Ellipsometry of functional organic surfaces and films:
Gespeichert in:
| Weitere Verfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cham, Switzerland
Springer
[2018]
|
| Ausgabe: | Second edition |
| Schriftenreihe: | Springer series in surface sciences
v. 52 |
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | xxvi, 547 Seiten Diagramme |
| ISBN: | 9783319758947 |
Internformat
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| 653 | |a Biomolecules at Surfaces | ||
| 653 | |a Characterization of Organic Semiconductors | ||
| 653 | |a Ellipsometric Real-time/In-situ Monitoring Techniques | ||
| 653 | |a Functional and Smart Films | ||
| 653 | |a Infrared Brillant Light Sources for Micro-ellipsometric Studies | ||
| 653 | |a OLEDs and OTFT | ||
| 653 | |a Optical Constants of Organic Layers | ||
| 653 | |a Organic and Hybrid Materials | ||
| 653 | |a Smart Polymer Surfaces and Films | ||
| 653 | |a In-Situ Monitoring Techniques | ||
| 653 | |a Microscopic and imaging ellipsometry | ||
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Datensatz im Suchindex
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|---|---|
| adam_text | Contents
1 Ellipsometry: A Survey of Concept
Christoph Cobet
1 1 Classification
1 2 Historical Context
1 3 Measurement Principles
131 Data Recording and Evaluation Steps
132 Determination of W and A
133 Fresnel Coefficients
1 4 Dielectric Properties
141 Dispersion Models—Lorentz Oscillator
142 Inhomogeneous Media and Structured Interfaces
1 5 Ellipsometric Configurations
151 Null-Ellipsometer
152 Rotating Polarizer/Analyzer
153 Rotating Compensator
154 Photo-Elastic Modulator Ellipsometer
155 Dual Rotating Compensator
156 Reflection Anisotropy Spectroscopy
References
Part I Biomolecules at Surfaces
2 Adsorption of Proteins at Solid Surfaces
Hans Arwin
2 1 Introduction
211 Historical Background
212 Opportunities and Challenges
213 Objectives and Outline
2 2 Methodology—Experimental Aspects
1
1
4
5
5
8
13
19
19
21
22
23
23
23
24
24
25
25
31
31
31
32
33
34
IX
X
Contents
2 3 Methodology—Modeling Aspects 35
231 Strategies to Determine Both Thickness
and Refractive Index 35
232 Spectral Representations of Protein Layers 38
233 Determination of Surface Mass Density 38
2 4 Applications 39
241 Protein Adsorption and Dynamics on Model
Surfaces 39
242 Studies of Protein Layer Structure 39
243 Protein Layer Based Biosensing 43
244 Other Applications 46
2 5 Outlook 46
References 47
3 DNA Structures on Silicon and Diamond 49
Simona D Pop, Karsten Hinrichs, Sylvia Wenmackers,
Christoph Cobet, Norbert Esser and Dietrich R T Zahn
3 1 Introduction 49
3 2 Dielectric Function 51
3 3 Applications to Thin Biomolecular Films 54
331 Single DNA Bases 54
332 Single- and Double-Stranded DNA Molecules 56
3 4 Summary 60
References 61
4 Thickness and Beyond Exploiting Spectroscopic Ellipsometry
and Atomic Force Nanolithography for the Investigation
of Ultrathin Interfaces of Biologic Interest 63
Pietro Parisse, Ilaria Solano, Michele Magnozzi, Francesco Bisio,
Loredana Casalis, Omella Cavalieri and Maurizio Canepa
4 1 Introduction 64
4 2 Optical Ellipsometry of Ultrathin Interfaces: Difference
Spectra 66
4 3 Atomic Force Nanolithography: Notes on Principles
and Application 76
4 4 Application of SE and Atomic Force Lithography Methods
to Ultrathin Soft Matter Films: Case Studies 79
441 Bio-Inert SAMs: Nanoshaving 79
442 Specific Immobilisation of Proteins on SAMs:
Grafting 84
4 5 Outlook 87
References 89
»tents
xi
Part II Smart Polymer Surfaces and Films
5 Glass Transition of Polymers with Different Architectures
in the Confinement of Nanoscopic Films
Michael Erber, Martin Tress, Eva Bittrich, Lars Bittrich
and Klaus-Jochen Eichhorn
Polymers: A Unique Class of Materials and Their Physical
Properties
Nanoscopic Polymer Films versus Bulk Polymers
521 Introduction
522 True or Mimicked Confinement Effects
523 Make a Long Controversial Story Short:
Conclusion
Comparison of Analytical Methods for the Determination
of Glass Transition of Polymers in Thin Polymer Films
531 Introduction
532 Ellipsometry
533 Broadband Dielectric Spectroscopy
534 AC-calorimetry
535 Other Techniques
Concepts of the Determination of Glass Transition
Applying Ellipsometry
541 Single Wavelength Ellipsometry
542 Spectroscopic vis-Ellipsometry (SE)
Glass Transition in Thin Polymeric Films in Dependence
of Film Thickness - Some Exclusive Examples
551 Effect of Polymer Architecture and Functional
Groups
552 Effect of Interfacial Interactions Between Polymer
and Substrate
Summary and Outlook
References
6 Polymer Brushes, Hydrogels, Polyelectrolyte Multilayers:
Stimuli-Responsivity and Control of Protein Adsorption
Eva Bittrich, Andreas Furchner, Meike Koenig, Dennis Aulich,
Petra Uhlmann, Karsten Hinrichs and Klaus-Jochen Eichhorn
6 1 Introduction
6 2 Ellipsometry on Swellable, Stimuli-Responsive Surface
Layers
621 Hydrophilic Polymer Brushes
622 Hydrogels
623 Polyelectrolyte Multilayers
6 3 Concepts of Determining the Adsorbed Amount of Protein
on Different Polymer Films
97
98
99
99
100
101
101
101
101
102
102
103
104
104
105
109
109
110
112
113
115
116
119
119
126
128
129
Contents
xii
6 4 Protein Adsorption on Different Types of Smart Polymer
Brushes 132
641 Polymer Brushes Preventing Protein Adsorption 132
642 Protein Adsorption at Polyelectrolyte Brushes 134
6 5 Conclusion 139
References 140
7 Structure and Interactions of Polymer Thin Films from
Infrared Ellipsometry 145
Andreas Furchner
7 1 Introduction 145
7 2 Composition 147
7 3 Molecular Orientation 150
7 4 Hydrated Polymer Films 155
741 In Situ Infrared Ellipsometry 156
742 Polymer Films and Brushes in Aqueous
Environments 157
743 Optical Effects and the Role of Water Bands 161
744 Structure and Interactions from Quantitative
In Situ IR-SE 16
7 5 Future Prospects 16
References 16
8 In Situ Spectroscopic Ellipsometry in the Field
of Industrial Membranes 17
Wojciech Ogieglo
8 1 Basics of Membrane Science and Technology 17
811 Principles of Membrane-Based Separations 17
812 Advantages and Challenges in Membrane Science
and Technology 17
813 Characterization of Membranes 17
8 2 Experimental Configurations and Optical Models for In-Situ
Ellipsometry for Thin Films and Membranes 17
821 Design of Measurement Chambers 17
822 Optical Modeling for Swelling Films
and Membranes 17
8 3 Sorption and Diffusion of Small Molecule Penetrants
in Membrane Polymers 17
831 Swelling and Diffusion Mechanisms
in Thin Films 17
832 Glassy Versus Rubbery Membranes - Polymer
Dynamics 18
833 Membrane Plasticization Studies 18
8 4 New Generation of Membrane Materials-Metal Organic
Frameworks (MOFs) and Polymers of Intrinsic Microporosity
(PIMs) 18
ts xiii
8 5 Towards Ellipsometry Applied Directly to Membranes 189
8 6 Outlook 193
References 193
III Nanostructured Surfaces and Organic/Inorganic Hybrids
Systems of Nanoparticles with SAMs and Polymers 199
Thomas W H Oates
9 1 Introduction 199
9 2 Modeling Nanoparticles: The Mie-Lorenz Solution 201
9 3 Distinguishing NPs Based on Their Dielectric Functions 202
931 Plasmonic Nanoparticles 203
932 Quantum Dots 205
9 4 Nanoparticles in Polymer Matrices 206
9 5 Nanoparticles and Self-assembled Monolayers 209
9 6 Effective Medium Approximations 211
9 7 Surface Coverage of 2-D Films 214
9 8 SEIRA 216
981 SEIRA Substrates 217
982 SEIRA Optical Models 218
983 Recent Advances in SEIRA 220
9 9 Conclusions and Outlook 221
References 221
Detection of Organic Attachment onto Highly Ordered
Three-Dimensional Nanostructure Thin Films hy Generalized
Ellipsometry and Quartz Crystal Microbalance with Dissipation
Techniques 225
Keith B Rodenhausen, Daniel Schmidt, Charles Rice, Tino Hofmann,
Eva Schubert and Mathias Schubert
10 1 Introduction 226
10 2 Surface Preparation 230
10 2 1 Glancing Angle Deposition 230
10 2 2 Atomic Layer Deposition 231
10 3 Theory 232
10 3 1 Generalized Ellipsometry 232
10 3 2 Quartz Crystal Microbalance with Dissipation 235
10 3 3 Additional Experimental Considerations 236
10 4 Review of Work in the Field 236
10 4 1 Fibronectin Protein Adsorption 236
10 4 2 Decanethiol Chemisorption 239
10 4 3 Surface-Enhanced Birefringence Chromatography 241
10 5 Conclusion 244
References 244
XIV
11 Polarizing Natural Nanostructures
Kenneth Järrendahl and Hans Arwin
11 1 Introduction
11 2 Theoretical Details and Definitions
11 3 The Polarizing Environment
11 4 Polarization Sensitivity and Vision of Animals
11 5 Polarization by Animals
11 6 Polarized Light in Reflections from Beetles
11 7 Concluding Remarks
References
Part IV Thin Films of Organic Semiconductors for OPV, OLEDs
and OTFT
12 Polymer Blends and Composites
Stergios Logothetidis
12 1 Introduction
12 2 Organic Electronics Devices
12 3 Spectroscopic Ellipsometry for the Investigation of Optical
and Electronic Properties of OE Nanolayers
12 3 1 Polymer: Fullerene Blends as Photoactive Layers for
OPVs
12 3 2 PEDOT PSS for Transparent Electrodes
12 4 Summary and Outlook
References
13 Small Organic Molecules
Ovidiu D Gordan and Dietrich R T Zahn
13 1 Introduction
13 2 Phthalocyanines and Molecular Orientation in Thin Films
13 3 Controlling the Molecular Orientation with a Molecular
Template
13 4 Amorphous Organic Thin Films
13 5 Error Sources for Determination of Molecular Orientation
13 6 Ultra-Thin Films
References
14 Optical Dielectric Properties of Thin Films Formed by Organic
Dye Aggregates
Katy Roodenko and Peter Thissen
14 1 Introduction
14 2 Excitonic Properties and Molecular Structures of Organic
Aggregates
14 3 Optical and Structural Properties of Molecular Aggregates
14 4 Conclusions and Outlook
References
XV
15 Conjugated Polymers: Relationship Between Morphology
and Optical Properties 335
^ Maria Isabel Alonso and Mariano Campoy-Quiles
15 1 Introduction 335
i « 15 2 Basic Concepts 336
; 15 2 1 Structure and Optical Properties 337
15 2 2 Ellipsometry and Dielectric Function 338
15 3 Examples of Structural Variations 342
y 15 3 1 Conformation 342
15 3 2 Crystallinity 344
/ 15 3 3 Anisotropy 346
15 4 Blending 347
15 5 Monitoring in Real Time 349
15 6 Summary 351
f References 351
t
16 Polarons in Conjugated Polymers 355
Christoph Cobet, Jacek Gasiorowski, Dominik Farka
and Philipp Stadler
16 1 Introduction 356
16 1 1 rc-Conjugation 356
16 1 2 Polarons and Metal-Insulator Transitions 358
16 1 3 Charge Injection 363
16 2 P3HT 364
16 2 1 Dielectric Function 364
16 2 2 Iodine Doping 366
16 3 Electrochemical Doping of P3HT 369
16 3 1 (Spectro-)Electrochemistry 370
16 3 2 In-situ Spectroelectrochemical Ellipsometry 371
16 4 MDMO-PPV - Iodine Doping 378
16 5 Polaron Formation in Push-Pull Polymers 380
16 6 Comments on Transmission (UV-VIS) and ATR
Spectroscopy 382
References 386
Part V Developments in Ellipsometric Real-Time/In-situ Monitoring
Techniques
17 Coupling Spectroscopic Ellipsometry and Quartz Crystal
Microbalance to Study Organic Films at the Solid-Liquid
Interface 391
Ralf P Richter, Keith B Rodenhausen, Nico B Eisele
and Mathias Schubert
17 1 Introduction 392
XVI
Contents
17 2 Theory 393
17 2 1 Approaches to Analyze SE Data 393
17 2 2 Approaches to Analyze QCM-D Data 399
17 3 Practice 404
17 3 1 Experimental Setup 404
17 3 2 Data Acquisition Procedure 406
17 3 3 Data Analysis Procedure 407
17 4 Applications 410
17 4 1 Solvation and Swelling of Polymer Films 412
17 4 2 Calibration Curves 413
17 4 3 Trapped Solvent in Monolayers of Discrete
Nanoscale Objects 414
17 5 Conclusions and Perspectives 415
References 416
18 TIRE and SPR-Enhanced SE for Adsorption Processes 419
Hans Arwin
18 1 Introduction 419
18 2 Theory 422
18 2 1 Surface Plasmon-Polaritons 422
18 2 2 Surface Plasmon-Polariton Resonances
in Ellipsometric Mode 425
18 3 Ellipsometric Setups for TIRE 427
18 4 Applications 428
18 4 1 TIRE for Bioadsorption Processes
and Biosensing 428
18 4 2 Biolayer Imaging with TIRE 429
18 4 3 TIRE for Gas Adsorption Studies 432
18 5 Concluding Remarks and Outlook 433
References 433
19 In-Line Quality Control of Organic Thin Film Fabrication
on Rigid and Flexible Substrates 437
Argiris Laskarakis and Stergios Logothetidis
19 1 Introduction 437
19 2 Adaptation of Spectroscopic Ellipsometry to r2r Fabrication
Processes 438
19 3 Optical Properties of OE Nanomaterials by In-Line SE 443
19 3 1 Inorganic Barrier Layers 443
19 3 2 PEDOT:PSS Transparent Electrodes 446
19 3 3 Multilayer Structures onto PET Rolls 452
19 3 4 P3HT:PCBM Nanolayers 453
19 4 Summary and Outlook 455
References 456
ntents
Application of In-Situ IR-Ellipsometry in Silicon
Electrochemistry to Study Ultrathin Films 459
Jörg Rappich, Karsten Hinrichs, Guoguang Sun and Xin Zhang
20 1 Introduction 460
20 2 Geometry for In-Situ Electrochemical and IR-Ellipsometric
Measurements on Si Surfaces 460
20 3 Preconditioning of the Si Surface by H-Termination 462
20 4 Grafting from Diazonium Compound 463
20 5 Oxidation as Consequence of Side Reactions 467
20 6 Molecular Orientation 468
20 7 Thickness Determination of the NB Film 468
20 8 IRSE Investigation of the Maleimidobenzene Modified Si
Surface 469
20 9 Thickness Determination of the MB Film 470
20 10 Summary of the IRSE Investigations of Si Surfaces Modified
by Diazonium Cations 470
20 11 Deposition of Ultra-Thin Polymeric Layers from Pyrrole 471
20 12 Doping of PANI Films with PSS 476
20 13 Summary 477
References 477
Part VI Infared Spectroscopic Methods for Characterization
of Thin Organic Films
21 Characterization of Thin Organic Films with Surface-Sensitive
FTIR Spectroscopy 483
Katy Roodenko, Damien Aureau, Florent Yang, Peter Thissen
and Jörg Rappich
21 1 Introduction 484
21 2 Attenuated Total Reflection (ATR) 485
21 3 Infrared Spectroscopy in Transmission and
Reflection Modes 490
21 3 1 Transmission Mode 490
21 3 2 Reflection Mode 492
21 3 3 Polarization Modulation Infrared Reflection
Absorption Spectroscopy 493
21 4 IR Spectroscopic Ellipsometry: IRSE 496
21 5 Summary 500
References 501
22 Brilliant Infrared Light Sources for Micro-ellipsometric Studies
of Organic Thin Films 505
Michael Gensch
22 1 Introduction 505
22 2 Infrared Synchrotron Beamlines for Spectroscopic
Ellipsometry Applications 506
xviii Contents
22 3 Applications 508
22 3 1 Mesoscopic Samples: Biosensors and Single Flake
Graphene 508
22 3 2 Nano Patterned Films: Polymer Brushes 511
22 4 Summary and Outlook 514
22 4 1 Femtosecond-Laser Based Broad Band Sources 515
22 4 2 Fourth Generation Broad Band IR/THz Light
Sources 516
References 517
Part VII Optical Constants
23 Common Polymers and Proteins 521
Andreas Furchner and Dennis Aulich
24 Organic Materials for Optoelectronic Applications 529
Andreas Furchner and Dennis Aulich
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV044748187 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T08:01:07Z |
| institution | BVB |
| institution_GND | (DE-588)1064344704 |
| isbn | 9783319758947 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-030143905 |
| oclc_num | 1039828056 |
| open_access_boolean | |
| owner | DE-29T DE-11 |
| owner_facet | DE-29T DE-11 |
| physical | xxvi, 547 Seiten Diagramme |
| publishDate | 2018 |
| publishDateSearch | 2018 |
| publishDateSort | 2018 |
| publisher | Springer |
| record_format | marc |
| series | Springer series in surface sciences |
| series2 | Springer series in surface sciences |
| spelling | Ellipsometry of functional organic surfaces and films Karsten Hinrichs, Klaus-Jochen Eichhorn, editors Second edition Cham, Switzerland Springer [2018] Springer © 2018 xxvi, 547 Seiten Diagramme txt rdacontent n rdamedia nc rdacarrier Springer series in surface sciences v. 52 Ellipsometrie (DE-588)4152025-7 gnd rswk-swf Oberfläche (DE-588)4042907-6 gnd rswk-swf Organischer Stoff (DE-588)4203832-7 gnd rswk-swf Dünne Schicht (DE-588)4136925-7 gnd rswk-swf Organische Verbindungen (DE-588)4043816-8 gnd rswk-swf Nanostruktur (DE-588)4204530-7 gnd rswk-swf Biomolecules at Surfaces Characterization of Organic Semiconductors Ellipsometric Real-time/In-situ Monitoring Techniques Functional and Smart Films Infrared Brillant Light Sources for Micro-ellipsometric Studies OLEDs and OTFT Optical Constants of Organic Layers Organic and Hybrid Materials Smart Polymer Surfaces and Films In-Situ Monitoring Techniques Microscopic and imaging ellipsometry (DE-588)4143413-4 Aufsatzsammlung gnd-content Organischer Stoff (DE-588)4203832-7 s Dünne Schicht (DE-588)4136925-7 s Oberfläche (DE-588)4042907-6 s Ellipsometrie (DE-588)4152025-7 s DE-604 Organische Verbindungen (DE-588)4043816-8 s Nanostruktur (DE-588)4204530-7 s 1\p DE-604 Hinrichs, Karsten 1964- (DE-588)121499529 edt Eichhorn, Klaus-Jochen edt Springer International Publishing (DE-588)1064344704 pbl Erscheint auch als Online-Ausgabe 978-3-319-75895-4 Vorangegangen ist 978-3-642-40127-5 Springer series in surface sciences v. 52 (DE-604)BV000600785 52 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=44777bec781941468d0b2a4f55ddcf4e&prov=M&dok_var=1&dok_ext=htm Inhaltstext HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030143905&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Ellipsometry of functional organic surfaces and films Springer series in surface sciences Ellipsometrie (DE-588)4152025-7 gnd Oberfläche (DE-588)4042907-6 gnd Organischer Stoff (DE-588)4203832-7 gnd Dünne Schicht (DE-588)4136925-7 gnd Organische Verbindungen (DE-588)4043816-8 gnd Nanostruktur (DE-588)4204530-7 gnd |
| subject_GND | (DE-588)4152025-7 (DE-588)4042907-6 (DE-588)4203832-7 (DE-588)4136925-7 (DE-588)4043816-8 (DE-588)4204530-7 (DE-588)4143413-4 |
| title | Ellipsometry of functional organic surfaces and films |
| title_auth | Ellipsometry of functional organic surfaces and films |
| title_exact_search | Ellipsometry of functional organic surfaces and films |
| title_full | Ellipsometry of functional organic surfaces and films Karsten Hinrichs, Klaus-Jochen Eichhorn, editors |
| title_fullStr | Ellipsometry of functional organic surfaces and films Karsten Hinrichs, Klaus-Jochen Eichhorn, editors |
| title_full_unstemmed | Ellipsometry of functional organic surfaces and films Karsten Hinrichs, Klaus-Jochen Eichhorn, editors |
| title_short | Ellipsometry of functional organic surfaces and films |
| title_sort | ellipsometry of functional organic surfaces and films |
| topic | Ellipsometrie (DE-588)4152025-7 gnd Oberfläche (DE-588)4042907-6 gnd Organischer Stoff (DE-588)4203832-7 gnd Dünne Schicht (DE-588)4136925-7 gnd Organische Verbindungen (DE-588)4043816-8 gnd Nanostruktur (DE-588)4204530-7 gnd |
| topic_facet | Ellipsometrie Oberfläche Organischer Stoff Dünne Schicht Organische Verbindungen Nanostruktur Aufsatzsammlung |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=44777bec781941468d0b2a4f55ddcf4e&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030143905&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000600785 |
| work_keys_str_mv | AT hinrichskarsten ellipsometryoffunctionalorganicsurfacesandfilms AT eichhornklausjochen ellipsometryoffunctionalorganicsurfacesandfilms AT springerinternationalpublishing ellipsometryoffunctionalorganicsurfacesandfilms |