Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes:
hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propa...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Dordrecht
Springer Netherlands
2002
|
| Schriftenreihe: | Catalysis by Metal Complexes
21 |
| Schlagworte: | |
| Online-Zugang: | UBT01 Volltext |
| Zusammenfassung: | hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the "noble gases of organic chemistry" and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint |
| Beschreibung: | 1 Online-Ressource (XIV, 536 p) |
| ISBN: | 9780306469459 |
| DOI: | 10.1007/0-306-46945-6 |
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| 520 | |a hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the "noble gases of organic chemistry" and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint | ||
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Datensatz im Suchindex
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| discipline | Chemie / Pharmazie |
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| spelling | Shilov, Alexander E. Verfasser aut Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by Alexander E. Shilov, Georgiy B. Shul’pin Dordrecht Springer Netherlands 2002 1 Online-Ressource (XIV, 536 p) txt rdacontent c rdamedia cr rdacarrier Catalysis by Metal Complexes 21 hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the "noble gases of organic chemistry" and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint Chemistry Physical Chemistry Inorganic Chemistry Organic Chemistry Inorganic chemistry Organic chemistry Physical chemistry Alkane (DE-588)4191827-7 gnd rswk-swf Katalyse (DE-588)4029921-1 gnd rswk-swf Alkane (DE-588)4191827-7 s Katalyse (DE-588)4029921-1 s 1\p DE-604 Shul’pin, Georgiy B. aut Erscheint auch als Druck-Ausgabe 9780792361015 https://doi.org/10.1007/0-306-46945-6 Verlag URL des Erstveröffentlichers Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Shilov, Alexander E. Shul’pin, Georgiy B. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes Chemistry Physical Chemistry Inorganic Chemistry Organic Chemistry Inorganic chemistry Organic chemistry Physical chemistry Alkane (DE-588)4191827-7 gnd Katalyse (DE-588)4029921-1 gnd |
| subject_GND | (DE-588)4191827-7 (DE-588)4029921-1 |
| title | Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes |
| title_auth | Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes |
| title_exact_search | Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes |
| title_full | Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by Alexander E. Shilov, Georgiy B. Shul’pin |
| title_fullStr | Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by Alexander E. Shilov, Georgiy B. Shul’pin |
| title_full_unstemmed | Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by Alexander E. Shilov, Georgiy B. Shul’pin |
| title_short | Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes |
| title_sort | activation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes |
| topic | Chemistry Physical Chemistry Inorganic Chemistry Organic Chemistry Inorganic chemistry Organic chemistry Physical chemistry Alkane (DE-588)4191827-7 gnd Katalyse (DE-588)4029921-1 gnd |
| topic_facet | Chemistry Physical Chemistry Inorganic Chemistry Organic Chemistry Inorganic chemistry Organic chemistry Physical chemistry Alkane Katalyse |
| url | https://doi.org/10.1007/0-306-46945-6 |
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