History of number: evidence from Papua New Guinea and Oceania
Gespeichert in:
Hauptverfasser: | , , , |
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Format: | Elektronisch E-Book |
Sprache: | English |
Veröffentlicht: |
Cham, Switzerland
Springer
[2018]
|
Schriftenreihe: | History of mathematics education
|
Schlagworte: | |
Online-Zugang: | DE-739 Volltext Inhaltsverzeichnis |
Beschreibung: | 1 Online-Ressource (xxvii, 461 Seiten) Illustrationen |
ISBN: | 9783319454832 |
DOI: | 10.1007/978-3-319-45483-2 |
Internformat
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Datensatz im Suchindex
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adam_text |
IMAGE 1
CONTENTS
1 INTRODUCTION 1
REFERENCES 3
2 BACKGROUND 5
2.1 ASYMMETRIC ORGANOCATALYSIS 5
2.1.1 HISTORICAL DEVELOPMENT 5
2.1.2 CLASSIFICATION 6
2.1.3 AMINOCATALYSIS 7
2.2 CATALYTIC ASYMMETRIC EPOXIDATION O F ELECTRON-DEFICIENT OLEFINS 15
2.2.1 MILESTONES IN CATALYTIC ASYMMETRIC OLEFIN EPOXIDATIONS 15
2.2.2 WEITZ-SCHEFFER EPOXIDATION 17
2.2.3 SYNTHETIC VERSATILITY O F A,(3-EPOXY KETONES 19
2.2.4 STATE O F THE ART: CATALYTIC ASYMMETRIC EPOXIDATION O F
A,(3-UNSATURATED KETONES 19
2.2.5 RECENT ADVANCES: THE ORGANOCATALYTIC APPROACH 2 4
2.2.6 ASYMMETRIC EPOXIDATION O F CYCLIC OE,|3-UNSATURATED KETONES 28
2.3 SYNTHESIS AND RELEVANCE OF 3-HYDROXY-L,2-DIOXOLANES AND
1,2-DIOXOLANES 30
2.3.1 PEROXIDIC NATURAL PRODUCTS 31
2.3.2 GENERAL METHODS FOR THE SYNTHESIS OF 3-HYDROXY-L,2-DIOXOLANES 32
REFERENCES 35
3 OBJECTIVES O F THIS PH.D. WORK 41
REFERENCES 43
4 RESULTS AND DISCUSSION 45
4.1 CATALYTIC ASYMMETRIC EPOXIDATION O F CYCLIC ENONES 45
I X
HTTP://D-NB.INFO/1018468935
IMAGE 2
X C O N T E N T S
4.1.1 SCREENING STUDIES 45
4.1.2 REACTION SCOPE AND DISCUSSION 55
4.1.3 SUMMARY AND CONCLUSIONS 73
4.2 CATALYTIC ASYMMETRIC EPOXIDATION AND HYDROPEROXIDATION OF ACYCLIC
ENONES 75
4.2.1 SCREENING STUDIES 75
4.2.2 REACTION SCOPE AND DISCUSSION 85
4.2.3 SUMMARY AND CONCLUSIONS 103
4.3 SYNTHETIC TRANSFORMATIONS O F OPTICALLY ACTIVE OC,P-EPOXY KETONES
AND 3-HYDROXY-1,2-DIOXOLANES 105
4.3.1 ONE-POT SYNTHESIS O F ALDOL PRODUCTS FROM A,(3-UNSATURATED KETONES
105
4.3.2 SYNTHESIS OF ALDOL PRODUCTS BY REDUCTIVE CLEAVAGE O F A,P-EPOXY
KETONES 108
4.3.3 SYNTHESIS OF 1,2-DIOXOLANES FROM PEROXYHEMIKETALS. . . . I L L 4.4
SUMMARY AND CONCLUSIONS 113
4.5 MECHANISTIC CONSIDERATIONS 113
4.5.1 EVALUATION OF MODIFIED CATALYSTS: STRUCTURE-ACTIVITY RELATIONSHIPS
113
4.5.2 ESI-MS STUDIES 116
4.5.3 FURTHER MECHANISTIC INVESTIGATIONS 120
4.5.4 SUMMARY AND CONCLUSIONS 121
4.6 PREPARATION O F STARTING MATERIALS 126
4.6.1 PREPARATION O F CYCLIC [^UNSATURATED KETONES 126
4.6.2 PREPARATION OF ACYCLIC A,P-UNSATURATED KETONES 128
4.7 CATALYST SYNTHESIS 131
4.7.1 SYNTHESIS OF CHIRAL PRIMARY AMINES BASED ON THE QUINUCLIDINE
SCAFFOLD 131
4.7.2 SYNTHESIS OF AMINO ACID-DERIVED DIAMINES 134
4.7.3 SYNTHESIS OF BINOL-DERIVED PHOSPHORIC ACIDS 135
REFERENCES 137
5 SUMMARY 141
6 OUTLOOK 147
REFERENCES 151
7 EXPERIMENTAL PART 153
7.1 GENERAL EXPERIMENTAL CONDITIONS 153
7.2 CATALYTIC ASYMMETRIC EPOXIDATION O F CYCLIC ENONES 156
7.2.1 GENERAL PROCEDURE 156
7.2.2 SCOPE O F OPTICALLY ACTIVE CYCLIC A, P-EPOXYKETONES . . . . 157
7.3 CATALYTIC ASYMMETRIC HYDROPEROXIDATION AND EPOXIDATION OF ACYCLIC
ENONES 172
IMAGE 3
CONTENTS XI
7.3.1 CATALYTIC ASYMMETRIC HYDROPEROXIDATION
OF ACYCLIC ENONES 172
7.3.2 SYNTHESIS O F (/?)-4-(7ERT-BUTYLPEROXY)DECAN-2-ONE 7?)-95A) 182
7.3.3 CATALYTIC ASYMMETRIC EPOXIDATION OF ACYCLIC ENONES. . . 182 7.3.4
HYDROPEROXIDATION OF 4,8-DIMETHYLNONA-3,7- DIEN-2-ONE (100) 194
7.3.5 HYDROPEROXIDATION OF CYCLOHEPTENONE (46S) AND CYCLOOCTENONE (46V)
196
7.4 SYNTHETIC TRANSFORMATIONS O F OPTICALLY ACTIVE PRODUCTS 198
7.4.1 ONE-POT SYNTHESIS OF ALDOL PRODUCTS 198
7.4.2 ORGANOSELENIUM-MEDIATED REDUCTIVE EPOXIDE OPENING 202
7.4.3 SYNTHESIS O F (S^^^-S-HEXYL-S-METHYL-L^- DIOXOLANE (127) 204
7.5 PREPARATION OF STARTING MATERIALS 206
7.5.1 PREPARATION OF CYCLIC OC,P-UNSATURATED KETONES 206
7.5.2 PREPARATION OF ACYCLIC A,P-UNSATURATED KETONES 216
7.6 CATALYST SYNTHESIS 232
7.6.1 SYNTHESIS OF 9-AMINO(9-DEOXY) CINCHONA ALKALOID DERIVATIVES 232
7.6.2 SYNTHESIS O F 9-E/7;'QUININE (147) 238
7.6.3 SYNTHESIS O F 6'-ISOPROPOXYCINCHONIDINE (146) 240
7.6.4 SYNTHESIS O F 9-AMINO(9-DEOXY)E;?I-6'HYDROXYCINCHONIDINE (68) 242
7.6.5 SYNTHESIS O F 2-(A-AMINOBENZYL)QUINUCLIDINE (86A) 243
7.6.6 SYNTHESIS O F AMINO ACID-DERIVED DIAMINES 246
7.6.7 SYNTHESIS OF
(17?,2/?)-A'-JSO-PROPYL-L,2DIPHENYLETHYLENE-L,2-DIAMINE (61) 251
7.6.8 SYNTHESIS O F
(5")-3,3'-BIS(TRIPHENYLSILYL)-1,1'BINAPHTHYL-2,2'-DIOL PHOSPHATE
((S)-7B) 252
REFERENCES 254
APPENDIX 257 |
any_adam_object | 1 |
author | Owens, Kay Lean, Glen Paraide, Patricia Muke, Charly |
author_GND | (DE-588)107248367X |
author_facet | Owens, Kay Lean, Glen Paraide, Patricia Muke, Charly |
author_role | aut aut aut aut |
author_sort | Owens, Kay |
author_variant | k o ko g l gl p p pp c m cm |
building | Verbundindex |
bvnumber | BV044703290 |
classification_rvk | SM 610 |
collection | ZDB-2-EDA |
ctrlnum | (ZDB-2-EDA)9783319454832 (OCoLC)1018468935 (DE-599)BVBBV044703290 |
dewey-full | 370 |
dewey-hundreds | 300 - Social sciences |
dewey-ones | 370 - Education |
dewey-raw | 370 |
dewey-search | 370 |
dewey-sort | 3370 |
dewey-tens | 370 - Education |
discipline | Pädagogik Mathematik |
doi_str_mv | 10.1007/978-3-319-45483-2 |
era | Geschichte gnd |
era_facet | Geschichte |
format | Electronic eBook |
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geographic | Papua-Neuguinea (DE-588)4044569-0 gnd Ozeanien (DE-588)4044257-3 gnd |
geographic_facet | Papua-Neuguinea Ozeanien |
id | DE-604.BV044703290 |
illustrated | Not Illustrated |
indexdate | 2024-08-10T01:37:10Z |
institution | BVB |
isbn | 9783319454832 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-030099963 |
oclc_num | 1018468935 |
open_access_boolean | |
owner | DE-739 DE-188 DE-11 |
owner_facet | DE-739 DE-188 DE-11 |
physical | 1 Online-Ressource (xxvii, 461 Seiten) Illustrationen |
psigel | ZDB-2-EDA ZDB-2-EDA_2018 |
publishDate | 2018 |
publishDateSearch | 2018 |
publishDateSort | 2018 |
publisher | Springer |
record_format | marc |
series2 | History of mathematics education |
spelling | Owens, Kay Verfasser (DE-588)107248367X aut History of number evidence from Papua New Guinea and Oceania Kay Owens and Glen Lean with Patricia Paraide and Charly Muke Cham, Switzerland Springer [2018] 1 Online-Ressource (xxvii, 461 Seiten) Illustrationen txt rdacontent c rdamedia cr rdacarrier History of mathematics education Geschichte gnd rswk-swf Education Mathematics History Mathematics / Study and teaching Mathematics Education History of Mathematical Sciences Zahl (DE-588)4067271-2 gnd rswk-swf Ethnomathematik (DE-588)4465939-8 gnd rswk-swf Mathematikunterricht (DE-588)4037949-8 gnd rswk-swf Papua-Neuguinea (DE-588)4044569-0 gnd rswk-swf Ozeanien (DE-588)4044257-3 gnd rswk-swf Ethnomathematik (DE-588)4465939-8 s Zahl (DE-588)4067271-2 s Papua-Neuguinea (DE-588)4044569-0 g Ozeanien (DE-588)4044257-3 g Mathematikunterricht (DE-588)4037949-8 s Geschichte z DE-604 Lean, Glen Verfasser aut Paraide, Patricia Verfasser aut Muke, Charly Verfasser aut Erscheint auch als Druck-Ausgabe 978-3-319-45482-5 https://doi.org/10.1007/978-3-319-45483-2 Verlag URL des Erstveröffentlichers Volltext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030099963&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Owens, Kay Lean, Glen Paraide, Patricia Muke, Charly History of number evidence from Papua New Guinea and Oceania Education Mathematics History Mathematics / Study and teaching Mathematics Education History of Mathematical Sciences Zahl (DE-588)4067271-2 gnd Ethnomathematik (DE-588)4465939-8 gnd Mathematikunterricht (DE-588)4037949-8 gnd |
subject_GND | (DE-588)4067271-2 (DE-588)4465939-8 (DE-588)4037949-8 (DE-588)4044569-0 (DE-588)4044257-3 |
title | History of number evidence from Papua New Guinea and Oceania |
title_auth | History of number evidence from Papua New Guinea and Oceania |
title_exact_search | History of number evidence from Papua New Guinea and Oceania |
title_full | History of number evidence from Papua New Guinea and Oceania Kay Owens and Glen Lean with Patricia Paraide and Charly Muke |
title_fullStr | History of number evidence from Papua New Guinea and Oceania Kay Owens and Glen Lean with Patricia Paraide and Charly Muke |
title_full_unstemmed | History of number evidence from Papua New Guinea and Oceania Kay Owens and Glen Lean with Patricia Paraide and Charly Muke |
title_short | History of number |
title_sort | history of number evidence from papua new guinea and oceania |
title_sub | evidence from Papua New Guinea and Oceania |
topic | Education Mathematics History Mathematics / Study and teaching Mathematics Education History of Mathematical Sciences Zahl (DE-588)4067271-2 gnd Ethnomathematik (DE-588)4465939-8 gnd Mathematikunterricht (DE-588)4037949-8 gnd |
topic_facet | Education Mathematics History Mathematics / Study and teaching Mathematics Education History of Mathematical Sciences Zahl Ethnomathematik Mathematikunterricht Papua-Neuguinea Ozeanien |
url | https://doi.org/10.1007/978-3-319-45483-2 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030099963&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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