Hydrogen storage technologies:
Gespeichert in:
| Weitere Verfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, NJ
Scrivener Publishing, Wiley
[2018]
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| Schriftenreihe: | Advances in hydrogen production and storage
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | Literaturangaben |
| Beschreibung: | xiv, 324 Seiten |
| ISBN: | 9781119459880 |
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Datensatz im Suchindex
| _version_ | 1804179056630956032 |
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| adam_text | Contents Preface Part I: Chemical and Electrochemical Hydrogen Storage 1 Metal Hydride Hydrogen Compression Systems Materials, Applications and Numerical Analysis Evangelos I. Gkanas and Martin Khzouz 1.1 Introduction 1.2 Adoption of a Hydrogen-Based Economy 1.2.1 Climate Change and Pollution 1.2.2 Toward a Hydrogen-Based Future 1.2.3 Hydrogen Storage 1.2.3.1 Compressed Hydrogen Storage 1.2.3.2 Hydrogen Storage in Liquid Form 1.2.3.3 Solid-State Hydrogen Storage 1.3 Hydrogen Compression Technologies 1.3.1 Reciprocating Piston Compressor 1.3.2 Ionic Liquid Piston Compressor 1.3.3 Piston-Metal Diaphragm Compressor 1.3.4 Electrochemical Hydrogen Compressor 1.4 Metal Hydride Hydrogen Compressors (MHHC) 1.4.1 Operation of a Two-Stage MHHC 1.4.2 Metal Hydrides 1.4.3 Thermodynamic Analysis of the Metal Hydride Formation 1.4.3.1 Pressure-Composition-Temperature (P-c-T) Properties 1.4.3.2 Slope and Hysteresis 1.4.4 Material Challenges for MHHCs 1.4.4.1 AB5 Intermetallics 1.4.4.2 AB, Intermetallics xiii 1 3 3 4 4 4 5 5 5 6 6 7 8 9 9 11 11 14 14 14 16 17 18 19
vi Contents 1.5 1.6 2 1.4.4.3 TiFe-Based АВ-Туре Intermetallics 1.4.4.4 Vanadium-Based ВСС Solid Solution Alloys Numerical Analysis of a Multistage MHHCSystem 1.5.1 Assumptions 1.5.2 Physical Model and Geometries 1.5.3 Heat Equation 1.5.4 Hydrogen Mass Balance 1.5.5 Momentum Equation 1.5.6 Kinetic Expressions for the Hydrogenation and Dehydrogenation 1.5.7 Equilibrium Pressure 1.5.8 Coupled Mass and Energy Balance 1.5.9 Validation of the Numerical Model 1.5.10 Material Selection for a Three-Stage MHHC 1.5.11 Temperature Evolution of the Complete Three-Stage Compression Cycle 1.5.12 Pressure and Storage Capacity Evolution During the Complete Three-Stage Compression Cycle 1.5.13 Importance of the Number of Stages and Proper Selection Conclusions Acknowledgments Nomenclature References Nitrogen-Based Hydrogen Storage Systems: A Detailed Overview Ankur Jain, Takayuki Ichikawa and Shivani Agarwal 2.1 Introduction 2.2 Amide/Imide Systems 2.2.1 Single-Cation Amide/Imide Systems 2.2.1.1 Lithium Amide/Imide 2.2.1.2 Sodium Amide/Imide 2.2.1.3 Magnesium Amide/Imide 2.2.1.4 Calcium Amide/Imide 2.2.2 Double-Cation Amide/Imide Systems 2.2.2.1 Li-Na-N-H 2.2.2.2 Li-Mg-N-H 2.2.2.3 Other Double-Cation Amides/Imides 2.3 Ammonia (NH3) as Hydrogen Storage Media 2.3.1 NH3 Synthesis 19 19 20 20 21 22 22 23 23 24 24 25 26 27 29 31 32 32 32 33 39 40 41 41 41 44 47 49 51 52 54 58 62 63
Contents Catalytic NH3 Synthesis Using Haber-Bosch Process 2.3.1.2 Alternative Routes for NH3 Synthesis 2.3.2 NH3 Solid-State Storage 2.3.2.1 Metal Ammine Salts 2.3.2.2 Ammine Metal Borohydride 2.3.3 NH3 Decomposition 2.3.4 Application of NH3 to Fuel Cell 2.4 Future Prospects References vii 2.3.1.1 3 4 Nanostructured Mg-Based Hydrogen Storage Materials: Synthesis and Properties Huaiyu Shao, Xiubo Xie, JiandingLi, Bo Li, Tong Liu and Xingguo Li 3.1 Introduction 3.2 Experimental Details 3.2.1 Synthesis of Metal Nanoparticles 3.2.2 Formation of the Nanostructured Hydrides and Alloys 3.2.3 Characterization and Measurements 3.3 Synthesis Results of the Nanostructured Samples 3.4 Hydrogen Absorption Kinetics 3.5 Hydrogen Storage Thermodynamics 3.6 Novel Mg-TM (TM=V, Zn, Al) Nanocomposites 3.6.1 Introduction 3.6.2 Structure and Morphology of Mg-TM Nanocomposites 3.6.3 Hydrogen Absorption Kinetics 3.6.4 Phase Evolution During Hydrogenation/ Dehydrogenation 3.6.5 Summary 3.7 Summary and Prospects Acknowledgments References Hydrogen Storage in Ti/Zr-Based Amorphous and Quasicrystal Alloys Akito Takasaki, Łukasz Gondek, Joanna Czub, Alicja Klimkowicz, Antoni Żywczak and Konrad Świerczek 4.1 Introduction 63 68 69 69 70 71 73 74 75 89 90 92 92 93 93 94 98 99 103 103 105 107 108 109 110 111 111 117 118
viii Contents 4.2 Production of Ti/Zr-Based Amorphous and Quasicrystals Alloys 4.3 Hydrogen Storage in T-Zr-Based Amorphous Alloys 4.3.1 Gaseous Hydrogenation 4.3.2 Electrochemical Hydrogenation 4.4 Hydrogen Storage in the Ti/Zr-Based Quasicrystal Alloys 4.4.1 Gaseous Hydrogenation 4.4.2 Electrochemical Hydrogenation 4.5 Comparison of Amorphous and Quasicrystal Phases on the Hydrogen Properties 4.6 Conclusions References 5 Electrochemical Method of Hydrogenation/Dehydrogenation of Metal Hydrides N.E. Galushkin, N.N. Yazvinskaya and D.N. Galushkin 5.1 Introduction 5.2 Electrochemical Method of Hydrogenation of Metal Hydrides 5.2.1 Hydrogen Accumulation in Electrodes of Cadmium-Nickel Batteries Based on Electrochemical Method 5.2.2 Hydrogen Accumulation in Sintered Nickel Matrix of Oxide-Nickel Electrode 5.2.2.1 Active Substance of Oxide-Nickel Electrodes 5.2.2.2 Sintered Nickel Matrices of Oxide-Nickel Electrodes 5.3 Electrochemical Method of Dehydrogenation of Metal Hydrides 5.3.1 Introduction 5.3.2 Thermal Runaway as the New Method of Hydrogen Desorption from Hydrides 5.3.2.1 Thermo-Chemical Method of Hydrogen Desorption 5.3.2.2 Thermal Runaway: A New Method of Hydrogen Desorption from Metal Hydrides 5.4 Discussion 5.5 Conclusions References 119 124 124 129 130 131 133 140 141 142 147 148 151 151 155 155 157 161 161 164 164 164 166 172 173
Contents Part II: Carbon-Based Materials For Hydrogen Storage 6 7 Activated Carbon for Hydrogen Storage Obtained from Agro-Industrial Waste Yesid Murillo-Acevedo, Paola Rodríguez-Estupiñán, Liliana Giraldo Gutiérrez and Juan Carlos Moreno-Piraján 6.1 Introduction 6.2 Experimental 6.3 Results and Discussion 6.4 Conclusions Acknowledgments References Carbonaceous Materials in Hydrogen Storage R. Pedicini, I. Gatto, M. F. Gatto and E. Passalacqua 7.1 Introduction 7.2 Materials Consisting of Only Carbon Atoms 7.2.1 Graphite 7.2.2 Carbon Nanofibers 7.2.3 Carbon Nanostructures 7.2.4 Graphene 7.2.5 Carbon Nanotubes (CNTs) and Carbon Multi-Walled Nanotubes (MWCNTs) 7.3 Materials Containing Carbon and Other Light Elements 7.3.1 Polyaniline (PANI), Polypyrrole (PPy) and Polythiophene (PTh) 7.3.2 Hyperbranched Polyurea (Р-Urea) and Poly(Amide-Amine) (РАМАМ) 7.3.3 Microporous Polymers (PIMs) 7.3.4 Conjugated Microporous Polymers (CMPs) 7.3.5 Hyper-Cross-Linked Polymers (HCPs) 7.3.6 Porous Aromatic Frameworks (PAFs) 7.4 Composite Materials Made by Polymeric Matrix 7.4.1 Composite Poly(Amide-Amine) (РАМАМ) 7.4.2 Polymer-Dispersed Metal Hydrides (PDMHs) 7.4.3 Mn Oxide Anchored to a Polymeric Matrix 7.5 Waste and Natural Materials 7.6 Conclusions References ix 177 179 180 182 183 192 193 193 197 198 199 199 200 202 203 203 205 206 207 207 208 209 209 210 211 211 212 217 220 223
x Contents 8 Beneficial Effects of Graphene on Hydrogen Uptake and Release from Light Hydrogen Storage Materials 229 Röhit RShahi 8.1 Introduction 230 8.2 General Aspects of Graphene 232 8.2.1 Synthesis of Graphene 233 8.2.1.1 Mechanical Cleavage of Highly Oriented Pyrolytic Graphite 233 8.2.1.2 Chemical Vapor Deposition 233 8.2.1.3 Chemical and Thermal Exfoliation of Graphite Oxide 234 8.2.1.4 Arc Discharge Method 234 8.2.2 Graphene as a Beneficial Additive for HS Materials 234 8.3 Beneficial Effect of Graphene: Key Results with Light Metal Hydrides (e.g., LiBH4, NaAlH4, MgH2) 236 8.3.1 Borohydrides (Tetrahydroborate) as HS Material 236 8.3.1.1 Effect of Graphene on Desorption Properties of LiBH4 237 8.4 Alanates as HS Materials 239 8.4.1 Effect of Graphene on Sorption Behavior of NaAlH4 240 8.4.2 Carbon Nanomaterial-Assisted Morphological Tuning of NaAlH4 to Improve Thermodynamics and Kinetics 242 8.5 Magnesium Hydride as HS Material 243 8.5.1 Catalytic Effect of Graphene on Sorption Behavior of Mg/MgH2 244 8.5.2 Nanoparticles Templated Graphene as an Additive for MgH2 246 8.6 Summary and Future Prospects 253 Acknowledgment 254 References 254 9 Hydrogen Adsorption on Nanotextured Carbon Materials G. Sdanghi, G. Mammana, A. Celzard and V. Fierro 9.1 Introduction 9.1.1 Essential Features of Hydrogen Adsorption on Porous Carbon Materials 9.1.2 Measurement of the Hydrogen Storage Capacity 9.1.3 Excess, Absolute and Total Hydrogen Adsorption 9.2 Hydrogen Storage in Carbon Materials 9.2.1 Activated Carbons 263 264 264 267 268 270 270
Contents: 9.2.2 Carbon Nanomaterials 9.2.2.1 Graphene 92.2.2 Fullerenes 9.2.2.3 Carbon Nanotubes 9.2.2.4 Carbon Nanofibers 9.2.3 Templated Carbons 9.2.3.1 Zeolite- and Silica-Derived Carbons 9.2.3.2 MOFs-Derived Carbons 9.2.4 Other Carbon Materials 9.2.4.1 Carbide-Derived Carbons 9.2.4.2 Hybrid Carbon-MOF Materials 9.2.4.3 Hyper-Cross-Linked Polymers-Derived Carbons 9.2.4.4 Carbon Nanorods, Nanohorns and Nanospheres 9.2.4.5 Carbon Nitrides 9.2.4.6 Carbon Aerogels 9.2.4.7 Other Exotic Carbon Materials Conclusion Acknowledgments References Appendix Index xi 273 273 276 276 279 282 282 284 289 289 289 291 291 293 293 294 295 297 297 310 321
Provides a comprehensive practical review of the available hydrogen storage technologies such as: electrochemical hydrogen storage; chemical hydrogen storage; graphene and hydrogen storage; nanotechnology and hydrogen storage; carbon- based materials and hydrogen storage. Hydrogen storage is considered a key technology for stationary and portable power generation especially for transportation. This volume covers the novel technologies to efficiently store and distribute hydrogen and discusses the underlying basics as well as the advanced details in hydrogen storage technologies. The book has two major parts: Chemical and electrochemical hydrogen storage and Carbon-based materials for hydrogen storage. The following subjects are detailed in Part I: • Multi stage compression system based on metal hydrides; • Metal-N-H systems and their physico-chemical properties; • Mg-based nano materials with enhanced sorption kinetics; • Gaseous and electrochemical hydrogen storage in the Ti-Z-Ni; • Electrochemical methods for hydrogenation/dehydrogenation of metal hydrides. In Part II the following subjects are addressed: • Activated carbon for hydrogen storage obtained from agro-industrial waste; • Hydrogen storage using carbonaceous materials; • Hydrogen storage performance of composite material consisting of single walled carbon nanotubes and metal oxide nanoparticles; • Hydrogen storage characteristics of graphene addition of hydrogen storage materials; • Discussion of the crucial features of hydrogen adsorption of nanotextured carbon-based materials. Audience The book will have a
wide audience including those in electrochemistry, physics, materials science and engineering, mechanical and chemical engineering as well as renewable energy and storage technologies. Mehmet Sankir received his PhD degree in Macromolecular Science and Engineering from the Virginia Polytechnic and State University, USA in 2005. He is a Full Professor in the Department of Materials Science and Nanotechnology Engineering, TOBB University of Economics and Technology, Ankara, Turkey and group leader of Advanced Membrane Technologies Laboratory. Dr. Sankir has actively carried out research and consulting activities in the areas of membranes for fuel cells, flow batteries, hydrogen generation and desalination. Nurdan Demirci Sankir is an Associate Professor in the Materials Science and Nanotechnology Engineering Department at the TOBB University of Economics and Technology (TOBB ETU), Ankara, Turkey. She received her MEng and PhD degrees in Materials Science and Engineering from the Virginia Polytechnic and State University, USA in 2005. She established the Energy Research and Solar Cell Laboratories at TOBB ETU. Nurdan has actively carried out research and consulting activities in the areas of photovoltaic devices, solution based thin film manufacturing, solar driven water splitting, photocatalytic degradation and nanostructured semiconductors. ISBN 978-1-119-45988-0 9781119459880 Cover design by Russell Richardson Front cover images from Mehmet Sankir А1ѕо available as an e-book Ш Wiley www.wiley.com www.scrivenerpublishing.com 9 781 19 459880
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| spelling | Hydrogen storage technologies edited by Mehmet Sankir and Nurdan Demirci Sankir Hoboken, NJ Scrivener Publishing, Wiley [2018] © 2018 xiv, 324 Seiten txt rdacontent n rdamedia nc rdacarrier Advances in hydrogen production and storage Literaturangaben Hydrogen Storage Hydrogen as fuel Energiespeicherung (DE-588)4014722-8 gnd rswk-swf Wasserstoffspeicherung (DE-588)4189283-5 gnd rswk-swf Energiespeicherung (DE-588)4014722-8 s Wasserstoffspeicherung (DE-588)4189283-5 s 1\p DE-604 Sankir, Mehmet (DE-588)1137272104 edt Demirci Sankir, Nurdan (DE-588)1137271973 edt Erscheint auch als Online-Ausgabe 978-1-119-46068-8 Erscheint auch als Online-Ausgabe 978-1-119-46057-2 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030669510&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030669510&sequence=000003&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Hydrogen storage technologies Hydrogen Storage Hydrogen as fuel Energiespeicherung (DE-588)4014722-8 gnd Wasserstoffspeicherung (DE-588)4189283-5 gnd |
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| title | Hydrogen storage technologies |
| title_auth | Hydrogen storage technologies |
| title_exact_search | Hydrogen storage technologies |
| title_full | Hydrogen storage technologies edited by Mehmet Sankir and Nurdan Demirci Sankir |
| title_fullStr | Hydrogen storage technologies edited by Mehmet Sankir and Nurdan Demirci Sankir |
| title_full_unstemmed | Hydrogen storage technologies edited by Mehmet Sankir and Nurdan Demirci Sankir |
| title_short | Hydrogen storage technologies |
| title_sort | hydrogen storage technologies |
| topic | Hydrogen Storage Hydrogen as fuel Energiespeicherung (DE-588)4014722-8 gnd Wasserstoffspeicherung (DE-588)4189283-5 gnd |
| topic_facet | Hydrogen Storage Hydrogen as fuel Energiespeicherung Wasserstoffspeicherung |
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