
| title_auth | Alkene polymerization reactions with transition metal catalysts |
| title_exact_search | Alkene polymerization reactions with transition metal catalysts |
| title_full | Alkene polymerization reactions with transition metal catalysts Yury V. Kissin |
| title_fullStr | Alkene polymerization reactions with transition metal catalysts Yury V. Kissin |
| title_full_unstemmed | Alkene polymerization reactions with transition metal catalysts Yury V. Kissin |
| title_short | Alkene polymerization reactions with transition metal catalysts |
| title_sort | alkene polymerization reactions with transition metal catalysts |
| topic | SCIENCE / Chemistry / Physical & Theoretical bisacsh Polymerization fast Transition metal catalysts fast Polymerization Transition metal catalysts Polymerisation (DE-588)4046704-1 gnd Katalyse (DE-588)4029921-1 gnd Alkene (DE-588)4001207-4 gnd Übergangsmetall (DE-588)4078494-0 gnd |
| topic_facet | SCIENCE / Chemistry / Physical & Theoretical Polymerization Transition metal catalysts Polymerisation Katalyse Alkene Übergangsmetall |
| url | http://www.sciencedirect.com/science/book/9780444532152 http://www.sciencedirect.com/science/bookseries/01672991/173 |
| work_keys_str_mv | AT kissinyv alkenepolymerizationreactionswithtransitionmetalcatalysts |