Verfügbarkeit: Surface-supported molecular architectures of bridged triphenylamines

Surface-supported molecular architectures of bridged triphenylamines:

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Bibliographische Detailangaben
1. Verfasser:	Steiner, Christian (VerfasserIn)
Format:	Abschlussarbeit Buch
Sprache:	English
Veröffentlicht:	Erlangen ; Nürnberg Friedrich-Alexander-Universität Erlangen-Nürnberg 2017
Schlagworte:	Überbrückte Verbindungen Triphenylaminderivate Molekülstruktur Hochschulschrift
Online-Zugang:	Inhaltsverzeichnis Inhaltsverzeichnis
Beschreibung:	XVI, 158, ii Seiten Illustrationen, Diagramme 21 cm

Internformat

MARC


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Datensatz im Suchindex

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adam_text	CONTENTS 1 ABSTRACT XIII 2 MOTIVATION 1 3 INTRODUCTION 5 3.1 MOLECULES ON SURFACES: AN O V E RV IE W .............................................................. 5 3.1.1 MOLECULAR SELF-ASSEMBLY....................................................................... 5 3.1.2 MOLECULE-MOLECULE INTERACTIONS ...................................................... 6 3.1.3 MOLECULE-SUBSTRATE INTERACTIONS .......................................................... 8 3.1.4 ON-SURFACE REACTIONS............................................................................. 9 3.2 EXPERIMENTAL METHODS: BASICS OF SCANNING PROBE M ICROSCOPY................... 10 3.2.1 SCANNING TUNNELING MICROSCOPY AND SPECTROSCOPY ............................. 10 3.2.2 NON-CONTACT ATOMIC FORCE M ICROSCOPY .............................................. 14 3.2.3 MEASUREMENT SETUP AND M O D I.............................................................. 17 3.3 EXPERIMENTAL S ETU P ............................................................................ 19 3.3.1 SCANNING PROBE MICROSCOPE AND ULTRA-HIGH VACUUM SYSTEM .... 19 3.3.2 CALIBRATION OF THE S E T U P ....................................................................... 21 3.3.3 SAMPLE PREPARATION AND MEASUREMENTS .............................................. 23 3.3.4 TRIANGULENES AS TRIPHENYLAMINE DERIVATIVES ...................................... 24 4 SELF-ASSEMBLY AND STABILITY OF BRIDGED TRIPHENYLAMINES ON METALS 27 4.1 INTRODUCTION........................................................................................................ 27 4.2 POROUS DTPA NETWORKS ON A U ( L L L ) ................................................................ 29 4.3 THERMAL STABILITY OF CDTPA MOLECULES ON A U ( L L L ) ...................................... 35 4.4 CDTPA AND ADTPA ON C U (LLL): EFFECTS OF A STRONG MOLECULE-SUBSTRATE INTERACTION........................................................................................................... 36 4.5 D ISCUSSION........................................................................................................... 45 4.6 C ONCLUSIONS........................................................................................................ 47 5 SELF-ASSEMBLY OF A BIMOLECULAR NETWORK ON A U (LLL) 49 5.1 INTRODUCTION........................................................................................................ 49 5.2 FORMATION OF A REGULAR BIMOLECULAR NETWORK CONSISTING OF ADTPA AND C D T P A ............................................................................................................... 51 5.3 IMPACT OF THE BIMOLECULAR SELF-ASSEMBLY ON THE MOLECULAR ORBITALS OF ADTPA AND C D T P A ......................................................................................... 57 5.4 D ISCUSSION........................................................................................................... 62 5.5 C ONCLUSIONS........................................................................................................ 65 6 FROM SELF-ASSEMBLED TO COVALENTLY LINKED NETWORKS 67 6.1 INTRODUCTION........................................................................................................ 67 6.2 SELF-ASSEMBLY OF HALOGENATED C T P A ............................................................. 69 6.3 ON-SURFACE SYNTHESIS OF 2D NANOSTRUCTURES ................................................. 6.4 ADVANTAGES AND LIMITS OF THE HIERARCHICAL SYNTHESIS BASED ON ULLMANN- TYPE COUPLING ................................................................................................ 6.4.1 ON-SURFACE SYNTHESIS OF MACROCYCLES AND C HAINS............................ 6.4.2 THE HIERARCHICAL SYNTHESIS................................................................. 6.4.3 PREPARATION CONDITIONS OF THE NETWORK F ORM ATION......................... 6.4.4 THE HIERARCHICAL APPROACH BEYOND ULLMANN-TYPE COUPLING .... 6.5 FUNCTIONALIZED P O R E S ...................................................................................... 6.6 D ISCUSSION......................................................................................................... 6.7 C ONCLUSIONS...................................................................................................... 7 ELECTRONIC PROPERTIES OF OD, ID AND 2D TPA-BASED NANO-ARCHITECTURES 7.1 INTRODUCTION...................................................................................................... 7.2 MOLECULAR ORBITALS OF THE CTPA BUILDING B LO C K ........................................ 7.3 BAND GAPS OF ID AND 2D P OLY M ERS.............................................................. 7.4 ELECTRONIC PROPERTIES OF SELF-ASSEMBLED C HAINS ........................................... 7.5 D ISCUSSION......................................................................................................... 7.6 C ONCLUSIONS...................................................................................................... 8 STRUCTURE FORMATION OF TRIPHENYLAMINES ON A KBR BULK INSULATOR 8.1 INTRODUCTION...................................................................................................... 8.2 3D GROWTH OF AMINO-CTPA NANO-CRYSTALLITES ........................................... 8.3 ID GROWTH OF HALOGEN-CTPA TT - TT STACKED C H A IN S ..................................... 8.4 2D GROWTH OF FILMS OF FLAT-LYING A D T P A ................................................. 8.5 SELF-ASSEMBLY OF CDTPA ON KBR( 0 0 1 ) ....................................................... 8.6 INSIGHTS FROM DENSITY FUNCTIONAL THEORY CALCULATIONS............................... 8.7 D ISCUSSION......................................................................................................... 8.8 CONCLUSIONS...................................................................................................... 9 SUMMARY 10 BIBLIOGRAPHY 11 ACKNOWLEDGEMENTS A ADDITIONAL MEASUREMENTS A.L SELF-ASSEMBLY OF HALOGENATED CTPA ON A U ( L L L ) ........................................ 73 74 76 80 82 87 89 90 92 95 95 97 97 102 106 108 109 109 111 116 120 125 128 129 131 133 137 157
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author	Steiner, Christian
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discipline	Biologie
format	Thesis Book
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spelling	Steiner, Christian Verfasser aut Surface-supported molecular architectures of bridged triphenylamines vorgelegt von Christian Steiner Erlangen ; Nürnberg Friedrich-Alexander-Universität Erlangen-Nürnberg 2017 XVI, 158, ii Seiten Illustrationen, Diagramme 21 cm txt rdacontent n rdamedia nc rdacarrier Dissertation Friedrich-Alexander-Universität Erlangen-Nürnberg 2017 Überbrückte Verbindungen (DE-588)4186549-2 gnd rswk-swf Triphenylaminderivate (DE-588)4378417-3 gnd rswk-swf Molekülstruktur (DE-588)4170383-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Triphenylaminderivate (DE-588)4378417-3 s Überbrückte Verbindungen (DE-588)4186549-2 s Molekülstruktur (DE-588)4170383-2 s DE-604 B:DE-101 application/pdf http://d-nb.info/1161557571/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030481549&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Steiner, Christian Surface-supported molecular architectures of bridged triphenylamines Überbrückte Verbindungen (DE-588)4186549-2 gnd Triphenylaminderivate (DE-588)4378417-3 gnd Molekülstruktur (DE-588)4170383-2 gnd
subject_GND	(DE-588)4186549-2 (DE-588)4378417-3 (DE-588)4170383-2 (DE-588)4113937-9
title	Surface-supported molecular architectures of bridged triphenylamines
title_auth	Surface-supported molecular architectures of bridged triphenylamines
title_exact_search	Surface-supported molecular architectures of bridged triphenylamines
title_full	Surface-supported molecular architectures of bridged triphenylamines vorgelegt von Christian Steiner
title_fullStr	Surface-supported molecular architectures of bridged triphenylamines vorgelegt von Christian Steiner
title_full_unstemmed	Surface-supported molecular architectures of bridged triphenylamines vorgelegt von Christian Steiner
title_short	Surface-supported molecular architectures of bridged triphenylamines
title_sort	surface supported molecular architectures of bridged triphenylamines
topic	Überbrückte Verbindungen (DE-588)4186549-2 gnd Triphenylaminderivate (DE-588)4378417-3 gnd Molekülstruktur (DE-588)4170383-2 gnd
topic_facet	Überbrückte Verbindungen Triphenylaminderivate Molekülstruktur Hochschulschrift
url	http://d-nb.info/1161557571/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030481549&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT steinerchristian surfacesupportedmoleculararchitecturesofbridgedtriphenylamines

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