Double photoionisation spectra of molecules:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Oxford, United Kingdom
Oxford University Press
2018
|
| Ausgabe: | First edition |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | v, 197 Seiten Illustrationen, Diagramme |
| ISBN: | 9780198788980 |
Internformat
MARC
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| 245 | 1 | 0 | |a Double photoionisation spectra of molecules |c John H.D. Eland and Raimund Feifel |
| 250 | |a First edition | ||
| 264 | 1 | |a Oxford, United Kingdom |b Oxford University Press |c 2018 | |
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Datensatz im Suchindex
| _version_ | 1804178125196623872 |
|---|---|
| adam_text | Contents
f
Preface vii
Acknowledgements ix
Archive of digital spectra x
Introduction 1
1 Basis of the TOF-PEPECO technique 4
2 Other techniques for spectra of doubly charged ions 6
3 Ionisation energies 7
4 Orbital configurations and dication states 8
5 Ionisation pathways and their effects 8
6 How TOF-PEPECO experiments are done 10
6.1 Light sources 10
6.2 The magnetic bottle TOF spectrometer 12
7 Order and format of the spectra 15
1 Atomic xenon, Xe 17
2 Diatomic molecules 25
2.1 Hydrogen bromide, HBr 29
2.2 Hydrogen iodide, HI 31
2.3 Nitrogen, N2 33
2.4 Carbon monoxide, CO 37
2.5 Nitric oxide, NO 41
2.6 Oxygen, O2 43
2.7 Bromine, Br2 47
2.8 Iodine monochloride, IC1 49
2.9 Iodine, I2 51
3 Triatomic molecules 53
3.1 Water, H20 56
3.2 Hydrogen sulphide, H2S 59
3.3 Hydrogen cyanide, HCN 61
3.4 Carbon dioxide, CO2 63
3.5 Nitrous oxide, N2O 66
iv Contents
3.6 Carbonyl sulphide, OCS 69
3.7 Carbon disulphide, CS2 71
3.8 Bromine and iodine cyanides, BrCN and ICN 74
3.9 Mercuric chloride, HgC^ 77
3.10 Nitrogen dioxide, NO2 79
3.11 Sulphur dioxide, SO2 81
4 Molecules with four, five or seven atoms 83
4.1 Ammonia, NH3 86
4.2 Acetylene (ethyne), C2H2 88
4.3 Formaldehyde (methanal), H2CO 91
4.4 Cyanogen, C2N2 93
4.5 Phosphorus trichloride, PCI3 95
4.6 Alethane, CH4 97
4.7 Methyl halides (monohalomethanes), CH3F, CH3CI, CH3I 100
4.8 Methylene halides (dihalomethanes), CH2CI2J CH2Br2, CH2I2 103
4.9 Carbon tetrahalides, CF4, CCI4, CBr4 105
4.10 Germane and germanium halides, GeH4, GeCl4, GeBr4 108
4.11 Sulphur hexafluoride, SF6 110
5 Conjugated and aromatic molecules 113
5.1 Ethylene (ethene), C2H4 116
5.2 Butadiene (iram-buta-1,3-diene), C4H6 118
5.3 Five-membered rings: pyrrole, furan and thiophene 120
5.4 Benzene, C6H6 122
5.5 Hexafluorobenzene, C6F6 and toluene, C6H5—CH3 125
5.6 Pyridine, C5H5N and the three diazines, C4H4N2 128
5.7 Naphthalene and azulene, C10 Hg 131
5.8 Quinoline, C9H7N and biphenyl, C12H10 133
5.9 Molecules with very low ionisation energies 136
6 Mainly aliphatic molecules 139
6.1 Monoiodides, CnH2«+iI 142
6.2 Aliphatic alcohols, C„H2„+iOH 144
6.3 Acetonitrile, CH3CN and methyl mercaptan, CH3SH 146
6.4 Acetaldehyde, CH3CHO and acetone, CH3COCH3 148
6.5 Three larger molecules 150
7 Core-core and core-valence double ionisation 153
7.1 Core-core double ionisation 157
7.1.1 Single-site double core holes in 1 s shells 157
7.1.2 Single-site double core holes in 2p and other shells 159
7.1.3 Two-site double core holes 160
Contents v
7.2 Core-valence double ionisation; generalities 162
7.3 Core-valence spectrum of ammonia, NH3 163
7.4 Core-valence spectra of carbon monoxide, CO 165
7.5 Core-valence spectra of C02 OCS and CS2 167
7.6 Core-valence spectra of CF4 170
7.7 Core-valence spectra of Si(CH3)4 171
7.8 Core-valence spectrum of CgH^ 172
7.9 Core-valence spectrum of fullerene, C60 174
Appendix 1 Mechanisms of double photoionisation 175
Appendix 2 Useful data for calibration 183
Appendix 3 Theoretical calculation of ionisation energies and spectra 188
Index 195
1 his compact guide is the first ever compendium of double photoionisation spectra, covering some 70 of the
most important small and medium sized molecules and thus providing an essential starting point for studies
of the consequences of ionisation by high energy photons in both terrestrial and astrophysical environments.
It also provides a complete non-mathematical description of all the phenomena and pathways involved in
molecular double photoionisation. Most spectra are presented with identification of the electronic states and
leading orbital configurations. I he technique of magnetic bottle time-of-flight electron spectroscopy, used
for all the spectra, is fully explained and compared with other techniques. For each molecule, the book gives
full references to relevant work by complementary techniques and to theoretical calculations.
Written in a clear non-mathematical style, this book is accessible to students as well as more experienced
researchers, the authors have designed the layout for easy retrieval of any desired spectrum through
the systematic organisation and ordering of the compounds and thorough indexing. As well as being
a compendium of spectra, the book is a textbook covering all the known phenomenological aspects of
molecular double photoionisation. I he important phenomena are first mentioned in the introductory
chapters, and are discussed in more detail in connection with the groups of molecules and individual cases
where they are most relevant. ihe most useful spectra will be available in digital form for users.
|
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| indexdate | 2024-07-10T07:59:00Z |
| institution | BVB |
| isbn | 9780198788980 |
| language | English |
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| spelling | Eland, John H. D. 1941- Verfasser (DE-588)1067600965 aut Double photoionisation spectra of molecules John H.D. Eland and Raimund Feifel First edition Oxford, United Kingdom Oxford University Press 2018 v, 197 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Molekül (DE-588)4039972-2 gnd rswk-swf Fotoionisation (DE-588)4174506-1 gnd rswk-swf Molekül (DE-588)4039972-2 s Fotoionisation (DE-588)4174506-1 s DE-604 Feifel, Raimund Verfasser (DE-588)1192391233 aut Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030072172&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030072172&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Eland, John H. D. 1941- Feifel, Raimund Double photoionisation spectra of molecules Molekül (DE-588)4039972-2 gnd Fotoionisation (DE-588)4174506-1 gnd |
| subject_GND | (DE-588)4039972-2 (DE-588)4174506-1 |
| title | Double photoionisation spectra of molecules |
| title_auth | Double photoionisation spectra of molecules |
| title_exact_search | Double photoionisation spectra of molecules |
| title_full | Double photoionisation spectra of molecules John H.D. Eland and Raimund Feifel |
| title_fullStr | Double photoionisation spectra of molecules John H.D. Eland and Raimund Feifel |
| title_full_unstemmed | Double photoionisation spectra of molecules John H.D. Eland and Raimund Feifel |
| title_short | Double photoionisation spectra of molecules |
| title_sort | double photoionisation spectra of molecules |
| topic | Molekül (DE-588)4039972-2 gnd Fotoionisation (DE-588)4174506-1 gnd |
| topic_facet | Molekül Fotoionisation |
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