Molecular and laser spectroscopy: advances and applications
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam
Elsevier
[2018]
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | xvi, 346 Seiten Illustrationen, Diagramme |
| ISBN: | 9780128498835 |
Internformat
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| 245 | 1 | 0 | |a Molecular and laser spectroscopy |b advances and applications |c V.P. Gupta, University of Lucknow, Lucknow, India |
| 264 | 1 | |a Amsterdam |b Elsevier |c [2018] | |
| 264 | 4 | |c © 2018 | |
| 300 | |a xvi, 346 Seiten |b Illustrationen, Diagramme | ||
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| 653 | 0 | |a Molecular spectroscopy | |
| 653 | 0 | |a Laser spectroscopy | |
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-030080441 | ||
Datensatz im Suchindex
| _version_ | 1804178140834037760 |
|---|---|
| adam_text | Contents
List of Contributors xi 4 Advantages of Near-Infrared Spectroscopy 19
Biography xiii 5 Spectral Analysis in the Near-Infrared
Preface XV Region 5 1 Conventional Spectral Analysis 19
Method 20
5 2 Chemometrics 22
1 Introduction and Overview 1 6 Quantum Mechanical Methods in
V P Gupta Near-Infrared Spectroscopy 23
6 1 Introduction 23
1 Introduction 162 Differences Between Quantum
2 Overview 5 Mechanical Approaches to Infrared and
2 1 Near-Infrared Spectroscopy 5 Near-Infrared Modes 23
2 2 Mid-Infrared Spectroscopy 563 General Overview of Anharmonic
2 3 Terahertz Spectroscopy (0 2 to 30 THz) 6 Approaches 23
2 4 Linear and Nonlinear Raman and 6 4 The Applications of Quantum Chemical
Infrared Spectroscopy and Microscopy 6 Methods to Near-Infrared Spectroscopy 24
2 5 Resonance Raman Spectroscopy 7 7 Instrumentation 27
2 6 Two-Photon Absorption Spectroscopy 771 Basic Technologies 27
2 7 Femtosecond Raman Spectroscopy 772 Advanced Technologies 28
2 8 Two-Dimensional Correlation 7 3 Imaging Spectrometry 29
Spectroscopy 8 8 Selected Applications 31
2 9 Laser Spectroscopy of Nanomaterials 881 Medicinal Plants 32
2 10 Laser-Induced Breakdown Spectroscopy 882 Foods 33
2 11 Photoacoustic Spectroscopy 983 Pharmaceutical 34
2 12 Matrix Isolation Spectroscopy 984 Polymers 35
Reference 985 Biomedical Applications Combined
With Imaging Studies 35
2 Near-IR Spectroscopy and Its 8 6 Advanced Imaging Technology 36
Applications 11 References 37
Yukihiro Ozaki, Christian W Huck, 3 Recent Advances in Sensor
Krzysztof B Bee Developments Based on Silver
1 Introduction 11 Halide Fibers for Mid-Infrared
2 Principles and Advantages of Near-Infrared Spectroscopy 2 1 Principles of Near-Infrared Spectroscopy 12 Spectrometric Analysis 39
12 H Michael Heise, Sven Delbeck, Lukas Küpper
3 Examples of Near-Infrared Spectra 13 1 Introduction 39
3 1 Water 13 1 1 Recent Spectrometer Developments 40
3 2 Methanol 14 2 Fundamentals of Infrared Fibers 41
3 3 High Reflective Green-Black Pigments 14 2 1 Experimental Details 41
3 4 Phenol and 2,6-Dihalogenated Phenols 14 2 2 Polycrystalline Fibers and Water
3 5 Comparison of a Near-Infrared Spectrum Adsorption 44
With an Infrared Spectrum 15 3 Mid-Infrared Fiber-Optic Probes 45
VII
viii Contents
4 General and Special Applications
of Fiber-Optic Probes 53
5 Conclusions 61
Acknowledgments 61
References 61
4 Terahertz Spectroscopy: Advances
and Applications 65
Shriganesh S Prabhu
1 Introduction 65
2 Terahertz Instrumentation 66
2 1 Terahertz Sources 66
2 2 Terahertz Detectors 69
3 Experimental Setups 70
3 1 Setup for Terahertz Time-Domain
Spectroscopy and Terahertz Emission
Spectroscopy 70
3 2 Extraction of n and k for Samples 71
3 3 Terahertz Imaging 72
4 Comparison of Terahertz Spectroscopy
With Other Spectroscopy Techniques 73
4 1 Advantages: Additional Information
Over Other Spectroscopy Techniques 74
4 2 Disadvantages: Limitations of the
Terahertz Spectroscopy 74
5 Application of Terahertz Spectroscopy 74
5 1 Pharmaceuticals 74
5 2 Bacteria Detection 76
5 3 Agriculture 80
6 Future Outlook 82
References 82
5 Coherent Optical Spectroscopy/
Microscopy and Applications 87
Vikas Kumar, Nicola Coluccelli, Dario Polli
1 Introduction 87
2 Coherent Optical Spectroscopy/Microscopy 88
3 Importance of Lasers in Optical
Spectroscopy/Microscopy 88
4 Linear and Nonlinear Spectroscopy/
Microscopy 89
5 Linear Spectroscopy/Microscopy Techniques 90
5 1 Infrared (Absorption) Spectroscopy 90
5 2 Confocal Microscopy 91
5 3 Laser-Induced Fluorescence Microscopy 92
5 4 Spontaneous Raman Spectroscopy/
Microscopy 93
6 Nonlinear Spectroscopy/Microscopy
Techniques 94
6 1 Coherent Raman Spectroscopy/
Microscopy 94
6 2 Second Harmonic Generation
Microscopy 108
6 3 Third Harmonic Generation Microscopy 110
6 4 Two-Photon Excitation Fluorescence
Microscopy 112
7 Conclusions 113
References 113
6 Applications of Raman and
Infrared Microscopy to Materials
and Biology 117
Sanchita S/7, Rekha Gautam, Siva Umapathy
1 Introduction 117
2 Principles and Instrumentation of Infrared
Spectroscopy 118
2 1 Fourier Transform Infrared
Microspectrometer 118
2 2 Advancement in Infrared
Spectroscopy 121
2 3 Applications of Infrared
Spectroscopy 121
3 Principles and Instrumentation of Raman
Spectroscopy 122
3 1 Raman Microspectrometer 122
3 2 Raman Imaging 127
3 3 Methods to Improve Signal-to-Noise
Ratio of Raman Signals 128
3 4 Applications of Raman Spectroscopy 129
4 Conclusion 141
Acknowledgments 142
References 142
7 Resonance Raman Spectroscopy:
Principles and Applications 147
Joydeep Chowdhury
1 Introduction 147
2 Raman and Resonance Raman Effect 148
3 Experimental Setup 149
3 1 Excitation Source 149
3 2 Collection Optics and Detectors 150
4 Applications of Resonance Raman
Spectroscopy 151
4 1 Application of Resonance Raman in
Agriculture: Carotenoids Detection 151
4 2 RR of Chlorophyll and
Bacteriochlorophylls 151
4 3 Raman Resonance in Art and
Archaeology 152
4 4 Resonance Raman Spectroscopy in Life
Sciences 152
4 5 Explosive Detection 154
Contents ix
5 Recent Applications of Resonance Raman
Spectroscopy 158
5 1 Carbon Nanotubes 158
5 2 Other Applications 160
6 Conclusions 160
Acknowledgments 161
References 161
8 Two-Photon Spectroscopy
of Organic Materials 165
Marcelo G Vivas, Leonardo De Boni
Cleber R Mendonqa
1 Introduction 165
2 Theoretical Background for Two-Photon
Absorption Process in Organic
Materials 166
2 1 Sum-Over-Essential States Approach 167
3 Two-Photon Absorption Spectroscopy
Techniques 171
3 1 Femtosecond Z-Scan Technique 171
3 2 Fluorescence Technique 172
4 Molecular Structure—Two-Photon
Absorption Properties Relationship 172
4 1 Dipolar Structures 173
4 2 Quadrupolar Structures 175
4 3 Octupolar Structures 175
4 4 Dendrimers 177
4 5 Unstable Species 178
5 Polarization Effect on the Two-Photon
Absorption Spectroscopy 180
5 1 Nonchiral Molecules 180
5 2 Chiral Molecules 185
6 Summary and Future Scope 187
Acknowledgments 188
References 188
9 Femtosecond Stimulated Raman
Spectroscopy 193
Palas Roy, Shreetama Karmakar,
Jyotishman Dasgupta
1 Introduction 193
1 1 Chemical Reactions and Reaction
Coordinates 194
1 2 Femtosecond Spectroscopic Methods 195
2 Theoretical Background on Femtosecond
Stimulated Raman Spectroscopy 196
3 Conventional Optical Layout for
Femtosecond Stimulated Raman
Spectroscopy Signal Detection 197
3 1 Broadband Probe 198
3 2 Raman Pump 198
3 3 Actinic Pump 199
3 4 Sample Preparation 201
3 5 Alternate Detection Strategies for
Femtosecond Stimulated Raman Signals 201
4 Applications of Femtosecond Stimulated
Raman Spectroscopy to Chemistry and
Biology 203
4 1 Excited-State Dynamics in Conjugated
Polymers 204
4 2 Excited Chromophores in Protein
Pockets 206
4 3 Reaction Dynamics in Small
Molecules 210
5 Summary and Future Scope 211
Acknowledgments 211
References 213
10 2D Correlation Spectroscopy and
Its Application in Vibrational
and Optical Spectroscopy 217
Yizhuang Xu, Yukihiro Ozaki, Isao Noda,
Young M Jung
1 Introduction 217
2 Background of Two-Dimensional
Correlation Spectroscopy 218
3 New Developments on
Two-Dimensional Correlation
Spectroscopy 219
3 1 Chemometrics-Combined
Two-Dimensional Correlation
Spectroscopy 219
3 2 Moving-Window Two-Dimensional
Analysis and Two-Dimensional
Waterfall Maps 220
3 3 Orthogonal Sample Design and
Related Techniques 221
3 4 Projection 2D 223
3 5 Two-Dimensional Codistribution
Spectroscopy 225
4 Applications of Two-Dimensional
Correlation Spectroscopy 225
5 Concluding Remarks 230
References 231
11 Laser Spectroscopy and Lasing
Actions in Nanomaterials 241
Yashashchandra Dwivedi
1 Introduction 241
2 Laser Spectroscopy of Nanomaterials 243
3 Time-Resolved Spectroscopy of
Nanomaterials 245
4 Lasing Action in Nanomaterials 250
x Contents
5 Ultrafast Pump—Probe Spectroscopy of
Nanomaterials 256
Acknowledgment 260
References 260
12 Laser-Induced Breakdown
Spectroscopy: Advanced Analytical
Technique 265
Chet R Bhatt, Charles T Chany, Fang Y Yueh,
Jagdish P Singh, Dustin L McIntyre
1 Introduction 265
2 Theoretical Details 266
2 1 Plasma Characterization 267
3 Calibration Models 268
4 Experimental Details 268
4 1 Spectral Detection System 269
5 Applications 269
5 1 Application to Solid Samples 269
5 2 Application to Food Science 272
References 280
13 Photoacoustic Spectroscopy:
Applications in Security
and Biology 283
Surya N Thakur
1 Introduction 283
1 1 Hie Photophone 284
1 2 The Spectrophone 284
2 Radiative and Nonradiative Transitions in
Molecules 285
2 1 Production of Photoacoustic Signal in
Gases 286
2 2 Production of Photoacoustic Signal in
Solids 288
3 Experimental Methods in Photoacoustic
Spectroscopy 289
3 1 Photoacoustic Cells for Static Gas
Samples 290
3 2 Photoacoustic Cell for Flowing Gaseous
Samples 291
3 3 Photoacoustic Cells for Solid Samples 293
3 4 Piezoelectric Transducers for Photo-
acoustic Detection 294
3 5 Quartz Tuning Fork for Photoacoustic
Detection 295
4 Photoacoustic Detection of Harmful
Chemicals 297
4 1 Photoacoustic Detection of Gaseous
Molecules 298
4 2 Photoacoustic Detection of
Condensed Matter 303
5 Hyperspectral Imaging and
Photoacoustic Spectroscopy 308
5 1 Photoacoustic Imaging 310
5 2 Photoacoustic Tomography 311
5 3 Combined Photoacoustic
Tomography—Optical Coherence
Tomography Imaging 314
6 Conclusion 314
Acknowledgments 314
References 314
14 Matrix Isolation Spectroscopy—A
Window to Molecular Processes 317
Pankaj Dubey, Jyoti Saini, Kanupriya Verma,
Ginny Karir, Anamika Mukhopadhyay,
K S Viswanathan
1 Introduction 317
2 Matrix Isolation Infrared Setup 318
2 1 Effusive and Supersonic Sources 319
3 Conformational Studies 319
4 Weak Intermolecular Interactions 323
4 1 Hydrogen-Bonding Interactions 323
4 2 Other Types of Noncovalent
Interactions 328
5 Photochemical Processes in the Matrix 329
5 1 Study of Reactive Species 329
5 2 Insertion of Metal Atoms Into
Covalent Bonds 329
6 Ions and Neutral Metal Clusters 330
6 1 Cations in the Matrix 331
6 2 Anions in the Matrix 331
6 3 Neutral Metal Clusters in Matrix 333
7 Laser Ablation Matrix Isolation 333
8 Species With Unusual Oxidation States 335
9 Role of Computational Chemistry 335
10 Other Experimental Techniques
to Probe Matrix-Isolated Species 336
References 337
Index
|
| any_adam_object | 1 |
| author2 | Gupta, V. P. 1942- |
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| dewey-tens | 530 - Physics |
| discipline | Physik |
| format | Book |
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| title | Molecular and laser spectroscopy advances and applications |
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| title_full | Molecular and laser spectroscopy advances and applications V.P. Gupta, University of Lucknow, Lucknow, India |
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