Crystal chemistry: from basics to tools for materials creation
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| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New Jersey ; London ; Singapore ; Beijing ; Shanghai ; Hong Kong ; Taipei ; Chennai ; Tokyo
World Scientific
[2017]
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | Literaturangaben Seite 243-244 |
| Beschreibung: | xiv, 248 Seiten Illustrationen, Diagramme, Portrait (farbig) |
| ISBN: | 9789813144194 9789813144187 |
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| 245 | 1 | 0 | |a Crystal chemistry |b from basics to tools for materials creation |c Gérard Férey |
| 264 | 1 | |a New Jersey ; London ; Singapore ; Beijing ; Shanghai ; Hong Kong ; Taipei ; Chennai ; Tokyo |b World Scientific |c [2017] | |
| 264 | 4 | |c © 2017 | |
| 300 | |a xiv, 248 Seiten |b Illustrationen, Diagramme, Portrait (farbig) | ||
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Datensatz im Suchindex
| _version_ | 1804177445025218560 |
|---|---|
| adam_text | Contents
il
Preface vii
Historical Introduction 1
Chapter 1 A First Familiarization with Geometric Shapes:
The Dense Packings 5
1.1 The Archimedian Polyhedra 5
1.2 From Polygons to Polyhedra for Some Chemistry 10
1.3 From Qualitative to Quantitative. Some Definitions 18
1.4 Simple Calculations on Dense Packings of Spheres 22
1.4.1 Primitive cubic packing 22
1.4.2 The centered cubic packing 23
1.4.3 The face centered cubic packing 24
1.4.4 The hexagonal packing 26
1.5. Some Remarks 27
1.5.1 Parameters influencing the dimension of the particles 27
1.5.2 Non-ideal dense packings 27
1.5.3 Real solid versus ideal solid 29
1.5.4 Movements of particles 29
1.5.5 The chemical importance of the interstice concept 30
Chapter 2 Some Notions of Symmetry 35
2.1 The Direct Axial Symmetries 36
2.2 The Inverse Axial Symmetries 38
2.3 The Symmetries at the Atomic Scale 42
2.4 The Miller Indices 47
Chapter 3 The Projections Their Reading, Their Uses... 49
3.1 The Steps of the Examination 49
3.1.1 The drawing 49
xii Crystal Chemistry — From Basics to Tools for Materials Creation
3.1.2 Calculations of distances and coordinations 51
3.1.3 Connections of polyhedra 54
3.1.4 Dense packings and complex structures 55
3.2 The Principal Structure Types (Wyckoff, 1968) 57
3.2.1 The M2X type (MZX = 2) 57
3.2.1.1 Li20 (Fig. 3.7) 57
3.2.1.2 Cu20 (Fig. 3.8) 58
3.2.2 The MX type (M/X = 1) 58
3.2.2.1 NiAs (Fig. 3.9) 58
3.2.2.2 Wurtzite: The hexagonal variety of ZnS
(Fig. 3.10) 59
3.2.2.3 Blende: The cubic variety of ZnS (Fig. 3.11) 60
3.2.3 The M2X3 type (M/X = 0.66) 61
3.2.3.1 a-Al203 form (corundum) (Fig. 3.12) 61
3.2.3.2 (Fig. 3.13) 62
3.2.4 The MX2 type (M/X = 0.50) 64
3.2.5 The M3X4, A2MX4 and AM2X4 types
(0.75 M/X 0.25 if A it M) 65
3.2.5.1 MgAl204 (Fig. 3.15) 65
3.2.5.2 LuFe204 (Fig. 3.19) 69
3.2.5.3 K2NiF4 (Fig. 3.20) 70
3.2.6 The MX3 type (M/X = 0.33) 71
3.2.6.1 Re03 (Fig. 3.21) 71
3.2.6.2 MX3 hexagonal framework (Fig. 3.23) 74
3.2.6.3 The MX3 pyrochlore type with a cubic
framework (Fig. 3.24) 75
3.2.6.4 Mo03 (Fig. 3.26) 78
3.2.6.5 YBa2Cu307, the guest and its variants 79
3.3 The Concept of Vacancy; Its Limits with the Existence
of Lone Pairs 82
3.4 Polyhedra, Connectivity and Formulation 85
3.5 True Coordination and the Bond Valence Method 91
Chapter 4 Some Disorder within Order! Tiltings, Vacancies and Supercells 95
4.1 Deformations of Polyhedra 96
4.2 Tilting of Polyhedra and Glazer’s Notation 98
4.3 Cationic Ordering and Supercells 106
4.4 Vacancies, Extented Defects and Non-Stoichiometry 109
4.4.1 The extended defects 110
4.4.2 Ordered extended defects; examples 115
Contents xiii
Chapter 5 Armatures, Gilders and Bricks!... Other Ways of Reading
a Structure 121
5.1 Nets 122
5.1.1 Flexible nets 124
5.1.2 Decorated nets 126
5.2 Rod Descriptions of Structures (O’Keeffe, 1992) 129
5.3 Building Units and Descriptions of Structures (Ferey, 2000) 132
5.4 The “Spin” Descriptions of Structures 138
Chapter 6 The Structural Relations ... Their Deciphering 141
6.1 Structural Relations between the Polymorphs of a Solid 141
6.1.1 Mechanisms of anionic glidings 141
6.1.2 Mechanisms involving rotation of blocks 145
6.2 Structural Relations between Solids
with Different Formula 148
6.2.1 Cationic ordering in perovskites 148
6.2.1.1 Double perovskites with a 1:1 order
on site M 149
6.2.1.2 Double perovskites with a 1:2 order
on site M 151
6.2.1.3 Double perovskites with a 1:3 order
on site M 151
6.2.1.4 Perovskites and cationic ordering
on the A sites 152
6.2.1.5 Ordered complex perovskites (orders
on both A and M sites) 152
6.2.2 Cationic ordering in spinels MM 204 153
6.2.3 Ordering between ions and vacancies 154
6.3 The Inverse Structures 158
6.4 Interconnection of Different Building Blocks 159
6.5 A [A .MX, .] Structural Recurrences in Oxides
(Raveau et al., 1991) 163
6.5.1 The Aurivillius phases 163
6.5.2. The Dion-Jacobson phases 165
6.5.3 The Ruddlesden-Popper phases 166
6.5.4 The structural recurrence in cuprates
(Raveau et al., 1991) 166
6.6 Structural Recurrence in Hexagonal Perovskites 174
6.7 Other Mechanisms of Intergrowth 177
6.8 Structural Evolutions Under Pressure 180
xiv Crystal Chemistry — From Basics to Tools for Materials Creation
Chapter 7 Crystal Chemistry? A Tool for Creation... or...
The New Architects of Matter 185
7.1 The Scale Up Concept: (Ferey, 2000) 186
7.1.1 Filling the topological polyhedron 190
7.1.2 The hybrid building blocks 191
7.1.3 The anionic substitution in the inorganic bricks 193
7.1.4 Decoration of polyhedra and construction
of the inorganic brick 195
7.2 The Concepts of Connectivity and Augmented Nets 199
7.3 From Concepts to Materials: The Different Steps 203
7.3.1 The inorganic building blocks 204
7.3.2 The pores and their occupation 204
7.3.2.1 General considerations 204
7.3.2.2 Applications 206
7.3.3 From the solid to the multi-material 208
Epilogue 211
Appendix 1 The Geometrical Characteristics of Platonic
and Archimedian Polyhedra 213
Appendix 2 The Exponential Scale, or the Mathematical Nature
of Polyhedra 239
Bibliography 243
Index 245
■CRYSTAL
CHEMISTRY
From Basics to Tools for Materials Creation
Devoted to a diverse group of solid state scientists, the book has two
objectives, both relating to structural chemistry: (i) a progressive analytic
familiarization with the main parameters that govern the organization of
crystallized matter and related crystal structures, (ii) a study of what are the
various ways to read a structure far beyond its representation in scientific
articles. Hence, the reader will, from numerous examples illustrated
in color, analyze what are the main characteristics of these structures,
from their geometric characteristics, their coordination polyhedra, their ;
connections with the resulting dimensionalities of these solids, including
also the defects they exhibit, before looking at possibilities to classify
structures, within which recurrence laws can emerge.
Chemists are required to understand the potentials of a new structure
for becoming future materials scientists. The first part of the book is by
no means a database for known structures, but facilitates a progressive
understanding of the organization of the solid state. With these tools in
hand, the reader is invited in the later part of the book to analyze new
structures, and to also use new concepts for viewing structures in a more
synthetic way for the future. Such new vision is already leading to the
creation of completely new solids with outstanding characteristics that
find applications in societal problems concerning energy, energy savings,
environment and health.
The content is not exclusively academic but relates to the creation of
innovative materials, through a more physical approach, that might
condition the future of materials.
The colorful images in the book are provided separately as supplementary
material and can be accessed at http://www.worldscientific.com/
worldscibooks/10.1142/10144
World Scientific
www.worldscientific.com
10144 he
ISBN 978-981-3144-18-7 ^
V
9 789813 1
44187
|
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| dewey-ones | 548 - Crystallography |
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| discipline | Chemie / Pharmazie Physik Chemie |
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| spelling | Férey, Gérard 1941- (DE-588)1128920743 aut Crystal chemistry from basics to tools for materials creation Gérard Férey New Jersey ; London ; Singapore ; Beijing ; Shanghai ; Hong Kong ; Taipei ; Chennai ; Tokyo World Scientific [2017] © 2017 xiv, 248 Seiten Illustrationen, Diagramme, Portrait (farbig) txt rdacontent n rdamedia nc rdacarrier Literaturangaben Seite 243-244 Crystallography Solid state chemistry Kristallchemie (DE-588)4165759-7 gnd rswk-swf Kristallchemie (DE-588)4165759-7 s DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029670038&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029670038&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Férey, Gérard 1941- Crystal chemistry from basics to tools for materials creation Crystallography Solid state chemistry Kristallchemie (DE-588)4165759-7 gnd |
| subject_GND | (DE-588)4165759-7 |
| title | Crystal chemistry from basics to tools for materials creation |
| title_auth | Crystal chemistry from basics to tools for materials creation |
| title_exact_search | Crystal chemistry from basics to tools for materials creation |
| title_full | Crystal chemistry from basics to tools for materials creation Gérard Férey |
| title_fullStr | Crystal chemistry from basics to tools for materials creation Gérard Férey |
| title_full_unstemmed | Crystal chemistry from basics to tools for materials creation Gérard Férey |
| title_short | Crystal chemistry |
| title_sort | crystal chemistry from basics to tools for materials creation |
| title_sub | from basics to tools for materials creation |
| topic | Crystallography Solid state chemistry Kristallchemie (DE-588)4165759-7 gnd |
| topic_facet | Crystallography Solid state chemistry Kristallchemie |
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