Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
Singapore
Springer
[2017]
|
| Schriftenreihe: | Springer Theses
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | xxvii, 196 Seiten Illustration |
| ISBN: | 9789811029042 |
| ISSN: | 2190-5053 |
Internformat
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| 100 | 1 | |a Hicks, Jamie |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands |c Jamie Hicks |
| 264 | 1 | |a Singapore |b Springer |c [2017] | |
| 300 | |a xxvii, 196 Seiten |b Illustration | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Springer Theses |x 2190-5053 | |
| 502 | |b Dissertation |c Monash University, Clayton, VIC, Australia | ||
| 650 | 4 | |a Chemistry | |
| 650 | 4 | |a Inorganic chemistry | |
| 650 | 4 | |a Organometallic chemistry | |
| 650 | 4 | |a Catalysis | |
| 650 | 4 | |a Organometallic Chemistry | |
| 650 | 4 | |a Inorganic Chemistry | |
| 650 | 4 | |a Chemie | |
| 650 | 0 | 7 | |a Amide |0 (DE-588)4279702-0 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Ligand |0 (DE-588)4035711-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Übergangsmetallkomplexe |0 (DE-588)4131837-7 |2 gnd |9 rswk-swf |
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| 689 | 0 | 0 | |a Übergangsmetallkomplexe |0 (DE-588)4131837-7 |D s |
| 689 | 0 | 1 | |a Amide |0 (DE-588)4279702-0 |D s |
| 689 | 0 | 2 | |a Ligand |0 (DE-588)4035711-9 |D s |
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| 856 | 4 | 2 | |m Digitalisierung UB Regensburg - ADAM Catalogue Enrichment |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029947655&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |3 Klappentext |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-029947655 | ||
Datensatz im Suchindex
| _version_ | 1804177911430774784 |
|---|---|
| adam_text | Contents
1 General Introduction................................................... 1
1.1 Transition Metals . .·........................................... 1
1.2 Low Oxidation State Transition Metal Complexes................... 2
1.2.1 Bulky Ligands Used into Stabilise Low Oxidation
State Complexes........................................... 2
1.2.2 Preparation of Low Oxidation State Transition
Metal Complexes........................................... 3
1.3 Metal-Metal Bonding in Transition Metal Complexes................ 4
1.3.1 History................................................. 4
1.3.2 Quintuple Bonds......................................... 5
1.4 Magnesium(I) Complexes........................................... 7
1.4.1 Reactivity of P-Diketiminate Stabilised Magnesium(I)
Complexes................................................. 8
1.4.2 Using p-Diketiminate Stabilised Magnesium(I)
Complexes as Reducing Agents in Inorganic Synthesis ... 9
References........................................................... 12
2 Extremely Bulky Amido d-Block Metal(II) Halide Complexes........... 15
2.1 Introduction.................................................... 15
2.1.1 Previously Reported Bulky Amido Transition Metal(II)
Halide Complexes......................................... 16
2.1.2 Previously Reported Bulky Amido Group 12 Metal(II)
Halide Complexes......................................... 18
2.1.3 Terphenyl Stabilised D-Block Metal Halide Complexes ... 20
2.1.4 Extremely Bulky Monodentate Amido Ligands................ 25
2.2 Research Outline................................................ 27
2.3 Results and Discussion....................................... . 28
2.3.1 Preparation of Bulky Potassium Amide Salts............... 28
2.3.2 Bulky Amido First Row Transition Metal(II)
Halide Complexes......................................... 29
2.3.3 Bulky Amido Group 12 Metal(II) Halide Complexes....... 36
xvii
xviii
Contents
2.4 Conclusion
2.5 Experimental................................................
References......(................................................
Preparation of Low Oxidation State Manganese Complexes
Stabilised by Bulky Amide Ligands................................
3.1 Introduction։...............................................
3.1.1 Low Oxidation State Manganese Complexes..............
3.2 Research Outline............................................
3.3 Results and Discussion......................................
3.3.1 Preparation and Characterisation of a Two-Coordinate
Manganese® Dimer with an Unsupported Metal-Metal
Bond.................................................
3.3.2 Preparation and Characterisation of a Two-Coordinate
Manganese(0) Heterobimetallic Complex
with ¡an Unsupported Mn-Mg Bond......................
3.3.3 Reactivity of a Two-Coordinate Manganese(O)
Heterobimetallic Complex.............................
3.4 Conclusion .[...............................................
3.5 Experimental
References. . . .
Preparation of Low Oxidation State Group 12 Metal Complexes
Stabilised by Bulky Amide Ligands.................................
4.1 Introduction!................................................
4.1.1 The First Molecular Compounds Possessing Group 12
Metal-Metal Bonds....................................
4.1.2 Isolation of the First Zinc® Dimer...................
4.1.3 Other Metal-Metal Bonded Zinc® Compounds.............
4.2 Research Outline.................................. . . . ....
4.3 Results and Discussion. . . .................................
4.3.1 Preparation and Characterisation of a Homologous
Series of Group 12 Metal® Dimers..................
4.3.2 Preparation and Characterisation of a Two-Coordinate
Zinc(O) Heterobimetallic Complex
with an Unsupported Zn-Mg Bond.....................
4.3.3 Attempts to Synthesise Two-Coordinate Cadmium(0)
or Mercury(0) Heterobimetallic Complexes
with [Unsupported M-Mg Bonds.........................
4.3.4 Reactivity of a Two-Coordinate Zinc(0) Heterobimetallic
Complex with an Unsupported Zn-Mg Bond...............
4.4 Conclusion J.................................................
4.5 Experimental.................................................
References.......J................................................
43
43
53
55
55
55
62
62
62
66
70
81
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87
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102
103
103
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111
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123
129
X
Contents xix
5 Preparation of Low Oxidation State Cobalt Complexes Stabilised
by a Bulky Amide Ligand............................................ 131
5.1 Introduction.................................................. 131
5.1.1 Low Oxidation State Cobalt Complexes Stabilised
by Bulky Bidentate Monoanionic Ligands........ 131
5.1.2 Low Oxidation State Cobalt Complexes Stabilised
by Bulky Monodentate Monoanionic Ligands............... 140
5.1.3 Other Relevant Low Coordinate, Low Oxidation
State Cobalt Complexes................................. 144
5.2 Research Outline.............................................. 148
5.3 Results and Discussion........................................ 148
5.3.1 Preparation and Characterisation of Two Low
Coordinate Amido Cobalt® Complexes..................... 148
5.3.2 Reactivity of the Two Amido Cobalt® Complexes........ 152
5.4 Conclusion.................................................. 155
5.5 Experimental.................................................. 156
References......................................................... 158
6 Preparation of Molybdenum Aminogermylene
and Aminogermylyne Complexes....................................... 161
6.1 Introduction............................................... . 161
6.1.1 Previously Reported Transition Metal Tetrelyne
Complexes.......................................... 161
6.2 Research Outline.............................................. 171
6.3 Results and Discussion........................................ 172
6.3.1 Preparation of Two Molybdenum Aminogermylene
Complexes.............................................. 172
6.3.2 Preparation of a Molybdenum Aminogermylyne
Complex................................................ 176
6.4 Conclusion.................................................... 180
6.5 Experimental.................................................. 180
References......................................................... 182
7 Appendix............................................................ 185
7.1 General Procedures............................................ 185
7.1.1 X-Ray Crystallography.................................. 185
7.1.2 Magnetic Susceptibility Measurements................... 185
7.1.3 EPR Spectroscopy Studies............................... 192
7.1.4 Computational Studies.................................. 192
7.2 Miscellaneous Data............................................ 193
7.3 Summary of Crystallographic Data.............................. 195
References......................................................... 196
This thesis describes the synthesis and characterization of numerous metal-
metal bonded complexes that are stabilized by extremely bulky amide
ligands. It provides a comprehensive overview of the field, including dis-
cussions on groundbreaking complexes and reactions, before presenting
in detail, exciting new findings from the Ph.D. studies. The thesis appeals
to researchers, professors and chemistry undergraduates with an interest
in inorganic and/or organometallic chemistry.
|
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| author | Hicks, Jamie |
| author_facet | Hicks, Jamie |
| author_role | aut |
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| dewey-full | 547.05 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.05 |
| dewey-search | 547.05 |
| dewey-sort | 3547.05 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| illustrated | Illustrated |
| indexdate | 2024-07-10T07:55:36Z |
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| isbn | 9789811029042 |
| issn | 2190-5053 |
| language | English |
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| spelling | Hicks, Jamie Verfasser aut Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands Jamie Hicks Singapore Springer [2017] xxvii, 196 Seiten Illustration txt rdacontent n rdamedia nc rdacarrier Springer Theses 2190-5053 Dissertation Monash University, Clayton, VIC, Australia Chemistry Inorganic chemistry Organometallic chemistry Catalysis Organometallic Chemistry Inorganic Chemistry Chemie Amide (DE-588)4279702-0 gnd rswk-swf Ligand (DE-588)4035711-9 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Übergangsmetallkomplexe (DE-588)4131837-7 s Amide (DE-588)4279702-0 s Ligand (DE-588)4035711-9 s DE-604 Erscheint auch als Online-Ausgabe 978-981-10-2905-9 Digitalisierung UB Regensburg - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029947655&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Regensburg - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029947655&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Hicks, Jamie Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands Chemistry Inorganic chemistry Organometallic chemistry Catalysis Organometallic Chemistry Inorganic Chemistry Chemie Amide (DE-588)4279702-0 gnd Ligand (DE-588)4035711-9 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4279702-0 (DE-588)4035711-9 (DE-588)4131837-7 (DE-588)4113937-9 |
| title | Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands |
| title_auth | Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands |
| title_exact_search | Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands |
| title_full | Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands Jamie Hicks |
| title_fullStr | Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands Jamie Hicks |
| title_full_unstemmed | Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands Jamie Hicks |
| title_short | Preparation, characterisation and reactivity of low oxidation state d-block metal complexes stabilised by extremely bulky amide ligands |
| title_sort | preparation characterisation and reactivity of low oxidation state d block metal complexes stabilised by extremely bulky amide ligands |
| topic | Chemistry Inorganic chemistry Organometallic chemistry Catalysis Organometallic Chemistry Inorganic Chemistry Chemie Amide (DE-588)4279702-0 gnd Ligand (DE-588)4035711-9 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Chemistry Inorganic chemistry Organometallic chemistry Catalysis Organometallic Chemistry Inorganic Chemistry Chemie Amide Ligand Übergangsmetallkomplexe Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029947655&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029947655&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
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