Scorpionates: the coordination chemistry of polypyrazolborate ligands
"This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and elect...
Gespeichert in:
1. Verfasser: | |
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Format: | Elektronisch E-Book |
Sprache: | English |
Veröffentlicht: |
London
Imperial College Press
c1999
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Schlagworte: | |
Online-Zugang: | FHN01 Volltext |
Zusammenfassung: | "This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their "Bite" can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 170 different scorpionate ligands are known today, and some are published for the first time in this book. The author, Swiatoslaw Trofimenko, discovered and developed this ligand system and has written several reviews on the subject. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances." |
Beschreibung: | x, 282 p. ill |
ISBN: | 9781848160422 |
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520 | |a "This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their "Bite" can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 170 different scorpionate ligands are known today, and some are published for the first time in this book. The author, Swiatoslaw Trofimenko, discovered and developed this ligand system and has written several reviews on the subject. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances." | ||
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Datensatz im Suchindex
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author | Trofimenko, Swiatoslaw |
author_facet | Trofimenko, Swiatoslaw |
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dewey-ones | 541 - Physical chemistry |
dewey-raw | 541.2/242 |
dewey-search | 541.2/242 |
dewey-sort | 3541.2 3242 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie |
format | Electronic eBook |
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id | DE-604.BV044633253 |
illustrated | Not Illustrated |
indexdate | 2024-07-10T07:57:42Z |
institution | BVB |
isbn | 9781848160422 |
language | English |
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oclc_num | 1012700750 |
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owner | DE-92 |
owner_facet | DE-92 |
physical | x, 282 p. ill |
psigel | ZDB-124-WOP ZDB-124-WOP FHN_PDA_WOP |
publishDate | 1999 |
publishDateSearch | 1999 |
publishDateSort | 1999 |
publisher | Imperial College Press |
record_format | marc |
spelling | Trofimenko, Swiatoslaw Verfasser aut Scorpionates the coordination chemistry of polypyrazolborate ligands Swiatoslaw Trofimenko London Imperial College Press c1999 x, 282 p. ill txt rdacontent c rdamedia cr rdacarrier "This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their "Bite" can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 170 different scorpionate ligands are known today, and some are published for the first time in this book. The author, Swiatoslaw Trofimenko, discovered and developed this ligand system and has written several reviews on the subject. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances." Scorpionates Chelate (DE-588)4123003-6 gnd rswk-swf Pyrazole (DE-588)4176446-8 gnd rswk-swf Chelate (DE-588)4123003-6 s Pyrazole (DE-588)4176446-8 s 1\p DE-604 Erscheint auch als Druck-Ausgabe 1860941729 Erscheint auch als Druck-Ausgabe 9781860941726 http://www.worldscientific.com/worldscibooks/10.1142/P148#t=toc Verlag URL des Erstveroeffentlichers Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
spellingShingle | Trofimenko, Swiatoslaw Scorpionates the coordination chemistry of polypyrazolborate ligands Scorpionates Chelate (DE-588)4123003-6 gnd Pyrazole (DE-588)4176446-8 gnd |
subject_GND | (DE-588)4123003-6 (DE-588)4176446-8 |
title | Scorpionates the coordination chemistry of polypyrazolborate ligands |
title_auth | Scorpionates the coordination chemistry of polypyrazolborate ligands |
title_exact_search | Scorpionates the coordination chemistry of polypyrazolborate ligands |
title_full | Scorpionates the coordination chemistry of polypyrazolborate ligands Swiatoslaw Trofimenko |
title_fullStr | Scorpionates the coordination chemistry of polypyrazolborate ligands Swiatoslaw Trofimenko |
title_full_unstemmed | Scorpionates the coordination chemistry of polypyrazolborate ligands Swiatoslaw Trofimenko |
title_short | Scorpionates |
title_sort | scorpionates the coordination chemistry of polypyrazolborate ligands |
title_sub | the coordination chemistry of polypyrazolborate ligands |
topic | Scorpionates Chelate (DE-588)4123003-6 gnd Pyrazole (DE-588)4176446-8 gnd |
topic_facet | Scorpionates Chelate Pyrazole |
url | http://www.worldscientific.com/worldscibooks/10.1142/P148#t=toc |
work_keys_str_mv | AT trofimenkoswiatoslaw scorpionatesthecoordinationchemistryofpolypyrazolborateligands |