High-temperature electrochemical energy conversion and storage: fundamentals and applications
Gespeichert in:
| Hauptverfasser: | , , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Boca Raton ; London ; New York
CRC Press, Taylor & Francis Group
[2018]
|
| Schriftenreihe: | Electrochemical energy storage and conversion
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | Includes bibliographical references |
| Beschreibung: | xvi, 207 Seiten Illustrationen, Diagramme |
| ISBN: | 9781498779272 |
Internformat
MARC
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| 100 | 1 | |a Shi, Yixiang |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a High-temperature electrochemical energy conversion and storage |b fundamentals and applications |c Yixiang Shi, Ningsheng Cai, Tianyu Cao, and Jiujun Zhang |
| 264 | 1 | |a Boca Raton ; London ; New York |b CRC Press, Taylor & Francis Group |c [2018] | |
| 264 | 4 | |c © 2018 | |
| 300 | |a xvi, 207 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Electrochemical energy storage and conversion | |
| 500 | |a Includes bibliographical references | ||
| 650 | 4 | |a Direct energy conversion | |
| 650 | 4 | |a High temperature electrolysis | |
| 650 | 4 | |a Energy storage | |
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| 700 | 1 | |a Cai, Ningsheng |e Verfasser |4 aut | |
| 700 | 1 | |a Cao, Tianyu |e Verfasser |4 aut | |
| 700 | 1 | |a Zhang, Jiujun |e Verfasser |0 (DE-588)1052280277 |4 aut | |
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Datensatz im Suchindex
| _version_ | 1804178127682797568 |
|---|---|
| adam_text | Contents
Foreword..............................................................ix
Preface...............................................................xi
Acknowledgments................................................. xiii
About the Authors.....................................................xv
Chapter 1 Introduction to High-Temperature Electrochemical Energy
Conversion and Storage....................................1
1.1 Introduction to Solid Oxide Fuel Cells...........2
1.2 Introduction to Solid Oxide Electrolysis Cells.......4
1.3 Molten Carbonate Fuel Cells..........................5
1.4 Introduction to High-Temperature Batteries...........5
References................................................6
Chapter 2 Solid Oxide Fuel Cells......................................9
2.1 Introduction.........................................9
2.2 Electrochemistry of SOFCs...........................10
2.3 Solid Oxide Fuel Cells Fueling with Syngas and
Hydrocarbons.......................................12
2.3.1 Hydrogen Electrochemical Oxidation...........13
2.3.2 Carbon Monoxide Electrochemical Oxidation....14
2.3.3 SOFC Performance and Mechanisms with
H2/CO Mixture Fuel..........................14
2.3.4 Hydrocarbon Electrochemical Oxidation........14
2.3.5 Carbon Deposition............................17
2.4 Modeling and Simulation of Solid Oxide Fuel Cells...17
2.4.1 PEN Modeling of Solid Oxide Fuel Cells.......19
2.4.2 Cell Unit Modeling of Solid Oxide Fuel Cells.19
2.4.3 Solid Oxide Fuel Cell Stack Modeling.........22
2.5 Solid Oxide Fuel Cell System........................22
2.5.1 Typical System Configurations................22
2.5.2 Fuel Processing for SOFC Systems.............27
2.5.2.1 Internal Reforming..................29
2.5.2.2 External Reforming..................32
2.5.3 C02 Capture in SOFC-Based Power Generation
Systems.....................................33
2.6 Summary.............................................35
References...............................................36
v
VI
Contents
Chapter 3 Solid Oxide Electrolysis Cells...................................41
3.1 Introduction............................................41
3.2 Fundamentals of the Solid Oxide Electrolysis Cell.......42
3.2.1 Basic Structures and Working Principles..........43
3.2.2 Thermodynamics...................................44
3.2.3 Reaction Kinetics of SOECs.......................46
3.3 Reaction Mechanisms in Nickel-Patterned Electrodes......48
3.3.1 Carbon Deposition Mechanism......................49
3.3.1.1 Distribution of Carbon Deposition.......49
3.3.1.2 Structure Features of Deposited Carbon..51
3.3.2 Electrochemical Conversion Mechanisms
of C0/C02........................................52
3.3.2.1 Electrochemical Reaction Kinetics.......52
3.3.2.2 Effects of Applied Voltage..............53
3.3.2.3 Effects of Temperature..................54
3.3.2.4 Effects of CO Partial Pressure..........55
3.3.2.5 Effects of C02 Partial Pressure.........56
3.3.2.6 Reaction Mechanism Speculations
for C02 Electrolysis....................57
3.4 Heterogeneous Chemistry and Electrochemistry of SOEC
Porous Electrodes.......................................58
3.4. Î Basic Performance................................59
3.4.2 Analysis of Methane Production Pathways..........60
3.4.3 Elementary Reaction Models and PEN Models........62
3.4.4 Effects of Key Parameters on the Negative
Electrode Process................................64
3.4.4.2 Sensitivity Analysis of Heterogeneous
Elementary Reaction Rates...............64
3.4.4.2 Effects of Applied Voltage..............65
3.4.4.3 Effects of Negative Electrode Thickness.... 65
3.4.4.4 Active Zones for Heterogeneous
Chemistry and Electrochemistry..........67
3.4.4.5 Effects of Porosity and Particle Diameter...71
3.4.4.6 Effects of Ionic Conductivity...........73
3.4.4.7 Effects of Gas Composition and
Temperature.............................73
3.4.5 Coupling of Reactions and Transfer Processes
in Positive Electrodes...........................75
3.4.6 Fuel-Assisted Electrolysis.......................77
3.5 Operating Condition Designs and Dynamic Behaviors
in Tubular Cells........................................81
3.5.2 Experiment.......................................81
3.5.2 Comprehensive Electrothermal Model for
Tubular SOECs....................................84
Contents vii
3.5.2.1 Optimization of Conversion Ratio and
Efficiency..............................85
3.5.2.2 Operating Condition Designs for
Methane Production......................88
3.5.2.3 Dynamic Operation Behaviors.............92
3.6 High-Temperature Electrolysis Systems and Integration
with Renewable/Fossil Energy Systems....................95
3.6.1 System Integration and Typical Configurations....95
3.6.2 Novel Criteria for Renewable Power Storage
Systems.........................................100
3.6.3 Power Storage Strategies in Renewable Power
Systems.........................................101
3.7 Challenges and Outlooks.................................102
References....................................................103
Chapter 4 Flame Fuel Cells................................................109
4.1 Introduction............................................109
4.2 Working Principles and Efficiency Analysis..............110
4.3 Fuel-Rich Combustion....................................113
4.3.1 Types of Burners................................114
4.3.1.1 McKenna Burner.........................114
4.3.1.2 Hencken Burner.........................115
4.3.1.3 Porous Combustors......................116
4.4 FFC Performance.........................................118
4.4.1 Electrochemical Performance.....................120
4.4.1.1 Effects of Equivalence Ratio...........123
4.4.1.2 Effects of Gas Flow Rate...............123
4.4.1.3 Effects of Burner—SOFC Distance........125
4.4.2 FFC Unit Configurations.........................128
4.5 Challenges in FFC.......................................132
4.5.1 Thermal Shock Resistance........................132
4.5.2 Carbon Deposition...............................135
4.5.2.1 Effects of Fuel Type...................136
4.5.2.2 Effects of Materials...................136
4.6 FFC Applications in CHP Systems.........................136
4.7 Summary.................................................139
References....................................................139
Chapter 5 Solid Oxide Direct Carbon Fuel Cell...........................145
5.1 Introduction............................................145
5.2 Thermodynamics of Carbon Conversion.....................146
5.2.1 Open Circuit Potential of DCFCs.................146
5.2.2 Theoretical Efficiency of DCFCs.................149
5.2.3 Practical Efficiency of DCFCs...................150
viii Contents
5.3 DCFC Configurations.................................151
5.3.1 Solid Oxide DCFCs...............................152
5.3.2 Molten Media in DCFCs...........................153
5.3.2.1 Molten Carbonate in DCFCs..............154
5.3.2.2 Liquid Metal in DCFC...................156
5.4 Role of CO in Carbon Conversion........................159
5.4.1 “CO Shuttle” Mechanism..........................159
5.4.2 Steam Gasification..............................161
5.4.3 Catalytic Gasification..........................163
5.4.4 Indirect Carbon Fuel Cell.......................165
5.5 Carbon Conversion in Molten Media.....................168
5.5.1 Wetting Conditions of Carbon by Molten
Carbonate......................................168
5.5.2 Carbon Conversion Mechanisms in Molten
Carbonate......................................171
5.5.3 Chemical and Electrochemical Reactions in
Liquid Metal................................. 175
5.5.3.1 Metal Oxidation in Liquid Metal Anodes ... 175
5.5.3.2 Carbon Conversion in Liquid Metal
Anodes.................................178
5.6 Development of Carbon-Based Fuel Cell Stacks
and Systems............................................184
5.6.1 Direct Carbon Fuel Cell Stacks and Associated
Systems........................................184
5.6.2 Integrated Gasification Fuel Cell Systems.......187
5.7 Chapter Summary........................................190
5.7.1 Technical Challenges of DCFCs...................191
5.7.1.1 Current Collection of DCFCs............191
5.7.1.2 Molten Media Stability.................193
5.7.1.3 Ash Content and Mineral Elements
in Coal................................193
5.7.2 Conclusions.....................................195
References...................................................196
Index.....................................................................203
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CRC Press
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ISBN:
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| illustrated | Illustrated |
| indexdate | 2024-07-10T07:59:02Z |
| institution | BVB |
| isbn | 9781498779272 |
| language | English |
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| spelling | Shi, Yixiang Verfasser aut High-temperature electrochemical energy conversion and storage fundamentals and applications Yixiang Shi, Ningsheng Cai, Tianyu Cao, and Jiujun Zhang Boca Raton ; London ; New York CRC Press, Taylor & Francis Group [2018] © 2018 xvi, 207 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Electrochemical energy storage and conversion Includes bibliographical references Direct energy conversion High temperature electrolysis Energy storage Energiespeicherung (DE-588)4014722-8 gnd rswk-swf Festoxidbrennstoffzelle (DE-588)4811042-5 gnd rswk-swf Festoxidbrennstoffzelle (DE-588)4811042-5 s Energiespeicherung (DE-588)4014722-8 s DE-604 Cai, Ningsheng Verfasser aut Cao, Tianyu Verfasser aut Zhang, Jiujun Verfasser (DE-588)1052280277 aut Erscheint auch als Online-Ausgabe 978-0-2037-0193-5 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030073521&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030073521&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Shi, Yixiang Cai, Ningsheng Cao, Tianyu Zhang, Jiujun High-temperature electrochemical energy conversion and storage fundamentals and applications Direct energy conversion High temperature electrolysis Energy storage Energiespeicherung (DE-588)4014722-8 gnd Festoxidbrennstoffzelle (DE-588)4811042-5 gnd |
| subject_GND | (DE-588)4014722-8 (DE-588)4811042-5 |
| title | High-temperature electrochemical energy conversion and storage fundamentals and applications |
| title_auth | High-temperature electrochemical energy conversion and storage fundamentals and applications |
| title_exact_search | High-temperature electrochemical energy conversion and storage fundamentals and applications |
| title_full | High-temperature electrochemical energy conversion and storage fundamentals and applications Yixiang Shi, Ningsheng Cai, Tianyu Cao, and Jiujun Zhang |
| title_fullStr | High-temperature electrochemical energy conversion and storage fundamentals and applications Yixiang Shi, Ningsheng Cai, Tianyu Cao, and Jiujun Zhang |
| title_full_unstemmed | High-temperature electrochemical energy conversion and storage fundamentals and applications Yixiang Shi, Ningsheng Cai, Tianyu Cao, and Jiujun Zhang |
| title_short | High-temperature electrochemical energy conversion and storage |
| title_sort | high temperature electrochemical energy conversion and storage fundamentals and applications |
| title_sub | fundamentals and applications |
| topic | Direct energy conversion High temperature electrolysis Energy storage Energiespeicherung (DE-588)4014722-8 gnd Festoxidbrennstoffzelle (DE-588)4811042-5 gnd |
| topic_facet | Direct energy conversion High temperature electrolysis Energy storage Energiespeicherung Festoxidbrennstoffzelle |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030073521&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030073521&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
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