Magnesium: from resources to production
Magnesium is one of the most abundant minerals in seawater. Extracting Mg from seawater could reduce cost of this mineral, resulting in positive implications for industries that use it. This book addresses mineral process engineering with emphasis on Mg and provides practicing engineers and students...
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Boca Raton, FL
CRC Press/Taylor & Francis Group
2019
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis Inhaltsverzeichnis Klappentext |
| Summary: | Magnesium is one of the most abundant minerals in seawater. Extracting Mg from seawater could reduce cost of this mineral, resulting in positive implications for industries that use it. This book addresses mineral process engineering with emphasis on Mg and provides practicing engineers and students with comprehensive knowledge on Mg and how it is extracted from seawater. The book takes a chemical engineering approach as separation of Mg from seawater involves the application of the powerful science of chemistry and transport phenomena principles. It presents a newly proposed process, preferential salt separation (PSS), for producing MgCl2 from seawater... |
| Item Description: | "A CRC title, part of the Taylor & Francis imprint, a member of the Taylor & Francis Group, the academic division of T&F Informa plc.". - Includes bibliographical references |
| Physical Description: | XIII, 128 Seiten Illustrationen, Diagramme |
| ISBN: | 9780815346333 9780367657192 |
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| adam_text | MAGNESIUM
/ ABDEL-AAL, HUSSEIN K.YYEAUTHOR
: 2018
TABLE OF CONTENTS / INHALTSVERZEICHNIS
OCCURRENCE & RESOURCES OF MAGNESIUM
MAGNESIUM AND MINERAL SALTS FROM SEAWATER : EXPLORATION STUDY
PRODUCTION OF MAGNESIUM CHLORIDE : AN OVERVIEW
PRODUCTION OF MAGNESIUM CHLORIDE FROM SEAWATER : PROPOSED METHOD :
PREFERENTIAL SALT SEPARATION (PSS)
COMMERCIAL METHODS FOR MAGNESIUM PRODUCTION
CURRENT APPLICATIONS OF MAGNESIUM AND PROSPECTIVE ONES IN THE FIELD OF
ENERGY DOMAIN
MAGNESIUM : A POTENTIAL HYDROGEN STORAGE MEDIUM
DIESES SCHRIFTSTUECK WURDE MASCHINELL ERZEUGT.
Contents
Preface...........................................................ix
Acknowledgments................................................. xi
Author...........................................................xiii
1. Introduction...................................................1
1.1 Introduction..............................................1
1.2 Resources of Magnesium....................................2
1.3 How to Obtain Magnesium?................................ 3
1.4 The Establishment of the International Society for the
Development of Research on Magnesium......................5
1.5 Minerals Cycle............................................6
1.6 The Motivation for Writing a Book on Magnesium............7
2. Occurrence and Resources of Magnesium..........................9
2.1 Background................................................9
2.2 Occurrence............................................. 10
2.3 Sources of Magnesium.....................................10
2.3.1 Magnesite.........................................13
2.3.2 Mining and Extraction.............................15
2.4 Magnesium Resources World Wide...........................16
2.4.1 Australian Resources, Deposits, and Processing....16
2.4.2 Magnesium Resources in China.................... 18
2.5 Primary Magnesium Production.............................18
2.6 Extraction is a Key Process............................19
3. Magnesium and Mineral Salts from Seawater: Exploration Study..23
3.1 Introduction.............................................23
3.2 Principal Mineral Resources..............................24
3.2.1 Historical Background.............................24
3.2.2 Minerals Extracted................................25
3.3 Minerals in Sea Salt.....................................26
3.4 Evaporation and Separation Sequence of Salts.............29
3.5 Theory of Evaporating Seawater and Precipitating Salts...33
3.5.1 Ocean Water Profile...............................33
3.5.2 Deep Sea Resources................................34
3.5.3 Evaporating Seawater..............................34
3.6 Economic Feasibility of Mineral Salts Recovery...........36
vi
Contents
4. Production of Magnesium Chloride: An Overview...................39
4.1 Introduction.............................................39
4.2 Magnesium Chloride from Seawater.........................40
4.2.1 Dow Process........................................40
4.2.2 Extraction from Dolomite and Magnesite Ores........41
4.3 MgCl2 Extraction from Desalination Plants...............41
4.4 Dual-Purpose Solvay-Dow: Conceptual Process..............42
4.5 Modified Desalination Scheme.............................42
4.5.1 Introduction.......................................42
4.5.2 Concentrate Management.............................43
4.5.3 Objective..........................................43
4.5.4 The Road Map to Our Proposed Multipurpose
Desalination Scheme................................44
4.5.5 Solar Evaporation Unit (Brine Concentration).......45
4.5.6 Chemical Conversion Unit...........................45
4.5.7 Auxiliary Units....................................45
4.5.8 Case Study: Process Analysis and Material Balance
Calculations..................................... 46
4.6 Seawater Bitterns........................................51
5. Production of Magnesium Chloride from Seawater: Proposed
Method-Preferential Salt Separation.............................53
5.1 Introduction.............................................53
5.2 Preferential Salt Separation.............................53
5.2.1 Background.........................................53
5.2.2 Experimental Work..................................54
5.2.3 Additional Experimental Work.................... 55
5.3 Experimental Results Using Preferential Salt
Separation— Dynamic-Flow .................................56
5.4 Preferential Salt Separation— Static-Flow or Batch Model.57
5.4.1 Experimental Results...............................57
5.5 Proposed Small-Scale Integrated Pilot Model..............57
5.6 Mathematical Model for the Evaporation of Seawater along
the Preferential Salt Separation: Flow of a Falling Film
across an Inclined Flat Surface...........................59
5.6.1 Introduction.......................................59
5.6.2 Theoretical Background.............................59
5.6.3 Results............................................60
5.7 Proposals for Other Separation Options: Separation of
Magnesium Chloride from Sodium Chloride in Seawater by
the Dense-Phase Technique.................................63
Contents vii
6. Commercial Methods for Magnesium Production...................65
6.1 Introduction/Classification............................ 65
6.2 Electrolytic Processes...................................67
6.2.1 Outline of Process Techniques.....................67
6.2.2 Fundamentals......................................68
6.2.3 Electrolysis of Magnesium Chloride................69
6.2.4 Types of Electrolytic Cells.......................70
6.2.5 Dow Process..................................... 71
6.2.6 Production of Magnesium Chloride from
Magnesium Oxide...................................72
6.3 Thermal Reduction Process................................73
6.4 Magnesium Processes for Tomorrow.........................76
6.4.1 First: Electrolytic Processes.....................76
6.4.1.1 Process 1—Pacific Northwest National
Laboratory................................76
6.4.1.2 Process 2—Solid Oxide Membrane
Technology (MgO)..........................77
6.4.1.3 Process 3—Norsk Hydro Process.............78
6.4.1.4 Process 4—Dow Modified Cell...............79
6.4.1.5 Process 5—Dead Sea Magnesium..............79
6.4.2 Second: Thermal Processes.........................79
6.5 Magnesium Recycling......................................80
6.6 Annual Production of Magnesium...........................80
7. Current Applications of Magnesium and Prospective Ones in
the Field of Energy Domain....................................83
7.1 Introduction........................................... 83
7.2 Current Applications of Magnesium........................84
7.3 Magnesium Alloys.........................................84
7.4 Mechanical Applications for Magnesium....................85
7.5 Other Applications.......................................87
7.6 Magnesium as Energy Carrier..............................88
7.6.1 Background........................................88
7.6.2 Process Description for Magnesium as Energy Carrier... 88
7.6.3 Design Features of the Proposed Energy System.....88
7.6.4 Process Description for Recycling Magnesium.......89
7.7 Magnesium as an Alternative Power Source.................91
7.8 Magnesium and Global Warming.............................94
7.9 Oil versus Magnesium: Hunting for Oil and Gas or Looking
for Magnesium?...........................................95
7.9.1 Background...................................... 95
7.9.2 Analysis and Discussion...........................96
viii Contents
8. Magnesium: A Potential Hydrogen Storage Medium...........97
8.1 Introduction...........................*............97
8.2 Storage of Hydrogen............................... 98
8.2.1 Background....................................98
8.2.2 Onboard Storage of Hydrogen..................100
8.3 Developments in the Storage Medium.................102
8.4 The Problems of Using Hydrides as a Source of Fuel for
Vehicles..................................... 102
8.5 Mechanism of Hydrides Formation....................103
8.6 Preparation of Magnesium Hydride....................104
8.7 Nanostructured Magnesium Hydrides................ 105
8.8 Preparation of High-Purity Magnesium Hydride by the
Second Hydrogenation Method........................105
8.9 Renewable Hydrogen-Magnesium Proposal............ 106
Appendix A: Magnesium Facts and Uses...................... 109
Appendix B: Common Compounds of Magnesium and
Magnesium Ores.............................. 115
Appendix C: A Letter about PSS..............................117
Bibliography............................................... 119
Index..................................................... 125
Magnesium
From Resources to Production
Magnesium is one of the most abundant minerals in seawater. Extracting magnesium from
seawater could reduce cost of this mineral, resulting in positive implications for industries
that use it. This book addresses mineral process engineering with emphasis on magnesium
and provides practicing engineers and students with comprehensive knowledge on mag-
nesium and how it is extracted from seawater and magnesium ores. It takes a chemical
engineering approach as separation of magnesium from seawater involves the application
of the powerful science of chemistry and transport phenomena principles. This monograph
discusses magnesium resources and occurrence, includes an exploration study on de-
riving magnesium and mineral salts from seawater, and features coverage of magnesium
chloride. It also covers commercial methods for magnesium production as an end product,
current and prospective applications in the energy domain, and offers an account of the
use of magnesium to store hydrogen in the form of magnesium hydride.
• Discusses in depth the subject of recovering magnesium in the form of
MgCL from seawater
• Offers theoretical background, presents a new topic on evaporating of
seawater and precipitating salts, and the order of their separation
• Explains in simple terms the basic steps underlying the separation of
MgCL to get magnesium metal
• Discusses technology of producing magnesium
• Presents a newly proposed approach, preferential salt separation (PSS),
for producing MgCL from seawater
• Emphasizes transport phenomena principles
• Compiles facts about and uses for magnesium in an appendix
|
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| indexdate | 2024-07-10T08:08:51Z |
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| spelling | Abdel-Aal, Hussein K. (DE-588)1168743192 aut Magnesium from resources to production Hussein K. Abdel-Aal Boca Raton, FL CRC Press/Taylor & Francis Group 2019 XIII, 128 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier "A CRC title, part of the Taylor & Francis imprint, a member of the Taylor & Francis Group, the academic division of T&F Informa plc.". - Includes bibliographical references Magnesium is one of the most abundant minerals in seawater. Extracting Mg from seawater could reduce cost of this mineral, resulting in positive implications for industries that use it. This book addresses mineral process engineering with emphasis on Mg and provides practicing engineers and students with comprehensive knowledge on Mg and how it is extracted from seawater. The book takes a chemical engineering approach as separation of Mg from seawater involves the application of the powerful science of chemistry and transport phenomena principles. It presents a newly proposed process, preferential salt separation (PSS), for producing MgCl2 from seawater... Magnesium Technologie (DE-588)4059276-5 gnd rswk-swf Magnesium (DE-588)4128915-8 gnd rswk-swf Magnesium (DE-588)4128915-8 s Technologie (DE-588)4059276-5 s DE-604 LoC Fremddatenuebernahme application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030497764&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Augsburg - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030497764&sequence=000005&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Augsburg - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030497764&sequence=000006&line_number=0003&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Abdel-Aal, Hussein K. Magnesium from resources to production Magnesium Technologie (DE-588)4059276-5 gnd Magnesium (DE-588)4128915-8 gnd |
| subject_GND | (DE-588)4059276-5 (DE-588)4128915-8 |
| title | Magnesium from resources to production |
| title_auth | Magnesium from resources to production |
| title_exact_search | Magnesium from resources to production |
| title_full | Magnesium from resources to production Hussein K. Abdel-Aal |
| title_fullStr | Magnesium from resources to production Hussein K. Abdel-Aal |
| title_full_unstemmed | Magnesium from resources to production Hussein K. Abdel-Aal |
| title_short | Magnesium |
| title_sort | magnesium from resources to production |
| title_sub | from resources to production |
| topic | Magnesium Technologie (DE-588)4059276-5 gnd Magnesium (DE-588)4128915-8 gnd |
| topic_facet | Magnesium Technologie |
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