Phosphorus chemistry: the role of phosphorus in prebiotic chemistry
Gespeichert in:
Hauptverfasser: | , , , |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Berlin ; Boston
De Gruyter
[2019]
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Schlagworte: | |
Online-Zugang: | http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110562378&searchTitles=true https://www.degruyter.com/doc/cover/9783110562378.jpg Inhaltsverzeichnis |
Beschreibung: | XV, 166 Seiten Illustrationen, Diagramme 24 cm x 17 cm |
ISBN: | 9783110562378 3110562375 |
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100 | 1 | |a Zhao, Yufen |e Verfasser |4 aut | |
245 | 1 | 0 | |a Phosphorus chemistry |b the role of phosphorus in prebiotic chemistry |c Yufen Zhao, Yan Liu, Xiang Gao, Pengxiang Xu |
263 | |a 201811 | ||
264 | 1 | |a Berlin ; Boston |b De Gruyter |c [2019] | |
300 | |a XV, 166 Seiten |b Illustrationen, Diagramme |c 24 cm x 17 cm | ||
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700 | 1 | |a Liu, Yan |e Verfasser |4 aut | |
700 | 1 | |a Gao, Xiang |e Verfasser |4 aut | |
700 | 1 | |a Xu, Pengxiang |e Verfasser |4 aut | |
710 | 2 | |a Walter de Gruyter GmbH & Co. KG |0 (DE-588)10095502-2 |4 pbl | |
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Datensatz im Suchindex
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adam_text | CONTENTS
FOREWORD* V
PREFACE I * VII
PREFACE * IX
1 THE INTERNATIONAL BACKGROUND OF THE ORIGIN OF LIFE * 1
1.1 ORIGINAL SOURCE OF PHOSPHORUS * 1
1.1.1 NUCLEAR REACTIONS * 1
1.1.2 PHOSPHORUS SURROUNDS CELESTIAL INTERVAL
AND INTERSTELLAR SPACE * 2
1.1.3 PHOSPHORUS IN METEORITES * 2
1.1.4 PHOSPHORUS IN COMETS * 3
1.1.5 ALKYL PHOSPHORIC ACID HOMOLOGUES * 3
1.1.6 PHOSPHORUS IN THE CRUST
-----
3
1.1.7 PHOSPHORYLATION UNDER PREBIOLOGICAL CONDITIONS * 4
1.1.8 OUTLOOK
-----
4
1.2 PHOSPHORUS AND SMALL BIOMOLECULES * 5
1.2.1 FORMATION OF AMINO ACIDS WITH PHOSPHORUS * 5
1.2.2 FORMATION OF BASES * 5
1.2.3 FORMATION OF NUCLEOSIDES WITH PHOSPHORUS
-----
6
1.2.4 FORMATION OF NUCLEOTIDES * 7
1.3 PHOSPHORUS AND BIOMACROMOLECULES * 9
1.3.1 FORMATION OF PEPTIDES WITH PHOSPHORUS
-----
9
1.3.2 NUCLEIC ACID PRE-BIOSYNTHESIS
-----
10
1.4 IRREPLACEABILITY OF PHOSPHORUS IN LIFE * 14
1.5 SUBJECT OF THE ORIGIN OF LIFE * 14
2 WHY NATURE CHOSE A-AMINO ACIDS? * 19
2.1 AMINO ACIDS AND THE ORIGINS OF LIFE * 19
2.2 GENERAL STRUCTURES OF AMINO ACIDS
AND THE BIOLOGICAL FUNCTIONS * 20
2.3 PREBIOTIC FORMATION OF AMINO ACIDS * 21
2.4 PREBIOTIC FORMATION OF PEPTIDES
-----
23
2.5 PHOSPHORUS CHEMISTRY FOR PREBIOTIC PEPTIDE FORMATION *
2.5.1 REACTION OF AMINO ACIDS WITH TRIMETAPHOSPHATE * 25
2.5.2 PEPTIDE FORMATION OF /V-PHOSPHORYL AMINO ACIDS * 28
2.5.3 PEPTIDE FORMATION MEDIATED BY ORGANIC
PHOSPHORUS REAGENTS * 31
2.6 PHOSPHORUS CHEMISTRY AND THE MOLECULAR EVOLUTION
OF HIGH-ENERGY P-N BOND * 33
3
3.1
3.2
3.2.1
3.2.2
3.3
3.3.1
3.3.2
3.4
3.4.1
3.4.2
3.4.3
3.5
3.5.1
4
4.1
4.2
4.3
4.4
4.5
4.6
5
5.1
5.2
5.2.1
5.2.2
5.3
5.4
/V-PHOSPHORYL AMINO ACIDS - MODELS FOR P-N BONDS IN PREBIOTIC CHEMICAL
EVOLUTION * 35
INTRODUCTION
-----
35
THE P-N BOND IN MODERN BIOLOGY * 36
PHOSPHOHISTIDINE * 37
PHOSPHOARGININE AND PHOSPHORYL-LYSINE * 37
POTENTIAL PREBIOTIC ORIGINS OF A/-A-PHOSPHORYL AMINO ACIDS * 38
THE PHOSPHORUS PROBLEM * 38
POSSIBLE PATHWAYS FOR ORIGIN OF A/-PHOSPHORYL
AMINO ACIDS * 39
REACTIVITY OF A/A-PHOSPHORYL AMINO ACIDS RELATED TO PREBIOTIC
CHEMISTRY
-----
40
A/-DIALKYLOXYPHOSPHORYL AMINO ACIDS * 40
NMAPAAS
-----
43
A/-PHOSPHONO-AMINO ACIDS * 45
SUMMARY * 46
PERSPECTIVES
-----
47
NUCLEOSIDE-PROTEIN COEVOLUTION AND THE ORIGIN
OF GENETIC CODE * 53
MAJOR PHASE IN THE ORIGIN OF LIFE
-----
53
ORIGIN OF GENETIC CODE * 55
THE EVOLUTION OF GENETIC CODE * 57
PHOSPHORUS PLAYS AN IMPORTANT ROLE IN THE ORIGIN OF LIFE * 59
A/-PHOSPHORYL AMINO ACIDS: MODEL FOR THE STUDY OF NUCLEOTIDE-PROTEIN
COEVOLUTION * 61
THE RELATIONSHIP OF DIPEPTIDE YIELDS WITH NUCLEOSIDE IN THE
PHOSPHORUS-ASSISTED CONDENSATION OF AMINO ACIDS * 62
THE PHOSPHORYL TRANSFER REACTIONS OF PENTACOORDINATED
PHOSPHORYL AMINO ACIDS* 67
THE RESEARCH PROGRESS OF PHOSPHORYL TRANSFER REACTION * 67
STUDY ON THE TRANSFER REACTION OF INTERMOLECULAR
0,0-PHENYLENEPHOSPHORYL GROUP * 69
SYNTHESIS AND ANALYSIS OF SER-HIS DIPEPTIDE * 69
THE INVESTIGATION OF THE INTERMOLECULAR TRANSFER MECHANISM OF
0,0-PHENYLENEPHOSPHORYL GROUP BETWEEN AMINO ACIDS * 71
THE TRANSFER REACTION OF A/-(0,0-DIISOPROPYL) PHOSPHORYL BETWEEN
DIFFERENT AMINO ACIDS * 74
THE STUDIES ON THE PHOSPHORYL TRANSFER REACTION BETWEEN DIFFERENT TYPES
OF AMINO ACIDS * 76
6 THE RESEARCH PROGRESS OF CHIRAL PENTACOORDINATE SPIROPHOSPHORANES WITH
BIS-A-AMINO ACID BONDS* 81
6.1 THE IMPORTANCE OF PENTACOORDINATE PHOSPHORUS COMPOUNDS
IN BIOLOGICAL PROCESSES * 81
6.2 THE SYNTHESIS METHOD OF CHIRAL PENTACOORDINATE
SPIROPHOSPHORANES * 82
6.3 SPECTROSCOPIC CHARACTERIZATION OF BISAMINO ACYL PENTACOORDINATE
SPIROPHOSPHORANES * 85
6.3.1 W
H
* 85
6.3.2
-----
88
6.3.3 X-RAY
-----
90
6.3.4 SOLID-STATE CD SPECTRA * 93
7 A NEW THEORETICAL MODEL FOR THE ORIGIN OF AMINO ACID HOMOCHIRALITY* 99
7.1 THE ORIGIN OF HOMOCHIRALITY * 99
7.2 MODEL FOR THE ORIGIN OF AMINO ACID HOMOCHIRALITY
-----
100
7.3 INTERACTION OF NUCLEOSIDES AND AMINO ACIDS
-----
101
7.4 THERMODYNAMIC PARAMETERS OF INTERACTION BETWEEN NUCLEOSIDES
AND AMINO ACIDS * 104
8 JV-PHOSPHORYL AMINO ACIDS AND THE ORIGIN OF CELL MEMBRANES * 109
8.1 THE ORIGIN AND EVOLUTION OF CELLS * 109
8.1.1 THE FORMATION OF PRIMITIVE CELLS - THE BEGINNING OF THE MUSIC
OF LIFE * 109
8.1.2 THE FORMATION OF PROKARYOTIC AND EUKARYOTIC CELL * 110
8.2 MEMBRANE STRUCTURES CONSTRUCTED BY AMPHIPHILIC A/-PHOSPHORYL AMINO
ACIDS * 110
8.2.1 SYNTHESIS OF AMPHIPHILIC /V-PHOSPHORYL AMINO ACIDS * 112
8.2.2 SELF-ASSEMBLED MONOLAYERS OF AMPHIPHILIC /V-PHOSPHORYL AMINO ACIDS
AT WATER-AIR INTERFACE AND THEIR CONDENSATION REACTIONS * 112
8.2.2.1 FORMATION OF MONOMOLECULAR MEMBRANES FROM AMPHIPHILIC
/V-PHOSPHORYL AMINO ACIDS AT THE WATER-AIR INTERFACE
-----
112
8.2.2.2 CONDENSATION OF AMPHIPHILIC /V-PHOSPHORYL AMINO ACIDS AT THE
WATER-AIR INTERFACE * 114
8.2.3 FORMATION AND REACTION OF BIMOLECULAR MEMBRANES*VESICLES IN
WATER BY AMPHIPHILIC /V-PHOSPHORYL AMINO ACIDS * 116
8.2.3.1 FORMATION AND CHARACTERIZATION OF VESICLES * 116
8.2.3.2 CONDENSATION IN VESICLE SYSTEMS * 118
8.3 EVOLUTION OF THE PROTOCELL MEMBRANE * 120
8.4 /V-PHOSPHORYL AMINO ACIDS AND THE ORIGIN OF LIFE * 121
8.4.1 SYNERGISTIC EFFECT OF MEMBRANE, NUCLEIC ACID AND PROTEIN * 121
8.4.2 THE COEVOLUTION THEORY OF NUCLEIC ACID, PROTEIN
AND CELL MEMBRANE * 121
9 THE POTENTIAL EVOLUTION PROTOTYPE OF MODERN ENZYME: DISCOVERY
OF SERYL-HISTIDINE DIPEPTIDE AND ITS FUNCTION
* 125
9.1 MINI-ACTIVATING ENZYME: SER-HIS * 125
9.2 THE CLEAVAGE ACTIVITIES OF SER-HIS ON DNA* 126
9.2.1 DISCOVERY OF THE HYDROLYSIS ACTIVITY OF SER-HIS ON DNA* 126
9.2.2 THE CLEAVAGE MECHANISM OF SER-HIS ON DNA AND THE PIVOTAL ROLE
OF FUNCTIONAL GROUPS IN SER-HIS * 127
9.2.3 MOLECULAR MODELING FOR INVESTIGATING DNA CLEAVAGE ACTIVITY
OF SER-HIS * 129
9.3 THE CLEAVAGE ACTIVITIES OF SER-HIS ON PROTEINS * 130
9.3.1 THE DISCOVERY OF THE CLEAVAGE ACTIVITIES
OF SER-HIS ON PROTEINS* 130
9.3.2 THE EFFECT OF DIFFERENT BUFFERS ON THE CLEAVAGE ACTIVITIES * 131
9.3.3 THE ROLE OF FUNCTIONAL GROUPS OF SER-HIS IN THE CLEAVAGE
ACTIVITIES * 131
9.3.4 THE STUDY OF THE INTERACTION OF SER-HIS WITH THE SUBSTRATE
PROTEINS * 132
9.3.5 THE CLEAVAGE ACTIVITIES OF SER-HIS ON CARBOXYLIC ESTER* 134
9.3.6 THE FUNCTIONAL REVERSIBILITY OF SER-HIS ON THE SUBSTRATE* 134
9.4 SER-HIS: THE EVOLUTION PROTOTYPE OF MODERN ENZYME * 135
10 THE INTERACTION BETWEEN ATP AND AMINO ACIDS* 141
10.1 THE STUDY OF THE ORIGIN AND EVOLUTION OF PROTEIN BASED
ON SMALL MOLECULE* 141
10.1.1 ATP - A LIVING FOSSIL AT THE MOLECULAR LEVEL * 141
10.1.2 ATP-BINDING PROTEIN - THE OLDEST PROTEIN * 142
10.2 THE STRUCTURE AND THE INTERACTION WITH AAS OF ATP* 145
10.2.1 THE STRUCTURE OF ATP * 145
10.2.2 STUDY ON THE WEAK INTERACTION BETWEEN AA AND ATP BY MS* 146
10.2.3 STUDY ON THE WEAK INTERACTION BETWEEN AA AND ATP BY FLUORESCENCE
SPECTROMETRY* 149
10.2.4 STUDY OF THE WEAK INTERACTION BETWEEN AA AND ATP BY NMR * 150
10.2.5 STUDY OF THE WEAK INTERACTION BETWEEN AA AND ATP BY THEORETICAL
CALCULATION * 151
10.2.6 THE INTERACTION BETWEEN AA AND ATP* 154
11 MARINE AND THE ORIGIN OF LIFE* 157
11.1 THE ORIGIN OF LIFE * 157
11.2 THE ORIGIN OF MARINE LIFE * 158
11.2.1 THE THEORY OF THE ORIGIN OF MARINE LIFE * 158
11.2.2 SIMULATION OF CHEMICAL EVOLUTION OF MARINE LIFE * 159
11.3 PHOSPHATE OXYGEN ISOTOPE AS A BIOMARKER* 160
11.3.1 THE OXYGEN ISOTOPE FRACTIONATION BETWEEN WATER AND PHOSPHATE *
161
11.3.1.1 OXYGEN ISOTOPE FRACTIONATION BETWEEN WATER AND BIOTIC APATITE *
161
11.3.1.2 OXYGEN ISOTOPE FRACTIONATION BETWEEN WATER AND AUTHIGENIC
APATITE * 162
11.3.1.3 OXYGEN ISOTOPE FRACTIONATION BETWEEN WATER AND DISSOLVED
PHOSPHATE * 163
11.3.2 THE APPLICATION OF OXYGEN ISOTOPE COMPOSITION OF PHOSPHATE * 164
11.3.2.1 THE PRIMARY VALUE OF THE OXYGEN ISOTOPE COMPOSITION
OF PHOSPHATE * 164
11.3.2.2 THE REVIEW OF THE PHOSPHATE OXYGEN ISOTOPE BIOMARKER* 164
|
any_adam_object | 1 |
author | Zhao, Yufen Liu, Yan Gao, Xiang Xu, Pengxiang |
author_facet | Zhao, Yufen Liu, Yan Gao, Xiang Xu, Pengxiang |
author_role | aut aut aut aut |
author_sort | Zhao, Yufen |
author_variant | y z yz y l yl x g xg p x px |
building | Verbundindex |
bvnumber | BV045241612 |
classification_tum | CHE 815f CHE 885f |
ctrlnum | (OCoLC)1082321686 (DE-599)DNB1154611256 |
discipline | Chemie |
format | Book |
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id | DE-604.BV045241612 |
illustrated | Illustrated |
indexdate | 2024-07-10T08:12:33Z |
institution | BVB |
institution_GND | (DE-588)10095502-2 |
isbn | 9783110562378 3110562375 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-030629813 |
oclc_num | 1082321686 |
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owner | DE-91G DE-BY-TUM |
owner_facet | DE-91G DE-BY-TUM |
physical | XV, 166 Seiten Illustrationen, Diagramme 24 cm x 17 cm |
publishDate | 2019 |
publishDateSearch | 2019 |
publishDateSort | 2019 |
publisher | De Gruyter |
record_format | marc |
spelling | Zhao, Yufen Verfasser aut Phosphorus chemistry the role of phosphorus in prebiotic chemistry Yufen Zhao, Yan Liu, Xiang Gao, Pengxiang Xu 201811 Berlin ; Boston De Gruyter [2019] XV, 166 Seiten Illustrationen, Diagramme 24 cm x 17 cm txt rdacontent n rdamedia nc rdacarrier Phosphor (DE-588)4045855-6 gnd rswk-swf Chemische Evolution (DE-588)4147631-1 gnd rswk-swf Chemische Evolution (DE-588)4147631-1 s Phosphor (DE-588)4045855-6 s DE-604 Liu, Yan Verfasser aut Gao, Xiang Verfasser aut Xu, Pengxiang Verfasser aut Walter de Gruyter GmbH & Co. KG (DE-588)10095502-2 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-11-056255-2 Erscheint auch als Online-Ausgabe, EPUB 978-3-11-056245-3 X:MVB http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110562378&searchTitles=true X:MVB https://www.degruyter.com/doc/cover/9783110562378.jpg DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030629813&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Zhao, Yufen Liu, Yan Gao, Xiang Xu, Pengxiang Phosphorus chemistry the role of phosphorus in prebiotic chemistry Phosphor (DE-588)4045855-6 gnd Chemische Evolution (DE-588)4147631-1 gnd |
subject_GND | (DE-588)4045855-6 (DE-588)4147631-1 |
title | Phosphorus chemistry the role of phosphorus in prebiotic chemistry |
title_auth | Phosphorus chemistry the role of phosphorus in prebiotic chemistry |
title_exact_search | Phosphorus chemistry the role of phosphorus in prebiotic chemistry |
title_full | Phosphorus chemistry the role of phosphorus in prebiotic chemistry Yufen Zhao, Yan Liu, Xiang Gao, Pengxiang Xu |
title_fullStr | Phosphorus chemistry the role of phosphorus in prebiotic chemistry Yufen Zhao, Yan Liu, Xiang Gao, Pengxiang Xu |
title_full_unstemmed | Phosphorus chemistry the role of phosphorus in prebiotic chemistry Yufen Zhao, Yan Liu, Xiang Gao, Pengxiang Xu |
title_short | Phosphorus chemistry |
title_sort | phosphorus chemistry the role of phosphorus in prebiotic chemistry |
title_sub | the role of phosphorus in prebiotic chemistry |
topic | Phosphor (DE-588)4045855-6 gnd Chemische Evolution (DE-588)4147631-1 gnd |
topic_facet | Phosphor Chemische Evolution |
url | http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110562378&searchTitles=true https://www.degruyter.com/doc/cover/9783110562378.jpg http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030629813&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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