Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers:
217 2. COPOLYMERIZATION OF PROPENE OR HIGHER I-ALKENES WITH 218 CARBON MONOXIDE 2. 1. Ligands and polymerization conditions 218 2. 2. Spiroketal formation 221 2. 3. Enantioselectivity 222 2. 4. Higher I-Alkenes 226 3. COPOLYMERIZATION OF STYRENE OR ITS DERIVATIVES WITH 226 CARBON MONOXIDE 4. COPOLYM...
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| Other Authors: | |
|---|---|
| Format: | Electronic eBook |
| Language: | English |
| Published: |
Boston, MA
Springer US
2003
|
| Series: | Catalysis by Metal Complexes
27 |
| Subjects: | |
| Online Access: | UBT01 Volltext |
| Summary: | 217 2. COPOLYMERIZATION OF PROPENE OR HIGHER I-ALKENES WITH 218 CARBON MONOXIDE 2. 1. Ligands and polymerization conditions 218 2. 2. Spiroketal formation 221 2. 3. Enantioselectivity 222 2. 4. Higher I-Alkenes 226 3. COPOLYMERIZATION OF STYRENE OR ITS DERIVATIVES WITH 226 CARBON MONOXIDE 4. COPOLYMERIZATION OF OTHER OLEANS WITH CARBON MONOXIDE 230 5. ASYMMETRIC TERPOLYMERIZATION OF MORE THAN Two KINDS OF 232 OLEFINS WITH CARBON MONOXIDE 6. POLYKETONE CONFORMATION 233 7. CONCLUSION 234 Chapter 8. Chain Propagation Mechanisms 237 Ayusman Sen 1. INTRODUCTION 237 2. PALLADIUM (II) BASED SYSTEMS 238 3. NICKEL (II) BASED SYSTEMS 256 4. RHODIUM (I) BASED SYSTEMS 257 5. CONCLUSION 261 Chapter 9. Theoretical Studies on Copolymerization of Polar Monomers 265 Peter Margl, Artur Michalak, and Tom Ziegler 1. INTRODUCTION 265 2. COPOLYMERIZATION OF CARBON MONOXIDE WITH ETHYLENE 267 2. 1. Experimental and calculated rates for the insertion processes for 267 copolymerization catalysed by Pd(II) systems. 2. 2. A more detailed look at the productive and unproductive cycles 270 in copolymerization catalysed by Pd(II) complexes. 2. 2. 1. The productive cycle 270 2. 2. 2. C2H4 misinsertion into an ethylene terminated polyketone 275 chain 2. 3. Experimental and calculated rates for the insertion processes for 277 alternating copolymerization catalyzed by Ni(II) systems 3. COPOLYMERIZATION OF OLEFINS WITH POLAR MONOMERS OTHER 280 THAN CO 3. 1. Preferred binding mode of oxygen containing monomers 282 3. 2. Preferred binding mode of nitrogen containing monomers 285 3. 3 |
| Physical Description: | 1 Online-Ressource (X, 325 p) |
| ISBN: | 9781441992666 |
| DOI: | 10.1007/978-1-4419-9266-6 |
Staff View
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| spelling | Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers edited by Ayusman Sen Boston, MA Springer US 2003 1 Online-Ressource (X, 325 p) txt rdacontent c rdamedia cr rdacarrier Catalysis by Metal Complexes 27 217 2. COPOLYMERIZATION OF PROPENE OR HIGHER I-ALKENES WITH 218 CARBON MONOXIDE 2. 1. Ligands and polymerization conditions 218 2. 2. Spiroketal formation 221 2. 3. Enantioselectivity 222 2. 4. Higher I-Alkenes 226 3. COPOLYMERIZATION OF STYRENE OR ITS DERIVATIVES WITH 226 CARBON MONOXIDE 4. COPOLYMERIZATION OF OTHER OLEANS WITH CARBON MONOXIDE 230 5. ASYMMETRIC TERPOLYMERIZATION OF MORE THAN Two KINDS OF 232 OLEFINS WITH CARBON MONOXIDE 6. POLYKETONE CONFORMATION 233 7. CONCLUSION 234 Chapter 8. Chain Propagation Mechanisms 237 Ayusman Sen 1. INTRODUCTION 237 2. PALLADIUM (II) BASED SYSTEMS 238 3. NICKEL (II) BASED SYSTEMS 256 4. RHODIUM (I) BASED SYSTEMS 257 5. CONCLUSION 261 Chapter 9. Theoretical Studies on Copolymerization of Polar Monomers 265 Peter Margl, Artur Michalak, and Tom Ziegler 1. INTRODUCTION 265 2. COPOLYMERIZATION OF CARBON MONOXIDE WITH ETHYLENE 267 2. 1. Experimental and calculated rates for the insertion processes for 267 copolymerization catalysed by Pd(II) systems. 2. 2. A more detailed look at the productive and unproductive cycles 270 in copolymerization catalysed by Pd(II) complexes. 2. 2. 1. The productive cycle 270 2. 2. 2. C2H4 misinsertion into an ethylene terminated polyketone 275 chain 2. 3. Experimental and calculated rates for the insertion processes for 277 alternating copolymerization catalyzed by Ni(II) systems 3. COPOLYMERIZATION OF OLEFINS WITH POLAR MONOMERS OTHER 280 THAN CO 3. 1. Preferred binding mode of oxygen containing monomers 282 3. 2. Preferred binding mode of nitrogen containing monomers 285 3. 3 Chemistry Organometallic Chemistry Catalysis Physical Chemistry Organic Chemistry Inorganic Chemistry Industrial Chemistry/Chemical Engineering Inorganic chemistry Organic chemistry Organometallic chemistry Physical chemistry Chemical engineering Sen, Ayusman edt Erscheint auch als Druck-Ausgabe 9781461348665 https://doi.org/10.1007/978-1-4419-9266-6 Verlag URL des Erstveröffentlichers Volltext |
| spellingShingle | Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers Chemistry Organometallic Chemistry Catalysis Physical Chemistry Organic Chemistry Inorganic Chemistry Industrial Chemistry/Chemical Engineering Inorganic chemistry Organic chemistry Organometallic chemistry Physical chemistry Chemical engineering |
| title | Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers |
| title_auth | Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers |
| title_exact_search | Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers |
| title_full | Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers edited by Ayusman Sen |
| title_fullStr | Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers edited by Ayusman Sen |
| title_full_unstemmed | Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers edited by Ayusman Sen |
| title_short | Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers |
| title_sort | catalytic synthesis of alkene carbon monoxide copolymers and cooligomers |
| topic | Chemistry Organometallic Chemistry Catalysis Physical Chemistry Organic Chemistry Inorganic Chemistry Industrial Chemistry/Chemical Engineering Inorganic chemistry Organic chemistry Organometallic chemistry Physical chemistry Chemical engineering |
| topic_facet | Chemistry Organometallic Chemistry Catalysis Physical Chemistry Organic Chemistry Inorganic Chemistry Industrial Chemistry/Chemical Engineering Inorganic chemistry Organic chemistry Organometallic chemistry Physical chemistry Chemical engineering |
| url | https://doi.org/10.1007/978-1-4419-9266-6 |
| work_keys_str_mv | AT senayusman catalyticsynthesisofalkenecarbonmonoxidecopolymersandcooligomers |