Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
Aachen
2016
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 128 Seiten Illustrationen 21 cm |
| ISBN: | 9788360391747 8360391742 |
Internformat
MARC
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| 245 | 1 | 0 | |a Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules |c vorgelegt von M. Sc. Roman Krzysztof Pluta |
| 264 | 1 | |a Aachen |c 2016 | |
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| 502 | |b Dissertation |c RWTH Aachen University |d 2016 | ||
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Datensatz im Suchindex
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|---|---|
| adam_text | TABLE
OF
CONTENTS
ABSTRACT
.........................................................................................................................................
1
CHAPTER
1:
INTRODUCTION
................................................................................................................
3
1.1
FLUORINE
...............................................................................................................................
3
1.2
EFFECT
OF
FLUORINE
ATOMS
ON
PHYSICAL
PROPERTIES
OF
ORGANIC
COMPOUNDS
..........................
6
1.2.1
SMALL
FLUORINATED
SUBSTITUENTS
...................................................................................
8
1.3
FLUORINE
IN
PHARMACEUTICALS
AND
AGROCHEMICALS
.............................................................
10
1.3.1
FLUORINE-18
IN
NUCLEAR
MEDICINE
................................................................................
12
CHAPTER
2:
TRIFLUOROMETHYLTHIOLATION
AND
TRIFLUOROMETHYLSELENYLATION
....................................
13
2.1
TRIFLUOROMETHYLTHIOLATION
.................................................................................................
13
2.1.1
HALOGEN
EXCHANGE
.....................................................................................................
14
2.1.2
TRIFLUOROMETHYLATION
OF
THIOLS
...................................................................................
15
2.1.3
DIRECT
NUCLEOPHILIC
TRIFLUOROMETHYLTHIOLATION
..........................................................
15
2.1.4
DIRECT
ELECTROPHILIC
TRIFLUOROMETHYLTHIOLATION
..........................................................
17
2.1.5
RADICAL
TRIFLUOROMETHYLTHIOLATION
.............................................................................
19
2.1.6
ALTERNATIVE
SOURCES
OF
SCF
3
SYNTHON
........................................................................
20
2.1.7
DIRECT
TRIFLUOROMETHYLTHIOLATION
OF
TERMINAL
ALKYNES
...............................................
21
2.1.8
DIRECT
TRIFLUOROMETHYLTHIOLATION
OF
NITROGEN
AND
SULFUR
NUCLEOPHILES
....................
26
2.2
TRIFLUOROMETHYLSELENYLATION
.............................................................................................
33
2.2.1
SYNTHESIS
OF
TRIFLUOROMETHYLSELENYLATED
COMPOUNDS
..............................................
33
2.2.2
TRIFLUOROMETHYLSELENYLATION
OF
BORONIC
ACIDS
AND
TERMINAL
ALKYNES
.......................
35
CHAPTER
3:
ASYMMETRIC
FLUORINATION
..........................................................................................
43
3.1
A-FLUORINATION
OF
CARBONYL
COMPOUNDS
...........................................................................
43
3.2
CATALYSIS
WITH
HYPERVALENT
IODINE
COMPOUNDS
................................................................
45
3.2.1
FLUORINATIONS
WITH
HYPERVALENT
IODINE
REAGENTS
......................................................
47
3.2.2
CATALYST
DEVELOPMENT
FOR
ASYMMETRIC
OXIDATIVE
FLUORINATION
OF
P-KETOESTERS
......
49
CHAPTER
4:
SUMMARY
...................................................................................................................
59
CHAPTER
5:
OUTLOOK
.....................................................................................................................
61
CHAPTER
6:
EXPERIMENTAL
DATA
.....................................................................................................
63
6.1
GENERAL
INFORMATION
..........................................................................................................
63
6.2
TRIFLUOROMETHYLTHIOLATION
.................................................................................................
65
6.2.1
SYNTHESIS
OF
A/-(TRIFLUOROMETHYLTHIO)PHTHALIMIDE
.....................................................
65
6.2.2
TRIFLUOROMETHYLTHIOLATION
OF
TERMINAL
ALKYNES
.........................................................
66
6.2.3
TRIFLUOROMETHYLTHIOLATION
OF
AMINES
.........................................................................
71
6.2.4
TRIFLUOROMETHYLTHIOLATION
OF
THIOLS
...........................................................................
79
6.3
TRIFLUOROMETHYLSELENYLATION
............................................................................................
81
6.3.1
PREPARATION
OF
TETRAMETHYLAMMONIUM
TRIFLUOROMETHANESELENOLATE
....................
81
6.3.2
TRIFLUOROMETHYLSELENYLATION
OF
TERMINAL
ALKYNES
......................................................
81
6.3.3
TRIFLUOROMETHYLSELENYLATION
OF
BORONIC
ACIDS
AND
BORONIC
ESTERS
...........................
87
6.4
ASYMMETRIC
OXIDATIVE
FLUORINATION
OF
P-KETOESTERS
.......................................................
93
6.4.1
SYNTHESIS
OF
CATALYSTS
.................................................................................................
93
6.4.2
ASYMMETRIC
FLUORINATION
OF
P-KETOESTERS
................................................................
104
6.4.3
FUNCTIONALIZATION
OF
A-FLUORO-P-KETOESTERS
.............................................................
112
CHAPTER
7:
LIST
OF
ABBREVIATIONS
................................................................................................
115
CHAPTER
8:
REFERENCES...............................................................................................................
117
|
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| genre_facet | Hochschulschrift |
| id | DE-604.BV044279679 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:48:34Z |
| institution | BVB |
| isbn | 9788360391747 8360391742 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-029684079 |
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| physical | 128 Seiten Illustrationen 21 cm |
| publishDate | 2016 |
| publishDateSearch | 2016 |
| publishDateSort | 2016 |
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| spelling | Pluta, Roman Verfasser (DE-588)1113614293 aut Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules vorgelegt von M. Sc. Roman Krzysztof Pluta Aachen 2016 128 Seiten Illustrationen 21 cm txt rdacontent n rdamedia nc rdacarrier Dissertation RWTH Aachen University 2016 Trifluormethylverbindungen (DE-588)4386003-5 gnd rswk-swf Chalkogenorganische Verbindungen (DE-588)4350852-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Trifluormethylverbindungen (DE-588)4386003-5 s DE-604 Chalkogenorganische Verbindungen (DE-588)4350852-2 s DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029684079&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Pluta, Roman Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules Trifluormethylverbindungen (DE-588)4386003-5 gnd Chalkogenorganische Verbindungen (DE-588)4350852-2 gnd |
| subject_GND | (DE-588)4386003-5 (DE-588)4350852-2 (DE-588)4113937-9 |
| title | Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules |
| title_auth | Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules |
| title_exact_search | Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules |
| title_full | Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules vorgelegt von M. Sc. Roman Krzysztof Pluta |
| title_fullStr | Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules vorgelegt von M. Sc. Roman Krzysztof Pluta |
| title_full_unstemmed | Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules vorgelegt von M. Sc. Roman Krzysztof Pluta |
| title_short | Development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules |
| title_sort | development of new synthetic methods for trifluormethylchalcogenation and fluorination of organic molecules |
| topic | Trifluormethylverbindungen (DE-588)4386003-5 gnd Chalkogenorganische Verbindungen (DE-588)4350852-2 gnd |
| topic_facet | Trifluormethylverbindungen Chalkogenorganische Verbindungen Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029684079&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT plutaroman developmentofnewsyntheticmethodsfortrifluormethylchalcogenationandfluorinationoforganicmolecules |