Metallabenzenes: an expert view
Gespeichert in:
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, NJ
Wiley
2017
|
| Schlagworte: | |
| Online-Zugang: | FRO01 UBG01 Volltext |
| Beschreibung: | Includes bibliographical references and index Cover; Title Page; Copyright; Contents; List of Contributors; Preface; Chapter 1 Metallabenzenes and Fused-Ring Metallabenzenes of Osmium, Ruthenium and Iridium: Syntheses, Properties and Reactions; 1.1 Introduction; 1.2 Syntheses and Properties of Metallabenzenes with Methylthiolate Substituents; 1.2.1 Osmabenzenes; 1.2.2 Iridabenzenes; 1.3 Syntheses and Properties of Fused-Ring Metallabenzenes; 1.3.1 Osmabenzofurans; 1.3.2 Ruthenabenzofurans; 1.3.3 Iridabenzofurans; 1.3.4 Iridabenzothiophenes; 1.3.5 Iridabenzothiazolium Cations; 1.4 Reactions of Metallabenzenes and Metallabenzenoids 1.4.1 Electrophilic Aromatic Substitution Reactions1.4.2 Rearrangement to Cyclopentadienyl Complexes; 1.4.3 Nucleophilic Aromatic Substitution Reactions; 1.5 Concluding Remarks; References; Chapter 2 The First Iridabenzenes: Syntheses, Properties, and Reactions; 2.1 Introduction; 2.2 Basic Theory; 2.3 Discovery of the First Stable Metallabenzenes; 2.4 Synthesis of Iridabenzene; 2.5 Valence Bond Structures and Electron Counting for Iridabenzene; 2.6 The Tris(trimethylphosphine) Reaction System; 2.7 Structure and Spectroscopy of Iridabenzene 3; 2.8 Chemical Reactivity of Iridabenzene 3 2.8.1 Ligand Substitution2.8.2 Oxidative Addition/Oxidation; 2.8.3 Cycloaddition; 2.8.4 Theoretical Study of Cycloaddition; 2.8.5 Electrophilic Addition; 2.8.6 Coordination to Mo(CO)3; 2.9 Iridaphenol; 2.10 Synthesis and Spectroscopy of Iridapyrylium; 2.11 Valence Bond Structures and Electron Counting for Iridapyrylium; 2.12 Chemical Reactivity of Iridapyrylium 37; 2.12.1 Ligand Addition; 2.12.2 Cycloaddition; 2.13 Comparison of Iridabenzene 3 and Iridapyrylium 37; 2.14 Synthesis and Spectroscopy of Iridathiabenzene; 2.15 Structure of Iridathiabenzene 50 2.16 Chemical Reactivity of Iridathiabenzene 502.16.1 Ligand Addition and Cycloaddition; 2.16.2 Coordination to Other Metals; 2.17 Comparison of Iridathiabenzene 50 and Iridapyrylium 37; 2.18 Synthesis and Structure of a Neutral Iridathiabenzene; 2.19 Spectroscopy of Neutral Iridathiabenzene 56; 2.20 Chemical Reactivity of Neutral Iridathiabenzene 56; 2.21 Related Metal-Coordinated Metallabenzenes; 2.22 Aromaticity; 2.22.1 Electronic Structure; 2.22.2 Structural (Geometric) Features; 2.22.3 Magnetic Properties; 2.22.4 Stability; 2.22.5 Chemical Reactivity; 2.22.6 Conclusion; 2.23 Final Word |
| Beschreibung: | 1 Online-Ressource |
| ISBN: | 9781119068075 9781119068099 |
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| 500 | |a 1.4.1 Electrophilic Aromatic Substitution Reactions1.4.2 Rearrangement to Cyclopentadienyl Complexes; 1.4.3 Nucleophilic Aromatic Substitution Reactions; 1.5 Concluding Remarks; References; Chapter 2 The First Iridabenzenes: Syntheses, Properties, and Reactions; 2.1 Introduction; 2.2 Basic Theory; 2.3 Discovery of the First Stable Metallabenzenes; 2.4 Synthesis of Iridabenzene; 2.5 Valence Bond Structures and Electron Counting for Iridabenzene; 2.6 The Tris(trimethylphosphine) Reaction System; 2.7 Structure and Spectroscopy of Iridabenzene 3; 2.8 Chemical Reactivity of Iridabenzene 3 | ||
| 500 | |a 2.8.1 Ligand Substitution2.8.2 Oxidative Addition/Oxidation; 2.8.3 Cycloaddition; 2.8.4 Theoretical Study of Cycloaddition; 2.8.5 Electrophilic Addition; 2.8.6 Coordination to Mo(CO)3; 2.9 Iridaphenol; 2.10 Synthesis and Spectroscopy of Iridapyrylium; 2.11 Valence Bond Structures and Electron Counting for Iridapyrylium; 2.12 Chemical Reactivity of Iridapyrylium 37; 2.12.1 Ligand Addition; 2.12.2 Cycloaddition; 2.13 Comparison of Iridabenzene 3 and Iridapyrylium 37; 2.14 Synthesis and Spectroscopy of Iridathiabenzene; 2.15 Structure of Iridathiabenzene 50 | ||
| 500 | |a 2.16 Chemical Reactivity of Iridathiabenzene 502.16.1 Ligand Addition and Cycloaddition; 2.16.2 Coordination to Other Metals; 2.17 Comparison of Iridathiabenzene 50 and Iridapyrylium 37; 2.18 Synthesis and Structure of a Neutral Iridathiabenzene; 2.19 Spectroscopy of Neutral Iridathiabenzene 56; 2.20 Chemical Reactivity of Neutral Iridathiabenzene 56; 2.21 Related Metal-Coordinated Metallabenzenes; 2.22 Aromaticity; 2.22.1 Electronic Structure; 2.22.2 Structural (Geometric) Features; 2.22.3 Magnetic Properties; 2.22.4 Stability; 2.22.5 Chemical Reactivity; 2.22.6 Conclusion; 2.23 Final Word | ||
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Datensatz im Suchindex
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| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| spelling | Metallabenzenes an expert view edited by L. James Wright, University of Auckland, New Zealand Hoboken, NJ Wiley 2017 1 Online-Ressource txt rdacontent c rdamedia cr rdacarrier Includes bibliographical references and index Cover; Title Page; Copyright; Contents; List of Contributors; Preface; Chapter 1 Metallabenzenes and Fused-Ring Metallabenzenes of Osmium, Ruthenium and Iridium: Syntheses, Properties and Reactions; 1.1 Introduction; 1.2 Syntheses and Properties of Metallabenzenes with Methylthiolate Substituents; 1.2.1 Osmabenzenes; 1.2.2 Iridabenzenes; 1.3 Syntheses and Properties of Fused-Ring Metallabenzenes; 1.3.1 Osmabenzofurans; 1.3.2 Ruthenabenzofurans; 1.3.3 Iridabenzofurans; 1.3.4 Iridabenzothiophenes; 1.3.5 Iridabenzothiazolium Cations; 1.4 Reactions of Metallabenzenes and Metallabenzenoids 1.4.1 Electrophilic Aromatic Substitution Reactions1.4.2 Rearrangement to Cyclopentadienyl Complexes; 1.4.3 Nucleophilic Aromatic Substitution Reactions; 1.5 Concluding Remarks; References; Chapter 2 The First Iridabenzenes: Syntheses, Properties, and Reactions; 2.1 Introduction; 2.2 Basic Theory; 2.3 Discovery of the First Stable Metallabenzenes; 2.4 Synthesis of Iridabenzene; 2.5 Valence Bond Structures and Electron Counting for Iridabenzene; 2.6 The Tris(trimethylphosphine) Reaction System; 2.7 Structure and Spectroscopy of Iridabenzene 3; 2.8 Chemical Reactivity of Iridabenzene 3 2.8.1 Ligand Substitution2.8.2 Oxidative Addition/Oxidation; 2.8.3 Cycloaddition; 2.8.4 Theoretical Study of Cycloaddition; 2.8.5 Electrophilic Addition; 2.8.6 Coordination to Mo(CO)3; 2.9 Iridaphenol; 2.10 Synthesis and Spectroscopy of Iridapyrylium; 2.11 Valence Bond Structures and Electron Counting for Iridapyrylium; 2.12 Chemical Reactivity of Iridapyrylium 37; 2.12.1 Ligand Addition; 2.12.2 Cycloaddition; 2.13 Comparison of Iridabenzene 3 and Iridapyrylium 37; 2.14 Synthesis and Spectroscopy of Iridathiabenzene; 2.15 Structure of Iridathiabenzene 50 2.16 Chemical Reactivity of Iridathiabenzene 502.16.1 Ligand Addition and Cycloaddition; 2.16.2 Coordination to Other Metals; 2.17 Comparison of Iridathiabenzene 50 and Iridapyrylium 37; 2.18 Synthesis and Structure of a Neutral Iridathiabenzene; 2.19 Spectroscopy of Neutral Iridathiabenzene 56; 2.20 Chemical Reactivity of Neutral Iridathiabenzene 56; 2.21 Related Metal-Coordinated Metallabenzenes; 2.22 Aromaticity; 2.22.1 Electronic Structure; 2.22.2 Structural (Geometric) Features; 2.22.3 Magnetic Properties; 2.22.4 Stability; 2.22.5 Chemical Reactivity; 2.22.6 Conclusion; 2.23 Final Word Aromatic compounds Benzene / Derivatives SCIENCE / Chemistry / Organic 1\p (DE-588)4143413-4 Aufsatzsammlung gnd-content Wright, Leonard James 1954- (DE-588)1142173569 edt Erscheint auch als Druck-Ausgabe 9781119068068 https://onlinelibrary.wiley.com/doi/book/10.1002/9781119068075 Verlag URL des Erstveröffentlichers Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Metallabenzenes an expert view Aromatic compounds Benzene / Derivatives SCIENCE / Chemistry / Organic |
| subject_GND | (DE-588)4143413-4 |
| title | Metallabenzenes an expert view |
| title_auth | Metallabenzenes an expert view |
| title_exact_search | Metallabenzenes an expert view |
| title_full | Metallabenzenes an expert view edited by L. James Wright, University of Auckland, New Zealand |
| title_fullStr | Metallabenzenes an expert view edited by L. James Wright, University of Auckland, New Zealand |
| title_full_unstemmed | Metallabenzenes an expert view edited by L. James Wright, University of Auckland, New Zealand |
| title_short | Metallabenzenes |
| title_sort | metallabenzenes an expert view |
| title_sub | an expert view |
| topic | Aromatic compounds Benzene / Derivatives SCIENCE / Chemistry / Organic |
| topic_facet | Aromatic compounds Benzene / Derivatives SCIENCE / Chemistry / Organic Aufsatzsammlung |
| url | https://onlinelibrary.wiley.com/doi/book/10.1002/9781119068075 |
| work_keys_str_mv | AT wrightleonardjames metallabenzenesanexpertview |