The theoretical basis of this book is developed ab ovo. This requires dealing with several problems arising in physical chemistry including the concept of entropy as a thermodynamic coordinate and its relation to probability. Thus Maxwell Boltzmann and Gibbs statistical thermodynamics, and quantum s...

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Bibliographic Details

Main Authors:	Koudriavtsev, Andrei (Author), Jameson, Reginald F. (Author), Linert, Wolfgang (Author)
Format:	Electronic eBook
Language:	English
Published:	Berlin, Heidelberg Springer Berlin Heidelberg 2001
Subjects:	Chemistry Physical Chemistry Appl.Mathematics/Computational Methods of Engineering Applications of Mathematics Thermodynamics Statistics for Engineering, Physics, Computer Science, Chemistry and Earth Sciences Physical chemistry Applied mathematics Engineering mathematics Statistics Massenwirkungsgesetz
Online Access:	UBT01 Volltext
Summary:	The theoretical basis of this book is developed ab ovo. This requires dealing with several problems arising in physical chemistry including the concept of entropy as a thermodynamic coordinate and its relation to probability. Thus Maxwell Boltzmann and Gibbs statistical thermodynamics, and quantum statistics are made considerable use of. A statistical mechanical derivation of the law of mass action for gases and solids is presented, and the problems arising in the application of the law of mass action to the liquid state are addressed. Molecular interactions and how to take them into account when deriving the law of mass action is discussed in some detail sketching a way alternativ to the use of activities. Finally, attention is drawn to the statistical mechanical background to Linear Free Energy Relationships (LFER's) and of Isokinetic Relationships (IKR's) and their connections with molecular interactions
Physical Description:	1 Online-Ressource (XIV, 328 p)
ISBN:	9783642567704
DOI:	10.1007/978-3-642-56770-4