Metal-polymer systems: interface design and chemical bonding
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim, Germany
Wiley-VCH
[2018]
|
| Schlagworte: | |
| Online-Zugang: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-33677-7/ Inhaltsverzeichnis |
| Beschreibung: | xii, 431 Seiten Illustrationen, Diagramme |
| ISBN: | 9783527336777 |
Internformat
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| 100 | 1 | |a Friedrich, Jörg |d 1948- |e Verfasser |0 (DE-588)102223451X |4 aut | |
| 245 | 1 | 0 | |a Metal-polymer systems |b interface design and chemical bonding |c Jörg Friedrich |
| 264 | 1 | |a Weinheim, Germany |b Wiley-VCH |c [2018] | |
| 264 | 4 | |c © 2018 | |
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| 653 | |a Chemie | ||
| 653 | |a Chemistry | ||
| 653 | |a Dünne Schichten, Oberflächen u. Grenzflächen | ||
| 653 | |a Materials Science | ||
| 653 | |a Materialwissenschaften | ||
| 653 | |a Metall-Polymer | ||
| 653 | |a Oberflächen- u. Kolloidchemie | ||
| 653 | |a Polymer Science & Technology | ||
| 653 | |a Polymer Synthesis | ||
| 653 | |a Polymersynthese | ||
| 653 | |a Polymerwissenschaft u. -technologie | ||
| 653 | |a Surface & Colloid Chemistry | ||
| 653 | |a Thin Films, Surfaces & Interfaces | ||
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Datensatz im Suchindex
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| adam_text | CONTENTS
PREFACE XI
1 HIGH-PERFORMANCE METAL-POLYMER COMPOSITES: CHEMICAL
BONDING, ADHESION, AND INTERFACE DESIGN 1
1.1 INTRODUCTION 1
REFERENCES 10
2 INTERPRETATION OF ADHESION PHENOMENA - REVIEW OF
THEORIES 13
2.1 GENERAL 13
2.2 MECHANICAL INTERLOCKING 20
2.2.1 MECHANICAL INTERLOCKING IN A MACROSCOPIC SCALE 20
2.2.2 MECHANICAL ADHESION ON A MICROSCALE 20
2.2.3 MECHANICAL ANCHORING ON A MOLECULAR SCALE 21
2.3 INTERDIFFUSION 23
2.3.1 DIBLOCK COPOLYMERS FOR INTERFACE-CROSSING ADHESION PROMOTION 23
2.3.2 INTERDIFFUSION AND WELDING 23
2.3.3 DIFFUSION OF METALS INTO POLYMERS 25
2.4 INTERPHASE FORMATION 28
2.4.1 POLYMER-POLYMER BLENDS 28
2.4.2 NANOPARTICLE COMPOSITES 29
2.4.3 TRANSCRYSTALLINE LAYERS 29
2.4.4 REDOX REACTIONS ACROSS THE METAL-POLYMER INTERFACE 30
2.4.5 REACTIONS OF TRANSITION METALS WITH AROMATIC POLYMERS 32
2.4.6 LOSS IN ANISOTROPIC ORIENTATION OF POLYMERS CAUSED BY PRETREATMENT
OR BY CONTACT TO METALS 34
2.4.7 WEAK BOUNDARY LAYER 36
2.5 WEAK MOLECULAR INTERACTIONS (COHESIVE FORCES) 38
2.5.1 THERMODYNAMIC ADSORPTION, WETTING MODEL 38
2.5.2 CONTACT ANGLE, SURFACE PROPERTIES, AND ADHESION 39
2.5.3 CONTACT ANGLE MEASUREMENT 40
2.5.4 ADVANCING AND RECEDING CONTACT ANGLES, CONTACT ANGLE
HYSTERESIS 42
2.5.5 REAL SURFACES 43
2.5.6 CRITICAL SURFACE TENSION - ZISMAN PLOT 44
2.5.7 SURFACE TENSION THEORIES 46
2.5.8 POLAR AND DISPERSIVE COMPONENTS OF SURFACE TENSION 47
2.5.9 ACID-BASE INTERACTIONS 48
2.5.10 RHEOLOGICAL MODEL 52
2.5.11 SUMMARY 52
2.6 ELECTROSTATIC ATTRACTION 52
2.7 CONTAMINATIONS, ROLE OF WATER, OR HUMIDITY 54
2.8 COUPLING AGENTS 55
2.9 USE OF GLUES (ADHESIVES) 59
2.10 HYDROPHOBIC RECOVERY 70
REFERENCES 72
3 INTERACTIONS AT INTERFACE 89
3.1 COMPOSITES AND LAMINATES 89
3.2 LAMINATE PROCESSING 90
3.3 POLYMERS AS SUBSTRATE OR AS COATING 92
3.4 CHEMICAL REACTIONS AT SURFACES 92
3.4.1 CHEMISORPTION 92
3.5 REACTIONS OF METAL ATOMS WITH POLYOLEFINS 97
3.6 REACTION OF METAL ATOMS WITH O-FUNCTIONAL GROUPS AT POLYMER
SURFACES 97
3.7 REACTIONS OF METAL ATOMS WITH AMINO GROUPS ON POLYMER
SURFACES 105
3.8 SILANE AND SILOXANE ADHESION-PROMOTING AGENTS 205
REFERENCES 107
4 CHEMICAL BONDS 113
4.1 BONDS IN POLYMERS 113
4.1.1 COVALENT C*H AND C*C BONDS IN POLYMERS 113
4.1.2 C*C DOUBLE, TRIPLE, CONJUGATED, AND AROMATIC BONDS 116
4.1.3 C*O, C=0, O*C=0, AND 0 = C 0 *O BONDS IN POLYMERS 227
4.1.4 N-CONTAINING FUNCTIONAL GROUPS 118
4.1.5 CHEMICAL BONDS IN OTHER MATERIALS 229
4.2 REACTIONS OF CHEMICAL BONDS DURING PRETREATMENT 229
4.2.1 ALIPHATIC CHAINS 229
4.2.2 PREFORMED DEGRADATION PRODUCTS AND PREFERRED REARRANGEMENT
PROCESSES 222
4.3 CHEMICAL BONDS AT INTERFACE 222
4.3.1 POLYMER-POLYMER LINKING 222
4.3.2 CARBON-METAL BONDS 123
4.3.3 COVALENT BONDS BETWEEN OXIDES AND POLYMERS 226
4.3.4 INTERFACE BETWEEN POLYMERS AND TRANSITION METALS 227
REFERENCES 130
5 FUNCTIONAL GROUPS AT POLYMER SURFACE AND THEIR
REACTIONS 135
5.1 OH GROUPS AT SURFACE 135
5.2 PRIMARY AMINO GROUPS AT POLYMER SURFACES 140
5.3 CARBOXYLIC GROUPS AS ANCHOR POINTS FOR GRAFTED MOLECULES 143
5.4 BROMINATION 146
5.5 SILANE BONDS 147
5.6 CLICK CHEMISTRY 148
5.7 ATRP 150
5.8 GRAFTING 152
5.8.1 GRAFTING OF FLUORESCENCE MARKERS ONTO FUNCTIONAL GROUPS AT
POLYOLEFIN SURFACES 153
5.8.2 COVALENT LINKING OF SPACER BONDED DYE SENSORS ONTO POLYOLEFIN
SURFACES 154
5.8.3 COVALENT LINKING OF SPACER BONDED DYE SENSORS ONTO POLYOLEFIN
SURFACES SUPPORTED BY A CUCURBITURIL JACKET 155
5.8.4 GRAFTING OF POLYGLYCEROLS ONTO POLYOLEFIN SURFACES FOR INTRODUCING
ANTIFOULING PROPERTY 156
5.8.5 SUMMARY OF COMPLEX STRUCTURES COVALENTLY GRAFTED ONTO POLYOLEFIN
SURFACES 159
5.9 POLYMERS DEPOSITED ONTO SILICON OR GLASS 162
5.10 MOLECULAR ENTANGLEMENT OF MACROMOLECULES OF COATING AND SUBSTRATE
AT POLYMER SURFACES (INTERPENETRATING NETWORK AT INTERFACE) 162
REFERENCES 165
6 PRETREATMENT OF POLYOLEFIN SURFACES FOR INTRODUCING FUNCTIONAL
GROUPS 173
6.1 SITUATION AT POLYOLEFIN SURFACES 173
62 PHYSICAL AND CHEMICAL ATTACKS OF POLYOLEFIN SURFACES 173
6.3 A FEW GENERAL REMARKS TO THE PRETREATMENT OF POLYOLEFINS 179
6 A INTRODUCTION OF FUNCTIONAL GROUPS TO POLYOLEFIN SURFACES 184
6.5 USUAL PRETREATMENT PROCESSES AND THEIR ADVANTAGES AND
DISADVANTAGES 186
6.5.1 OXYGEN PLASMA EXPOSURE 186
6.5.2 STRUCTURAL DEGRADATION OF POLYMER ON EXPOSURE TO OXYGEN
PLASMA 187
6.5.3 DEGRADATION OF POLYMERS BY EXPOSURE TO OXYGEN PLASMA 192
6.5.4 CROSS-LINKING OF POLYMERS BY PLASMA-EMITTED UV RADIATION 198
6.6 SURFACE OXIDATION BY ATMOSPHERIC-PRESSURE PLASMAS (DIELECTRIC
BARRIER DISCHARGE-DBD, ATMOSPHERIC PRESSURE GLOW DISCHARGE-APGD
OR CORONA DISCHARGE, SPARK JET, ETC.) 201
6.7 FLAME TREATMENT 204
6.8 SILICOATER PROCESS (PYROSIL) 205
6.9 LASER ABLATION 205
6.10 UV IRRADIATION WITH EXCIMER LAMPS 206
6.11 OZONE 211
6.12 MECHANICAL PRETREATMENT 213
6.13 CRYOGENIC BLASTING 214
6.14 SKELETONIZING 2I4
6.15 ROUGHENING FOR MECHANICAL INTERLOCKING AND INCREASING OF SURFACE
AREA BY PLASMA AND SPUTTER ETCHING 215
6.16 SOLVENT CLEANING 215
6.17 SOLVENT WELDING 217
6.18 CHEMICAL TREATMENT BY CHROMIC ACID AND CHROMO-SULFURIC
ACID 218
6.19 CHEMICAL ETCHING AND FUNCTIONALIZING OF FLUORINE-CONTAINING
POLYMERS 220
6.20 OXYFLUORINATION 221
6.21 SULFONATION 222
6.22 SPUTTERING FOR FILM DEPOSITION 223
6.23 CROSS-LINKING AS ADHESION IMPROVING PRETREATMENT (CASING) 225
6.24 MONOSORT FUNCTIONALIZATION AND SELECTIVE CHEMICAL REACTIONS 226
6.24.1 WELL-DEFINED FUNCTIONALIZATION OF POLYMER SURFACES BY CLASSIC
ORGANIC CHEMISTRY 226
6.24.2 SELECTIVE MONOSORT FUNCTIONALIZATION OF POLYMER SURFACES BY
OXYGEN
PLASMA EXPOSURE AND POST-PLASMA CHEMICAL TREATMENT FOR PRODUCING
OH GROUPS 227
REFERENCES 237
7 ADHESION-PROMOTING POLYMER LAYERS 259
7.1 GENERAL 259
7.2 HISTORICAL DEVELOPMENT 261
7.3 INFLUENCE OF PLASMA WATTAGE ON CHEMICAL STRUCTURE OF PLASMA
POLYMERS 263
7.4 PULSED-PLASMA POLYMERIZATION 265
7.5 PRESSURE-PULSED PLASMA 267
7.6 COPOLYMERIZATION IN PULSED PLASMAS 271
7.7 SOME ADDITIONAL DETAILS TO THE MECHANISMS OF PLASMA
POLYMERIZATION 275
7.8 OFTEN-OBSERVED ABNORMAL SIDE REACTIONS OCCURRING IN THE PLASMA
ONLY 278
7.9 STRUCTURE OF PLASMA POLYMERS 281
7.10 USE OF PLASMA POLYMERS AS ADHESION-PROMOTING LAYERS 286
7.11 ADHESION PROMOTION OF VERY THICK LAYERS 289
7.12 SUMMARY 290
REFERENCES 290
8 MONOSORT FUNCTIONAL GROUPS AT POLYMER SURFACES 299
8.1 INTRODUCTION 299
8.2 BROMINATION OF POLYOLEFIN SURFACE BY EXPOSURE TO THE BR2 PLASMA 305
8.3 BROMOFORM AS PRECURSOR 309
8.4 DEPOSITION OF PLASMA POLYMERS CARRYING C*BR GROUPS 312
8.5 LOSS IN BROMINE GROUPS BY WET-CHEMICAL PROCESSING 313
8.6 OTHER HALOGENATIONS 314
8.6.1 CHLORINATION 315
8.6.2 FLUORINATION 317
8.6.3 IODINATION 317
8.6.4 MEASURING THE ELECTRON TEMPERATURE IN HALOFORM PLASMAS 317
8.6.5 COMPARISON OF HALOGENATION PROCESSES 318
8.7 C*BR AS ANCHORING POINT FOR GRAFTING 319
8.7.1 CHANGING THE C*BR FUNCTIONALIZATION INTO NH2
FUNCTIONALIZATION 319
8.7.2 OTHER FUNCTIONAL GROUPS 321
8.7.3 GRAFTING ONTO C*BR GROUPS 322
8.8 UNDERWATER CAPILLARY DISCHARGE PLASMA OR GLOW DISCHARGE
ELECTROLYSIS (GDE) 323
8.9 CONCLUSIONS 323
REFERENCES 332
9
CHEMICAL GRAFTING ONTO MONOSORT FUNCTIONALIZED POLYOLEFIN
SURFACES 337
9.1 GENERAL ASPECTS 337
9.2 GRAFTING OF SPACERS ONTO RADICALS 344
9.3 GRAFTING OF SPACERS AND OLIGOMERS BY REACTION WITH C*-OH GROUPS AT
THE POLYOLEFIN SURFACE 346
9.4 GRAFTING OF LINEAR SPACERS AND OLIGOMERS ONTO C*BR GROUPS 347
9.5 INTRODUCTION OF SPACERS WITH SILOXANE CAGES (POSS) 349
9.6 GRAFTING VIA CLICK REACTION 350
9.7 INFLUENCE OF SPACERS ON THE METAL-POLYMER ADHESION 351
9.8 SUMMARY 352
REFERENCES 353
10 CONCLUSIONS AND OUTLOOK TO THE NEW INTERFACE DESIGN 357
10.1 INTRODUCTION 357
10.2 PHYSICAL EFFECTS PRODUCED BY COVALENT BONDING OF METAL TO
POLYMER 360
10.3 INTRODUCTION OF FUNCTIONAL GROUPS ONTO POLYOLEFIN SURFACES
ASSOCIATED
WITH DAMAGING OF POLYMER STRUCTURE NEAR SURFACE 363
10.4 THERMAL EXPANSION COEFFICIENTS OF METALS AND POLYMERS 365
10.5 DIFFERENCES BETWEEN AL-POLYOLEFIN AND POLYOLEFIN-AL LAMINATES 366
10.6 PROTECTION OF COVALENT METAL-POLYMER BONDS ALONG THE INTERFACE 367
10.7 REACTION PAYS FOR GRAFTING SPACER MOLECULES ONTO POLYOLEFIN
SURFACES 368
10.8 SPECIAL REQUIREMENTS FOR METAL DEPOSITION ESPECIALLY
ALUMINUM 370
10.9 USED WAYS TO INTRODUCE SPACERS FOR MAXIMUM ADHESION 372
10.9.1 SPACER ATTACHMENT ONTO NH2 GROUPS 372
10.9.2 SPACER GRAFTING ONTO OH-GROUPS AT POLYMER SURFACE 375
10.9.3 SPACER ANCHORING ONTO C*BR GROUPS 376
10.9.4 SILANE ATTACHMENT 376
10.9.5 SILANE HYDROLYSIS AND SUBSEQUENT PARTIAL CROSS-LINKING 377
10.9.6 ADHESION STRENGTH MEASUREMENTS 381
10.9.7 SUMMARY AND CONCLUSIONS 383
REFERENCES 388
11 SHORT TREATISE ON ANALYSIS CHEMICAL FEATURES 395
11.1 GENERAL 395
11.2 BULK ANALYSIS 395
11.2.1 INFRARED SPECTROSCOPY 396
11.2.2 UV-VIS SPECTROSCOPY 400
11.2.3 NMR SPECTROSCOPY 401
11.2.4 MALDI- AND ESI-TOF-MS 403
11.2.5 HPLC AND GPC/SEC 405
11.3 SURFACE ANALYSIS 406
11.3.1 SAMPLING DEPTH 406
11.3.2 XPS 408
11.3.3 TOF-SIMS 410
11.3.4 SEIRA AND IRR AS 412
REFERENCES 414
INDEX 415
|
| any_adam_object | 1 |
| author | Friedrich, Jörg 1948- |
| author_GND | (DE-588)102223451X |
| author_facet | Friedrich, Jörg 1948- |
| author_role | aut |
| author_sort | Friedrich, Jörg 1948- |
| author_variant | j f jf |
| building | Verbundindex |
| bvnumber | BV044562617 |
| classification_rvk | UV 9250 VE 8000 ZM 7020 ZM 7026 ZM 7654 |
| ctrlnum | (OCoLC)1010939932 (DE-599)DNB1130800466 |
| dewey-full | 540 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 540 - Chemistry and allied sciences |
| dewey-raw | 540 |
| dewey-search | 540 |
| dewey-sort | 3540 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften / Fertigungstechnik |
| format | Book |
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| id | DE-604.BV044562617 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:55:58Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527336777 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-029961194 |
| oclc_num | 1010939932 |
| open_access_boolean | |
| owner | DE-11 DE-703 DE-92 DE-706 DE-20 DE-384 |
| owner_facet | DE-11 DE-703 DE-92 DE-706 DE-20 DE-384 |
| physical | xii, 431 Seiten Illustrationen, Diagramme |
| publishDate | 2018 |
| publishDateSearch | 2018 |
| publishDateSort | 2018 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Friedrich, Jörg 1948- Verfasser (DE-588)102223451X aut Metal-polymer systems interface design and chemical bonding Jörg Friedrich Weinheim, Germany Wiley-VCH [2018] © 2018 xii, 431 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Metall (DE-588)4038860-8 gnd rswk-swf Verbundwerkstoff (DE-588)4062670-2 gnd rswk-swf Chemie (DE-588)4009816-3 gnd rswk-swf Polymeres Netzwerk (DE-588)4307122-3 gnd rswk-swf Kunststoff (DE-588)4033676-1 gnd rswk-swf Kunststoff-Metall-Verbund (DE-588)4205895-8 gnd rswk-swf Chemie Chemistry Dünne Schichten, Oberflächen u. Grenzflächen Materials Science Materialwissenschaften Metall-Polymer Oberflächen- u. Kolloidchemie Polymer Science & Technology Polymer Synthesis Polymersynthese Polymerwissenschaft u. -technologie Surface & Colloid Chemistry Thin Films, Surfaces & Interfaces Polymeres Netzwerk (DE-588)4307122-3 s Chemie (DE-588)4009816-3 s DE-604 Kunststoff-Metall-Verbund (DE-588)4205895-8 s Kunststoff (DE-588)4033676-1 s Metall (DE-588)4038860-8 s Verbundwerkstoff (DE-588)4062670-2 s Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, ePDF 978-3-527-67992-8 Erscheint auch als Online-Ausgabe, ePub 978-3-527-67991-1 Erscheint auch als Online-Ausgabe, Mobi 978-3-527-67990-4 Erscheint auch als Online-Ausgabe, oBook 978-3-527-67989-8 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-33677-7/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029961194&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Friedrich, Jörg 1948- Metal-polymer systems interface design and chemical bonding Metall (DE-588)4038860-8 gnd Verbundwerkstoff (DE-588)4062670-2 gnd Chemie (DE-588)4009816-3 gnd Polymeres Netzwerk (DE-588)4307122-3 gnd Kunststoff (DE-588)4033676-1 gnd Kunststoff-Metall-Verbund (DE-588)4205895-8 gnd |
| subject_GND | (DE-588)4038860-8 (DE-588)4062670-2 (DE-588)4009816-3 (DE-588)4307122-3 (DE-588)4033676-1 (DE-588)4205895-8 |
| title | Metal-polymer systems interface design and chemical bonding |
| title_auth | Metal-polymer systems interface design and chemical bonding |
| title_exact_search | Metal-polymer systems interface design and chemical bonding |
| title_full | Metal-polymer systems interface design and chemical bonding Jörg Friedrich |
| title_fullStr | Metal-polymer systems interface design and chemical bonding Jörg Friedrich |
| title_full_unstemmed | Metal-polymer systems interface design and chemical bonding Jörg Friedrich |
| title_short | Metal-polymer systems |
| title_sort | metal polymer systems interface design and chemical bonding |
| title_sub | interface design and chemical bonding |
| topic | Metall (DE-588)4038860-8 gnd Verbundwerkstoff (DE-588)4062670-2 gnd Chemie (DE-588)4009816-3 gnd Polymeres Netzwerk (DE-588)4307122-3 gnd Kunststoff (DE-588)4033676-1 gnd Kunststoff-Metall-Verbund (DE-588)4205895-8 gnd |
| topic_facet | Metall Verbundwerkstoff Chemie Polymeres Netzwerk Kunststoff Kunststoff-Metall-Verbund |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-33677-7/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029961194&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT friedrichjorg metalpolymersystemsinterfacedesignandchemicalbonding AT wileyvch metalpolymersystemsinterfacedesignandchemicalbonding |