Foundations of inorganic chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Mill Valley, California
University Science Books
[2018]
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext http://www.springer.com Inhaltsverzeichnis |
| Beschreibung: | xxiii, 739, 46 Seiten Illustrationen, Diagramme 23.5 cm x 15.5 cm |
| ISBN: | 1891389955 9781891389955 |
Internformat
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Datensatz im Suchindex
| _version_ | 1806414484026163200 |
|---|---|
| adam_text |
CONTENTS
Preface xix
CHAPTER 1
Periodic Trends in Fundamental
Properties of Atoms and Simple Ions 1
1 1 The Connections of Inorganic Chemistry
to Other Fields of Chemical Science 1
1 2 The Periodic Table and Ions of the Elements 2
1 3 Core and Valence Electrons; Characteristic
Valence Electron Configurations of Atoms
and Ions 14
1 4 Identifying “Ions” in Chemical Formulas;
Assigning Oxidation Numbers 21
1 5 Types of Atomic Radii and Their Periodic
Trends 25
1 6 Periodic Trends in Pauling Electronegativities
of Atoms 33
1 7 Background Reading for Chapter 1 35
1 8 Exercises 36
CHAPTER 2
Monatomic Ions and Their
Acid-Base Reactivity 43
Overview of the Chapter 43
2 1 Acidity of Cations 44
2 2 Predicting the Acidity Classifications
of Cations 49
2 3 Explaining the Acidic Tendencies of Cations:
Why Halides of Some Cations Fail to React 53
2 4 Predominance Diagrams and Nonmetal Hydrides
as Acids 60
2 5 Predominance Diagrams and the Precipitation
of Metal Cations as Oxides or Hydroxides 65
2 6 Monatomic Anions as Bases 69
2 7 Background Reading for Chapter 2 76
2 8 Exercises 76
CHAPTER 3
Polyatomic Ions: Their Structures and
Acid-Base Properties 87
Overview of the Chapter 87
3 1 Drawing Lewis Structures (Review);
Homopolyatomic Anions 87
3 2 The Lewis Acid-Base Concept and
Complex Ions 95
3 3 Orbital Shapes, Covalent Bond Types, and
the Periodicity of Bond Energies 103
3 4 Lewis Structures, Maximum Total Coordination
Numbers, and Fluoro Anions 118
3 5 The Formulas of Oxo Anions 123
3 6 The Basicity of Oxo Anions 129
ix
X CONTENTS
3 7 Predominance Diagrams for Oxo Anions and
Oxo Acids 134
3 8 Most Common Forms of the Elements in
Natural Waters 142
3 9 Nomenclature of Oxo Anions and Acids 148
3 10 Background Reading for Chapter 3 152
3 11 Exercises 152
CHAPTER 4
Ionic Compounds in the Solid State,
in Minerals, and in Solution 165
Overview of the Chapter 165
4 1 Ionic Lattice Types and Radius Ratios 166
4 2 Ionic Solids: Coulombic Attractions and
Lattice Energies 177
4 3 Solubility Rules and Tendencies I—IV for
Salts of Oxo and Fluoro Anions: Their
Geochemical Consequences 183
4 4 The Contrasting Effects of Lattice and
Hydration Energies on Salt Solubilities 192
4 5 The Role of Entropy Changes in Precipitation
Reactions 199
4 6 Background Reading for Chapter 4 206
4 7 Exercises 206
CHAPTER 5
Trends in Coordination Equilibria 213
5 1 Structural Analysis of Ligands:
Monodentate and Chelating Ligands 214
5 2 Coordination by Macrocyclic Ligands 227
5 3 Bridging Ligands and Metal-Organic
Framework Compounds 234
5 4 The Hard and Soft Acid-Base
Principle 242
5 5 Bonding Principles Behind the
HSAB Principle and Polar Covalent
Bonding 254
5 6 HSAB and the Solubilities of Halides and
Chalcogenides 258
5 7 HSAB and the Biological Functions and
Toxicology of the Elements 264
5 8 Medicinal Inorganic Chemistry 273
5 9 Background Reading for Chapter 5 281
5 10 Exercises 282
CHAPTER 6
Principles of Oxidation-Reduction
Reactivity 297
6 1 Standard Reduction Potentials and Their
Diagrammatic Representation 299
6 2 Activity Series of Metals, Nonmetals, and Oxo
Anions/Acids 314
6 3 Explosions and Safety in the Laboratory 326
6 4 Effects of Precipitation, Complexation, and
Softness on Oxidizing and Reducing Ability 337
6 5 Effects of pH on Redox Chemistry:
Pourbaix Diagrams 343
6 6 Thermochemical Analysis of Redox
Reactions 359
6 7 Background Reading for Chapter 6 371
6 8 Exercises 372
CHAPTER 7
Introduction to Transition Metal
Complexes 385
7 1 Crystal Field Theory 386
7 2 High-Spin and Low-Spin Electron
Configurations: Magnetic Properties
of Metal Ions 391
7 3 Electronic Absorption Spectra of d-Block and
/-Block Complex Ions 397
7 4 The Spectrochemical Series of Ligands and the
Effects of Covalency 402
7 5 Thermodynamic and Structural Consequences of
Crystal Field Effects 408
7 6 Crystal Field Splitting in Complexes of Other
Geometries 414
7 7 Geometric Preferences; Rates and Mechanisms
of Ligand Exchange 423
7 8 Heme and Hemoglobin: A Connection to
Biochemistry 428
7 9 Background Reading for Chapter 7 432
7 10 Exercises 432
CHAPTER 8
Oxides and Silicates as Materials 445
8 1 Materials and Their Physical Properties 446
8 2 The Structure Types and Physical Properties of
the Oxides of the Elements 453
CONTENTS Xi
8 3 Close Packing of Anions: Isomorphous
Substitution in Mixed-Metal Oxides 463
8 4 Ferromagnetic, Antiferromagnetic, and
Superconducting Solid Ionic Oxides 476
8 5 Acidity, Solubility, and Atmospheric
Chemistry of Oxides 482
8 6 Polysilicates: Basic Structural Types, Uses,
and Chemistry 493
8 7 Aluminosilicates 505
8 8 Background Reading for Chapter 8 514
8 9 Exercises 515
CHAPTER 9
The Underlying Reasons for
Periodic Trends 527
9 1 Quantum Mechanics: Wave and Particle
Properties of Electrons 527
9 2 Shielding, Slater's Rules, and Core and
Valence Electrons 537
9 3 Periodic Trends in Ionization Energies and
Electron Affinities 546
9 4 Calculations of Atomic Radii and Reasons
for Their Periodic Trends 550
9 5 Periodic Trends in Electronegativities
of Atoms: Explanation and Theoretical
Prediction 558
9 6 Relativistic Effects on Orbitals 562
9 7 Background Reading for Chapter 9 568
9 8 Exercises 568
CHAPTER 10
Symmetry 577
10 1 Symmetry Operations and Elements 579
10 2 Molecular Point Groups, Polarity, and
Chirality 585
10 3 Character Tables for Symmetry Point
Groups 593
10 4 Symmetry Labels for Bonding and
Antibonding Orbitals in Diatomic
Molecules 599
10 5 Background Reading for Chapter 10 603
10 6 Exercises 604
CHAPTER 11
Molecular Orbital Theory: A Bridge
Between Foundational and Advanced
Inorganic Chemistry 611
Overview of the Chapter 611
11 1 Molecular Orbital Theory for Homonuclear
Diatomic Molecules 612
11 2 Orbital Mixing in Homonuclear Diatomic
Molecules: Bond Energies and Bond
Lengths 621
11 3 Electronic Spectroscopy and Molecular
Orbital Theory 626
11 4 Heteroatomic Diatomic Molecules and Ions 633
11 5 Molecular Orbitals for Selected Two- and
Three-Dimensional High-Symmetry (Dnh, Td,
and Oh) Complexes and Molecules 640
11 6 d-Block Organometallic Compounds:
The Role of a-Donor, n- Donor, and n-Acceptor
Ligands 649
11 7 Background Reading for Chapter 11 666
11 8 Exercises 666
CHAPTER 12
The Elements as Molecules and
Materials 679
12 1 Elemental Substances: Structures and
Physical Properties 680
12 2 Molecular Orbital Theory and Conductivity
Properties of Linear Oligomers and Polymers
of Elements 689
12 3 Allotropes of the Nonmetals 700
12 4 Metals and Alloys 710
12 5 Inorganic Materials That Are Structurally
Related to Carbon Allotropes 722
12 6 Summary Overview of Relationships Among
Ionic, Covalent, and Metallic Structures
and Bonding 728
12 7 Background Reading for Chapter 12 730
12 8 Exercises 731
Appendix: Answers to Odd-Numbered
Exercises A-1
Photo and Figure Credits C-1 |
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| spellingShingle | Wulfsberg, Gary 1944- Foundations of inorganic chemistry Anorganische Chemie (DE-588)4002145-2 gnd Säure-Base-Gleichgewicht (DE-588)4051270-8 gnd Chemie (DE-588)4009816-3 gnd |
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| title | Foundations of inorganic chemistry |
| title_auth | Foundations of inorganic chemistry |
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| title_full | Foundations of inorganic chemistry Gary Wulfsberg (Middle Tennessee State University) |
| title_fullStr | Foundations of inorganic chemistry Gary Wulfsberg (Middle Tennessee State University) |
| title_full_unstemmed | Foundations of inorganic chemistry Gary Wulfsberg (Middle Tennessee State University) |
| title_short | Foundations of inorganic chemistry |
| title_sort | foundations of inorganic chemistry |
| topic | Anorganische Chemie (DE-588)4002145-2 gnd Säure-Base-Gleichgewicht (DE-588)4051270-8 gnd Chemie (DE-588)4009816-3 gnd |
| topic_facet | Anorganische Chemie Säure-Base-Gleichgewicht Chemie |
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