Aspects of ceric alkoxide and siloxide chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
Tübingen
2018
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Inhaltsverzeichnis |
| Beschreibung: | Enthält Sonderabdrucke |
| Beschreibung: | xviii, 144 Seiten, 188 verschieden gezählte Seiten Illustrationen, Diagramme 21 cm |
Internformat
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| 245 | 1 | 0 | |a Aspects of ceric alkoxide and siloxide chemistry |c vorgelegt von M. Sc. Jochen Friedrich |
| 264 | 1 | |a Tübingen |c 2018 | |
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| 500 | |a Enthält Sonderabdrucke | ||
| 502 | |b Dissertation |c Eberhard Karls Universität Tübingen |d 2018 | ||
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| 650 | 0 | 7 | |a Alkoholate |0 (DE-588)4141898-0 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Cerverbindungen |0 (DE-588)4147505-7 |2 gnd |9 rswk-swf |
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| 689 | 1 | 1 | |a Siloxygruppe |0 (DE-588)4375652-9 |D s |
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Datensatz im Suchindex
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|---|---|
| adam_text | TABLE OF CONTENTS
PREFACE.............................................................................................................................................
I
ACKNOWLEDGMENTS..........................................................................................................................II
TABLE OF
CONTENTS..........................................................................................................................
IV
ABBREVIATIONS...............................................................................................................................
VII
NOMENCLATURE..............................................................................................................................
VIII
ABSTRACT..........................................................................................................................................
IX
ZUSAMMENFASSUNG
.................
XI
LIST OF
PUBLICATIONS....................................................................................................................
XIII
PERSONAL
CONTRIBUTIONS..........................................................
XIV
OBJECTIVES.....................................................................................................................................XVI
A INTRODUCTION
1. OVERVIEW ON RELEVANT SYNTHESIS PROCEDURES AND SELECTED CERIUM
COMPLEXES
............
1
1.1 SYNTHESIS OF INORGANIC SALTS OF TETRAVALENT CERIUM
...............................................
2
1.2 IMPLEMENTATION OF CERIC ORGANO AMMONIUM CHLORIDES *CAC* INTO THE
SYNTHESIS
OF CERIUM(IV)
ALKOXIDES.........................................................................................
4
1.3 CAN - A VERSATILE STARTING MATERIAL, NOT ONLY FOR THE SYNTHESIS OF
CERIUM(IV)
ALKOXIDES.....................................................................................
5
1.3.1 DEVELOPMENT OF THE CAN PROTOCOL
..............................................................
6
1.3.2 BASIC EXAMPLES OF CEIV ALKOXIDES SYNTHESIZED ACCORDING TO THE CAN
PROTOCOL..........................................................................................................8
1.3.3 DISTINCT VARIATIONS OF THE CLV PROTOCOL - USE OF CERIC AMMONIUM
NITRATE
AND CEROUS AMMONIUM NITRATE IN SALT METATHESES TOWARD TRI- AND
TETRAVALENT CERIUM
COMPLEXES....................................................................8
1.4 SALT METATHESIS REACTIONS OF HETEROLEPTIC CEIV ALKOXY-NITRATES AND
PROTONOLYSIS
REACTIONS OF THE ALKOXY-AMIDE COMPLEX [CE(0/BU)2{N(SIME3)2}2]
............
10
1.5 ALTERNATIVE ALKOXY-DERIVED HETERO LEPTIC CERIC PRECURSORS FOR
METATHESIS
REACTIONS..................................................................................................................14
1.6 SYNTHESIS OF CERIUM COMPLEXES FEATURING SILOXY LIGANDS AND S I-0
MOIETIES 15
1.7 SYNTHESIS O F CAN AND C4CF-DERIVED CERIUM(IV) COMPLEXES BEARING
BIDENTATE
IMIDOPHOSPHONIUMOXY AND TRIDENTATE COBALTOCENIUM PHOSPHONOXY LIGAND...
17
2. DECOMPOSITION AND OLIGOMERIZATION OF CERIUM(IV) ALKOXIDES
22
3. CERIUM(IV) ALKOXIDES AS PRECURSOR IN TRANSALCOHOLYSIS, PROTONOLYSIS
AND LIGAND
EXCHANGE
REACTIONS.........................................................................................................
25
3.1 MONOMETALLIC CERIUM(IV) COMPLEXES DERIVED FROM HOMOLEPTIC CEIV TERT-
BUTOXIDE AND
ISOPROPOXIDE..................................................................................26
3.2 BIMETALLIC COMPLEXES DERIVED FROM HOMOLEPTIC CE,V ISOPROPOXIDE
.............
.30
3.3 ORGANOMETALLIC COMPLEXES DERIVED FROM HOMOLEPTIC CEIV ISOPROPOXIDE
.....
32
4.
LITERATURE...........................................................................................................................33
B SUMMARY OF THE MAIN RESULTS
1. CERIUM ALKOXIDE
CHEMISTRY............................................................................................
41
2. CERIUM SILOXIDE
CHEMISTRY.............................................................................................
44
2.1 OXIDATIVE FUNCTIONALIZATION OF CEROUS TRIS(TERT-BUTOXY)SILOXIDES
...................
45
2.2 REACTIVITY OF COMPLEX CE[OSI(ORBU)
3
]
3
CL(THF).............................................47
2.3 ACCESS TO CERIC 8ILOXIDE COMPLEXES FROM INORGANIC CEIV S
ALTS......................50
2.4 ELECTROCHEMICAL INVESTIGATIONS OF CERIUM S ILOXIDE COMPLEXES
.......................
52
3.
LITERATURE...........................................................................................................................55
C UNPUBLISHED RESULTS
1. DETAILED ANALYSIS OF PRODUCTS DERIVED FROM PHOTO LYTIC DECOMPOSITION
OF
[CE(0CH2FBU)3(N03)(MECN)]2......................................................................................59
2. SURFACE OXIDATION OF AN MCM-41 SUPPORTED CEM SILYLAMIDE COMPLEX AND
THE
SYNTHESIS O F A CEM MODEL COMPLEX
.................................
62
3. REACTIVITY OF CEROUS TRIS(TER/-BUTOXY)SILOXIDE TOWARD OXIDANTS
COMMONLY USED IN
CERIUM
CHEMISTRY.............................................................................................................82
4. INVESTIGATIONS INTO THE REACTIVITY OF CERIC
TRIS(TER/-BUTOXY)SILOXIDES 99
4.1 PRELIMINARY EXPERIMENTS SCREENING THE REACTIVITY OF CE[OSI(OFBU)
3
]
3
CL(THF)
IN SALT METATHESIS
REACTIONS.............................................................................100
4.2 SCREENING THE REACTIVITY OF CE[OSI(OFBU)
3
]
3
CL(THF) WITH ALKYLATION REAGENTS
.............................................................................................................................117
D PUBLICATIONS
PAPERS I, II AND III
MANUSCRIPT IV, SUBMITTED
MANUSCRIPT V
APPENDIX
|
| any_adam_object | 1 |
| author | Friedrich, Jochen |
| author_GND | (DE-588)1165799766 |
| author_facet | Friedrich, Jochen |
| author_role | aut |
| author_sort | Friedrich, Jochen |
| author_variant | j f jf |
| building | Verbundindex |
| bvnumber | BV045333654 |
| ctrlnum | (OCoLC)1060646716 (DE-599)BSZ510533299 |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| spelling | Friedrich, Jochen Verfasser (DE-588)1165799766 aut Aspects of ceric alkoxide and siloxide chemistry vorgelegt von M. Sc. Jochen Friedrich Tübingen 2018 xviii, 144 Seiten, 188 verschieden gezählte Seiten Illustrationen, Diagramme 21 cm txt rdacontent n rdamedia nc rdacarrier Enthält Sonderabdrucke Dissertation Eberhard Karls Universität Tübingen 2018 Siloxygruppe (DE-588)4375652-9 gnd rswk-swf Alkoholate (DE-588)4141898-0 gnd rswk-swf Cerverbindungen (DE-588)4147505-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Cerverbindungen (DE-588)4147505-7 s Alkoholate (DE-588)4141898-0 s DE-604 Siloxygruppe (DE-588)4375652-9 s Eberhard Karls Universität Tübingen (DE-588)36187-2 oth B:DE-101 application/pdf http://d-nb.info/1169153216/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030720474&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Friedrich, Jochen Aspects of ceric alkoxide and siloxide chemistry Siloxygruppe (DE-588)4375652-9 gnd Alkoholate (DE-588)4141898-0 gnd Cerverbindungen (DE-588)4147505-7 gnd |
| subject_GND | (DE-588)4375652-9 (DE-588)4141898-0 (DE-588)4147505-7 (DE-588)4113937-9 |
| title | Aspects of ceric alkoxide and siloxide chemistry |
| title_auth | Aspects of ceric alkoxide and siloxide chemistry |
| title_exact_search | Aspects of ceric alkoxide and siloxide chemistry |
| title_full | Aspects of ceric alkoxide and siloxide chemistry vorgelegt von M. Sc. Jochen Friedrich |
| title_fullStr | Aspects of ceric alkoxide and siloxide chemistry vorgelegt von M. Sc. Jochen Friedrich |
| title_full_unstemmed | Aspects of ceric alkoxide and siloxide chemistry vorgelegt von M. Sc. Jochen Friedrich |
| title_short | Aspects of ceric alkoxide and siloxide chemistry |
| title_sort | aspects of ceric alkoxide and siloxide chemistry |
| topic | Siloxygruppe (DE-588)4375652-9 gnd Alkoholate (DE-588)4141898-0 gnd Cerverbindungen (DE-588)4147505-7 gnd |
| topic_facet | Siloxygruppe Alkoholate Cerverbindungen Hochschulschrift |
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