C-furanosides: synthesis and stereochemistry
Carbon analogs of carbohydrates, dubbed C-glycosides, have remained an important and interesting class of mimetics, be it in natural product synthesis, for pharmacological applications, as conformational probes, or for biological studies. C-Furanosides: Synthesis and Stereochemistry provides a much-...
Gespeichert in:
| Hauptverfasser: | , , , |
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
London, United Kingdom
Academic Press, an imprint of Elsevier
[2018]
|
| Schlagworte: | |
| Online-Zugang: | FAW01 Volltext Volltext Volltext |
| Zusammenfassung: | Carbon analogs of carbohydrates, dubbed C-glycosides, have remained an important and interesting class of mimetics, be it in natural product synthesis, for pharmacological applications, as conformational probes, or for biological studies. C-Furanosides: Synthesis and Stereochemistry provides a much-needed overview of synthetic and stereochemical principles for C-furanosides: analogs of a 5-membered ring carbohydrate glycoside (furanoside), in which the anomeric oxygen has been replaced with a carbon. While our understanding of conformational behavior and of stereoselective synthesis in 6-membered ring compounds is quite good, our ability to predict the conformation of 5-membered ring compounds, or to predict the stereochemical outcome of a given reaction, remains anecdotal. Through a comprehensive review of literature approaches to the different C-furanoside stereoisomers, as well as an interpretation of the outcome in terms of a reasonable number of stereochemical models, C-Furanosides: Synthesis and Stereochemistry enables the reader to determine the best approach to a particular C-glycoside compound, and also hopes to provide a certain level of rationalization and predictability for the synthesis of new systems |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | 1 online resource |
| ISBN: | 9780128037898 012803789X |
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| 520 | |a Carbon analogs of carbohydrates, dubbed C-glycosides, have remained an important and interesting class of mimetics, be it in natural product synthesis, for pharmacological applications, as conformational probes, or for biological studies. C-Furanosides: Synthesis and Stereochemistry provides a much-needed overview of synthetic and stereochemical principles for C-furanosides: analogs of a 5-membered ring carbohydrate glycoside (furanoside), in which the anomeric oxygen has been replaced with a carbon. While our understanding of conformational behavior and of stereoselective synthesis in 6-membered ring compounds is quite good, our ability to predict the conformation of 5-membered ring compounds, or to predict the stereochemical outcome of a given reaction, remains anecdotal. Through a comprehensive review of literature approaches to the different C-furanoside stereoisomers, as well as an interpretation of the outcome in terms of a reasonable number of stereochemical models, C-Furanosides: Synthesis and Stereochemistry enables the reader to determine the best approach to a particular C-glycoside compound, and also hopes to provide a certain level of rationalization and predictability for the synthesis of new systems | ||
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| discipline | Chemie / Pharmazie |
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| illustrated | Not Illustrated |
| indexdate | 2024-07-10T08:16:38Z |
| institution | BVB |
| isbn | 9780128037898 012803789X |
| language | English |
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| spelling | Goekjian, Peter Verfasser aut C-furanosides synthesis and stereochemistry Peter Goekjian, Arnaud Haudrechy, Boudjema Menhour, Claire Coiffier London, United Kingdom Academic Press, an imprint of Elsevier [2018] 1 online resource txt rdacontent c rdamedia cr rdacarrier Includes bibliographical references and index Carbon analogs of carbohydrates, dubbed C-glycosides, have remained an important and interesting class of mimetics, be it in natural product synthesis, for pharmacological applications, as conformational probes, or for biological studies. C-Furanosides: Synthesis and Stereochemistry provides a much-needed overview of synthetic and stereochemical principles for C-furanosides: analogs of a 5-membered ring carbohydrate glycoside (furanoside), in which the anomeric oxygen has been replaced with a carbon. While our understanding of conformational behavior and of stereoselective synthesis in 6-membered ring compounds is quite good, our ability to predict the conformation of 5-membered ring compounds, or to predict the stereochemical outcome of a given reaction, remains anecdotal. Through a comprehensive review of literature approaches to the different C-furanoside stereoisomers, as well as an interpretation of the outcome in terms of a reasonable number of stereochemical models, C-Furanosides: Synthesis and Stereochemistry enables the reader to determine the best approach to a particular C-glycoside compound, and also hopes to provide a certain level of rationalization and predictability for the synthesis of new systems SCIENCE / Chemistry / Organic bisacsh Diastereoisomers fast Diastereoisomers Hauchy, Arnaud aut Menhour, Boudjema aut Coiffier, Claire aut Erscheint auch als Druck-Ausgabe 9780128037393 https://www.sciencedirect.com/science/book/9780128037393 Verlag URL des Erstveröffentlichers Volltext http://www.sciencedirect.com/science/book/9780128037393 Verlag URL des Erstveröffentlichers Volltext http://library.smu.ca:2048/login?url=https://www.sciencedirect.com/science/book/9780128037393 Verlag URL des Erstveröffentlichers Volltext |
| spellingShingle | Goekjian, Peter Hauchy, Arnaud Menhour, Boudjema Coiffier, Claire C-furanosides synthesis and stereochemistry SCIENCE / Chemistry / Organic bisacsh Diastereoisomers fast Diastereoisomers |
| title | C-furanosides synthesis and stereochemistry |
| title_auth | C-furanosides synthesis and stereochemistry |
| title_exact_search | C-furanosides synthesis and stereochemistry |
| title_full | C-furanosides synthesis and stereochemistry Peter Goekjian, Arnaud Haudrechy, Boudjema Menhour, Claire Coiffier |
| title_fullStr | C-furanosides synthesis and stereochemistry Peter Goekjian, Arnaud Haudrechy, Boudjema Menhour, Claire Coiffier |
| title_full_unstemmed | C-furanosides synthesis and stereochemistry Peter Goekjian, Arnaud Haudrechy, Boudjema Menhour, Claire Coiffier |
| title_short | C-furanosides |
| title_sort | c furanosides synthesis and stereochemistry |
| title_sub | synthesis and stereochemistry |
| topic | SCIENCE / Chemistry / Organic bisacsh Diastereoisomers fast Diastereoisomers |
| topic_facet | SCIENCE / Chemistry / Organic Diastereoisomers |
| url | https://www.sciencedirect.com/science/book/9780128037393 http://www.sciencedirect.com/science/book/9780128037393 http://library.smu.ca:2048/login?url=https://www.sciencedirect.com/science/book/9780128037393 |
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